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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Charge-coupled device for low background observations

A charge-coupled device with a low-emissivity metal layer located between a sensing layer and a substrate provides reduction in ghost images. In a typical charge-coupled device of a silicon sensing layer, a silicon dioxide insulating layer, with a glass substrate and a metal carrier layer, a near-infrared photon, not absorbed in the first pass, enters the glass substrate, reflects from the metal carrier, thereby returning far from the original pixel in its entry path. The placement of a low-emissivity metal layer between the glass substrate and the sensing layer reflects near infrared photons before they reach the substrate so that they may be absorbed in the silicon nearer the pixel of their points of entry so that the reflected ghost image is coincident with the primary image for a sharper, brighter image.

Loh, Edwin D.↗
NASA NTRS2012

Absolute Radiometric Calibration of Narrow-Swath Imaging Sensors with Reference to Non-Coincident Wide-Swath Sensors

An inter-calibration method is developed to provide absolute radiometric calibration of narrow-swath imaging sensors with reference to non-coincident wide-swath sensors. The method predicts at-sensor radiance using non-coincident imagery from the reference sensor and knowledge of spectral reflectance of the test site. The imagery of the reference sensor is restricted to acquisitions that provide similar view and solar illumination geometry to reduce uncertainties due to directional reflectance effects. Spectral reflectance of the test site is found with a simple iterative radiative transfer method using radiance values of a well-understood wide-swath sensor and spectral shape information based on historical ground-based measurements. At-sensor radiance is calculated for the narrow-swath sensor using this spectral reflectance and atmospheric parameters that are also based on historical in situ measurements. Results of the inter-calibration method show agreement on the 2 5 percent level in most spectral regions with the vicarious calibration technique relying on coincident ground-based measurements referred to as the reflectance-based approach. While the variability of the inter-calibration method based on non-coincident image pairs is significantly larger, results are consistent with techniques relying on in situ measurements. The method is also insensitive to spectral differences between the sensors by transferring to surface spectral reflectance prior to prediction of at-sensor radiance. The utility of this inter-calibration method is made clear by its flexibility to utilize image pairings with acquisition dates differing in excess of 30 days allowing frequent absolute calibration comparisons between wide- and narrow-swath sensors.

McCorkel, Joel↗
NASA NTRS1993

Arctic coastal polynya observations with ERS-1 SAR and DMSP SSM/I

Work to improve the characterization of the distribution of new and young sea ice types and open water amount within Arctic coastal polynyas through the combined use of ERS-1 SAR (Synthetic Aperture Radar) and DMSP SSM/I (Defense Meteorological Satellite Program Special Sensor Microwave/Imager) data is described. Two St. Lawrence Island polynya events are studied using low resolution, geocoded SAR images and coincident SSM/I data. The SAR images are analyzed in terms of polarization and spectral gradient ratios. Results of the combined analysis show that the SAR ice type classification is consistent with that from SSM/I and that the combined use of SAR and SSM/I can improve the characterization of thin ice better than either data set can do alone.

Cavalieri, D. J.↗
DOE OSTI2022

Three-dimensional (3D) velocity map imaging: from technique to application

The velocity map imaging (VMI) technique was first introduced by Eppink and Parker in 1997, as an improvement to the original ion imaging method by Houston and Chandler in 1987. The method has gained huge popularity over the past two decades and has become a standard tool for measuring high-resolution translational energy and angular distributions of ions and electrons. VMI has evolved gradually from 2D momentum measurements to 3D measurements with various implementations and configurations. The most recent advancement has brought unprecedented 3D performance to the technique in terms of resolutions (both spatial and temporal), multi-hit capability as well as acquisition speed while maintaining many attractive attributes afforded by conventional VMI such as being simple, cost-effective, visually appealing and versatile. Here, in this tutorial, we will discuss many technical aspects of the recent advancement and its application in probing correlated chemical dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Comparison of Shuttle Imaging Radar-B ocean wave image spectra with linear model predictions based on aircraft measurements

