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At least 55 records · Page 3

The origin of chondrules - Experimental investigation of metastable liquids in the system Mg2SiO4-SiO2

Laser-melted magnesium silicate droplets were supercooled 400-750 C below their equilibrium liquidus temperatures before crystallization and their texture was compared with that of meteoritic and lunar chondrules. Crystal morphology, width and texture were studied in relation to nucleation temperature and bulk composition. It was found that the only phase to nucleate from the forsterite-enstatite normative melts was forsterite. Highly siliceous glass, about 65% SiO2 by weight, was identified interstitially to the forsterite crystals in seven of the MgSiO4 spherules and was thought to be present in all.

Blander, M.↗

Vapor Growth of Alloy-Type Semiconductor Crystals

The present effort is part of a continuing research program directed towards the investigation of basic vapor transport phenomena and of crystal growth properties of electronic materials. The primary purpose of ground-based studies is the development and definition of optimum experimental parameters for flight experiments. The ground-based effort includes the investigation of gravity-driven convection effects on mass transport rates and on crystal morphology for different orientations of the density gradient with respect to the gravity vector, and as a function of pressure and of temperature. In addition to the experimental tasks, theoretical efforts involve the quantitative thermodynamic analysis of the systems under investigation, the computation of fluid dynamic parameters, and the consideration of other possible effects on fluid flow under vertical, stabilizing and microgravity conditions. The specific experiments to be performed in a microgravity environment include the investigation of vapor transport and crystal growth phenomena of the GeSe-Xenon system and of the mass flux and growth of bulk and layer-type crystals of Hg sub (1-x) Cd sub x Te using HgI as a transport agent.

Wiedemeier, H.↗

Simulation of triglycine sulfate crystal growth in space

Consideration is given to the numerical simulation of the solution growth of triglycine sulfate in space, with heat transfer, mass transfer, buoyancy-driven convection, the dependence of solubility on temperature, and finite interface kinetics taken into account. In the bulk solution, weak thermal convection was established quickly. The thermal convection then becomes dominated by solutionally driven motion. The convection due to the steady background g is predicted to influence both the growth rate and the crystal morphology. The time required for buoyancy-driven convection to influence the growth rate depends on the magnitude of g, i.e., more time for smaller g. Under the same cooling condition, the average growth rate increases as the magnitude of g increases. A steady average growth rate of 1.0 mm/d can be obtained when a properly designed cooling rate is applied to the sting. The most uniform growth is obtained when the g vector is aligned such that the solution flows normal towards the center of the crystal surface.

Sun, Jianhua↗

The Isothermal Dendritic Growth Experiment (IDGE): USMP-4 One-Year-Report

Dendrites describe the tree-like crystal morphology commonly assumed in many material systems--particularly in metals and alloys that freeze from supercooled or supersaturated melts. There remains a high level of engineering interest in dendritic solidification because of the role of dendrites in the determination of cast alloy microstructures. Microstructure plays a key role in determining the physical properties of cast or welded products. In addition, dendritic solidification provides an example of non-equilibrium physics and is one of the simplest non-trivial examples of dynamic pattern formation, where an amorphous melt, under simple starting conditions, evolves into a complex ramified microstructure. Although it is well-known that dendritic growth is controlled by the transport of latent heat from the moving solid-melt interface as the dendrite advances into a supercooled melt, an accurate, and predictive model has not been developed. Current theories consider: 1) the transfer of heat or solute from the solid-liquid interface into the melt, and 2) the interfacial crystal growth and growth selection physics for the interface. However, the effects of gravity-induced convection on the transfer of heat from the interface prevent either element from being adequately tested solely under terrestrial conditions. The Isothermal Dendritic Growth Experiment (IDGE) constituted a series of three NASA-supported microgravity experiments, all of which flew aboard the space shuttle, Columbia. This experimental space flight series was designed and operated to grow and record dendrite solidification in the absence of gravity-induced convective heat transfer, and thereby produce a wealth of benchmark-quality data for testing solidification scaling laws. The data collection from the on-orbit phase of the IDGE flight series is now complete. We are currently completing analyses and moving towards final data archiving.

