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At least 55 records · Page 3

Long-term aging of elastomers: Chemical stress relaxation of fluorosilicone rubber and other studies

Aerospace applications of elastomers are considered, including: propellant binders, bladder materials for liquid propellant expulsion systems, and fuel tank sealants for high-speed aircraft. A comprehensive molecular theory for mechanical properties of these materials has been developed but has only been tested experimentally in cases where chemical degradation processes are excluded. Hence, a study is being conducted to ascertain the nature, extent, and rate of chemical changes that take place in some elastomers of interest. Chemical changes that may take place in the fluorosilicone elastomer, LS 420, which is regarded as a fuel and high-temperature-resistant rubber are investigated. The kinetic analysis of the chemical stress relaxation and gel permeation chromatography studies comprise the major portion of the report.

Kalfayan, S. H.

Development of procedures for calculating stiffness and damping properties of elastomers. Part 3: The effects of temperature, dissipation level and geometry

Effects of temperature, dissipation level and geometry on the dynamic behavior of elastomer elements were investigated. Force displacement relationships in elastomer elements and the effects of frequency, geometry and temperature upon these relationships are reviewed. Based on this review, methods of reducing stiffness and damping data for shear and compression test elements to material properties (storage and loss moduli) and empirical geometric factors are developed and tested using previously generated experimental data. A prediction method which accounts for large amplitudes of deformation is developed on the assumption that their effect is to increase temperature through the elastomers, thereby modifying the local material properties. Various simple methods of predicting the radial stiffness of ring cartridge elements are developed and compared. Material properties were determined from the shear specimen tests as a function of frequency and temperature. Using these material properties, numerical predictions of stiffness and damping for cartridge and compression specimens were made and compared with corresponding measurements at different temperatures, with encouraging results.

Smalley, A. J.

Chemiluminescence Study on Thermal Degradation of Aircraft Tire Elastomers

Since the autoxidative process accounts in part for the degradation of rubber, including aircraft tires, it was felt that a study of the chemiluminescence from unsaturated elastomers could contribute significantly to an understanding of the degradation mechanism. The study revealed similarities in chemiluminescence behavior between four elastomers which were investigated, and it shows that similar oxidation mechanisms occur. Oxidative chemiluminescence was observed from purified samples of cis-1,4-polybutadiene, cis-1,4-polyisoprene, trans-polypentenamer, and 1,2-polybutadiene in an oxygen atmosphere at 25-150 C. The elastomer samples were placed in a 600 watt oven which is equipped with gas inlets for introducing any desired atmosphere. Chemiluminescence emission from the samples was focused with a two inch quartz lens onto the detector of a 12" photomultiplier which is connected to a photon counter. A strip-chart recorder, connected to the counter, permitted automatic data collection. Diagrams of the apparatus are included. The chemical reactions which occurred from the thermal decomposition of the polymer samples are described, and results (and tabulated data) are discussed.

Mendenhall, G. D.

Perfluroether triazine elastomers

In order to obtain high performance elastomers with the high thermal stability and chemical inertness of perfluoroalkylene triazine and a low glass transition temperature, perfluoroether triazine elastomers were synthesized. The procedure for elastomer synthesis is described as well as general experimental methods. Results are presented and discussed. The screening of catalysts for the dehydration of perfluoroether diamide is also considered.

Korus, R. A.

Development of procedures for calculating stiffness and damping of elastomers in engineering applications, part 7

An elastomer shear damper was designed, tested, and compared with the performance of the T 55 power turbine supported on the production engine roller bearing support. The Viton 70 shear damper was designed so that the elastomer damper could be interchanged with the production T 55 power turbine roller bearing support. The results show that the elastomer sheer dampener permitted stable operation of the power turbine to the maximum operating speed of 16,000 rpm.

Rieger, A.

The effects of strain and temperature on the dynamic properties of elastomers

This paper presents the results of a program of analysis and tests to determine the dynamic properties of elastomers as a function of strain and ambient temperature. Measurements were also made to determine the temperature distribution in the elastomer samples during the tests. These measured properties were compared with analytical predictions based on a visco-elastic model designed to take into account the self-heating of the materials as a function of strain. The test method used was well-established Base Excitation Resonant Mass Technique. The specimens tested were two cylindrical button compression specimens and a shear specimen. Strain was shown to be an important parameter in determining the dynamic properties of the elastomers. In general, these properties were much more sensitive to strain than to frequency. The self-heating effect was found to account for a portion of the strain sensitivity of these properties.

Darlow, M. S.

Design of elastomer dampers for a high-speed flexible rotor

This paper describes the methods used to design elastomerically damped supports for high-speed, flexible rotor-bearing systems. The procedure consists of using a damped natural frequency analysis to identify stiffness and damping requirements for the supports over the speed range. Optimum values for these coefficients are found and unbalance response analysis is used to calculate expected rotor behavior. Equations for calculating the shear and compressive stiffness and damping of button-type elastomer mounts are given, as is a procedure for their application to the design of the elastomeric mounts. These techniques were successfully applied to the design of damped elastomeric supports for a high-speed rotor, which traverses two bending critical speeds. Results of the testing showed that the rotor was well behaved and showed linear response to unbalance. Measured modal damping exceeded expectations and tests were conducted with both high- and low-loss elastomers, enabling the exploration of the practical range of elastomer damping capability.

