Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “analytical techniques”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Analytical Techniques for Retrieval of Atmospheric Composition with the Quadrupole Mass Spectrometer of the Sample Analysis at Mars Instrument Suite on Mars Science Laboratory

The Sample Analysis at Mars (SAM) instrument suite is the largest scientific payload on the Mars Science Laboratory (MSL) Curiosity rover, which landed in Mars׳ Gale Crater in August 2012. As a miniature geochemical laboratory, SAM is well-equipped to address multiple aspects of MSL׳s primary science goal, characterizing the potential past or present habitability of Gale Crater. Atmospheric measurements support this goal through compositional investigations relevant to martian climate evolution. SAM instruments include a quadrupole mass spectrometer, a tunable laser spectrometer, and a gas chromatograph that are used to analyze martian atmospheric gases as well as volatiles released by pyrolysis of solid surface materials (Mahaffy et al., 2012). This report presents analytical methods for retrieving the chemical and isotopic composition of Mars׳ atmosphere from measurements obtained with SAM׳s quadrupole mass spectrometer. It provides empirical calibration constants for computing volume mixing ratios of the most abundant atmospheric species and analytical functions to correct for instrument artifacts and to characterize measurement uncertainties. Finally, we discuss differences in volume mixing ratios of the martian atmosphere as determined by SAM (Mahaffy et al., 2013) and Viking (Owen et al., 1977, Oyama and Berdahl, 1977) from an analytical perspective. Although the focus of this paper is atmospheric observations, much of the material concerning corrections for instrumental effects also applies to reduction of data acquired with SAM from analysis of solid samples.

quadropole mass spectometer↗
NASA NTRS1975

Spectroscopic analysis of solar and cosmic X-ray spectra. 1: The nature of cosmic X-ray spectra and proposed analytical techniques

Techniques for the study of the solar corona are reviewed as an introduction to a discussion of modifications required for the study of cosmic sources. Spectroscopic analysis of individual sources and the interstellar medium is considered. The latter was studied via analysis of its effect on the spectra of selected individual sources. The effects of various characteristics of the ISM, including the presence of grains, molecules, and ionization, are first discussed, and the development of ISM models is described. The expected spectral structure of individual cosmic sources is then reviewed with emphasis on supernovae remnants and binary X-ray sources. The observational and analytical requirements imposed by the characteristics of these sources are identified, and prospects for the analysis of abundances and the study of physical parameters within them are assessed. Prospects for the spectroscopic study of other classes of X-ray sources are also discussed.

Walker, A. B. C., Jr.↗
NASA NTRS2015

New Insights into Amino Acid Preservation in the Early Oceans Using Modern Analytical Techniques

Protein- and non-protein-amino acids likely occupied the oceans at the time of the origin and evolution of life. Primordial soup-, hydrothermal vent-, and meteoritic-processes likely contributed to this early chemical inventory. Prebiotic synthesis and carbonaceous meteorite studies suggest that non-protein amino acids were likely more abundant than their protein-counterparts. Amino acid preservation before abiotic and biotic destruction is key to biomarker availability in paleoenvironments and remains an important uncertainty. To constrain primitive amino acid lifetimes, a 1992 archived seawater/beach sand mixture was spiked with D,L-alanine, D,L-valine (Val), alpha-aminoisobutyric acid (alpha-AIB), D,L-isovaline (Iva), and glycine (Gly). Analysis by high performance liquid chromatography with fluorescence detection (HPLC-FD) showed that only D-Val and non-protein amino acids were abundant after 2250 days. The mixture was re-analyzed in 2012 using HPLC-FD and a triple quadrupole mass spectrometer (QqQ-MS). The analytical results 20 years after the inception of the experiment were strikingly similar to those after 2250 days. To confirm that viable microorganisms were still present, the mixture was re-spiked with Gly in 2012. Aliquots were collected immediately after spiking, and at 5- and 9-month intervals thereafter. Final HPLC-FD/QqQ-MS analyses were performed in 2014. The 2014 analyses revealed that only alpha-AIB, D,L-Iva, and D-Val remained abundant. The disappearance of Gly indicated that microorganisms still lived in the mixture and were capable of consuming protein amino acids. These findings demonstrate that non-protein amino acids are minimally impacted by biological degradation and thus have very long lifetimes under these conditions. Primitive non-protein amino acids from terrestrial synthesis, or meteorite in-fall, likely experienced great-er preservation than protein amino acids in paleo-oceanic environments. Such robust molecules may have reached a steady state concentration dependent on ocean circulation through hydrothermal systems and synthetic input processes. We are presently trying to estimate this concentration.