During October 1984, coincident Shuttle Imaging Radar-B synthetic aperture radar (SAR) imagery and wave measurements from airborne instrumentation were acquired. The two-dimensional wave spectrum was measured by both a radar ocean-wave spectrometer and a surface-contour radar aboard the aircraft. In this paper, two-dimensional SAR image intensity variance spectra are compared with these independent measures of ocean wave spectra to verify previously proposed models of the relationship between such SAR image spectra and ocean wave spectra. The results illustrate both the functional relationship between SAR image spectra and ocean wave spectra and the limitations imposed on the imaging of short-wavelength, azimuth-traveling waves.

Monaldo, Frank M.↗
NASA NTRS1989

Setting limits on q0 from gravitational lensing

Gravitational lensing by galaxies in a wide variety of cosmological models is considered. For closed models, the lensing depends on the parameter beta(crit). If beta(crit) is greater than zero, a normal lensing case can be obtained with two bright images separated by an angle twice beta(crit) and a third, arbitrarily dim image between them coincident with the position of the lensing galaxy nucleus. As the QSO approaches the antipodal redshift, which can occur in models with large values of the cosmological constant, the cross sections for lensing blow up. An overfocused case where beta(crit) is less than zero can be obtained for a QSO beyond the antipodal redshift. In this case, when a lensing event occurs, only one arbitrarily dim image coincident with the position of the lensing galaxy nucleus is seen. If galaxy rotation curves are always flat or slowly rising, the overfocused case always produces one image.

Gott, J. Richard, III↗
DOE OSTI2025

Imaging a light-induced molecular elimination reaction with an X-ray free-electron laser

Tracking the motion of individual atoms during chemical reactions represents a severe experimental challenge, especially if several competing reaction pathways exist or if the reaction is governed by the correlated motion of more than two molecular constituents. Here we demonstrate how ultrashort X-ray pulses combined with coincident ion imaging can be used to trace molecular iodine elimination from laser-irradiated diiodomethane (CH 2 I 2 ), a reaction channel of fundamental importance but small relative yield that involves the breaking of two molecular bonds and the formation of a new one. We map bending vibrations of the bound molecule, disentangle different dissociation pathways, image the correlated motion of the iodine atoms and the methylene group leading to molecular iodine ejection, and trace the vibrational motion of the formed product. Our results provide a quantitative mechanistic picture behind previously suggested reaction mechanisms and prove that a variety of geometries are involved in the molecular bond formation.

Atomic and molecular interactions with photons↗
NASA NTRS2006

Radiometric Characterization Results for the IKONOS, Quickbird, and OrbView-3 Sensor

Radiometric calibration of commercial imaging satellite products is required to ensure that science and application communities better understand commercial imaging satellite properties. Inaccurate radiometric calibrations can lead to erroneous decisions and invalid conclusions and can limit intercomparisons with other systems. To address this calibration need, the NASA Applied Sciences Directorate (ASD) at Stennis Space Center established a commercial satellite imaging radiometric calibration team consisting of three independent groups: NASA ASD, the University of Arizona Remote Sensing Group, and South Dakota State University. Each group independently determined the absolute radiometric calibration coefficients of available high-spatial-resolution commercial 4-band multispectral products, in the visible though near-infrared spectrum, from GeoEye(tradeMark) (formerly SpaceImaging(Registered TradeMark)) IKONOS, DigitalGlobe(Regitered TradeMark) QuickBird, and GeoEye (formerly ORBIMAGE(Registered TradeMark) OrbView. Each team member employed some variant of reflectance-based vicarious calibration approach, requiring ground-based measurements coincident with image acquisitions and radiative transfer calculations. Several study sites throughout the United States that covered a significant portion of the sensor's dynamic range were employed. Satellite at-sensor radiance values were compared to those estimated by each independent team member to evaluate the sensor's radiometric accuracy. The combined results of this evaluation provide the user community with an independent assessment of these sensors' absolute calibration values.

