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At least 55 records · Page 3

Characterization of as-welded microstructure of heat-affected zone in modified 9Cr–1Mo–V–Nb steel weldment

Non-equilibrium microstructure of the heat-affected zone (HAZ) in the as-welded modified 9Cr–1Mo–V–Nb pipe steel (P91) weldment deposited by gas tungsten arc welding (GTAW) and flux core arc welding (FCAW) has been characterized by field-emission scanning electron microscope (FESEM) and electron backscatter diffraction (EBSD). The heterogeneous structures in the sub-layers of the as-welded HAZ are attributable to phase transformations caused by the welding thermal cycles and the local structure variations in the as-received base metal. Coarse-grained heat-affected zone (CGHAZ) has a prior austenite grain (PAG) size of 20 μm. Fine uniformly-distributed precipitates and a higher fraction of MX carbonitrides are observed in the CGHAZ. Fine-grained heat-affected zone (FGHAZ) consists of the finest grains (1.22 μm measured by EBSD, 5 μm PAG size), coarse undissolved M{sub 23}C{sub 6} carbides within the PAG boundaries and fine nucleated M{sub 23}C{sub 6} particles within the martensite laths. Inter-critical heat-affected zone (ICHAZ) consists of partially austenitized grains and over-tempered martensite laths. EBSD kernel average misorientation (KAM) map in the FGHAZ close to the ICHAZ illustrates the greatest local strain variations with a moderate normalized KAM value of 0.92°. The majority (88.1%) of the matrix grains in the CGHAZ are classified as deformed grains by EBSD grain average misorientation (GAM) evaluation. The FGHAZ close to the ICHAZ has the most recrystallized grains with an area fraction of 14.4%. The highest density variation of precipitates within grains in the FGHAZ originates from the inhomogeneous chemistry in the base metal. - Highlights: •A comprehensive characterization of the as-welded HAZ of P91 weldment is conducted. •Structural features in the each layer of the HAZ are quantified by EBSD. •Structural heterogenities in HAZ are due to welding cycle and base metal structure. •FGHAZ contains the finest grain structure and largest precipitate density variation.

36 MATERIALS SCIENCE↗

Water chemistry in flume channel and hyporheic zone (i.e., porewater) associated with: “Rethinking Aerobic Respiration in the Hyporheic Zone Under Variation in Carbon and Nitrogen Stoichiometry”

Dissolved oxygen (DO), total organic carbon (TOC), total nitrogen (TN), molecular data for organic matter, and biochemical reactions for surface water and porewater (i.e., hyporheic zone) collected from a water recirculating flume located at the University of Texas, Austin. The flume contained real river water from Lower Colorado River(Austin, TX) and clean sand. Hyporheic exchange in the flume was induced through The study aims to understand relationships between aerobic metabolism of organic matter and molecular characteristics of organic matter, such as thermodynamic signature and nitrogen content, through the extent of the hyporheic zone at 10 cm- resolution, and through time. During the experiment, organic matter (dry leaves) was added to the flume and removed after 24 hours. The water samples were collected before the addition of leaves, at the time of removal of leaves, and at hour 72. The water samples were analyzed using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) and total organic carbon (TOC) and total nitrogen (TN) analysis. Dissolved oxygen content throughout the surface water and the hyporheic zone of the flume was measured with a large planar optode. This data package is associated with the publication ’ Rethinking Aerobic Respiration in the Hyporheic Zone Under Variation in Carbon and Nitrogen Stoichiometry’ published in Environmental Science and Technology (Turețcaia et al., 2023 https://doi.org/10.1021/acs.est.3c04765). The dataset is comprised of five folders (1) Diss_O2_pic, (2) input_files (3) output_files; (4) python_code; and (5) R_code . Diss_O2_pic contains siximages of dissolved oxygen distribution in a bedform at hours 0, 24, and 72 of the experiment conducted in a large recirculation flume. Images are in separate R and G channels (i.e., RGB). The input_files contains (1) a csv file with FTICR peaks identified within each sample, (2) a csv file with molecular information pertinent to FTICR data with Gibbs free energy calculations adjusted for environmental temperature, (3) a csv file containing concentrations of non-purgeable organic carbon measured throughout the experiment , (4) a csv file containing concentrations of total nitrogen measured throughout the experiment, (5) a csv file containing total biochemical reactions (i.e., transformations) identified in the dataset, (6) a csv containing transformation profiles, and (7) a csv file containing transformations with formulas, and (8) a jpg file with schematic representation of locations for sample collection. The output_files contains (1) and xlsx file containing percent biochemical reactions containing nitrogen identified across all 39 sample, (2) a csv file of merged FTICR data and molecular information files, (3) a csv files containing average Gibbs free energy within sampling domains and at each sampling location, (4) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 0, (5) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 24, (6) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 72, (7) a csv file with percent chemical classes identified across sampling locations at hour 0, (8) a csv file with percent chemical classes identified across sampling locations at hour 24, (9) a csv file with percent chemical classes identified across sampling locations at hour 72, and (10) a csv file containing percent nitrogen containing biochemical reactions identified across sampling locations at hours 0, 24, and 72. The python_code contains seven ipynb files which are Jupyter Notebooks used for data analysis and figures generation. The R_code contains 3 R files with R code used for data analysis and figures generation. This data package contains the processed data used in the associated manuscript. This data has not been previously published.

