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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Effects of regolith/megaregolith insulation on the cooling histories of differentiated asteroids

The cooling histories of differentiated asteroids are calculated employing a variety of thermal-conductivity structures to simulate the potential insulating effects of regolith and megaregolith layers on the cooling rate. It was found that a combination of relatively thick megaregolith and regolith can potentially reduce the core cooling rate by more than a factor of 10 below the rate predicted by models with conventional thermal conductivity structure. Thus, differences in cratering (regolith production) histories may have resulted in radically different cooling rates for asteroids of similar radius, or in similar cooling rates from asteroids of different radius.

Haack, Henning↗

The deep lunar electrical conductivity profile - Structural and thermal inferences

Simultaneous lunar surface and orbital magnetometer records are reexamined, to ascertain intervals which may be suitable for measuring lunar inductive response in the solar wind and terrestrial magnetosheath. Power spectral estimates of the response tangent to the lunar surface, defined in terms of transfer and gain functions, are obtained for the 0.0001-0.01 Hz frequency range. The maximum consistency of estimates from different time intervals is found when the initial analysis is limited to the tangential direction of maximum incident power, or that direction in which the ratio of signal to background noise is greatest. Spherically symmetric plasma confinement theory is used in the interpretation of transfer function data, by way of forward model calculations, under the assumption of continuous electrical conductivity increase with depth. Results are presented for internal electrical conductivity profile, metallic core radius, and selenotherm limits.

Hood, L. L.↗

The Relationship between Ionic Conductivity and Solvation Structures of Localized High-Concentration Fluorinated Electrolytes for Lithium-Ion Batteries

Localized high concentration electrolyte (LHCE) combines a diluent with high concentration electrolyte (HCE), offering promising properties. The ions, solvent, and diluent interact to form a complex heterogenous liquid structure, where high salt concentration clusters are embedded in diluent. Optimizing LHCE for desired electrolyte properties like high ionic conductivity, low viscosity, effective solid electrolyte interphase (SEI) formability, within the vast chemical and compositional design space requires deeper understanding and theoretical guidance. For this work, we investigated the structures and conductivity of LHCEs based on a fluorinated solvent with two different diluents at varying concentrations. The 2,2,3,3-tetrafluoropropyl trifluoroacetate (TFPTFA) enters the solvation cluster due to its stronger Li-ion interactions, whereas 1,1,2,2-tetrafuoroethyl 2,2,2-trifuoroethyl ether (TFETFE) enters only at extremely high diluent concentrations. The ionic conductivity increases with decreasing diluent concentrations, with a slope change during cluster percolation. Overall, TFETFE demonstrates higher effectiveness than TFPTFA, forming higher local salt concentration clusters, and resulting in higher ionic conductivity.

cluster chemistry↗

Expanded capabilities of the CarMa code in modeling resistive wall mode dynamics with 3-D conductors

In this work, an improved version of the CarMa code is presented, called CarMa-D, for the analysis of resistive wall modes (RWMs) in fusion devices, simultaneously considering the effects of volumetric three-dimensional conducting structures, plasma dynamics, toroidal rotation or drift-kinetic damping. Unlike static CarMa, CarMa-D does not rely on the simplifying assumptions such as neglecting the plasma mass, toroidal rotation and kinetic damping. The new coupling strategy is based on matrix-based Padé rational functions approximation of plasma a response. The arising mathematical model is formally equivalent to the original CarMa model, but with a higher number of degrees of freedom to model the dynamics of the plasma. CarMa-D overcomes the main limitations of the original CarMa, in particular: (i) the massless assumption for the plasma is removed, allowing modeling of global modes growing both on ideal kink time scales and in the typical RWM growth rate regime, with a suitable treatment of the model; (ii) the effects of toroidal plasma flow and drift kinetic damping can be included into the new model, providing a powerful tool to study macroscopic phenomena where both plasma dynamics and 3-D conducting structures play important roles.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Molecular Dynamics Simulation of the Antiamoebin Ion Channel: Linking Structure and Conductance

Molecular dynamics simulations were carried out in order to ascertain which of the potential multimeric forms of the transmembrane peptaibol channel, antiamoebin, is consistant with its measured conductance. Estimates of the conductance obtained through counting ions that cross the channel and by solving the Nernst-Planck equation yield consistent results, indicating that the motion of ions inside the channel can be satisfactorily described as diffusive.The calculated conductance of octameric channels is markedly higher than the conductance measured in single channel recordings, whereas the tetramer appears to be non-conducting. The conductance of the hexamer was estimated to be 115+/-34 pS and 74+/-20 pS, at 150 mV and 75 mV, respectively, in satisfactory agreement with the value of 90 pS measured at 75 mV. On this basis we propose that the antiamoebin channel consists of six monomers. Its pore is large enough to accommodate K(+) and Cl(-) with their first solvation shells intact. The free energy barrier encountered by K(+) is only 2.2 kcal/mol whereas Cl(-) encounters a substantially higher barrier of nearly 5 kcal/mol. This difference makes the channel selective for cations. Ion crossing events are shown to be uncorrelated and follow Poisson statistics. keywords: ion channels, peptaibols, channel conductance, molecular dynamics

Wilson, Michael A.↗

Mechanically Strong, Thermally Stable, and Electrically Conductive Nanocomposite Structure and Method of Fabricating Same

A nanocomposite structure and method of fabricating same are provided. The nanocomposite structure is a polymer in an extruded shape with carbon nanotubes (CNTs) longitudinally disposed and dispersed in the extruded shape along a dimension thereof. The polymer is characteristically defined as having a viscosity of at least approximately 100,000 poise at a temperature of 200 C.