Glicksman, M. E.↗

Laser-zone growth in a Ribbon-To-Ribbon, RTR, process silicon sheet growth development for the large area silicon sheet task of the low cost silicon solar array project

A ribbon-to-ribbon process was used for routine growth of samples for analysis and fabrication into solar cells. One lot of solar cells was completely evaluated: ribbon solar cell efficiencies averaged 9.23% with a highest efficiency of 11.7%. Spherical reflectors have demonstrated significant improvements in laser silicon coupling efficiencies. Material analyses were performed including silicon photovoltage and open circuit photovoltage diffusion length measurements, crystal morphology studies, modulus of rupture measurements, and annealing/gettering studies. An initial economic analysis was performed indicating that ribbon-to-ribbon add-on costs of $.10/watt might be expected in the early 1980's.

Gurtler, R. W.↗

Growth of single crystals by vapor transport

The primary objectives of the program were to establish basic vapor transport and crystal growth properties and to determine thermodynamic, kinetic and structural parameters relevant to chemical vapor transport systems for different classes of materials. An important aspect of these studies was the observation of the effects of gravity-caused convection on the mass transport rate and crystal morphology. These objectives were accomplished through extensive vapor transport, thermochemical and structural studies on selected Mn-chalcogenides, II-VI and IV-VI compounds.

Wiedemeier, H.↗

Experimental investigation of the effects of gravity on thermosolutal convection and compositional homogeneity in Bridgman grown, compound semiconductors

Lead-tin-telluride has been grown in a thermally stable mode (solutally unstable) and in a solutally stable (thermally unstable) mode in a Bridgman configuration. Significant differences in the crystal morphology and the compositional homogeneity have been found between the two configurations. In addition, for the solutally stable configuration, evidence has been found that the flow characteristics in the melt change drastically during the course of the run.

Crouch, R. K.↗

Crystal Growth Research in Space

The objectives of this work are to develop growth techniques and theory leading to improved bulk growth of semiconductor single crystals. Ground based experiments will be complemented by experiments carried out in the low-g environment provided by the space shuttle. Analytical studies and laboratory investigations are being conducted to better define the causes of crystalline defects and inhomogeneities. The compound semiconductor lead-tin-telluride is being used as the modeling material. Theoretical techniques are being developed to predict the thermal and solutal fields which are present during bulk growth from a melt. Techniques for measuring the thermophysical properties of semiconductors at high temperatures have been developed. During the past year electrochemical etching techniques have been developed for delineation of inhomogeneous regions in crystals. Thermal diffusivity measurements have been completed for the solid and liquid phases of PbTe and PbSnTe. Preliminary results have been obtained on the effects on crystal morphology of gravity, interface shape and interaction between the melt and the container.

Crouch, R. K.↗

Photoelectrochemical fabrication of spectroscopic diffraction gratings

Photoelectrochemical etching was demonstrated as a means of fabricating a variety of periodic structures in semiconductors. The semiconductor is used as an electrode in an electrochemical cell, and is in contact with a liquid electrolyte. When the crystal is held at a positive voltage and illuminated, etching occurs in only the illuminated regions to a depth proportional to the illumination intensity and exposure time. In Phase 1, it was determined that diffraction gratings could be produced in gallium arsenide crystals by this method, using either a scanned focused laser beam or by uniform illumination of a ruling mask defined in metal or photoresist on the crystal surface. The latter approach was determined to produce V-grooves if the mask is oriented along certain crystallographic directions. These V-grooves were produced with an exceedingly smooth crystal morphology due to the highly controllable nature of the process and the mild electrolytes involved. The results form the basis for photoelectrochemical fabrication of deep, low pitch Eschelle gratings for use in high orders in NASA spectrographic instrumentation such as the Space Telescope Imaging Spectrograph.

Rauh, R. David↗

Protein crystal growth in low gravity

The mechanisms involved in protein crystallization and those parameters which influence the growth process and crystalline perfection were studied. The analysis of the flows around growing crystals is detailed. The preliminary study of the growth of isocitrate lyase and the crystal morphologies found are discussed. Preliminary results of controlled nucleation studies are presented.