54 ENVIRONMENTAL SCIENCES↗

Bending of an Isotropic Plate with Two Identical Coaxial Through Cracks Depending on the Width of the Contact Zone of Their Faces and in the Presence of Plastic Zones Near Their Tips

We formulate and solve the problem of biaxial bending of an isotropic plate with two coaxial through cracks of identical lengths by distributed bending moments applied at infinity under the action of external load symmetric about the cracks with regard for the contact zone of their faces and in the presence of plastic zones near the crack tips, where the Tresca plasticity conditions are satisfied in the form of a surface layer or a plastic hinge. By using complex potentials of the plane problem and the classical theory of bending of the plates, we obtain an analytic solution of the problem in the class of functions bounded in the vicinity of the vertices of the plastic zones. The length of the plastic zones and the crack-tip opening displacements are found numerically.

42 ENGINEERING↗

Uniform momentum and temperature zones in unstably stratified turbulent flows

Wall-bounded turbulent flows exhibit a zonal arrangement, in which streamwise velocity organizes into uniform momentum zones (UMZs), separated by thin layers of elevated interfacial shear. While significant research efforts have focused on these structural features in neutrally stratified flows, the effects of unstable thermal stratification on UMZs and on analogous uniform temperature zones (UTZs) have not been considered previously. In this article, statistical properties of UMZs and UTZs are investigated using a suite of large eddy simulations of unstably stratified turbulent channel flow spanning weakly to highly convective conditions. When normalized by the friction velocity and stability-dependent mixing length, the mean velocity gradient based on UMZ interfacial velocity jumps and the vorticity thickness exhibits good collapse for all stabilities, establishing a link between UMZ properties and scaling predictions from Monin–Obukhov similarity theory. A similar relationship is found between UTZ properties and surface-layer scaling of the mean temperature gradient. In the mixed layer, mean UMZ depth is quasi-constant with wall-normal distance, while the deepest UTZs are found in the centre of the boundary layer. These instantaneous structures are found to be linked to the well-mixed velocity and temperature profiles in the convective mixed layer. Conditional averaging indicates that both UMZ and UTZ interfaces are associated with ejections of momentum and warm updrafts below the interface and sweeps of momentum and cool downdrafts above the interface. These results demonstrate a tangible connection between instantaneous structural features, mean properties and scaling laws in unstably stratified flows.

