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At least 55 records · Page 3

Ultra-clear Aerogels for Insulated Glass in Refrigeration Doors (CRADA Final Report)

Display refrigerators commonly employ glass doors to provide product visibility; however, these doors exhibit significantly poorer thermal insulation than solid doors, resulting in increased heat transfer and higher energy consumption. To address this limitation, this project investigated the use of silica aerogel as a transparent insulating medium for refrigerator glass doors, with the objective of enhancing thermal performance without compromising visual clarity. In Phase I of the project, we assessed the feasibility of silica aerogel insulation through laboratory and full-scale studies, including material characterization, durability testing, and heat transfer measurements, along with the development and performance evaluation of prototype glass doors under realistic operating conditions. In Phase II, the project focused on scaling the technology toward practical deployment. This included scaling up the manufacturing process to achieve a surface area roughly 20 times larger for commercial applications, developing full-scale prototypes that integrated silica aerogel into standard display refrigerator doors, and conducting field evaluations to assess thermal performance, energy savings, and operational durability under real-world conditions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

An Overview of SBIR Phase 2 Materials Structures for Extreme Environments

Technological innovation is the overall focus of NASA's Small Business Innovation Research (SBIR) program. The program invests in the development of innovative concepts and technologies to help NASA's mission directorates address critical research and development needs for agency projects. This report highlights innovative SBIR Phase II projects from 2007-2012 specifically addressing Areas in Materials and Structures for Extreme Environments which is one of six core competencies at NASA Glenn Research Center. There are twenty three technologies featured with emphasis on a wide spectrum of applications such as fine-filament superconductor wire, composite oxide cathode materials, nano-composites, high radiation solar cell, wrapped multilayer insulation, thin aerogel, and much more. Each article in this booklet describes an innovation, technical objective, and highlights NASA commercial and industrial applications. This report serves as an opportunity for NASA personnel including engineers, researchers, and program managers to learn of NASA SBIR's capabilities that might be crosscutting into this technology area. As the result, it would cause collaborations and partnerships between the small companies and NASA Programs and Projects resulting in benefit to both SBIR companies and NASA.

nano composites↗

NASA Tech Briefs, July 2012

Topics covered include: Instrument Suite for Vertical Characterization of the Ionosphere-Thermosphere System; Terahertz Radiation Heterodyne Detector Using Two-Dimensional Electron Gas in a GaN Heterostructure; Pattern Recognition Algorithm for High-Sensitivity Odorant Detection in Unknown Environments; Determining Performance Acceptability of Electrochemical Oxygen Sensors; Versatile Controller for Infrared Lamp and Heater Arrays; High-Speed Scanning Interferometer Using CMOS Image Sensor and FPGA Based on Multifrequency Phase-Tracking Detection; Ultra-Low-Power MEMS Selective Gas Sensors; Compact Receiver Front Ends for Submillimeter-Wave Applications; Dynamically Reconfigurable Systolic Array Accelerator; Blocking Losses With a Photon Counter; Motion-Capture-Enabled Software for Gestural Control of 3D Mod; Orbit Software Suite; CoNNeCT Baseband Processor Module Boot Code SoftWare (BCSW); Trajectory Software With Upper Atmosphere Model; ALSSAT Version 6.0; Employing a Grinding Technology to Assess the Microbial Density for Encapsulated Organisms; Demonstration of Minimally Machined Honeycomb Silicon Carbide Mirrors; Polyimide Aerogel Thin Films; Nanoengineered Thermal Materials Based on Carbon Nanotube Array Composites; Composite Laminate With Coefficient of Thermal Expansion Matching D263 Glass; Robust Tensioned Kevlar Suspension Design; Focal Plane Alignment Utilizing Optical CMM; Purifying, Separating, and Concentrating Cells From a Sample Low in Biomass; Virtual Ultrasound Guidance for Inexperienced Operators; Beat-to-Beat Blood Pressure Monitor; Non-Contact Conductivity Measurement for Automated Sample Processing Systems; An MSK Radar Waveform; Telescope Alignment From Sparsely Sampled Wavefront Measurements Over Pupil Subapertures; Method to Remove Particulate Matter from Dusty Gases at Low Pressures; Terahertz Quantum Cascade Laser With Efficient Coupling and Beam Profile; Measurement Via Optical Near-Nulling and Subaperture Stitching; 885-nm Pumped Ceramic Nd:YAG Master Oscillator Power Amplifier Laser System; Airborne Hyperspectral Imaging System; Heat Shield Employing Cured Thermal Protection Material Blocks Bonded in a Large-Cell Honeycomb Matrix; and Asymmetric Supercapacitor for Long-Duration Power Storage.

