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At least 55 records · Page 3

Phase Transitions in Metal–Organic Frameworks Directly Monitored through In Situ Variable Temperature Liquid-Cell Transmission Electron Microscopy and In Situ X-ray Diffraction

Zr 6 -based metal–organic frameworks (MOFs) with tetratopic organic linkers have been extensively investigated owing to their versatile structural tunability. While diverse topologies and polymorphism in the resulting MOFs are often encountered with tetratopic linkers and Zr 6 nodes, reports on phase transitions within these systems are rare. Thus, we have a limited understanding of polymorph transformations, hindering the rational development of pure phase materials. In this study, a phase transition from a microporous MOF, scu-NU-906, to a mesoporous MOF, csq-NU-1008, was discovered and monitored through in situ variable temperature liquid-cell transmission electron microscopy (VT-LCTEM), high-resolution transmission electron microscopy (HRTEM), and in situ variable temperature powder X-ray diffraction (VT-PXRD). Furthermore, it was found that the microporous- to-mesoporous transformation in the presence of formic acid occurs via a concomitant dissolution–reprecipitation process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Machine-learning identification of the variability of mean velocity and turbulence intensity for wakes generated by onshore wind turbines: Cluster analysis of wind LiDAR measurements

Light detection and ranging (LiDAR) measurements of isolated wakes generated by wind turbines installed at an onshore wind farm are leveraged to characterize the variability of the wake mean velocity and turbulence intensity during typical operations, which encompass a breadth of atmospheric stability regimes and rotor thrust coefficients. The LiDAR measurements are clustered through the k-means algorithm, which enables identifying the most representative realizations of wind turbine wakes while avoiding the imposition of thresholds for the various wind and turbine parameters. Considering the large number of LiDAR samples collected to probe the wake velocity field, the dimensionality of the experimental dataset is reduced by projecting the LiDAR data on an intelligently truncated basis obtained with the proper orthogonal decomposition (POD). The coefficients of only five physics-informed POD modes are then injected in the k-means algorithm for clustering the LiDAR dataset. The analysis of the clustered LiDAR data and the associated supervisory control and data acquisition and meteorological data enables the study of the variability of the wake velocity deficit, wake extent, and wake-added turbulence intensity for different thrust coefficients of the turbine rotor and regimes of atmospheric stability. Furthermore, the cluster analysis of the LiDAR data allows for the identification of systematic off-design operations with a certain yaw misalignment of the turbine rotor with the mean wind direction.

17 WIND ENERGY↗

The relation between quasars’ optical spectra and variability

Abstract Brightness variation is an essential feature of quasars, but its mechanism and relationship to other physical quantities are not understood well. We aimed to find the relationship between the optical variability and spectral features to reveal the regularity behind the random variation. It is known that a quasar’s Fe ii/Hβ flux ratio and equivalent width of [O iii]5007 are negatively correlated; this is called Eigenvector 1. In this work, we visualized the relationship between the position on this Eigenvector 1 (EV1) plane and how the brightness of the quasars had changed after ∼10 yr. We conducted three analyses, using a different quasar sample in each. The first analysis showed the relation between the quasars’ distributions on the EV1 plane and how much they had changed brightness, using 13438 Sloan Digital Sky Survey quasars. This result shows how brightness changes later are clearly related to the position on the EV1 plane. In the second analysis, we plotted the sources reported as “changing-look quasars” (or “changing-state quasars”) on the EV1 plane. This result shows that the position on the EV1 plane corresponds to the activity level of each source, and the bright or dim states of them are distributed on the opposite sides divided by the typical quasar distribution. In the third analysis, we examined the transition vectors on the EV1 plane using sources with multiple-epoch spectra. This result shows that the brightening and dimming sources move on a similar path and they reach a position corresponding to the opposite activity level. We also found this trend is opposite to the empirical rule that $R_{\rm {Fe\, \small {II}}}$ positively correlated with the Eddington ratio, which has been proposed based on the trends of a large number of quasars. From all these analyses, it is indicated that quasars tend to oscillate between both sides of the distribution ridge on the EV1 plane; each of them corresponds to a dim state and a bright state. This trend in optical variation suggests that significant brightness changes, such as changing-look quasars, are expected to repeat.

Astronomy & Astrophysics↗

Aeroacoutic characteristics of a large, variable-pitch, variable-speed fan system

The acoustic and aerodynamic performance of the new drive fans for the NASA Ames 40- by 80-/80- by 120-foot wind tunnel was investigated. Results show that a fan system with variable-speed and variable-pitch rotor blades allows the operator to control noise and energy consumption, at a given mass flow rate, through the choice of blade speed and pitch. A low speed and high blade pitch will generally create the least noise at the least energy cost. An empirical method is described which predicts the sound power of this fan system reasonably well.