Mechanics↗

HERSCHEL PACS AND SPIRE OBSERVATIONS OF BLAZAR PKS 1510-089: A CASE FOR TWO BLAZAR ZONES

We present the results of observations of blazar PKS 1510-089 with the Herschel Space Observatory PACS and SPIRE instruments, together with multiwavelength data from Fermi/LAT, Swift, SMARTS, and Submillimeter Array. The source was found in a quiet state, and its far-infrared spectrum is consistent with a power law with a spectral index of {alpha} {approx_equal} 0.7. Our Herschel observations were preceded by two 'orphan' gamma-ray flares. The near-infrared data reveal the high-energy cutoff in the main synchrotron component, which cannot be associated with the main gamma-ray component in a one-zone leptonic model. This is because in such a model the luminosity ratio of the external-Compton (EC) and synchrotron components is tightly related to the frequency ratio of these components, and in this particular case an unrealistically high energy density of the external radiation would be implied. Therefore, we consider a well-constrained two-zone blazar model to interpret the entire data set. In this framework, the observed infrared emission is associated with the synchrotron component produced in the hot-dust region at the supra-parsec scale, while the gamma-ray emission is associated with the EC component produced in the broad-line region at the sub-parsec scale. In addition, the optical/UV emission is associated with the accretion disk thermal emission, with the accretion disk corona likely contributing to the X-ray emission.

79 ASTRONOMY AND ASTROPHYSICS↗

GAMMA RAYS FROM THE TYCHO SUPERNOVA REMNANT: MULTI-ZONE VERSUS SINGLE-ZONE MODELING

Recent Fermi and VERITAS observations of the prototypical Type Ia supernova remnant (SNR) Tycho have discovered {gamma}-rays with energies E in the range 0.4 GeV {approx}< E {approx}< 10 TeV. Crucial for the theory of Galactic cosmic-ray origin is whether the {gamma}-rays from SNRs are produced by accelerated hadrons (protons and ions) or by relativistic electrons. Here we show that strong constraints on the leptonic model imposed in the framework of the commonly used single-zone model are essentially removed if the analysis of the broadband radiation spectrum of Tycho is done in the two-zone (or, in general, multi-zone) approach, which is likely to apply to every SNR. Importantly, we show that the single-zone approach may underpredict the {gamma}-ray fluxes by an order of magnitude. A hadronic model can, however, also fit the detected {gamma}-ray spectrum. The difference between {gamma}-ray fluxes of hadronic and leptonic origins becomes significant only at {approx}<300 MeV, which could be revealed by spectral measurements of Tycho and other SNRs at these energies.

79 ASTRONOMY AND ASTROPHYSICS↗

Temporal changes of seismic velocities in the San Jacinto Fault zone associated with the 2016 M w 5.2 Borrego Springs earthquake

We study temporal changes of seismic velocities associated with the 10 June 2016 Mw 5.2 Borrego Springs earthquake in the San Jacinto fault zone, using nine component Green's function estimates reconstructed from daily cross correlations of ambient noise. The analysed data are recorded by stations in two dense linear arrays, at Dry Wash (DW) and Jackass Flat (JF), crossing the fault surface trace ~3 km northwest and southeast of the event epicentre. The two arrays have 9 and 12 stations each with instrument spacing of 25–100 m. Relative velocity changes (δv/v) are estimated from arrival time changes in the daily correlation coda waveforms compared to a reference stack. The obtained array-average δv/v time-series exhibit changes associated with the Borrego Springs event, superposed with seasonal variations. The earthquake-related changes are characterized by a rapid coseismic velocity drop followed by a gradual recovery. This is consistently observed at both arrays using time- and frequency-domain δv/v analyses with data from different components in various frequency bands. Larger changes at lower frequencies imply that the variations are not limited to the near surface material. A decreasing coseismic velocity reduction with coda wave lapse time indicates larger coseismic structural perturbations in the fault zone and near-fault environment compared to the surrounding rock. Observed larger changes at the DW array compared to the JF array possibly reflect the northwestward rupture directivity of the Borrego Springs earthquake.

Geochemistry & Geophysics↗

Micrometeorite craters on lunar glass particles - The relationship between radial fracture zones and spall zones.

Discussion of the microimpact-crater morphology observed by scanning electron microscopy on a glass bead (nearly 580 microns in maximum diameter) recovered from zone A of the Luna 16 sample. The microcrater has a diameter of approximately 200 microns and a centrally located melted region or pit that is slightly elevated above the surrounding area. Around the pit is a radial fracture zone half of which has spalled off. The spall zone is more than half again as large as the radial fracture zone.