Feigelson, Robert S.↗

InAsSbBi, a direct band-gap, III-V, LWIR material

In the last several years Dr. Stringfellow's group at the University of Utah has reported success in incorporating over 3 percent Bi in InAs and 1.5 percent in InAsSb using Organometallic Vapor Phase Epitaxy (OMVPE) growth techniques. For InAs the lattice constant increase is linear with a=6.058+0.966x (InAs(1-x)Bi(x)), and a decrease in band gap energy of dEg / dx = -55meV / at a percentage Bi. Extrapolating this to the ternary minimum band gap at InAs(0.35)Sb(0.65), an addition of 1 to 2 percent Bi should drop the band gap to the 0.1 to 0.05eV range (10 to 20 microns). These alloys are direct band gap semiconductors making them candidates for far IR detectors. The current status of the InAsSbBi alloys is that good crystal morphology and x ray diffraction data has been obtained for up to 3.4 percent Bi. The Bi is metastable at these concentrations but the OMVPE grown material has been able to withstand the 400 C growth temperature for several hours without phase separation.

Stringfellow, G. B.↗

Crystal Growth Furnace - An overview of the system configuration and planned experiments on the first United States Microgravity Laboratory mission

Attention is given to the Crystal Growth Furnace (CGF) currently in the Level IV integration cycle at the Kennedy Space Center in preparation for its maiden flight on the first United States Microgravity Laboratory (USML-1) mission to be launched in May 1992. CGF was developed for NASA under the Microgravity Science and Application division programs at NASA Headquarters. An overview of the CGF system and the system configuration for the USML-1 mission are presented, and the planned on-orbit experiments are described. The four important scientific experiments selected from industry and educational institutions for the CGF USML-1 mission will enable a better understanding of the complex phenomena inherent in materials processing that will lead to the ultimate improvement of both processes and materials. Crystal growth by chemical vapor transport has resulted in improved growth conditions with crystal morphology, lower defect densities, and higher growth rates than terrestrially observed.

Srinivas, R.↗

Space flight data from the isothermal dendritic growth experiment

The Isothermal Dendritic Growth Experiment (IDGE) is a NASA space flight experiment which flew as part of the United States Microgravity Payload (USMP-2), in early 1994. The IDGE measured dendritic growth rates, tip radii, and crystal morphologies of ultra-pure succinonitrile (CN-(CH2)2-CN) at supercoolings in the range from 0.05 - 2.0 K. Data taken in the form of slow-scan binary digitized images telemetered to the ground from orbit in near-real time, combined with the IDGE terrestrial data set, provide the first quantitative assessment of various theories on dendritic solidification and the effects of convection on dendritic growth.

Glicksman, M. E.↗

On the Lower Limit of Chondrule Cooling Rates: The Significance of Iron Loss in Dynamic Crystallization Experiments

It is unlikely that the presence of chondrules, and thus their formation, within the protoplanetary nebula would be predicted if it were not for their ubiquitous presence in most chondritic meteorites. The study of these enigmatic, igneous objects has a direct influence on how meteoritic and solar system researchers model the processes operating and the materials present within our protoplanetary nebula. Key to understanding chondrule formation is a determination of constraints on their thermal histories. The three important variables in this history are their peak melting temperatures, the duration of their melting at peak temperatures, and the rate at which these object cool. Although these three variables are interdependent, it is cooling rate that provides the most powerful constraint. Cooling rate has a direct affect on the development of both crystal morphology and the elemental distributions within these grains. To date, experiments have indicated that chondrule cooling rates are in the range of 10's to 100's of degrees per hour for porphyritic chondrules (the most abundant type). The cooling rate for radial and barred chondrules is thought to be more rapid. To generate these cooling rates (rapid relative to the cooling of the nebula as a whole, but slow compared to simple black body radiation) the environment of chondrule formation must have been localized, and the abundance of solid materials must have been greatly enhanced above a gas of solar composition. Thus accurate determinations of chondrule cooling rates is critical in understanding both their formation and the nebular environment in which they formed. In a quest to more accurately determine the lower limit on cooling rates and to determine in more detail the effects of Fe loss from a molten sample to Pt wire loops, Weinbruch et al. have explored this issue experimentally and reevaluated the findings of Radomsky and Hewins in light of their new results. The basic conclusions of their paper are an important contribution to our understanding of how experimental techniques can affect established constraints on chondrule formation and are thus of interest to a wide audience. We do believe, however, that their methodology produces results that provide inappropriate impressions of the applicability of their study to chondrule formation and nebular processes. Furthermore, the extensive body of previous experimental work on chondrule bulk compositions cannot be invalidated, as they suggest, by the results of Weinbruch et al. It is for these reasons that within this comment we address to applicability of the results presented by Weinbruch et al. to previous studies, and illustrate how the experimental conditions chosen for their series of experiments introduced a significant bias in their results.

