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DOE OSTI2024

Aluminosilicate colloidal gels: from the early age to the precipitation of zeolites

Aluminosilicate hydrogels are often considered to be precursors for the crystallisation of zeolites carried out under hydrothermal conditions. The preparation of mechanically homogeneous aluminosilicate gels enables the study of these materials through bulk rheology and observation of the aging dynamics until the precipitation of crystalline zeolites. The first part of this study deals with the establishment of ternary state diagrams, in order to identify the range of chemical formulations that enable preparation of single-phase homogeneous gels. Then, by studying the viscoelastic moduli during the gelation reaction, and by yielding the gel under large deformation, we propose an empirical law considering the partial order of reaction on each chemical element, to predict the gelation time according to the chemical formulation. The scaling behavior of the elastic properties of this colloidal gel shows a transition from a strong link behavior to a weak link regime. Long term aging results in the shrinkage of the gel, accompanied by syneresis of interstitial liquid at the surface. Zeolites precipitate through crystallisation by a particle attachment mechanism, when thermodynamic equilibrium is reached. The stoichiometry of the precipitated zeolites is not only consistent with the concentration of the remaining species in the supernatant but, surprisingly, it is also very close to the partial order of the reaction of the chemical elements involved in the determination of the critical gel point. This indicates a strong correlation between the morphology of the soft amorphous gel network that is formed at an early age and those of the final solid precipitated crystals.

36 MATERIALS SCIENCE↗

NASA NTRS2005

Diagnostics Adapted for Heat-Treating Furnace Environment

Diagnostics developed for the in situ monitoring of rocket combustion environments were adapted for use in heat-treating furnaces. Simultaneous, in situ monitoring of the carbon monoxide, carbon dioxide, methane, water, and hydrogen concentrations in the endothermic gas of a heat-treating furnace were demonstrated under a Space Act Agreement between the NASA Lewis Research Center, the Heat Treating Network, and Akron Steel Treating Company. This endothermic gas, or "endogas," is produced in a catalytic process, where natural gas is "cracked" in the presence of air. Variations in the composition of the natural gas supplied lead to variations in the composition of the endothermic gas. These variations could lead to an unacceptable quality of steel products that are hardened through the carborization process that uses this gas. Conventional methods of monitoring the endogas include measuring the dew point of the gas and the oxygen concentration. From these data, the carbon monoxide content of the gas can be calculated. This carbon monoxide concentration creates the carbon potential needed for carburization. Several weak links are present in this approach. The oxygen monitor deteriorates over time, and the measurement might be inaccurate by 50 percent. Also, the chemistry equations, which are based on several assumptions, such as secondary species concentrations, provide only an approximate estimate of the carbon monoxide concentration. To address these weaknesses, we investigated a new method based on ordinary Raman spectroscopy, in which the carbon monoxide concentration is measured directly and in situ. This method measures the laser light scattered from the molecules. Each species interacts with the light and scatters the light at a different frequency. Spectral monitoring of the scattered light intensity at each molecular frequency of interest provides the species concentrations. One advantage over the conventional method is that several species can be monitored simultaneously. A second advantage is that the measurement is direct; there is no need to make assumptions, to filter the gas, or to calibrate the instrument. An instrument was designed consisting of a laser and a detection system within an enclosure, connected to an optical probe by fibers. For determining carbon monoxide concentration, the probe is mounted on the endothermic gas line, close to the generator. Optical fibers with a length of 150 ft have been used to transmit laser light from the instrument to the probe. There, the light is focused into the gas, and the scattered light is collected and transmitted back to the instrument where it is analyzed with a photomultiplier and lock-in amplifier. Laboratory tests have shown that with the current system the concentration of carbon monoxide, water, nitrogen, oxygen, and hydrogen in the air can be monitored with an accuracy of 1 percent. The concentration of carbon dioxide in the air can be monitored with an accuracy of 0.5 percent, and the concentration of methane with an accuracy of 0.2 percent. This instrument was taken to the Akron Steel Treating Plant, where field tests are in progress to verify the system capabilities. Planned developments are improving the accuracy, monitoring multiple locations, and reducing instrument size and cost.