Holekamp, Kara↗
DOE OSTI2022

Two- and three-body fragmentation of multiply charged tribromomethane by ultrafast laser pulses

We investigate the two- and three-body fragmentation of tribromomethane (bromoform, CHBr 3 ) resulting from multiple ionization by 28-femtosecond near-infrared laser pulses with a peak intensity of 6 × 10 14 W cm -2 . The analysis focuses on channels consisting exclusively of ionic fragments, which are measured by coincidence momentum imaging. The dominant two-body fragmentation channel is found to be Br + + CHBr 2 +. Weaker HBr + + CBr 2 +, CHBr + + Br 2 +, CHBr 2+ + Br 2 +, and Br + + CHBr 2 2+ channels, some of which require bond rearrangement prior to or during the fragmentation, are also observed. The dominant three-body fragmentation channel is found to be Br + + Br + + CHBr + . This channel includes both concerted and sequential fragmentation pathways, which we identify using the native frames analysis method. We compare the measured kinetic energy release and momentum correlations with the results of classical Coulomb explosion simulations and discuss the possible isomerization of CHBr 3 to BrCHBr–Br (iso-CHBr 3 ) prior to the fragmentation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Two-body dissociation of formic acid following double ionization by ultrafast laser pulses

We studied the fragmentation of planar formic acid (HCOOH) molecules following their double ionization by intense ultrashort laser pulses. Deuterium tagging (i.e., HCOOD) combined with coincidence momentum imaging measurements of all fragment ions enabled determination of the role of the hydroxyl and carboxyl hydrogen atoms in the breakup. Specifically, we observe a strong preference for the hydroxyl (OD) group to remain intact in a ${\mathrm{HCOOD}}^{2+}{\rightarrow}{\mathrm{OD}}^{+}+{\mathrm{HCO}}^{+}$ fragmentation, which is an order of magnitude more likely than ${\mathrm{OH}}^{+}+{\mathrm{DCO}}^{+}$. An even larger preference for breaking the H-C bond over the O-H bond is observed in the ${\mathrm{H}}^{+}+{\mathrm{DCO}}_{2}^{+}$ and ${\mathrm{D}}^{+}+{\mathrm{HCO}}_{2}^{+}$ deprotonation channels. Bond rearrangement, leading to ${\mathrm{H}}_{2}^{+}$ or ${\mathrm{H}}_{2}{\mathrm{O}}^{+}$ formation, exhibits no isotopic preference. The kinetic-energy-release distributions of the ${\mathrm{OH}}^{+}+{\mathrm{DCO}}^{+}$ and ${\mathrm{O}}^{+}+{\mathrm{H}}_{2}{\mathrm{CO}}^{+}$ breakup channels suggest that more than one process contributes to these final products, although further theoretical work is needed to identify the specific paths.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2024

Native frames: An approach for separating sequential and concerted three-body fragmentation

Disentangling sequential and concerted three-body fragmentation has been a longstanding endeavor in studies of molecular dynamics. To accomplish this goal, we recently introduced a novel method to separate sequential from concerted breakup, where the sequential events are analyzed in their native frames [J. Rajput et al., Phys. Rev. Lett. 120, 103001 (2018)]. The essence of this method is the use of the Jacobi coordinates' conjugate momenta to reduce the dimensionality of the multibody fragmentation in combination with a clear signature for sequential breakup. To demonstrate this method, we employ coincidence momentum imaging to study the strong-field dissociative ionization of OCS into O + +C + + S + , which typically undergoes concerted fragmentation or sequential breakup involving either a metastable CO 2+ or CS 2+ molecule. We identify sequential breakup using a uniform distribution as a function of the angle between the conjugate momenta, associated with the first and second fragmentation steps, which is due to the rotation of the intermediate molecule in the fragmentation plane. Furthermore, by exploiting this uniform distribution, we separate the sequential and concerted distributions in any plot created from the measured momenta.

