Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “concentration potential”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

Atomic Oxygen Durability of Second Surface Silver Microsheet Glass Concentrators

Second surface silver microsheet glass concentrators are being developed for potential use in future solar dynamic space power systems. Traditional concentrators are aluminum honeycomb sandwich composites with either aluminum or graphite epoxy face sheets, where a reflective aluminum layer is deposited onto an organic leveling layer on the face sheet. To protect the underlying layers, a SiO2 layer is applied on top of the aluminum reflective layer. These concentrators may be vulnerable to atomic oxygen degradation due to possible atomic oxygen attack of the organic layers at defect sites in the protective and reflective coatings. A second surface microsheet glass concentrator would be inherently more atomic oxygen durable than these first surface concentrators. In addition, a second surface microsheet glass concentrator design provides a smooth optical surface and allows for silver to be used as a reflective layer, which would improve the reflectivity of the concentrator and the performance of the system. A potential threat to the performance of second surface microsheet glass concentrators is atomic oxygen attack of the underlying silver at seams and edges or at micrometeoroid and debris (MMD) impacts sites. Second surface silver microsheet glass concentrator samples were fabricated and tested for atomic oxygen durability. The samples were iteratively exposed to an atomic oxygen environment in a plasma asher. Samples were evaluated for potential degradation at fabrication seams, simulated MMD impact sites, and edges. Optical microscopy was used to evaluate atomic oxygen degradation. Reflectance was obtained for an impacted sample prior to and after atomic oxygen exposure. After an initial atomic oxygen exposure to an effective fluence of approx. 1 x 10(exp 21) atoms/cm(exp 2), oxidation of the silver at defect sites and edges was observed. Exposure to an additional approx. 1 x 10(exp 21) atoms/cm(exp 2) caused no observed increase in oxidation. Oxidation at an impact site caused negligible changes in reflectance. In all cases oxidation was found to be confined to the vicinity of the seams, impact sites, edges or defect sites. Asher to in-space atomic oxygen correlation issues will be addressed.

deGroh, Kim K.↗

Stress corrosion cracking of a titanium alloy in chloride-containing liquid environments

Ti-8 Al-1 Mo-1 V was tested in solvents containing chloride, bromide or iodide ions. It was found that the region II plateau velocity could be correlated with the inverse of the viscosity for several solvents. It seems most likely that this reflects the influence of the viscosity on the diffusion coefficient of some species involved in a mass transfer process which limits the crack growth. Associated tests were performed in which the potential, pH and concentration of Cl- were varied, in some of the same solutions as used for the viscosity tests. It is concluded from these tests that the absence of cathodic protection against cracking in solutions of low pH arises from an ohmic effect which isolates the crack tip from external potential control.

Smyrl, W. H.↗

Low cost point focus solar concentrator, phase 1

Design concepts and plans for mass-production facilities and equipment, field installation, and maintenance were developed and used for cost analysis of a pneumatically stabilized plastic film point focus solar concentrator which has potential application in conjunction with Brayton cycle engines or supply of thermal energy. A sub-scale reflector was fabricated and optically tested by laser ray tracing to determine focal deviations of the surface slope and best focal plane. These test data were then used for comparisons with theoretical concentrator performance modeling and predictions of full-scale design performance. Results of the economic study indicate the concentrator design will have low cost when mass-produced and has cost/performance parameters that fall within current Jet Propulsion Laboratory goals.

Source record↗

Plasma dynamics on current-carrying magnetic flux tubes

A 1D numerical simulation is used to investigate the evolution of a plasma in a current-carrying magnetic flux tube of variable cross section. A large potential difference, parallel to the magnetic field, is applied across the domain. The result is that density minimum tends to deepen, primarily in the cathode end, and the entire potential drop becomes concentrated across the region of density minimum. The evolution of the simulation shows some sensitivity to particle boundary conditions, but the simulations inevitably evolve into a final state with a nearly stationary double layer near the cathode end. The simulation results are at sufficient variance with observations that it appears unlikely that auroral electrons can be explained by a simple process of acceleration through a field-aligned potential drop.