Working, Dennis C.↗

Halogenation-Dependent Effects of the Chlorosulfolipids of Ochromonas danica on Lipid Bilayers

The chlorosulfolipids are amphiphilic natural products with stereochemically complex patterns of chlorination and sulfation. Despite their role in toxic shellfish poisoning, potential pharmacological activities, and unknown biological roles, they remain understudied due to the difficulties in purifying them from natural sources. The structure of these molecules, with a charged sulfate group in the middle of the hydrophobic chain, appears incompatible with the conventional lipid bilayer structure. Questions about chlorosulfolipids remain unanswered partly due to the unavailability of structural analogues with which to conduct structure–function studies. Here, we approach this problem by combining enantioselective total synthesis and membrane biophysics. Using a combination of Langmuir pressure–area isotherms of lipid monolayers, fluorescence imaging of vesicles, mass spectrometry imaging, natural product isolation, small-angle X-ray scattering, and cryogenic electron microscopy, we show that danicalipin A (1) likely inserts into lipid bilayers in the headgroup region and alters their structure and phase behavior. Specifically, danicalipin A (1) thins the bilayer and fluidizes it, allowing even saturated lipid to form fluid bilayers. Lipid monolayers show similar fluidizing upon insertion of danicalipin A (1). Furthermore, we show that the halogenation of the molecule is critical for its membrane activity, likely due to sterically controlled conformational changes. Synthetic unchlorinated and monochlorinated analogues do not thin and fluidize lipid bilayers to the same extent as the natural product. Overall, this study sheds light on how amphiphilic small molecules interact with lipid bilayers and the importance of stereochemistry and halogenation for this interaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fault-Tolerant Heat Exchanger

A compact, lightweight heat exchanger has been designed to be fault-tolerant in the sense that a single-point leak would not cause mixing of heat-transfer fluids. This particular heat exchanger is intended to be part of the temperature-regulation system for habitable modules of the International Space Station and to function with water and ammonia as the heat-transfer fluids. The basic fault-tolerant design is adaptable to other heat-transfer fluids and heat exchangers for applications in which mixing of heat-transfer fluids would pose toxic, explosive, or other hazards: Examples could include fuel/air heat exchangers for thermal management on aircraft, process heat exchangers in the cryogenic industry, and heat exchangers used in chemical processing. The reason this heat exchanger can tolerate a single-point leak is that the heat-transfer fluids are everywhere separated by a vented volume and at least two seals. The combination of fault tolerance, compactness, and light weight is implemented in a unique heat-exchanger core configuration: Each fluid passage is entirely surrounded by a vented region bridged by solid structures through which heat is conducted between the fluids. Precise, proprietary fabrication techniques make it possible to manufacture the vented regions and heat-conducting structures with very small dimensions to obtain a very large coefficient of heat transfer between the two fluids. A large heat-transfer coefficient favors compact design by making it possible to use a relatively small core for a given heat-transfer rate. Calculations and experiments have shown that in most respects, the fault-tolerant heat exchanger can be expected to equal or exceed the performance of the non-fault-tolerant heat exchanger that it is intended to supplant (see table). The only significant disadvantages are a slight weight penalty and a small decrease in the mass-specific heat transfer.

Izenson, Michael G.↗

Can We Probe the Conductivity of the Lithosphere and Upper Mantle Using Satellite Tidal Magnetic Signals?

A few studies convincingly demonstrated that the magnetic fields induced by the lunar semidiurnal (M2) ocean flow can be identified in satellite observations. This result encourages using M2 satellite magnetic data to constrain subsurface electrical conductivity in oceanic regions. Traditional satellite-based induction studies using signals of magnetospheric origin are mostly sensitive to conducting structures because of the inductive coupling between primary and induced sources. In contrast, galvanic coupling from the oceanic tidal signal allows for studying less conductive, shallower structures. We perform global 3-D electromagnetic numerical simulations to investigate the sensitivity of M2 signals to conductivity distributions at different depths. The results of our sensitivity analysis suggest it will be promising to use M2 oceanic signals detected at satellite altitude for probing lithospheric and upper mantle conductivity. Our simulations also suggest that M2 seafloor electric and magnetic field data may provide complementary details to better constrain lithospheric conductivity.

Schnepf, N. R.↗

On the cause of equatorial spread F.

It is suggested that convective electric fields in the equatorial ionosphere are generated by neutral winds (zonal or meridional) which act on regions having structure in their field aligned Pedersen conductivity integrals. The conductivity structure is presumably caused by long-lived metallic ions concentrated irregularly below the F layer at altitudes where their collision and gyrofrequencies are comparable. The resulting plasma convection leads to large-scale irregularities and sets up gradients in the electric field that drive other instability mechanisms to produce small-scale irregularities. The mechanism proposed requires a different velocity above and below 200 km for winds in the magnetic east-west direction, but for winds in the magnetic meridian direction, an altitude gradient is not required.

Hanson, W. B.↗

Electromagnetic deep-probing (100-1000 KMS) of the Earth's interior from artificial satellites: Constraints on the regional emplacement of crustal resources

An algorithm was developed to address the problem of electromagnetic coupling of ionospheric current systems to both a homogeneous Earth having finite conductivity, and to an Earth having gross lateral variations in its conductivity structure, e.g., the ocean-land interface. Typical results from the model simulation for ionospheric currents flowing parallel to a representative geologic discontinuity are shown. Although the total magnetic field component at the satellite altitude is an order of magnitude smaller than at the Earth's surface (because of cancellation effects from the source current), the anomalous behavior of the satellite observations as the vehicle passes over the geologic contact is relatively more important pronounced. The results discriminate among gross lithospheric structures because of difference in electrical conductivity.

Hermance, J. F.↗