Source record↗

DOE OSTI2026

Hygrothermal aging effects on polyimide and acrylate-based adhesive materials in high-performance flat-flex cable assemblies

Flat-flex assemblies are widely used across a diverse range of technologies, including consumer electronics, automotive systems, aerospace and defense applications, and medical devices, due to their compact form factor and flexibility. However, environmental stressors like temperature and humidity are known to degrade performance over time, though the main mechanisms for degradation remain unknown. Here, in this work, we examined the aging behavior of copper/polyimide/adhesive laminate systems under varying temperature and humidity conditions, focusing on material degradation and its effects on mechanical and dielectric properties. Results show that peel strength and breakdown voltage decrease with exposure time, temperature, and humidity; spectroscopic characterization revealed that the adhesive, and not the polyimide, is the weak link in the material stack-up. The adhesive, identified as a butyl acrylate-acrylonitrile (BA-AN) copolymer, exhibited age-related spectral changes that correlated with exposure severity and duration. Hydrolysis at BA ester and AN nitrile groups was identified as the primary degradation mechanism, producing amides, acids, and alcohols. We developed a mechanistic model that connects kinetic parameters for BA-AN spectral band decay to peel strength and breakdown voltage, and implicates hydrolysis at the AN moiety, not BA, in performance decrements. Modeling predictions at ambient conditions indicate faster decline in peel strength than dielectric strength at early times, followed by plateauing of both properties at longer times. These findings provide critical insights into laminate aging mechanisms and highlight the importance of addressing BA-AN degradation to improve the long-term reliability of these systems in high-humidity environments.

organic↗

DOE OSTI2026

KTaO 3 -Based Supercurrent Diode

The supercurrent diode effect (SDE), characterized by nonreciprocal critical currents, represents a promising building block for future dissipationless electronics and quantum circuits. Realizing SDE requires breaking both time-reversal and inversion symmetry in the device. Here we use conductive atomic force microscope (c-AFM) lithography to pattern reconfigurable superconducting weak links (WLs) at the LaAlO 3 /KTaO 3 (LAO/KTO) interface. By deliberately engineering the WL geometry at the nanoscale, we realize SDE in these devices in the presence of modest out-of-plane magnetic fields. The SDE polarity can be reversed by simply changing the WL position, and the rectification efficiency reaches up to 13% under optimal magnetic field conditions. Time-dependent Ginzburg–Landau simulations reveal that the observed SDE originates from asymmetric vortex motion in the inversion-symmetry-breaking device geometry. This demonstration of SDE in the LAO/KTO system establishes a versatile platform for investigating and engineering vortex dynamics, forming the basis for engineered quantum circuit elements.

C-AFM lithography↗

DOE OSTI2025

Theoretical description of atomtronic Josephson junctions in an optical lattice

Experimental realizations of “atomtronic” Josephson junctions have recently been created in annular traps in relative rotation with respect to potential barriers that generate the weak links. If these devices are additionally subjected to an optical lattice potential, then they can incorporate strong-coupling Mott physics within the design, which can modify the behavior and can allow for interesting new configurations of barriers and of superfluid flow patterns. We examine theoretically the behavior of a Bose superfluid in an optical lattice in the presence of an annular trap and a barrier across the annular region which acts as a Josephson junction. As the superfluid is rotated, circulating super-currents appear. Beyond a threshold superfluid velocity, phase slips develop, which generate vortices. We use a finite temperature strong-coupling expansion about the mean-field solution of the Bose Hubbard model to calculate various properties of such devices. Additionally, we discuss some of the rich behavior that can result when there are Mott regions within the system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2026

Josephson dynamics in two-dimensional ring-shaped condensates

We investigate Josephson transport in a fully closed, two-dimensional superfluid circuit formed by a ring-shaped 87 Rb Bose-Einstein condensate that contains two optical barriers acting as movable weak links. Translating these barriers at controlled speeds imposes a steady bias current, enabling direct mapping of the current-chemical-potential (𝐼−Δ⁢𝜇) characteristics. For narrow junctions (𝑤 ≈ 1µ⁢m), the circuit exhibits a pronounced dc branch that terminates at a critical current 𝐼 𝑐 = 9⁢(1) × 10 3 s −1 ; above this threshold, the system switches to an ac, resistive regime. Classical-field simulations that include the moving barriers quantitatively reproduce both the nonlinear 𝐼−Δ⁢𝜇 curve and the measured 𝐼 𝑐 , validating the underlying microscopic picture. Analysis of the ensuing phase dynamics shows that dissipation is mediated by the nucleation and traversal of vortex-antivortex pairs through the junctions, while the bulk condensate remains globally phase locked—direct evidence of the ring's topological constraint enforcing quantized circulation. These results establish a cold-atom analog of a superconducting quantum interference device in which Josephson dynamics can be resolved at the single-vortex level, providing a versatile platform for atomtronic circuit elements, nonreciprocal Josephson devices, and on-chip Sagnac interferometers for multiaxis rotation sensing.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2024

Fractional AC Josephson effect in a topological insulator proximitized by a self-formed superconductor