Atomic & molecular processes in external fields↗
NASA NTRS1995

Clouds and the Earth's Radiant Energy System (CERES) algorithm theoretical basis document: Overviews (subsystem 0) - Volume 1

The theoretical bases for the Release 1 algorithms that will be used to process satellite data for investigation of the Clouds and the Earth's Radiant Energy System (CERES) are described. The architecture for software implementation of the methodologies is outlined. Volume 1 provides both summarized and detailed overviews of the CERES Release 1 data analysis system. CERES will produce global top-of-the-atmosphere shortwave and longwave radiative fluxes at the top of the atmosphere, at the surface, and within the atmosphere by using the combination of a large variety of measurements and models. The CERES processing system includes radiance observations from CERES scanning radiometers, cloud properties derived from coincident satellite imaging radiometers, temperature and humidity fields from meteorological analysis models, and high-temporal-resolution geostationary satellite radiances to account for unobserved times. CERES will provide a continuation of the ERBE record and the lowest error climatology of consistent cloud properties and radiation fields. CERES will also substantially improve our knowledge of the Earth's surface radiation budget.

Wielicki, Bruce A.↗
NASA NTRS1995

The Alignment Test System for AXAF-I's High Resolution Mirror Assembly

The AXAF-1 High Resolution Mirror Assembly (HRMA) consists of four nested mirror pairs of Wolter Type-1 grazing incidence optics. The HRMA assembly and alignment will take place in a vibration-isolated, cleanliness class 100, 18 meter high tower at an Eastman Kodak Company facility in Rochester, NY. Each mirror pair must be aligned such that its image is coma-free, and the four pairs must be aligned such that their images are coincident. In addition, both the HRMA optical axis and focal point must be precisely known with respect to physical references on the HRMA. The alignment of the HRMA mirrors is measured by the HRMA Alignment Test System (HATS), which is an integral part of the tower facility. The HATS is configured as a double-pass, autocollimating Hartmann test where each mirror aperture is scanned to determine the state of alignment. This paper will describe the design and operation of the HATS.

Waldman, Mark↗
NASA NTRS1977

Significance of operator variation and the angle of illumination in lineament analysis on synoptic images

The significance of operator variation and the angle of illumination in acquired imagery is analyzed for lineament analysis. Five operators analyzed a LANDSAT image and four photographs of a plastic relief map illuminated at a low angle from varying directions of the Prescott, Arizona region. Significant differences were found in both number and length of the lineaments recognized by the different investigators for the images. The actual coincidence of lineaments recognized by the investigators for the same image is exceptionally low. Even the directional data on lineament orientation is significantly different from operator to operator and from image to image. Cluster analysis of the orientation data displays a clustering by operators rather than by images. It is recommended that extreme caution be taken before attempting to compare different investigators' results in lineament analysis.

Siegal, B. S.↗
DOE OSTI2023

A plano–convex thick-lens velocity map imaging apparatus for direct, high resolution 3D momentum measurements of photoelectrons with ion time-of-flight coincidence

Since their inception, velocity map imaging (VMI) techniques have received continued interest in their expansion from 2D to 3D momentum measurements through either reconstructive or direct methods. Recently, much work has been devoted to the latter of these by relating electron time-of-flight (TOF) to the third momentum component. The challenge is having a timing resolution sufficient to resolve the structure in the narrow (<10 ns) electron TOF spread. Here, we build upon the work in VMI lens design and 3D VMI measurement by using a plano–convex thick-lens (PCTL) VMI in conjunction with an event-driven camera (TPX3CAM) providing TOF information for high resolution 3D electron momentum measurements. We perform simulations to show that, with the addition of a mesh electrode to the thick-lens geometry, the resulting plano–convex electrostatic field extends the detectable electron cutoff energy range while retaining the high resolution. This design also extends the electron TOF range, allowing for a better momentum resolution along this axis. We experimentally demonstrate these capabilities by examining above-threshold ionization in xenon, where the apparatus is shown to collect electrons of energy up to ∼7 eV with a TOF spread of ∼30 ns, both of which are improved compared to a previous work by factors of ∼1.4 and ∼3.75, respectively. Finally, the PCTL-VMI is equipped with a coincident ion TOF spectrometer, which is shown to effectively extract unique 3D momentum distributions for different ionic species in a gas mixture. These techniques have the potential to lend themselves to more advanced measurements involving systems where the electron momentum distributions possess non-trivial symmetries.

