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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRS2020

Determination of Autogenous Ignition Temperature for Isopropyl Alcohol and Ethanol

As part of a recent liquid rocket engine shutdown investigation, a commercial partner requested that NASA provide the autogenous ignition (or autoignition) temperature (AIT) of isopropyl alcohol (IPA). NASA provided the available data, but the data were somewhat scattered, likely due to test configuration and test technique differences. NASA Engineering and Safety Center (NESC) support was requested to experimentally determine the AIT of IPA and ethanol, both of which are extensively applied to propulsion systems. This report contains the outcome of the NESC assessment.

Autoignition Temperature; Isopropyl Alcohol; Comme↗
NASA NTRS2004

Deployment of a Fast-GCMS System to Measure C2 to C5 Carbonyls, Methanol and Ethanol Aboard Aircraft

Through funding of this proposal, a fast response gas chromatograph/mass spectrometer (FGCMS) instrument to measure less than or equal to C4 carbonyl compounds and methanol was developed for the NASA GTE TRACE-P (Global Tropospheric Experiment, Transport And Chemical Evolution Over The Pacific) mission. The system consists of four major components: sample inlet, preconcentration system, gas chromatograph (GC), and detector. The preconcentration system is a custom-built cryogen-conservative system. The GC is a compact, custom-built unit that can be temperature programmed and rapidly cooled. Detection is accomplished with an Agilent Technologies 5973 mass spectrometer. The FGCMS instrument provides positive identification because the compounds are chromatographically separated and mass selected. During TRACE-P, a sample was analyzed every 5 minutes. The FGCMS limit of detection was between 5 and 75 pptv, depending on the compound. The entire instrument package is contained in a standard NASA instrument rack (106 cm x 61 cm x 135 cm), consumes less than 1200 watts and is fully automated with LabViEW 6i. Methods were developed or producing highly accurate gas phase standards for the target compounds and for testing the system in the presence of potential interferents. This report presents data on these tests and on the general overall performance of the system in the laboratory and aboard the DC-8 aircraft during the mission. Vertical profiles for acetaldehyde, methanol, acetone, propanal, methyl ethyl ketone, and butanal from FGCMS data collected over the entire mission are also presented.

Apel, Eric C.↗
NASA NTRS2008

Assessing blood brain barrier dynamics or identifying or measuring selected substances, including ethanol or toxins, in a subject by analyzing Raman spectrum signals

A non-invasive method for analyzing the blood-brain barrier includes obtaining a Raman spectrum of a selected portion of the eye and monitoring the Raman spectrum to ascertain a change to the dynamics of the blood brain barrier.Also, non-invasive methods for determining the brain or blood level of an analyte of interest, such as glucose, drugs, alcohol, poisons, and the like, comprises: generating an excitation laser beam at a selected wavelength (e.g., at a wavelength of about 400 to 900 nanometers); focusing the excitation laser beam into the anterior chamber of an eye of the subject so that aqueous humor, vitreous humor, or one or more conjunctiva vessels in the eye is illuminated; detecting (preferably confocally detecting) a Raman spectrum from the illuminated portion of the eye; and then determining the blood level or brain level (intracranial or cerebral spinal fluid level) of an analyte of interest for the subject from the Raman spectrum. In certain embodiments, the detecting step may be followed by the step of subtracting a confounding fluorescence spectrum from the Raman spectrum to produce a difference spectrum; and determining the blood level and/or brain level of the analyte of interest for the subject from that difference spectrum, preferably using linear or nonlinear multivariate analysis such as partial least squares analysis. Apparatus for carrying out the foregoing methods are also disclosed.