Parker, Eric T.↗
NASA NTRS1967

Analytical technique permits comparison of reliability of alternate mechanical designs

Failure Rate Index analysis permits comparison of reliability of alternate mechanical designs. All failure modes for a mechanical component are identified, and computed on an index which relates the failure mode to failure of the component. The summation of all failure mode indexes relates the potential reliability of the component.

Henning, F. W.↗
NASA NTRS1974

Analytical techniques and instrumentation, a compilation

Procedures for conducting materials tests and structural analyses of aerospace components are presented as a part of the NASA technology utilization program. Some of the subjects discussed are as follows: (1) failures in cryogenic tank insulation, (2) friction characteristics of graphite and graphite-metal combinations, (3) evaluation of polymeric products in thermal-vacuum environment, (4) erosion of metals by multiple impacts with water, (5) mass loading effects on vibrated ring and shell structures, (6) nonlinear damping in structures, and (7) method for estimating reliability of randomly excited structures.

Source record↗
NASA NTRS1974

Analytical techniques and instrumentation: A compilation

Technical information on developments in instrumentation is arranged into four sections: (1) instrumentation for analysis; (2) analysis of matter; (3) analysis of electrical and mechanical phenomena; and (4) structural analysis. Patent information for two of the instruments described is presented.

Source record↗
NASA NTRS1974

Analytical techniques for identification and study of organic matter in returned lunar samples

The results of geochemical research are reviewed. Emphasis is placed on the contribution of mass spectrometric data to the solution of specific structural problems. Information on the mass spectrometric behavior of compounds of geochemical interest is reviewed and currently available techniques of particular importance to geochemistry, such as gas chromatograph-mass spectrometer coupling, modern sample introduction methods, and computer application in high resolution mass spectrometry, receive particular attention.

Burlingame, A. L.↗
NASA NTRS1974

Instrumental and analytic techniques for separating protons from electrons in the cosmic ray flux

Techniques are being investigated to aid in distinguishing between electrons and the large background of interacting protons which simulate electron-induced electromagnetic cascades. For cosmic ray primaries, incident on the HECRE ionization spectrometer, statistical criteria are employed to test the cascade curves with the incident energy and starting point as free parameters. The physical significance of the distribution of apparent cascade starting points is being studied using Monte Carlo 100-GeV protons. The proposed use of a CsI detector module (totally-active and high Z) to further discriminate against protons is described.

Crannell, C. J.↗
NASA NTRS1976

Spectroscopic analysis of solar and cosmic X-ray spectra. I - The nature of cosmic X-ray spectra and proposed analytical techniques

X-ray spectroscopic techniques developed in the study of the temperature and density structure of the solar corona are reviewed as introduction to a discussion of the modifications in these techniques which will be required for the study of cosmic X-ray sources. The structure of the interstellar medium - the presence of interstellar grains, the presence of molecules, the ionization structure - are considered in relation to the X-ray opacity of the interstellar medium. The expected spectral structure of individual cosmic X-ray sources is reviewed with emphasis on galactic supernova remnants and galactic binary X-ray sources.

Walker, A. B. C., Jr.↗
NASA NTRS1978

Analytical techniques for the study of some parameters of multispectral scanner systems for remote sensing

The author has identified the following significant results. The concept of average mutual information in the received spectral random process about the spectral scene was developed. Techniques amenable to implementation on a digital computer were also developed to make the required average mutual information calculations. These techniques required identification of models for the spectral response process of scenes. Stochastic modeling techniques were adapted for use. These techniques were demonstrated on empirical data from wheat and vegetation scenes.

Wiswell, E. R.↗
NASA NTRS1978

Comparison of several NASTRAN analytical techniques for large structures

In order to plan for the finite element structural analysis of future aircraft, five static analysis techniques using the MacNeal-Schwendler Corporation version of NASTRAN were evaluated. The structure was analyzed as: (1) a single model with a symmetric loading condition; (2) a single model with symmetric/nonsymmetric loading conditions; (3) three substructures in three phases using tape storage with a symmetric loading condition; (4) three superelements using data base storage with a symmetric loading condition; and (5) three superelements using data base storage with cyclic symmetry for symmetric/nonsymmetric loading conditions. The superelement techniques proved superior to the single model approaches by reducing computer time for redesign work by as much as 70 percent.

Zemer, D. T.↗