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Composition dependent effects in gas chromatography

Fundamantal concepts are developed which are required to optimize a gas chromatograph-mass spectrometer chemical analysis system suitable for use on an unmanned roving vehicle for Mars exploration. Prior efforts have developed simulation models for the chromatograph which were compared with data obtained from a test facility. Representation of binary systems by superposition was shown to be a first-order approximation and in certain cases large discrepencies were noted. This subtask has as its objective generation of additional binary data and analysis of the observed nonlinear effects.

Lavoie, R. C.↗

Broad-Band Measurements of Cen X-3 With XTE and CGRO

Centaurus X-3 has played a key role in the development of our understanding of galactic x-ray binary sources. Timing analysis of the UHURU x-ray observations for the luminous Cen X-3 source (L approximately 10(exp 38) erg/s) revealed the first evidence for coherent x-ray pulsations from an object in a binary system (Giaconni 1971; Schreier 1972). It was quickly understood that the luminous pulsed x-ray emission could be generated by the accretion of matter from a companion star onto a rotating neutron star and led to the adoption of binary star models as the fundamental model for galactic x-ray sources (e.g. Pringle and Rees 1972; Lamb 1973). Based on modeling and refined observations since the original measurements, we now believe that Cen X-3 is a high mass x-ray binary system that contains a disk-fed pulsar with a period of 4.84 seconds that is in a 2.087 day orbit around an O-star companion. Since the pulsar discovery, its period has been intermittently monitored and those studies show a long term spin-up of the pulsar punctuated by short intervals of spin-down (e.g. Finger 1994). The implied torques are thought to originate from the interaction of an accretion disk with the magnetic field of a neutron star (Ghosh and Lamb 1979).

Vestrand, W. Thomas↗

A Priori Analysis of Subgrid-Scale Models for Large Eddy Simulations of Supercritical Binary-Species Mixing Layers

Models for large eddy simulation (LES) are assessed on a database obtained from direct numerical simulations (DNS) of supercritical binary-species temporal mixing layers. The analysis is performed at the DNS transitional states for heptane/nitrogen, oxygen/hydrogen and oxygen/helium mixing layers. The incorporation of simplifying assumptions that are validated on the DNS database leads to a set of LES equations that requires only models for the subgrid scale (SGS) fluxes, which arise from filtering the convective terms in the DNS equations. Constant-coefficient versions of three different models for the SGS fluxes are assessed and calibrated. The Smagorinsky SGS-flux model shows poor correlations with the SGS fluxes, while the Gradient and Similarity models have high correlations, as well as good quantitative agreement with the SGS fluxes when the calibrated coefficients are used.

turbulence↗

Segregation during directional melting and its implications on seeded crystal growth: A theoretical analysis

Directional melting of binary systems, as encountered during seeding in melt growth, is analyzed for concurrent compositional changes at the crystal-melt interface. It is shown that steady state conditions cannot normally be reached during seeding and that the growth interface temperature at the initial stages of seeded growth is a function of backmelt conditions. The theoretical treatment is numerically applied to Hg1-xCdXTe and Ga-doped Ge.

Bourret, E. D.↗

Observation of X-ray eclipses from LMC X-4

Observations made with the Rotation Modulation Collimator system (RMC) have revealed that X-ray source X-4 in the Large Magellanic Cloud (LMC X-4) is most likely part of a binary system. An analysis of the star's coordinates is presented, with attention given to orbital period and flux intensity variations. Stellar mass and orbital inclination angle are estimated for both X-4 and its companion star.

Li, F.↗

High-resolution X-ray observations of nearby binary systems Flaring and evidence for unseen companions

The high-resolution imager (HRI) of the Einstein Observatory has the resolution necessary to resolve components of some nearby binaries. From an analysis of four systems that are within 10 pc of the sun and that contain one or more dM stars, the occurrence of X-ray flares with time scales of tens of minutes is reported. One of the stars has an extended X-ray image which is interpreted as evidence for the existence of an unseen companion.

Harris, D. E.↗

An alternative model for estimating liquid diffusion coefficients requiring no viscosity data

An equation, based on the free volume of a liquid solvent, was derived via dimensional analysis, to predict binary diffusion coefficients. The equation assumed that interaction between the solute and liquid solvent molecules followed a Lennard-Jones potential. The equation was compared to other diffusivity equations and was found to give good results over the temperature range examined.

Morales, Wilfredo↗

Gravity Induced Formation of Concentration Gradients in Supersaturated Binary Solutions

Experimental and theoretical studies of the formation of solute concentration gradient in supersaturated binary solutions in a gravitational field were carried out. The formation of solute concentration gradient was associated with the gravity induced redistribution of subcritical solute clusters. The birth-death process of the new solute-rich phase domains (subcritical solute clusters) was described in terms of the time-dependent Ginzburg Landau model developed for metastable state relaxation in binary (solute + solvent) non-critical solutions in the presence of a gravitational field. A new mathematical Ansatz was developed for solution of the model equations. This Ansatz has allowed to approach for the first time the following important problems: (1) Microstructure of solute distribution inside of the subcritical solute clusters. The analytical results obtained demonstrate that solute inside of the subcritical solute clusters is heterogeneously distributed with a spatially periodic structure. (2) Macrostructure of the solute subcritical clusters distribution in a gravitational field. The subcritical solute clusters are found to be distributed heterogeneously in a gravitational field. This heterogeneity, which is due to the heterogeneous birth-death process of the subcritical solute clusters in a gravitational field, initiates a noticeable solute concentration gradient in vertical columns of supersaturated binary solutions. An analysis and comparison of theoretical results and experimental data related to the solute concentration gradient formation in a gravitational field are presented. It is also demonstrated that the critical radius of solute clusters (radius of nucleation) and induction time are gravity-dependent.