Swift, Daniel W.↗

Indicator Devices for Detection of Trace Gaseous Hydrazines

The relatively recent decrease in the acceptable time-weighted-average for hydrazines from 100 parts-per-billion (ppb) to 10 ppb rendered many trace hydrazine detectors either insensitive or inaccurate. Development of a rapid detection method for hydrazines at the new 10-ppb concentration was necessary so that test area personnel could reliably assess airborne hydrazines concentrations of a potentially contaminated area prior to entry. The reduction of Au(III) to Au(0) by hydrazines is a well characterized reaction and application of the corresponding yellow to purple color change was selected as a potentially useful means for detection of trace hydrazines in air. Tests with small quantities of KAuCl4 deposited on a variety of substrates were conducted using verified sources of 1,1-dimethylhydrazine, methylhydrazine, and hydrazine at approximately 10 ppb in air. Substrates tested were glass fiber filter paper, glass beads, anion exchange resin (AuCl4- form), and diatomaceous earth. The most successful of these substrates were glass fiber filter paper and diatomaceous earth. The KAuC14 impregnated glass fiber filter paper appeared to be somewhat light sensitive so further tests were conducted using the diatomaceous earth substrate. KAuCl4 concentration, substrate particle size, and sampler configuration were evaluated. Based on these tests, the device selected for further evaluation was a 5mm OD by 50mm glass tube containing 0.02-0.03g of 45/60 mesh diatomaceous earth coated with 2 percent KAuCl4. When connected to a sampling pump, response of the device to changes in relative humidity, ambient light, and high levels of other fluids, which might also be found in a propellant test area, was evaluated. False positive responses were not detected for exposures to relative humidity changes from 10 to 80 percent, sunlight for greater than 10 minutes, or percent levels of ammonia, isopropyl alcohol, nitrogen dioxide, and hydrogen. In addition, body emissions did not produce a false positive response in view of potential application for use inside protective clothing. The device was shown to reliably detect less than 10 ppb of the hydrazines tested using a 10 to 20L sample followed by a 2 to 5 minute color development time. Some field tests were conducted in parallel with conventional acidic firebrick sorbent tubes. There was generally very good agreement between the devices and firebrick sorbent tubes when greater than 10 ppb of a hydrazine was present.

Dee, Lou A.↗

Effects of off-axis radiation on reflective concentrating systems for space power

Off-axis incident radiation, resulting from misalignment of a concentrator relative to incident solar flux, can potentially result in high flux concentrations at positions other than the design focal point. It is suggested that the impact of these concentrations should be considered when choosing materials and thermal control strategies for structures adjacent to the concentrator. A numerical (ray tracing) analysis of the effects of off-axis radiation on the proposed solar concentrator for the Space Station Freedom is performed. The magnitude and position of the reflected flux peaks are identified for a matrix of off-axis angles and target distances. The principles of geometric optics are presented to illustrate that the results of the numerical study are justified, and these results are explained in terms of these basic optical principles. A method that allows prediction of the reflected flux field for a generalized parabolic reflective concentrating system is presented.

Campbell, J. S.↗

Tropospheric OH in a three-dimensional chemical tracer model - An assessment based on observations of CH3CCl3

The paper introduces the representation of tropospheric chemistry allowing for calculation of chemical reaction rates within a chemical tracer model (CTM) simulation with the accuracy comparable to that of a detailed chemical model. The global distribution of tropospheric OH is calculated as a function of time, atmospheric composition, temperature, and solar irradiance. The globally integrated OH concentration weighted by frequency of reaction with CH3CCl3 is evaluated, along with the feasibility of using the observed latitudinal distribution of CH3CCl3 as a test for computed concentrations of OH. Seasonal variations of CH3CCl3 are also considered as a potential test for computed concentrations of OH. It is demonstrated that annual cycles of CH3CCl3 are controlled, or strongly influenced, by dynamical processes at latitudes northward of 25 deg South.