Lambert, James L.↗
NASA NTRS1995

FTIR instrumentation to monitor vapors from Shuttle tile waterproofing materials

The Space Shuttle Thermal Protection System (TPS) tiles and blankets are waterproofed using DimethylEthoxySilane (DMEX) in the Orbiter Processing Facilities (OPF). DMES has a Threshold Limit Value (TLV) for exposure of personnel to vapor concentration in air of 0.5 ppm. The OPF high bay cannot be opened for normal work after a waterproofing operation until the DMES concentration is verified by measurement to be below the TLV. On several occasions the high bay has been kept closed for up to 8 hours following waterproofing operations due to high DMES measurements. In addition, the Miran 203 and Miran 1 BX infrared analyzers calibrated at different wavelengths gave different readings under the same conditions. There was reason to believe that some of the high DMES concentration readings were caused by interference form water and ethanol vapors. The Toxic Vapor Detection Laboratory (TVDL) was asked to test the existing DMES instruments and identify the best qualified instrument. In addition the TVDL was requested to develop instrumentation to ensure the OPF high bay could be opened safely as soon as possible after a waterproofing operation. A Fourier Transform Infrared (FTIR) spectrophotometer instrument developed for an earlier project was reprogrammed to measure DMES vapor along with ethanol, water, and several common solvent vapors. The FTIR was then used to perform a series of laboratory and field tests to evaluate the performance of the single wavelength IR instruments in use. The results demonstrated that the single wavelength IR instruments did respond to ethanol and water vapors, more or less depending on the analytical IR wavelength selected. The FTIR was able to separate the responses to DMES, water and ethanol, and give consistent readings for the DMES vapor concentration. The FTIR was then deployed to the OPF to monitor real waterproofing operations. The FTIR was also used to measure the time for DMES to evaporate from TPS tile under a range of humidity conditions in controlled laboratory tests. The combination of laboratory and field tests with the FTIR instrument demonstrated superior sensitivity, ability to reject interference from water and ethanol vapors, ruggedness to be transported from the lab to the OPF and set up without special procedures or degradation of performance. The multiple component vapor analysis algorithm was developed at KSC and incorporates automatic baseline correction and shape fitting of the spectra. The analysis for DMES, TetraMethylDiSiloxane (TMDS), ethanol, methanol, isopropanol, and baseline parameters uses 161 points per sample at 4 cm(exp -1) resolution, and processes an eight scan sample every ten seconds. The standard deviation of the measurements is 0.013 ppm and the upper linear limit is 125 ppm DMES. Based on successful demonstration of capabilities we produced three mobile instrument carts to be used in each OPF to support future waterproofing operations. The design and building of the 'DMES Carts' were accomplished in Fiscal year 1995.

Mattson, C. B.↗
NASA NTRS1999

Non-Toxic Reaction Control System for the Reusable First Stage Vehicle

This paper presents the Boeing Reusable Space Systems vision of a Reaction Control System (RCS) for the Reusable First Stage (RFS) being considered as a replacement for the Solid Rocket Booster for the Space Shuttle. The requirement is to,achieve reliable vehicle control during the upper atmospheric portion of the RFS trajectory while enabling more efficient ground operations, unhindered by constraints caused by operating with highly toxic RCS propellants. Boeing's objective for this effort is to develop a safer, more efficient and environmentally friendly RCS design approach that is suitable for the RFS concept of operations, including a low cost, efficient turnaround cycle. The Boeing RCS concept utilizes ethanol and liquid oxygen in place of the highly toxic, suspected carcinogen, ozone- depleting mono-methyl-hydrazine and highly toxic nitrogen tetroxide. The Space Shuttle Upgrade program, under the leadership of the NASA Johnson Space Flight Center, is currently developing liquid oxygen and ethanol (ethyl alcohol) technology for use as non-toxic orbital maneuvering system (OMS) and RCS. The development of this liquid oxygen and ethanol technology for the Space Shuffle offers a significant leverage to select much of the same technology for the RFS program. There are significant design and development issues involved with bringing this liquid oxygen and ethanol technology to a state of maturity suitable for an operational RCS, The risks associated with a new LOX and Ethanol RCS are mitigated by maintaining kerosene and hydrogen peroxide RCS technology as an alternative. These issues, presented within this paper, include managing the oxygen supply and achieving reliable ignition in the short pulse mode of engine operation. Performance, reliability and operations requirements are presented along with a specific RCS design concept to satisfying these requirements. The work reported in this paper was performed under NASA Marshall Space Flight Center Contract to define Reusable First Stage design concepts for the Space Shuttle.