Glass, B. P.↗

Prediction of subsurface fracture in mining zone of Papua using passive seismic tomography based on Fresnel zone

Fracture prediction in a block cave of underground mine is very important to monitor the structure of the fracture that can be harmful to the mining activities. Many methods can be used to obtain such information, such as TDR (Time Domain Relectometry) and open hole. Both of them have limitations in range measurement. Passive seismic tomography is one of the subsurface imaging method. It has advantage in terms of measurements, cost, and rich of rock physical information. This passive seismic tomography studies using Fresnel zone to model the wavepath by using frequency parameter. Fresnel zone was developed by Nurhandoko in 2000. The result of this study is tomography of P and S wave velocity which can predict position of fracture. The study also attempted to use sum of the wavefronts to obtain position and time of seismic event occurence. Fresnel zone tomography and the summation wavefront can predict location of geological structure of mine area as well.

58 GEOSCIENCES↗

Geophysical Monitoring of Foam used to Deliver Remediation Treatments within the Vadose Zone

Foam is a promising vehicle for delivering amendments into the vadose zone for in situ remediation; it is an approach being considered for in situ treatment and stabilization of metals and radionuclides located within the deep vadose zone of the Department of Energy (DOE) Hanford site, WA. A central aspect of evaluating the effectiveness of this approach is the ability to monitor foam distribution, its transformation, and the reactions that it induces in the subsurface, ideally in a non-invasive manner. In this study, we performed laboratory experiments to evaluate the potential of geophysical methods (complex resistivity and time domain reflectometry, TDR) as tools for monitoring foam assisted amendment delivery in the deep vadose zone. Our results indicated great sensitivity of electrical methods to foam transportation and evolution in unsaturated porous media that were related to foam bubble coalescence and drainage processes. Specifically, we observed (1) a decrease of electrical resistivity (increase of electrical conductivity) by over an order of magnitude in both silica sand and natural sediment matrices during foam transportation; (2) an increase of resistivity (decrease of conductivity) by over two fold during foam coalescence and drainage; (3) a distinct phase and imaginary conductivity signature related to the evolution of water films on sediment grains during foam injection and evolution processes. To assist with the interpretation of these data, TDR measurements were used to monitor moisture content, which provided complementary information about foam distribution and drainage. Our results clearly demonstrated the sensitivity of electrical and TDR signals to foam transportation and evolution in unsaturated porous media and suggested the potential of these methods for monitoring the response of a system to foam based remediation treatments at field scales.

Hanford↗

Predicting High Energy Arcing Fault Zones of Influence for Aluminum Using an Arc Flash Modeling Approach: Evaluation of a model bias, uncertainty, parameter sensitivity and zone of influence estimation

This report documents the development of an arc flash hazard model to calculate the incident energy and zone of influence from high energy arcing faults involving aluminum. The NRC has identified the potential for (HEAFs) involving aluminum to increase the damage zone beyond what is currently postulated in fire probabilistic risk assessment (PRA) methodologies. To estimate the hazard from HEAFs involving aluminum an arc flash model was developed. Differences between the initial model and nuclear power plant (NPP) fire PRA scenarios were identified. Modification of the initial model established from existing literature and test data was used to minimize these differences. The developed model was evaluated against NRC datasets to understand the model prediction and relative uncertainties. Finally, a range of fire PRA zone of influences (ZOI) were developed based on the developed model, target fragility estimates and update HEAF PRA methodology. The results were developed to support an NRC LIC-504 evaluation in tandem with other modeling efforts. The report documents the effort and provides a reference for any future advancements in arc flash modeling.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Comparative compressibility of hydrous wadsleyite and ringwoodite: Effect of H 2 O and implications for detecting water in the transition zone: EFFECT OF WATER ON D K /D P OF WADSLEYITE