Izmailov, Alexander F.↗

OGLE-2018-BLG-0022: First Prediction of an Astrometric Microlensing Signal from a Photometric Microlensing Event

In this work, we present the analysis of the binary microlensing event OGLE-2018-BLG-0022 that is detected toward the Galactic bulge field. The dense and continuous coverage with the high-quality photometry data from ground-based observations combined with the space-based Spitzer observations of this long timescale event enables us to uniquely determine the masses M1=0.40 ± 0.05Me and M2=0.13 ± 0.01Me of the individual lens components. Because the lens-source relative parallax and the vector lens-source relative proper motion are unambiguously determined, we can likewise unambiguously predict the astrometric offset between the light centroid of the magnified images (as observed by the Gaia satellite) and the true position of the source. This prediction can be tested when the individual-epoch Gaia astrometric measurements are released.

Han, Cheongho↗

OGLE-2018-BLG-0022: First Prediction of an Astrometric Microlensing Signal from a Photometric Microlensing Event

In this work, we present the analysis of the binary microlensing event OGLE-2018-BLG-0022 that is detected toward the Galactic bulge field. The dense and continuous coverage with the high-quality photometry data from ground-based observations combined with the space-based Spitzer observations of this long timescale event enables us to uniquely determine the masses M 1 = 0.40 ± 0.05 M ⊙ and M 2 = 0.13 ± 0.01 M ⊙ of the individual lens components. Because the lens-source relative parallax and the vector lens-source relative proper motion are unambiguously determined, we can likewise unambiguously predict the astrometric offset between the light centroid of the magnified images (as observed by the Gaia satellite) and the true position of the source. This prediction can be tested when the individual-epoch Gaia astrometric measurements are released.

Cheongho Han↗

Phytoplankton Diversity and Chemotaxonomy in Contrasting North Pacific Ecosystems

Background. Phytoplankton is the base of majority of ocean ecosystems. It is responsible for half of the global primary production, and different phytoplankton taxa have a unique role in global biogeochemical cycles. In addition, phytoplankton abundance and diversity are highly susceptible to climate induced changes, hence monitoring of phytoplankton and its diversity is important and necessary. Methods. Water samples for phytoplankton and photosynthetic pigment analyses were collected in boreal winter 2017, along transect in the North Pacific Subtropical Gyre (NPSG) and the California Current System (CCS). Phytoplankton community was analyzed using light and scanning electron microscopy and photosynthetic pigments by high-performance liquid chromatography. To describe distinct ecosystems, monthly average satellite data of MODIS Aqua Sea Surface temperature and Chlorophyll a concentration, as well as Apparent Visible Wavelength were used. Results. A total of 207 taxa have been determined, mostly comprised of coccolithophores (35.5%), diatoms (25.2%) and dinoflagellates (19.5%) while cryptophytes, phytoflagellates and silicoflagellates were included in the group ``others" (19.8%). Phytoplankton spatial distribution was distinct, indicating variable planktonic dispersal rates and specific adaptation to ecosystems. Dinoflagellates, and nano-scale coccolithophores dominated NPSG, while micro-scale diatoms, and cryptophytes prevailed in CCS. A clear split between CCS and NPSG is evident in dendogram visualising LINKTREE constrained binary divisive clustering analysis done on phytoplankton counts and pigment oncentrations. Of all pigments determined, alloxanthin, zeaxanthin, divinyl chlorophyll b and lutein have highest correlation to phytoplankton counts. Conclusion. Combining chemotaxonomy and microscopy is an optimal method to determine phytoplankton diversity on a large-scale transect. Distinct communities between the two contrasting ecosystems of North Pacific reveal phytoplankton groups specific adaptations to trophic state, and support the hypothesis of shift from microto nano-scale taxa due to sea surface temperatures rising, favoring stratification and oligotrophic conditions.

oceanography↗

Chromospheres and coronae in binary systems

Recent observations and spectral analysis of chromospheres and coronae are discussed for various types of binary systems containing cool stars. These include the W UMa-type systems, the RS CVn variables, and selected widely separated binary systems such as VV Cephei and the giant stars in the Hyades cluster. In many cases evidence for extreme examples of solar activity are found. Radiative losses in ultraviolet resonance lines can be at least one or two orders of magnitude larger than those found in the quiet sun. In lambda And, a RS CVn type system, there is evidence for inhomogeneous structure in the chromosphere and transition region. Rotation appears to be a determinant in the energy losses of these atmospheres although not the only one.