Source record↗

Next Generation Life Support: High Performance EVA Glove

The objectives of the High Performance EVA Glove task are to develop advanced EVA gloves for future human space exploration missions and generate corresponding standards by which progress may be quantitatively assessed. New technologies and manufacturing techniques will be incorporated into the new gloves to address finger and hand mobility, injury reduction and durability in nonpristine environments. Three prototypes will be developed, each focusing on different technological advances. A robotic assist glove will integrate a powered grasping system into the current EVA glove design to reduce astronaut hand fatigue and hand injuries. A mechanical counter pressure (MCP) glove will be developed to further explore the potential of MCP technology and assess its capability for countering the effects of vacuum or low pressure environments on the body by using compression fabrics or materials to apply the necessary pressure. A gas pressurized glove, incorporating new technologies, will be the most flight-like of the three prototypes. Advancements include the development and integration of aerogel insulation, damage sensing components, dust-repellant coatings, and dust tolerant bearings.

Walsh, Sarah K.↗

Meta-aerogels: Auxetic Shape-memory Polyurethane Aerogels

Shape-memory poly(isocyanurate-urethane) (PIR-PUR) aerogels are low-density monolithic nanoporous solids that remember and return to their permanent shape through a heating actuation step. Herein, through structural design at the macro scale, the shape-memory response is augmented with an auxetic effect manifested by a negative Poisson’s ratio of approximately -0.8 at 15% compressive strain. Thus, auxetic shape-memory PIR-PUR monoliths experience volume contraction upon compression at a temperature above the glass transition temperature of the base polymer (Tg ~ 30 °C), and they can be stowed indefinitely in that temporary shape by cooling below Tg. By heating back above Tg, the compressed/shrunk form expands back to their original shape/size. This technology is relevant to a broad range of industries spanning the commercial, aeronautical, and aerospace sectors. The materials are referred to as meta-aerogels and their potential applications include minimally invasive medical devices, soft robotics, and in situations where volume is at a premium, as for example for storage of deployable space structures and planetary habitats during transport to the point of service.

Sadeq Malakooti↗

Microwave AeroGel Volatile Collector (MAGVC) Aerogel and Microwave Radiation Study

The MAGVC is a volatile extraction system that uses microwave radiation to sublimate and collect water trapped in regolith on the lunar surface It is comprised of: - Microwave source (magnetron) - Aerogel-insulated chamber (depicted as a dome) - Volatile storage system (depicted as 4 tanks) - Autonomous operating system

Aerogel↗

Electrically Conductive Amine Functionalized Reduced Graphite Oxide Foam for CO 2 Removal from the Air

Rapid regeneration of CO 2 adsorbents is critical to improving the productivity of direct air capture (DAC) systems. In this study, we codesigned a material to have appropriate electrical conductivity and CO 2 adsorption properties to enable efficient CO 2 capture from air. Specifically, we present a poly(ethylenimine) (PEI)-impregnated thermally annealed graphite oxide (TAGO900) foam adsorbent tailored for vacuum-assisted electrically driven thermal swing adsorption (V-ETSA). This structured adsorbent leverages the high electrical conductivity of the reduced graphite oxide framework to enable fast and direct heating of the adsorbent material by electrical resistance heating (Joule heating). An optimal sample, 40 wt % PEI (molecular weight 25k) impregnated TAGO900, shows the best balance between adsorption capacity (1.54 mmol g –1 ) and adsorption rates (0.016 mmol g –1 min –1 ) using fixed bed breakthrough experiments at 25 °C and 70% RH using 50 sccm 400 ppm of CO 2 /N 2 flow. Compared to conventional temperature vacuum swing adsorption (TVSA), the V-ETSA approach achieves substantially faster CO 2 desorption, achieving average desorption rates (including cooling time) of 0.09 mmol g –1 min –1 ─approximately 2.5 times faster than TVSA under similar operating conditions. The maximum desorption rate reaches 0.23 mmol/g/min during the desorption stage. These results underscore the importance of the direct heating strategy, such as Joule heating, for fast and highly productive vacuum swing adsorption in DAC systems.