Review of recent mineral physics literature shows consistent trends for the influence of Fe and H 2 O on the bulk modulus (K0) of wadsleyite and ringwoodite, the major phases of Earth's mantle transition zone (410–660 km). However, there is little consensus on the first pressure derivative, K0' = (dK/dP)P=0, which ranges from about 4 to >5 across experimental studies and compositions. Here we demonstrate the importance of K0' in evaluating the bulk sound velocity of the transition zone in terms of water content and provide new constraints on the effect of H 2 O on K0' for wadsleyite and ringwoodite by conducting a comparative compressibility study. In the experiment, multiple crystals of hydrous Fo90 wadsleyite containing 2.0 and 0.25 wt % H 2 O were loaded into the same diamond anvil cell, along with hydrous ringwoodite containing 1.4 wt % H 2 O. By measuring their pressure-volume evolution simultaneously up to 32 GPa, we constrain the difference in K0' independent of the pressure scale, finding that H 2 O has no effect on K0', whereas the effect of H 2 O on K0 is significant. The fitted K0' values of hydrous wadsleyite (0.25 and 2.0 wt % H 2 O) and hydrous ringwoodite (1.4 wt % H 2 O) examined in this study were found to be identical within uncertainty, with K0' ~3.7(2). New secondary-ion mass spectrometry measurements of the H 2 O content of these and previously investigated wadsleyite samples shows the bulk modulus of wadsleyite is reduced by 7.0(5) GPa/wt % H 2 O, independent of Fe content for upper mantle compositions. Because K0' is unaffected by H 2 O, the reduction of bulk sound velocity in very hydrous regions of transition zone is expected to be on the order of 1.6%, which is potentially detectible in high-resolution, regional seismology studies.

58 GEOSCIENCES↗

Interface-Driven Plasticity: The Presence of an Interface Affected Zone in Metallic Lamellar Composites: The Presence of an Interface Affected Zone…

Large strain deformation is used to make fine nanolayered two-phase composites from stacks of conventional polycrystalline sheets. The final materials made by this technique possess a crystallographically highly oriented structure containing nearly atomically perfect interfaces prevailing ubiquitously throughout the material. How this ordered structure evolves with strain from the coarser, more disordered state is not known. Here, using microstructural analysis and computational modeling, we discover a local interface-affected zone (IAZ) possessing the same crystallographically sharp structure in coarse layered composites as the final nanolayered composites. This means that this strongly oriented interface “zone” survives the mechanical work and overtakes the structure as it refines to the nanoscale. In essence, through the formation of this interface zone, the crossover to a highly oriented nanostructure occurs. Using microstructural analysis and crystal plasticity simulations, we show that the IAZ is a consequence of slip accommodation at the interface. This insight is valuable for developing processing strategies for superior interface-dominated materials.

36 MATERIALS SCIENCE↗

Biaxial Bending of an Isotropic Plate with Through Rectilinear Crack with Regard for the Width of the Contact Zone of its Edges and in the Presence of Plastic Zones Near its Tips

We pose and solve the problem of the biaxial bending of an isotropic plate with through rectilinear crack by distributed bending moments applied at infinity. The edges of the crack are in contact over the zone of constant width and plastic zones are formed near the crack tips. By using the Tresca plasticity conditions in the form of a surface layer and a plastic hinge, we determine the length of the plastic zone and the crack opening displacements near the tips. The numerical analysis of the problem is performed.

42 ENGINEERING↗

Transition Zone Morphology Dynamics of Dissolved Oxygen (DO) in a Salinity-Impacted Hyporheic Zone

Freshwater salinization is a common yet underappreciated environmental problem in rivers, yet how this process impacts the transport of dissolved oxygen (DO) in the hyporheic zone remains unknown. Here, using flume experiments and numerical simulations, we have demonstrated that the morphological dynamics of the DO transition zone are controlled by the dimensionless number Da·Ra –2 , a measure of the rate of aerobic respiration to free convection. At low Da·Ra –2 , the oxic front breaks up into fingers which subsequently grow, and leads to accelerating of DO transport and shrinking of the anaerobic zone in the underlying sediment. As Da·Ra –2 increases, the growth rate of the instability decreases, and the DO plume fingers are suppressed and delayed compared with the saltwater-freshwater interface, the mixing area between saltwater and freshwater. These results indicate that the freshwater salinization syndrome can have significant impacts on the functioning of aquifer ecosystems unless regulated and managed effectively.

54 ENVIRONMENTAL SCIENCES↗