Dupree, A. K.↗

The impact of IUE on binary star studies

The use of IUE observations in the investigation of binary stars is discussed. The results of data analysis of several classes of binary systems are briefly reviewed including zeta Aurigae and VV Cephei stars, mu Sagittarii, epsilon Aurigae, beta Lyrae and the W Serpentis stars, symbiotic stars, and the Algols.

Plavec, M. J.↗

A High Binary Fraction for the Most Massive Close-in Giant Planets and Brown Dwarf Desert Members

Stellar multiplicity is believed to influence planetary formation and evolution, although the precise nature and extent of this role remain ambiguous. We present a study aimed at testing the role of stellar multiplicity in the formation and/or evolution of the most massive, close-in planetary and substellar companions. Using past and new direct imaging observations, as well as the Gaia DR2 catalogue, we searched for wide binary companions to 38 stars hosting massive giant planets or brown dwarfs (M > 7 MJup) on orbits shorter than ∼1 au. We report the discovery of a new component in the WASP-14 system, and present an independent confirmation of a comoving companion to WASP-18. From a robust Bayesian statistical analysis, we derived a binary fraction of per cent between 20 and 10 000 au for our sample, twice as high as for field stars with a 3σ significance. This binary frequency was found to be larger than for lower-mass planets on similar orbits, and we observed a marginally higher binary rate for inner companions with periods shorter than 10 d. These results demonstrate that stellar companions greatly influence the formation and/or evolution of these systems, suggesting that the role played by binary companions becomes more important for higher-mass planets, and that this trend may be enhanced for systems with tighter orbits. Our analysis also revealed a peak in binary separation at 250 au, highlighting a shortfall of close binaries among our sample. This indicates that the mechanisms affecting planet and brown dwarf formation or evolution in binaries must operate from wide separations, although we found that the Kozai–Lidov mechanism is unlikely to be the dominant underlying process. We conclude that binarity plays a crucial role in the existence of very massive short-period giant planets and brown dwarf desert inhabitants, which are almost exclusively observed in multiple systems.

C Fontanive↗

Effect of anisotropic thermal conductivity on the morphological stability of a binary alloy

A linear morphological stability analysis is presented for a planar interface during unidirectional solidification of a binary alloy, in the case of a crystal having an anisotropic thermal conductivity. A dispersion relation shows that the onset of instability depends on the orientation of the growth direction with respect to principal crystallographic axes and on the orientation of the wavevector of the perturbation. The onset of instability can be either oscillatory (traveling waves) or nonoscillatory in time. For growth along a principal axis of the crystal there is an exchange of stabilities, and the onset of instability is nonoscillatory.

Coriell, S. R.↗

The new eclipsing magnetic binary system E 1114 + 182

A comprehensive analysis of E 1114 + 182, the first eclipsing AM Herculis binary system and the shortest-period eclipsing cataclysmic variable known, is presented. The time-resolved X-ray observations which led to the system's recognition as an AM Her system with a roughly 90 minute orbital period are reported. The current optical photometric and polarimetric ephemeris and a description of the system's phase-modulated properties are given. The detailed photometric eclipse profile and the highly variable spectroscopic behavior are addressed. This information is used to determine systemic parameters and derive new information on the line emission regions. The data put severe constraints on current torque models for keeping the binary and white dwarf rotation in phase.

Biermann, P.↗

Rotational Properties of the Binary and Non-Binary Populations in the Trans-Neptunian Belt

We present results for the short-term variability of binary trans-Neptunian objects (BTNOs). We performed CCD photometric observations using the 3.58 m Telescopio Nazionale Galileo (TNG), the 1.5 m Sierra Nevada Observatory (OSN) telescope, and the 1.23 m Centro Astronómico Hispano Alemán (CAHA) telescope at Calar Alto Observatory. We present results based on five years of observations and report the short-term variability of six BTNOs. Our sample contains three classical objects: (174567) 2003 MW12, or Varda, (120347) 2004 SB60, or Salacia, and 2002 VT130; one detached disk object: (229762) 2007 UK126; and two resonant objects: (341520) 2007 TY430 and (38628) 2000 EB173, or Huya. For each target, possible rotational periods and/or photometric amplitudes are reported. We also derived some physical properties from their light curves, such as density, primary and secondary sizes, and albedo. We compiled and analyzed a vast light curve database for TNOs including centaurs to determine the light-curve amplitude and spin frequency distributions for the binary and non-binary populations. The mean rotational periods, from the Maxwellian fits to the frequency distributions, are 8.63 plus or minus 0.52 hours for the entire sample, 8.37 plus or minus 0.58 hours for the sample without the binary population, and 10.11 plus or minus 1.19 hours for the binary population alone. Because the centaurs are collisionally more evolved, their rotational periods might not be so primordial. We computed a mean rotational period, from the Maxwellian fit, of 8.86 plus or minus 0.58 hours for the sample without the centaur population, and of 8.64 plus or minus 0.67 hours considering a sample without the binary and the centaur populations. According to this analysis, regular TNOs spin faster than binaries, which is compatible with the tidal interaction of the binaries. Finally, we examined possible formation models for several systems studied in this work and by our team in previous papers.

photometric↗