amines↗

Inexpensive and durable aerogel-based VIP cores

The goal of this project was development of low-cost aerogels to be used as cores of Vacuum Insulated Panels (VIP). The specific aims were: 1. Aerogels to be based on phenolic chemistry to minimize flammability. 2. Aerogels to be in monolithic form and to have mechanical properties sufficient to allow their use as cores of VIPs without collapsing after evacuation. 3. Aerogels to have a cost per kg lower than the cost of fumed silica, one of the most common VIP cores. The achievements are: 1. Phenolic aerogels have been fabricated in monolithic form with thermal conductivity of 0.023 W/m·K, density ~ 0.25 g/cm 3 and a modulus of compression > 10 MPa. The aerogels can withstand the stresses of VIP evacuation without any appreciable deformation. 2. Drying of aerogels was carried in the initial stages of the project via sublimation of frozen solvents, following the procedure described in M. F. Bertino and T. Selden, “Fabrication of Aerogels and Aerogel Composites by Ambient Pressure Sublimation of Frozen Solvents”, PCT/US20/39485. Monoliths as large as 30 x 30 x 2 cm can be fabricated with the proprietary ambient fabrication technique which are free of cracks and warping. 3. Cost analysis was carried out and refined multiple times, cost drivers were identified, and the fabrication procedure was streamlined. Our cost model yields an aerogel cost of $\$$5.78/kg, which compares well with the price of fumed silica ($\$$6.2/kg FOB New York as of March 2023). 4. The monoliths can be cut into custom shapes and used as VIP cores. Cores fabricated with our technique have a thermal conductivity λ = 0.011 W/m·K at a pressure >10 mbar. 5. A variant of the technology yielded fireproof materials, described in M. F. Bertino, T. Moon, G. Waller, J. Ko and D. Clifford, “Fireproof thermal insulation”, Provisional Patent Application 63/415,386. 6. A spin-off company was created (ThermaGel Innovations, Inc.) which licensed technologies developed under this award. PI Bertino is a board member of the newco which is now raising capital to build a pilot plant.

36 MATERIALS SCIENCE↗

Solid-State Thermodynamic Vent System (STVS) for Control of Cryogenic Propellants

A Solid-State Thermodynamic Vent System (STVS) is a novel Cryogenic Fluid Management (CFM) technology for spacecraft cryogenic propellant tanks that may reduce boiloff while providing greater control over the propellant condition. By exploiting the vacuum-induced cryocooling (VIC) potential of cryogen-saturated silica aerogel material, an internal STVS heat exchanger (HX) can expel some sacrificial cryogenic propellant to the vacuum of space to produce cooling within the storage tank. This cooling is transferred directly to the stored fluid, thereby reducing boiloff and increasing hold times. Testing proved the effectiveness of the concept by reducing the liquid nitrogen (LN 2 ) boiloff rate and tank pressure by roughly 70% and 77%, respectively, during a single pump-down cycle, which sacrificed around 1.8 kg of propellant.

Cryogenic Fluid↗

Polymer Crosslinked 3-D Assemblies of Nanoparticles: Mechanically Strong Lightweight Porous Materials