Instruments & Instrumentation↗
NASA NTRS1987

The response of SAR imagery to azimuth travelling ocean surface waves as determined from shuttle SAR imagery

Comparisons between two-dimensional ocean wave spectra, derived from synthetic aperture radar (SAR) imagery, and two-dimensional wave spectra from independent instruments have shown good agreement. The procedure by which raw SAR image intensity-variance spectra are converted to estimates of wave spectra is dependent upon models of how a SAR is able to image ocean waves. The greatest uncertainty exists about the mechanism by which azimuth (along track) traveling waves are imaged. In this paper, independent wave spectra from an airborne, radar ocean wave spectrometer (ROWS) are systematically compared with spatially and temporally coincident shuttle SAR image intensity-variance spectra to determine an optimum description of the relationship between the two. The result of these comparisons is to demonstrate that a SAR image intensity-variance spectrum is nearly proportional to the ocean wave slope-variance spectrum for azimuth traveling waves.

Monaldo, Frank M.↗
DOE OSTI2025

Imaging transient molecular configurations in UV-excited diiodomethane

Femtosecond structural dynamics of diiodomethane (CH 2 I 2 ) triggered by ultraviolet (UV) photoabsorption at 290 and 330 nm are studied using time-resolved coincident Coulomb explosion imaging driven by a near-infrared probe pulse. Here, we map the dominant single-photon process, the cleavage of the carbon–iodine bond producing rotationally excited CH 2 I radical, identify the contributions of the three-body (CH 2 + I + I) dissociation and molecular iodine formation channels, which are primarily driven by the absorption of more than one UV photon, and demonstrate the existence of a weak reaction pathway involving the formation of short-lived transient species resembling iso-CH 2 I 2 -like geometries with a slightly shorter I–I separation compared to the ground-state CH 2 I 2 . These transient molecular configurations, which can be separated from the other channels by applying a set of conditions on the correlated momenta of three ionic fragments, are formed within ∼100 fs after the initial photoexcitation and decay within the next 100 fs.

Atomic and molecular processes↗
NASA NTRS2017

Chasing Shadows: Rotation of the Azimuthal Asymmetry in the TW Hya Disk

We have obtained new images of the protoplanetary disk orbiting TW Hya in visible, total intensity light with the Space Telescope Imaging Spectrograph (STIS) on the Hubble Space Telescope (HST), using the newly commissioned BAR5 occulter. These HSTSTIS observations achieved an inner working angle of approximately 0 "2, or11.7 au, probing the system at angular radii coincident with recent images of the disk obtained by ALMA and in polarized intensity near-infrared light. By comparing our new STIS images to those taken with STIS in 2000 and with NICMOS in 1998, 2004, and 2005, we demonstrate that TW Hyas azimuthal surface brightness asymmetry moves coherently in position angle. Between 50 au and 141 au we measure a constant angular velocity in the azimuthal brightness asymmetry of 22.deg7 yr(exp -1) in a counterclockwise direction, equivalent to a period of 15.9yrassuming circular motion. Both the (short) inferred period and lack of radial dependence of the moving shadow pattern are inconsistent with Keplerian rotation at these disk radii. We hypothesize that the asymmetry arises from the fact that the disk interior to 1 au is inclined and precessing owing to a planetary companion, thus partially shadowing the outer disk. Further monitoring of this and other shadows on protoplanetary disks potentially opens anew avenue for indirectly observing the sites of planet formation.

protoplanetary disk orbiting TW Hya↗