Tecza, J. A.

Synthesis of perfluoroalkylether oxadiazole elastomers

A method for the simultaneous chain extension and crosslinking of perfluoroalkylethers which yields a thermally stable perfluoroalkylether oxadiazole elastomer crosslinked by trifunctional perfluoroalkylether-1,3,5-triazine is reported. In the preparation, hydroxylamine crystals prepared from hydroxylamine hydrochloride to which sodium butoxide had been added is mixed with perfluoroalkylether dinitrile to obtain the monomer, as the nitrile is converted to amidoxime. Monomers are heated at 140 to 200 C to form poly(perfluoroalkylether oxadiazole) with a 1,2,4-oxadiazole structure by a step-growth polymerization reaction. Simultaneous chain extension and crosslinking are observed to occur when the purified monomer is heated directly and when the remaining nitrile in the monomer is allowed to react with excess ammonia to form the corresponding amidine, which is then heated. Weight loss studies show the thermal stability of the perfluoroalkylether elastomer to be generally better than fluorosilicone or polyester elastomers, especially in air, indicating its potential usefulness for high-performance elastomeric applications.

Rosser, R. W.

Synthesis of perfluoroalkylether triazine elastomers

A method of perfluoroalkylether triazine elastomer synthesis is described. To form an elastomer, the resultant polymer is heated in a closed oven at slightly reduced pressures for 1-day periods at 100, 130 and 150 C. A high-molecular-weight perfluoroalkylether triazine elastomer is produced that exhibits thermal and oxidative stability. This material is potentially useful in applications such as high-temperature seals, 'O' rings, and wire enamels.

Rosser, R. W.

The Effect of Cross-Link Density on the Toughening Mechanism of Elastomer-Modified Epoxies

A DGEBA epoxide resin (EPON 828) was elastomer modified by using three different carboxyl terminated butadiene acrylonitrile copolymers. The fracture toughness of these elastomer modified epoxies was measured in terms of the critical strain energy release rate, G sub IC. The toughening mechanism was elucidated using a tensile dilatometry technique. A plot of volume strain versus longitudinal strain often reveals the types of micromechanical deformations occurring in the uniaxial tensile specimen up to yield. Several microscopy techniques were employed to corroborate the tensile dilatometry results. The role of matrix ductility on the toughening mechanism of elastomer modified epoxies was investigated. By reducing the cross link density with various equivalent weight epoxide resins. Fracture toughness was again measured in terms of G sub IC. The characterization of the toughening mechanism was performed using a uniaxial tensile dilatometry technique and corroborated using various microscopy techniques.

Pearson, R. A.

Long-time dynamic compatibility of two ethylene propylene elastomers with hydrazine

A test method is described for predicting the long-time survivability of elastomers in hydrazine under dynamic stressing conditions. The method selected is based upon the existence and approximate invariance of a 'physical property surface' relating the mechanical response of the elastomer in terms of stress, strain, time, and temperature. The property surface was generated for two selected elastomers (EPT-10 and AF-E-332). A novel carousel testing tank was designed to allow sequential testing of eight tensile specimens immersed in liquid hydrazine within a constant-temperature water bath. The test procedure and data reduction methods used to generate the property surface are described. The utility and validity of these results applied to fatigue and flexure loading to these elastomeric materials over long-time periods are discussed.

Coulbert, C. D.

Elastomers Compatible With High-Pressure Oxygen

Compatibility increased by fluorination. Report describes experiments aimed at improving compatibility of some fluorinated elastomers with high-pressure oxygen. Such elastomers needed for seals, gaskets, and positive-expulsion devices used with high-pressure oxygen. Oxygen - compatibility tests carried out on five elastomers chosen on the basis of literature survey.

Martin, Jon W.

Bonding Elastomers To Metal Substrates

Improved, economical method for bonding elastomers to metals prevents failures caused by debonding. In new technique, vulcanization and curing occur simultaneously in specially designed mold that acts as form for desired shape of elastomer and as container that positions and supports metal parts. Increases interface adhesion between metal, adhesive, and elastomer.

Dickerson, George E.

Model For Bending Actuators That Use Electrostrictive Graft Elastomers

Recently, it was reported that an electrostrictive graft elastomer exhibits large electric field-induced strain (4%). Combined with its high mechanical modulus, the elastomer can offer very promising electromechanical properties, in terms of output mechanical energy density, for an electroactive polymeric material. Therefore, it has been considered as one of the candidates that can be used in high performance, low mass actuation devices in many aerospace applications. Various bilayer- based bending actuators have been designed and fabricated. An analytic model based on beam theory in the strength of materials has been derived for the transverse deflection, or curvature, and the longitudinal strain of the bi-layer beam. The curvature and strain are functions of the applied voltage and the thickness, width, and Young s modulus of the active and passive layers. The model can be used to optimize the performance of electrostrictive graft elastomer-based actuators to meet the requirements of various applications. In this presentation, optimization and sensitivity studies are applied to the bending performance of such actuators.