In analogy to supramolecular assemblies, which are pursued because of properties above and beyond those of the individual molecules, self-standing monolithic three-dimensional assemblies of nanoparticles also have unique properties attributed to their structure. For example, ultra low-density 3-D assemblies of silica nanoparticles, known as silica aerogels, are characterized by large internal void space, high surface area and very low thermal conductivity. Aerogels, however, are also extremely fragile materials, limiting their application to a few specialized environments, e.g., in nuclear reactors as Cerenkov radiation detectors, in space (refer to NASA's Stardust Program) and aboard certain planetary vehicles (thermal insulators on Mars Rovers in 1997 and 2004). The fragility problem is traced to well-defined weak points in the aerogel skeletal framework, the interparticle necks. Using the surface functionality of the nanoparticle building blocks as a focal point, we have directed attachment of a conformal polymer coating over the entire framework, rendering all necks wider. Thus, although the bulk density may increase only by 3x, the mesoporosity (pores in the range 2-50 nm) remains unchanged, while the strength of the material increases by up to 300... Having addressed the fragility problem, aerogels are now robust materials, and a variety of applications, ranging from thermal/acoustic insulators to catalyst supports, to platform for sensors, and dielectrics are all within reach. Our approach employs molecular science to manipulate nanoscopic matter for achieving useful macroscopic properties, and in our view it resides at the core of what defines nanotechnology. In that spirit, this technology is expandable in three directions. Thus, we have already crosslinked successfully amine-modified silica, and we anticipate that more rich chemistry will be realized by been creative with the nanoparticle surface modifiers. On the other hand, although we do not expect orders-of-magnitude increase in strength, nevertheless, by varying the polymer we expect to impart other properties such as hydrophobicity, thermal stability and perhaps electrical conductivity. Besides polymers, crosslinkers will include metals and ceramics (e.g., through POSS precursors). Finally, network morphology directs load dissipation, and of approximately 30 different crosslinked oxide aerogels, vanadia, whose structure is fibrous rather than particulate, yields a much stronger (by 4..) material than silica of the same density. It seems imperative to implement control of network morphology, even through templating.

Leventis, Nicholas↗

The Non-Destructive Separation of Diverse Astrobiologically Relevant Organic Molecules By Customizable Capillary Zone Electrophoresis and Monolithic Capillary Electrochromatography

The in situ detection of organic molecules in space is key to understanding the variety and the distribution of the building blocks of life, and possibly the detection of extraterrestrial life itself. Gas chromatography mass spectrometry (GC-MS) has been the most sensitive analytical instrument for organic analyses in flight, and was used on missions from NASA’s Viking, Phoenix, Curiosity missions to ESA’s Rosetta space probe. While pyrolysis GC-MS revealed the first organics on Mars, this step alters or degrades certain fragile molecules that are excellent biosignatures including polypeptides, oligonucleotides and polysaccharides, rendering the intact precursors undetectable. We have identified a solution tailored to the detection of biopolymers and other biomarkers by the use of liquid-based capillary electrophoresis and electrochromatography. In this study, we show that a capillary electrochromatography (CEC) approach using monolithic stationary phases with tailor-made surface chemistry can separate and identify various polycyclic aromatic hydrocarbons (PAHs), nucleobases and aromatic acids that could be formed under astrophysically relevant conditions. In order to simulate flyby organic sample capture, we conducted hypervelocity impact experiments which consisted of accelerating peptide-soaked montmorillonite particles to a speed of 5.6 km/sec, and capturing them in an amorphous silica aerogel of 10 and 30 mg/cc bulk density. Bulk peptide extraction from aerogel followed by capillary zone electrophoresis led to the detection of only two stereoisomeric peptide peaks. The recovery rates of each step of the extraction procedure after the hypervelocity impact suggest that major peptide loss occurred during the impact. Our study provides initial exploration of feasibility of this approach for capturing intact peptides, and subsequently detecting candidate biomolecules during flight missions that would be missed by GC-MS alone. As the monolith-based electrochromatography technology could be customized to detect specific classes of compounds as well as miniaturized, these results demonstrate the potential of the instrumentation for future astrobiology-related spaceflight missions.