Keith, E. L.↗
NASA NTRS1999

Non-Toxic Reaction Control System for the Reusable First Stage Vehicle

This paper presents the Boeing Reusable Space Systems vision of a Reaction Control System (RCS) for the Reusable First Stage (RFS) being considered as a replacement for the Solid Rocket Booster for the Space Shuttle. The requirement is to achieve reliable vehicle control during the upper atmospheric portion of the RFS trajectory while enabling more efficient ground operations, unhindered by constraints caused by operating with highly toxic RCS propellants. Boeing's objective for this effort is to develop a safer, more efficient and environmentally friendly RCS design approach that is suitable for the RFS concept of operations, including a low cost, efficient turnaround cycle. The Boeing RCS concept utilizes ethanol and liquid oxygen in place of the highly toxic, suspected carcinogen, ozone-depleting mono-methyl-hydrazine and highly toxic nitrogen tetroxide. The Space Shuttle Upgrade program, under the leadership of the NASA Johnson Space Flight Center, is currently developing liquid oxygen and ethanol (ethyl alcohol) technology for use as non-toxic orbital maneuvering system (OMS) and RCS. The development of this liquid oxygen and ethanol technology for the Space Shuttle offers a significant leverage to select much of the same technology for the RFS program. There are significant design and development issues involved with bringing this liquid oxygen and ethanol technology to a state of maturity suitable for an operational RCS. The risks associated with a new LOX and Ethanol RCS are mitigated by maintaining kerosene and hydrogen peroxide RCS technology as an alternative. These issues, presented within this paper, include managing the oxygen supply and achieving reliable ignition in the short pulse mode of engine operation. Performance, reliability and operations requirements are presented along with a specific RCS design concept to satisfying these requirements. The work reported in this paper was performed under NASA Marshall Space Flight Center Contract Number NAS8-97272 to define Reusable First Stage design concepts for the Space Shuttle.

Keith, E. L.↗
NASA NTRS2001

Effects of Potassium Permanganate Oxidation on Subsurface Microbial Activity

In situ chemical oxidation has the potential for degrading large quantities of organic contaminants and can be more effective and timely than traditional ex situ treatment methods. However, there is a need to better characterize the potential effects of this treatment on natural processes. This study focuses on potential inhibition to anaerobic dechlorination of trichloroethene (TCE) in soils from a large manufacturing facility as a result of in situ oxidation using potassium permanganate (KMn04)Previous microcosm studies established that natural attenuation occurs on-site and that it is enhanced by the addition of ethanol to the system. A potential remediation scheme for the site involves the use of potassium permanganate to reduce levels of TCE in heavily contaminated areas, then to inject ethanol into the system to "neutralize" excess oxidant and enhance microbial degradation. However, it is currently unknown whether the exposure of indigenous microbial populations to potassium permanganate may adversely affect biological reductive dechlorination by these microorganisms. Consequently, additional microcosm studies were conducted to evaluate this remediation scheme and assess the effect of potassium permanganate addition on biological reductive dechlorination of TCE. Samples of subsurface soil and groundwater were collected from a TCE-impacted area of the site. A portion of the soil was pretreated with nutrients and ethanol to stimulate microbial activity, while the remainder of the soil was left unamended. Soil/groundwater microcosms were prepared in sealed vials using the nutrient-amended and unamended soils, and the effects of potassium permanganate addition were evaluated using two permanganate concentrations (0.8 and 2.4 percent) and two contact times (1 and 3 weeks). TCE was then re-added to each microcosm and TCE and dichloroethene (DCE) concentrations were monitored to determine the degree to which microbial dechlorination occurred following chemical oxidation. Evidence of microbial degradation was generally detected within four weeks after TCE addition. Increases in DCE concentrations were consistent with decreases in TCE. The concentration of TCE in the nutrient-amended samples exposed to 2.4% KMnO4 for one week degraded somewhat more slowly than the samples exposed to the 0.8% KMnO4. The rates of degradation did not correlate with the length of KMn04 exposure for the nutrient-amended microcosms. Microbial degradation of TCE in the unamended microcosms was generally similar to that observed in the nutrient-amended microcosms. One treatment condition (unamended, one week exposure, 2.4% KMnO4) was exposed to elevated levels of ethanol and showed little evidence of degradation. It is suspected that the high levels of ethanol were toxic to the microorganisms. The results of the study indicate that exposure of indigenous soil and groundwater microbial populations to KMnO4 at concentrations of 0.8 to 2.4% do not impair the ability of the microbial populations to dechlorinate TCE. Consequently, the combination of chemical oxidation followed by enhanced biological reductive dechlorination appears to be a viable remedial strategy for highly-impacted subsurface areas of the site.