Paque, Julie M.↗

Characterization of the Effects of Precursor Mineralogy on Hematite Spectra: Application to Martian Hematite Mineralization

The Thermal Emission Spectrometer (TES) instrument aboard Mars Global Surveyor discovered several isolated deposits of gray, crystalline hematite in Sinus Meridiani, Aram Chaos, and Valles Marineris. A variety of formation mechanisms has been proposed for the martian hematite deposits, including aqueous and nonaqueous processes. Comparison of the average Sinus Meridiani hematite spectrum measured by TES to laboratory emissivity spectra for a variety of naturally occurring hematites shows small but potentially important differences. In particular, the emissivity minimum at 300 and 445/cm in the Sinus Meridiani (SM) spectrum is displaced 10-25/cm to lower frequencies compared to some natural hematite samples. In addition, these bands in the TES data are narrower than the broad bands seen in many natural hematite spectra. These differences may imply that the natural variability of hematite spectra has not been fully characterized, especially with respect to the reaction pathway (precursor mineralogy and temperature of hematite formation) and crystal morphology. Here, we describe the thermal infrared spectral characteristics of several series of synthetic hematite samples derived by direct precipitation, dehydroxylation of fine-grained goethite and the oxidation of magnetite. Several natural hematite sample spectra are also presented for comparison. Transmission electron microscopy (TEM) and Mossbauer spectral analyses of selected samples were performed in order to help determine the causes of the changes seen in the infrared spectra.

Glotch, Timothy D.↗

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

The objective of the project is to determine the relative contributions of gravity-driven fluid flows to the compositional distribution, incorporation of impurities and defects, and deviation from stoichiometry observed in the crystals grown by vapor transport as results of buoyancy-driven convection and growth interface fluctuations caused by irregular fluid-flows. ZnSe and related ternary compounds, such as ZnSeS and ZnSeTe, were grown by vapor transport technique with real time in situ non-invasive monitoring techniques. The grown crystals were characterized extensively to correlate the grown crystal properties with the growth conditions. Significant effects of gravity vector orientation on the growth crystal morphology and point defect distribution were observed.

Source record↗

Third and Final Shuttle Mission of the Isothermal Dendritic Growth Experiment Conducted: Highest Supercooling Ever Recorded Achieved

Dendrites describe the treelike crystal morphology commonly assumed in metals and alloys that freeze from supercooled or supersaturated melts. There remains a high level of engineering interest in dendritic solidification because the size, shape, and orientation of the dendrites determine the final microstructure of a material. It is the microstructure that then determines the physical properties of cast or welded products. Although it is well known that dendritic growth is controlled by the transport of latent heat from the moving solid-liquid interface, an accurate and predictive model has not yet been developed. The effects of gravity-induced convection on the transfer of heat from the interface have prevented adequate testing, under terrestrial conditions, of solidification models. The Isothermal Dendritic Growth Experiment (IDGE) constituted a series of three microgravity experiments flown aboard the Space Shuttle Columbia. The apparatus was used to grow and record dendrite solidification in the absence of gravity-induced convective heat transfer, thereby producing a wealth of benchmark-quality data for testing solidification models and theories.

Glicksman, Martin E.↗

Calcium Sulfate in Atacama Desert Basalt: A Possible Analog for Bright Material in Adirondack Basalt, Gusev Crater

The Atacama Desert in northern Chile is one of the driest deserts on Earth (< 2mm/y). The hyper-arid conditions allow extraordinary accumulations of sulfates, chlorides, and nitrates in Atacama soils. Examining salt accumulations in the Atacama may assist understanding salt accumulations on Mars. Recent work examining sulfate soils on basalt parent material observed white material in the interior vesicles of surface basalt. This is strikingly similar to the bright-white material present in veins and vesicles of the Adirondack basalt rocks at Gusev Crater which are presumed to consist of S, Cl, and/or Br. The abundance of soil gypsum/anhydrite in the area of the Atacama basalt suggested that the white material consisted of calcium sulfate (Ca-SO4) which was later confirmed by SEM/EDS analysis. This work examines the Ca-SO4 of Atacama basalt in an effort to provide insight into the possible nature of the bright material in the Adirondack basalt of Gusev Crater. The objectives of this work are to (i) discuss variations in Ca-SO4 crystal morphology in the vesicles and (ii) examine the Ca-SO4 interaction(s) with the basalt interior.

Sutter, B.↗