Spivakovsky, C. M.↗

The dynamics of the stratospheric polar vortex and its relation to springtime ozone depletions

Recent aircraft observations have determined the structure of polar vortices during winter and their relationship to polar ozone depletions, based on high dynamical isolation and the extremely low temperatures required for stratospheric cloud formation. The aircraft data reveal large gradients of potential vorticity and concentrations of conservative trace species at the transition from high-latitude to polar air, implying that the inward mixing of heat and constituents is strongly inhibited, and that the perturbed polar stratospheric chemistry associated with the ozone hole is isolated from the rest of the stratosphere until the vortex breaks up in late spring. It is therefore the overall polar vortex which limits the annual polar ozone depletions' maximum area-coverage.

Schoeberl, Mark R.↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered Threshold Limit Values (TLV) for HydraZine (HZ), MonoMethylHydrazine (MMH), and Unsymmetrical DiMethylHydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to IO ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure to potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

Development of an Automated Reader for Analysis and Storage of Personnel Dosimeter Badge Data

The collection and archiving of data from personnel dosimeters has become increasingly important in light of the lowered threshold limit values (TLV) for hydrazine (HZ), monomethylhydrazine (MMH), and unsymmetrical dimethylhydrazine (UDMH). The American Conference of Government Industrial Hygienists (ACGIH) lowered the TLV from 100 parts per billion (ppb) to 10 ppb and has caused increased concern over long term exposures of personnel to trace levels of these hypergols and other potentially harmful chemicals. An automated system of reading the exposure levels of personnel dosimeters and storing exposure data for subsequent evaluation has been developed. The reading of personnel dosimeter badges for exposure lo potentially harmful vapor concentrations of hydrazines or other chemicals is performed visually by comparing the color developed by the badge with a calibrated color comparator. The result obtained using visual comparisons of the developed badge color with the comparator may vary widely from user to user. The automated badge reader takes the variability out of the dosimeter reading by accurately comparing the reflectance obtained from a colored spot on the badge with a reading on the same spot prior to any exposure to chemical vapors. The observed difference between the reflectance values is used as part of a calculation of the dose value for the badge based on a stored calibration curve. The badge reader also stores bar-code data unique to each badge, as well as bar-code information on the user, as part of the permanent badge record. The start and stop exposure times for each badge are recorded and can be used as part of the calculated concentration, in ppm, for each badge logged during a recording period. The badge reader is equipped with a number of badge holders, each of which is unique to a specific type of personnel dosimeter badge. This gives the reader maximum flexibility to allow for the reading of several different types of badges. Test results of the badge reader for several different types of personnel dosimeter badges are presented within the body of this paper.

Meneghelli, B. J.↗

Contaminated water treatment

Method and system for processing of a liquid ("contaminant liquid") containing water and containing urine and/or other contaminants in a two step process. Urine, or a contaminated liquid similar to and/or containing urine and thus having a relatively high salt and urea content is passed through an activated carbon filter to provide a resulting liquid, to remove most of the organic molecules. The resulting liquid is passed through a semipermeable membrane from a membrane first side to a membrane second side, where a fortified drink having a lower water concentration (higher osmotic potential) than the resulting liquid is positioned. Osmotic pressure differential causes the water, but not most of the remaining inorganic (salts) contaminant(s) to pass through the membrane to the fortified drink. Optionally, the resulting liquid is allowed to precipitate additional organic molecules before passage through the membrane.

Gormly, Sherwin J.↗

A Brief Overview of Relevant Silicon Carbide Electronics and Sensor Development for Long Duration Venus Surface Exploration

This presentation concentrates on the potential of long duration Venus surface missions, and the role of Silicon Carbide (SiC) electronics and sensor advancements in such exploration. For example, SiC integrated circuit (IC) electronics have matured to a state where a simple long-life scientific probe is feasible for extended Venus surface operations. These electronics have been demonstrated for more than a year at 500˚C, and 60 days in high-fidelity simulated Venus surface conditions [1-2]. Further, high temperature chemical sensing technology, including SiC-based gas sensors, integrated with SiC electronics can enable future exploration of the Venus surface atmosphere [3]. Continued maturation of these high temperature electronics and sensors has been part of the Long-Lived In-Situ Solar System Explorer (LLISSE) project to provide an operational system for in situ exploration of the Venus surface up to 60 days [4]. A key focus of this work includes increasing the complexity and decreasing the power consumption of the ICs which will pave the way to enhanced capabilities, such as long-duration Venus seismic measurements and other mission capabilities currently under development. This is in parallel to work expanding the capabilities of the sensor technology to provide science measurements on the Venus surface. This presentation will give an overview of possible extended duration Venus surface exploration and some of the SiC-based technologies that can enable this exploration.