A lateral Josephson junction in which the surface of a 3D topological insulator serves as the weak link should support topologically protected excitations related to Majorana fermions. The resulting 4π-periodic current-phase relationship could be detected under high-frequency excitation by the suppression of odd Shapiro steps. Here, in this study, we demonstrate such devices through the self-formation of a Pd-Te superconducting layer from a telluride topological insulator, and observe suppressed first and third Shapiro steps. Other devices, including those where the Pd-Te layer is bolstered by an additional Al layer, show no suppression of Shapiro steps, a difference supported by simulations. Though we rule out the known trivial causes of suppressed Shapiro steps in our devices, we nevertheless argue that corroborating measurements and disorder-aware theoretical descriptions of these systems are needed before confidently claiming the observation of Majorana states.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2025

Characterization and Damping Control of Mechanical Connections to Improve Performance of Horn Stripline

Magnetic focusing horns are critical components for creating a stable beam of neutrinos for neutrino facilities, such as the Long Baseline Neutrino Facility (LBNF) and the Neutrinos and Main Injector (NuMI) beam lines at Fermilab. The pulsed magnetic horns are powered by high current electricity through long striplines, which must survive in a harsh radiation environment for the operational life of the component. Each stripline assembly consists of four layers of Al 6101-T6. As an electro-mechanical system, the stripline layers are bolted together with ceramic isolators for electrical insulation and to facilitate passive cooling and mechanical stability. The striplines experience vibrational force in addition to clamping force, repetitive thermal and electro-magnetic loading. The holes of stripline plates for ceramic joints represent one of the weak links for potential failure. Damping can be achieved by adding damp material to the joint. By characterizing behavior of the joint and optimizing their damping properties through FEA and EMA, the stripline performance and longevity can be improved. Appropriate damp materials are the key.

Liu, Zunping [Fermilab]↗

NASA NTRS1975

Superconducting quantum-interference devices

Published document discusses devices which are based on weak-link Josephson elements that join superconductors. Links can take numerous forms, and circuitry utilizing links can perform many varied functions with unprecedented sensitivity. Theoretical review of Josephson's junctions include tunneling junctions, point contact devices, microbridges, and proximity-effect devices.

Peters, P. N.↗

NASA NTRS1977

Germanium coated microbridge and method

A superconducting microbridge is provided for use in superconducting quantum interference devices wherein a pair of spaced layers of superconductive material are connected by a weak link bridge to establish an electrical junction. The superconductive layers and bridge are coated with a semiconductor material shunting the bridge at room temperatures to prevent the destruction of the device by minute electrical currents while the coating acts as a dielectric permitting normal electrical behavior of the microbridge at cryogenic temperatures.

Holderman, L. B.↗

NASA NTRS1982

Advanced reliability modeling of fault-tolerant computer-based systems

Two methodologies for the reliability assessment of fault tolerant digital computer based systems are discussed. The computer-aided reliability estimation 3 (CARE 3) and gate logic software simulation (GLOSS) are assessment technologies that were developed to mitigate a serious weakness in the design and evaluation process of ultrareliable digital systems. The weak link is based on the unavailability of a sufficiently powerful modeling technique for comparing the stochastic attributes of one system against others. Some of the more interesting attributes are reliability, system survival, safety, and mission success.

Bavuso, S. J.↗

NASA NTRS1982

Parallel-processing with surface plasmons, a new strategy for converting the broad solar spectrum

A new strategy for efficient solar-energy conversion is based on parallel processing with surface plasmons: guided electromagnetic waves supported on thin films of common metals like aluminum or silver. The approach is unique in identifying a broadband carrier with suitable range for energy transport and an inelastic tunneling process which can be used to extract more energy from the more energetic carriers without requiring different materials for each frequency band. The aim is to overcome the fundamental 56-percent loss associated with mismatch between the broad solar spectrum and the monoenergetic conduction electrons used to transport energy in conventional silicon solar cells. This paper presents a qualitative discussion of the unknowns and barrier problems, including ideas for coupling surface plasmons into the tunnels, a step which has been the weak link in the efficiency chain.

Anderson, L. M.↗

NASA NTRS1986

Improved perfluoroalkylether fluid development

The feasibility of transforming a commercial linear perfluoroalkylether fluid into a material stable in the presence of metals and metal alloys in oxidizing atmospheres at 300 C without the loss of the desirable viscosity temperature characteristics was determined. The approach consisted of thermal oxidative treatment in the presence of catalyst to remove weak links, followed by transformation of the created functional groups into phospha-s-triazine linkages. It it found that the experimental material obtained in 66% yield from the commercial fluid exhibits, over an 8 hr period at 300 C in the presence of Ti(4Al, 4Mn) alloy, thermal oxidative stability better by a factor of 2.6x1000 based on volatiles evolved than the commercial product. The viscosity and molecular weight of the developed fluid are unchanged and are essentially identical with the commercial material. No metal corrosion occurs with the experimental fluid at 300 C.