Rowland, Martin A.↗
NASA NTRS2006

Interaction of Ethyl Alcohol Vapor with Sulfuric Acid Solutions

We investigated the uptake of ethyl alcohol (ethanol) vapor by sulfuric acid solutions over the range approx.40 to approx.80 wt % H2SO4 and temperatures of 193-273 K. Laboratory studies used a fast flow-tube reactor coupled to an electron-impact ionization mass spectrometer for detection of ethanol and reaction products. The uptake coefficients ((gamma)) were measured and found to vary from 0.019 to 0.072, depending upon the acid composition and temperature. At concentrations greater than approx.70 wt % and in dilute solutions colder than 220 K, the values approached approx.0.07. We also determined the effective solubility constant of ethanol in approx.40 wt % H2SO4 in the temperature range 203-223 K. The potential implications to the budget of ethanol in the global troposphere are briefly discussed.

sulfate aerosols↗
NASA NTRS1972

Fuel droplet burning rates at high pressures

Combustion of methanol, ethanol, propanol -1, n - pentane, n - heptane and n - decane was observed in air under natural convection conditions at pressures up to 100 atm. The droplets were simulated by porous spheres with diameters in the range 0.63 - 1.90 cm. The pressure levels of the tests were high enough so that near critical combustion was observed for methanol and ethanol. Measurements were made of the burning rate and liquid surface temperatures of the fuels. The data were compared with variable property analysis of the combustion process, including a correction for natural convection. The burning rate predictions of the various theories were similar and in fair agreement with the data. The high pressure theory gave the best prediction for the liquid surface temperatures of ethanol and propanol -1 at high pressure. The experiments indicated the approach of critical burning conditions for methanol and ethanol at pressures on the order of 80 - 100 atm, which was in good agreement with the predictions of both the low and high pressure analysis.

Canada, G. S.↗
NASA NTRS1973

Fuel droplet burning rates at high pressures.

Combustion of methanol, ethanol, propanol-1, n-pentane, n-heptane, and n-decane was observed in air under natural convection conditions, at pressures up to 100 atm. The droplets were simulated by porous spheres, with diameters in the range from 0.63 to 1.90 cm. The pressure levels of the tests were high enough so that near-critical combustion was observed for methanol and ethanol. Due to the high pressures, the phase-equilibrium models of the analysis included both the conventional low-pressure approach as well as high-pressure versions, allowing for real gas effects and the solubility of combustion-product gases in the liquid phase. The burning-rate predictions of the various theories were similar, and in fair agreement with the data. The high-pressure theory gave the best prediction for the liquid-surface temperatures of ethanol and propanol-1 at high pressure. The experiments indicated the approach of critical burning conditions for methanol and ethanol at pressures on the order of 80 to 100 atm, which was in good agreement with the predictions of both the low- and high-pressure analysis.

Canada, G. S.↗
NASA NTRS1995

Interstellar Alcohols

We have investigated the gas-phase chemistry in dense cores where ice mantles containing ethanol and other alcohols have been evaporated. Model calculations show that methanol, ethanol, propanol, and butanol drive a chemistry leading to the formation of several large ethers and esters. Of these molecules, methyl ethyl ether (CH3OC2H5) and diethyl ether (C2H5)2O attain the highest abundances and should be present in detectable quantities within cores rich in ethanol and methanol. Gas-phase reactions act to destroy evaporated ethanol and a low observed abundance of gas-phase C,H,OH does not rule out a high solid-phase abundance. Grain surface formation mechanisms and other possible gas-phase reactions driven by alcohols are discussed, as are observing strategies for the detection of these large interstellar molecules.

Charnley, S. B.↗
NASA NTRS1997

Gauche Ethyl Alcohol: Laboratory Assignments and Interstellar Identification

Ethyl alcohol (ethanol) is known to possess a pair of closely spaced excited torsional substates (gauche+, gauche-) at an energy of approximately 57 K above the ground (trans) torsional substate. We report an extended analysis of some gauche - gauche+ Q-branch ((Delta)J = 0) transitions with a three-substate fixed frame axis method (FFAM) Hamiltonian. Our approach accounts for complex trans-gauche interactions for the first time. In addition, we are able to obtain intensities for perturbed rotational transitions, and to determine the trans to gauche+ separation to be 1185399.1 MHz. A complete ground state rotational-torsional partition function accounting for the previously neglected gauche substates is presented. Based on our analysis, a total of 14 U lines obtained towards Orion KL can now be assigned to gauche substates of ethanol. Analysis of these lines yields a rotational temperature of 223 K and a total (trans + gauche) column density of 7.0 x 10(exp 15)/sq cm. The column density is in reasonable agreement with the recent value of 2-3 x 10(exp 15)/sq cm based on observations of trans-ethanol by Ohishi et al., although there is some disparity in the rotational temperatures. Eight additional U lines in the literature are assigned to transitions of gauche ethanol.

Pearson, J. C.↗