Flyby sample return↗

Incorporation of alpha-Ketoglutaric Acid as a Fixed Bed Scrubber Media for the Neutralization of Hydrazine Family Hypergolic Fuels

A candidate scrubber media, alpha-ketoglutaric acid (aKGA) adsorbed onto a silica-based substrate was examined as a potential alternative to the hydrazine-family hypergolic fuel neutralization techniques currently utilized at NASA/Kennedy Space Center (KSC). Helvenson et. al. has indicated that aKGA will react with hydrazines to produce non-hazardous, possibly biodegradable products. Furthermore, the authors have previously tested and demonstrated the use of aKGA aqueous solutions as a replacement neutralizing agent for citric acid, which is currently used as a scrubbing agent in liquid scrubbers at KSC. Specific properties examined include reaction efficiency, the loading capacity of aKGA onto various silica substrates, and the comparison of aKGA media performance to that of the citric acid vapor scrubber systems at KSC and a commercial vapor scrubber media. Preliminary investigations showed hydrophobic aerogel particles to be an ideal substrate for the deposition of the aKGA. Current studies have shown that the laboratory produced aKGA-Aerogel absorbent media are more efficient and cost effective than a commercially available fixed bed scrubber media, although much less cost effective than liquid-based citric acid scrubbers (although possibly safer and less labor intensive). A comparison of all three alternative scrubber technologies (liquid aKGA, solid-phase aKGA, and commercially available sorbent materials) is given considering both hypergolic neutralization capabilities and relative costs (as compared to the current citric acid scrubbing technology in use at NASA/KSC).

DeVor, R. W.↗

Asteroids and Comets Outreach Compilation

Contents include various different animations in the area of Asteroids and Comets. Titles of the short animated clips are: STARDUST Mission; Asteroid Castallia Impact Simulation; Castallia, Toutatis and the Earth; Simulation Asteroid Encounter with Earth; Nanorover Technology Task; Near Earth Asteroid Tracking; Champollian Anchor Tests; Early Views of Comets; Exploration of Small Bodies; Ulysses Resource Material from ESA; Ulysses Cometary Plasma Tail Animation; and various discussions on the Hale-Bopp Comet. Animation of the following are seen: the Stardust aerogel collector grid collecting cometary dust particles, comet and interstellar dust analyzer, Wiper-shield and dust flux monitor, a navigation camera, and the return of the sample to Earth; a comparison of the rotation of the Earth to the Castallia and Tautatis Asteroids; an animated land on Tautatis and the view of the motion of the sky from its surface; an Asteroid collision with the Earth; the USAF Station in Hawaii; close-up views of asteroids; automatic drilling of the Moon; exploding Cosmic Particles; and the dropping off of the plasma tail of a comet as it travels near the sun.

Source record↗

Conformal Lightweight Antenna Structures for Aeronautical Communication Technologies

This project is to develop antennas which enable beyond line of sight (BLOS) command and control for UAVs. We will take advantage of newly assigned provisional Ku-band spectrum for UAVs and use unique antenna designs to avoid interference with ground systems. This will involve designing antennas with high isotropic effective radiated power (EIRP) and ultra-low sidelobes. The antennas will be made with polymer aerogel as a substrate to both reduce weight and improve performance, as demonstrated in an Aero Seedling. In addition, designing the antennas to be conformal to the aircraft fuselage will reduce drag.

antennas↗

Conformal Lightweight Antenna Structures for Aeronautical Communication Technologies

This project developed an antenna to enable beyond line of sight (BLOS) command and control for small UAVs. We took advantage of a newly assigned provisional Ku-band spectrum for UAVs and used unique antenna design to avoid interference with ground systems. This required the design of an antenna with high isotropic effective radiated power (EIRP) and ultra-low sidelobes. The antenna was made with polymer aerogel as a substrate to both reduce weight and improve performance, as demonstrated in an Aero Seedling. In addition, designing the antennas to be conformal to the aircraft fuselage will reduce drag.

polyimide↗

Conformal Lightweight Antenna Structures for Aeronautical Communication Technologies

This project is to develop antennas which enable beyond line of sight (BLOS) command and control for UAVs (Unmanned Aerial Vehicles). We will take advantage of newly assigned provisional Ku-band spectrum for UAVs and use unique antenna designs to avoid interference with ground systems. This will involve designing antennas with high isotropic effective radiated power (EIRP) and ultra-low sidelobes. The antennas will be made with polymer aerogel as a substrate to both reduce weight and improve performance, as demonstrated in an Aero Seedling. In addition, designing the antennas to be conformal to the aircraft fuselage will reduce drag.

aerogels↗