high temperature Venus surface electronics sensors↗

Exploring the Potential of Hydrogen as a Lift Gas for Nasa’s Scientific Balloon Program

The United States National Aeronautics and Space Administration (NASA) Balloon Program has a rich history of conducting scientific research in the stratosphere, offering a unique platform for experiments in the near-space environment. One critical component of these high-altitude balloons is the choice of lift gas, which is pivotal to achieving the desired altitude and, thus, mission objectives. Traditionally, helium has been the preferred lift gas due to its inert properties and safety considerations. However, the increasing demand and limited global helium reserves have prompted NASA to explore alternative lift gases, with hydrogen emerging as the most logical choice. Hydrogen boasts several advantages, including its abundant availability, cost-effectiveness, and enhanced lift capability compared to helium. Moreover, it can support a wide range of scientific payloads, enabling extended mission durations and increased payload capacities, ultimately strengthening the program’s scientific potential. However, adopting hydrogen as a lift gas is not without challenges. Safety concerns, especially during the launch and recovery phases, are paramount. NASA and the other major players in the scientific ballooning community have been developing stringent safety protocols and engineering solutions to mitigate these risks. This development includes specialized support systems, leak detection mechanisms, and enhanced launch and recovery procedures. Additionally, environmental considerations must be carefully evaluated. Hydrogen release has the potential to increase concentrations of various greenhouse gases, and its usage must be balanced against the benefits it offers to scientific research and exploration. This paper delves into the ongoing research and development efforts to ensure balloon-based research’s long-term sustainability and its ability to continue pushing the boundaries of scientific discovery. This research demonstrates NASA’s commitment to innovation, safety, and environmental responsibility while maintaining its mission to advance our understanding of the Earth and the cosmos.

balloon↗

Thin film, concentrator, and multijunction space solar cells: Status and potential

Recent, rapid advances in a variety of solar cell technologies offer the potential for significantly enhancing, or enabling entirely new, mission capabilities. Thin film solar cells are of particular interest. A review is provided of the status of those thin film cell technologies of interest for space applications, and the issues to be resolved before mission planners can consider them. A short summary of recent developments in concentrator and multijunction space solar cell and array technology is given.

Flood, Dennis J.↗

Thin film, concentrator and multijunction space solar cells: Status and potential

Recent, rapid advances in a variety of solar cell technologies offer the potential for significantly enhancing, or enabling entirely new, mission capabilities. Thin film solar cells are of particular interest in that regard. A review is provided of the status of those thin film cell technologies of interest for space applications, and the issues to be resolved before mission planners can consider them. A short summary is also given of recent developments in concentrator and multijunction space solar cell and array technology.

Flood, Dennis J.↗

Ethylene monitoring and control system

A system that can accurately monitor and control low concentrations of ethylene gas includes a test chamber configured to receive sample gas potentially containing an ethylene concentration and ozone, a detector configured to receive light produced during a reaction between the ethylene and ozone and to produce signals related thereto, and a computer connected to the detector to process the signals to determine therefrom a value of the concentration of ethylene in the sample gas. The supply for the system can include a four way valve configured to receive pressurized gas at one input and a test chamber. A piston is journaled in the test chamber with a drive end disposed in a drive chamber and a reaction end defining with walls of the test chamber a variable volume reaction chamber. The drive end of the piston is pneumatically connected to two ports of the four way valve to provide motive force to the piston. A manifold is connected to the variable volume reaction chamber, and is configured to receive sample gasses from at least one of a plurality of ports connectable to degreening rooms and to supply the sample gas to the reactive chamber for reaction with ozone. The apparatus can be used to monitor and control the ethylene concentration in multiple degreening rooms.

Nelson, Bruce N.↗