Costen, Robert C.

Asymmetric Dielectric Elastomer Composite Material

Embodiments of the invention provide a dielectric elastomer composite material comprising a plurality of elastomer-coated electrodes arranged in an assembly. Embodiments of the invention provide improved force output over prior DEs by producing thinner spacing between electrode surfaces. This is accomplished by coating electrodes directly with uncured elastomer in liquid form and then assembling a finished component (which may be termed an actuator) from coated electrode components.

Stewart, Brian K.

Evaluation of a Conductive Elastomer Seal for Spacecraft

An electrically conductive elastomer was evaluated as a material candidate for a spacecraft seal. The elastomer used electrically conductive constituents as a means to reduce the resistance between mating interfaces of a sealed joint to meet spacecraft electrical bonding requirements. The compound's outgassing levels were compared against published NASA requirements. The compound was formed into a hollow O-ring seal and its compression set was measured. The O-ring seal was placed into an interface and the electrical resistance and leak rate were quantified. The amount of force required to fully compress the test article in the sealing interface and the force needed to separate the joint were also measured. The outgassing and resistance measurements were below the maximum allowable levels. The room temperature compression set and leak rates were fairly high when compared against other typical spacecraft seal materials, but were not excessive. The compression and adhesion forces were desirably low. Overall, the performance of the elastomer compound was sufficient to be considered for future spacecraft seal applications.

Daniels, Christopher C.

A chain stretch-based gradient-enhanced model for damage and fracture in elastomers

Similar to quasi-brittle materials, it has been recently shown that elastomers can exhibit a macroscopically diffuse damage zone that accompanies the fracture process. In this study, we introduce a stretch-based gradient-enhanced damage (GED) model that allows the fracture to localize and also captures the development of a physically diffuse damage zone. This capability contrasts with the paradigm of the phase field method for fracture, where a sharp crack is numerically approximated in a diffuse manner. Capturing fracture localization and diffuse damage in our approach is achieved by considering nonlocal effects that encompass network topology, heterogeneity, and imperfections. These considerations motivate the use of a statistical damage function dependent upon the nonlocal deformation state. From this model, fracture toughness is realized as an output. While GED models have been classically utilized for damage modeling of structural engineering materials (e.g., concrete), they face challenges when trying to capture the cascade from damage to fracture, often leading to damage zone broadening (de Borst and Verhoosel, 2016). This deficiency contributed to the popularity of the phase-field method over the GED model for elastomers and other quasi-brittle materials. Other groups have proceeded with damage-based GED formulations that prove identical to the phase-field method (Lorentz et al., 2012), but these inherit the aforementioned limitations. To address this issue in a thermodynamically consistent framework, we implement two modeling features (a nonlocal driving force bound and a simple relaxation function) specifically designed to capture the evolution of a physically meaningful damage field and the simultaneous localization of fracture, thereby overcoming a longstanding obstacle in the development of these nonlocal strain- or stretch-based approaches. Here, we discuss several numerical examples to understand the features of the approach at the limit of incompressibility, and compare them to the phase-field method as a benchmark for the macroscopic response and fracture energy predictions.

Elastomers

Thermoplastic Elastomers and Their Physical Gels Electrospun into Tunable Microfibrous Nonwoven Mats: Structure Formation and Property Enhancement

Abstract Thermoplastic elastomers (TPEs) based on styrenic block copolymers constitute excellent examples of self‐networking macromolecules that are employed in a wide range of contemporary technologies as molded parts. In such applications, these TPEs exist as dense (nonporous) films or other shapes. Here, it is first demonstrated that a series of commercial TPEs possessing comparable compositions can be electrospun from solution to form microfibers that are arranged into nonwoven mats that are breathable. An important consideration for microfiber formation is the copolymer molecular weight, which regulates i) the viscosity of the parent solution prior to electrospinning, ii) the ability of these copolymers to self‐assemble during electrospinning, iii) the microfiber morphology, and iv) the mechanical properties of the resultant microfibers. The addition of a midblock‐selective aliphatic oil to these TPEs yields thermoplastic elastomer gels (TPEGs), wherein the copolymer morphology and mechanical properties become highly composition‐tunable. Electrospinning TPEGs from a binary oil+solvent solution introduces a micelle inversion mechanism that begins with an oil‐rich micellar core and ends with a styrene‐rich micellar core, required for network stabilization, as the solvent dries during microfiber solidification. This work has implications for the production of controllably low‐modulus microfibrous materials possessing modestly improved toughness but exceptional extensibility and enhanced optical transparency.

Shamsi, Mohammad