Jones, W. R., Jr.↗

NASA NTRS1984

The role of optimization in structural model refinement

To evaluate the role that optimization can play in structural model refinement, it is necessary to examine the existing environment for the structural design/structural modification process. The traditional approach to design, analysis, and modification is illustrated. Typically, a cyclical path is followed in evaluating and refining a structural system, with parallel paths existing between the real system and the analytical model of the system. The major failing of the existing approach is the rather weak link of communication between the cycle for the real system and the cycle for the analytical model. Only at the expense of much human effort can data sharing and comparative evaluation be enhanced for the two parallel cycles. Much of the difficulty can be traced to the lack of a user-friendly, rapidly reconfigurable engineering software environment for facilitating data and information exchange. Until this type of software environment becomes readily available to the majority of the engineering community, the role of optimization will not be able to reach its full potential and engineering productivity will continue to suffer. A key issue in current engineering design, analysis, and test is the definition and development of an integrated engineering software support capability. The data and solution flow for this type of integrated engineering analysis/refinement system is shown.

Lehman, L. L.↗

NASA NTRS1988

Stabilizing PFAE Against Oxidation

Process makes commercial perfluoroalkylether (PFAE) hydraulic fluid more stable in presence of metals in hot oxidizing atmospheres. Consists of thermal oxidation in presence of catalyst to remove weak links, followed by transformation of newly-created functional groups into phospha-s-triazine linkages, which impart antioxidation and anticorrosion properties. A 66-percent yield of stable PFAE obtained. Fluid used as lubricant, grease, or hydraulic fluid at temperatures from -55 to +300 degree C in presence of metals in oxidizing atmosphere.

Jones, W. R., Jr.↗

NASA NTRS1987

Improved perfluoroalkyl ether fluid development

The feasibility of transforming a commercial linear perfluoroalkylether fluid into a material stable in the presence of metals and metal alloys in oxidizing atmospheres at 300 C without the loss of the desirable viscosity temperature characteristics was determined. The approach consisted of thermal oxidative treatment in the presence of catalyst to remove weak links, followed by transformation of the created functional groups into phospha-s-triazine linkages. It is found that the experimental material obtained in 66 percent yield from the commercial fluid exhibits, over an 8 hr period at 300 C in the presence of Ti(4Al, 4Mn) alloy, thermal oxidative stability better by a factor of 2.6 x 1000 based on volatiles evolved than the commercial product. The viscosity and molecular weight of the developed fluid are unchanged and are essentially identical with the commercial material. No metal corrosion occurs with the experimental fluid at 300 C.

Jones, William R., Jr.↗

NASA NTRS1988

Transport critical current and magnetization measurements of melt-processed YBa2Cu3O(7-x)

This paper reports on the magnetic field dependence of the transport critical current and dc magnetic susceptibility measurements on YBa2Cu3O(7-x) superconductors formed by melt-solid reactions at 950 C between Ba-Cu-O (or Tb-Ba-cu-O) and solid nonstoichiometric Y-Ba-Cu oxide. Four-probe dc critical current measurements at 77, 64, and 4.2 K show strong depression of the critical current density with increasing magnetic field, in agreement with a model of weakly linked superconducting regions. Diamagnetic shielding and Meissner flux expulsion measurements in the temperature range 10-300 K show about one-third volume fraction of perfect superconductivity. Both shielding and flux expulsion were observed to be approximately temperature independent below 60 K, indicating strong coupling between the grains throughout the entire volume below this temperature.

Hermann, A. H.↗

NASA NTRS1990

Autoclavable addition polyimides for 371 C composite applications

Studies were conducted to improve the thermo-oxidative stability (TOS) of PMR type polyimides by the substitution of para-aminostyrene (PAS) for the nadic ester endcap in second generation PMR polyimides (PMR-2). The nadic endcap which provides the PMR polyimides with their relative ease of fabrication, both by limiting the molecular weight of the prepolymer and by undergoing the final addition cure without volatiles, is also the weak link with regard to TOS. A polyimide formulated with PAS endcaps, called V-CAP, utilizes a two step reaction sequence similar to that of the PMR polyimides and can be easily autoclave molded into low void composite materials. Resin studies included two formulations of both PMR-2 and V-CAP, corresponding to n=9 and n=14 prepolymer stoichiometry. Unidirectional reinforced T40R graphite fiber laminates were fabricated from each of the resins was post-cured in either air at 385 C or nitrogen at 400 C. Composite specimens were aged in air at 371 C and mechanical properties were measured at 371 C before and after exposure.

Vannucci, R. D.↗