Soderman, P. T.↗

Interannual variability versus seasonal variability in the tropical Atlantic

Monthly fields of sea surface temperature and wind stress for the tropical Atlantic are constructed for January 1964 to December 1979. Inside the Gulf of Guinea the amplitude of the seasonal variability of SST ranges between 2.5 and 4 times greater than the interannual variability. In the remainder of the equatorial Atlantic this measure is less than 2. Standard deviations of wind stress anomalies indicate that, except near the Intertropical Convergence Zone, the magnitude of interannual fluctuations is greater than that of seasonal ones. The joint analyses of these SST and wind stress fields indicate the largest positive SST anomaly in the Gulf of Guinea (July, 1968) was immediately preceded by the only reversal of the trade winds west along the equator.

Picaut, J.↗

A method for linearizing a nonlinear system with six state variables and three control variables

A nonlinear system governed by x = f(x,u) with six state variables and three control variables is considered in this project. A set of transformations from (x,u) - space to (z,v) - space is defined such that the linear tangent model is independent of the operating point in the z-space. Therefore, it is possible to design a control law satisfying all operating points in the transformed space. An algorithm to construct the above transformations and to obtain the associated linearized system is described in this report. This method is applied to a rigid body using pole placement for the control law. Results are verified by numerical simulation. Closed loop poles in x-space using traditional local linearization are compared with those pole placements in the z-space.

Hsia, W. S.↗

Variability of pigment biomass in the California Current system as determined by satellite imagery. I - Spatial variability

Spatial variability of chlorophyll in the California Current system was analyzed using Coastal Zone Color Scanner (CZCS) imagery. A total of 48 images were analyzed to produce seasonal averages and variances, gradients, and power spectra. Roughly one third to one half of the variance in pigment biomass can be explained by consistent, large-scale gradients. In general, biomass is higher in the north and in nearshore areas. Nearshore areas also have proportionally more small-scale variability than the areas offshore. Slopes of the power spectra for nearshore areas are about -2.2 (for spatial scales of 10-100 km), while slopes for offshore areas are about -3. In addition, the power spectra show evidence of a change in slope at about 10 km, with slopes of about -1 for shorter-length scales. This may indicate that biological processes dominate the smaller scales, while mesoscale eddies and geostrophic currents dominate the larger scales.

Smith, Raymond C.↗

Variable magnification variable dispersion glancing incidence imaging x ray spectroscopic telescope

A variable magnification variable dispersion glancing incidence x ray spectroscopic telescope capable of multiple high spatial revolution imaging at precise spectral lines of solar and stellar x ray and extreme ultraviolet radiation sources includes a primary optical system which focuses the incoming radiation to a primary focus. Two or more rotatable carriers each providing a different magnification are positioned behind the primary focus at an inclination to the optical axis, each carrier carrying a series of ellipsoidal diffraction grating mirrors each having a concave surface on which the gratings are ruled and coated with a multilayer coating to reflect by diffraction a different desired wavelength. The diffraction grating mirrors of both carriers are segments of ellipsoids having a common first focus coincident with the primary focus. A contoured detector such as an x ray sensitive photographic film is positioned at the second respective focus of each diffraction grating so that each grating may reflect the image at the first focus to the detector at the second focus. The carriers are selectively rotated to position a selected mirror for receiving radiation from the primary optical system, and at least the first carrier may be withdrawn from the path of the radiation to permit a selected grating on the second carrier to receive radiation.

Hoover, Richard↗

Chromospheric variability of M giant semiregular variables

The results of monitoring the chromospheric emission from three M giant semiregular variables, W Cyg, NU Pav, and Theta Aps at low dispersion with the IUE satellite are reported along with high-dispersion IUE spectra for R Lyr and Delta(2) Lyr. The chromospheric emission is variable in all of the first three stars, and the Mg II strength generally follows changes in the continuum. However, the changes are not directly proportional, and there is a phase lag between the emission in the continuum and that in the Mg II lines, at least in W Cyg and probably in NU Pav. R Lyr showed changes in Mg II lines strengths and profiles uncorrelated with Al II 2669 A strength or with the strengths of fluorescent Fe I lines. The chromospheres of all these stars are clearly modified by stellar pulsation. The position and extent of the emitting layers of the chromospheres of the stars are estimated.

Eaton, Joel A.↗

Differentiating the role of land surface variability and cloudiness variability on global energy transport within the atmosphere and oceans

The following provides the final report on NASA IDP Project NAGW-1840 'Differentiating the Role of Land Surface Variability on Global Energy Transport within the Atmosphere and Oceans'. The project was designed to investigate the role of regional perturbations in the earth radiation budget on atmospheric and oceanic energy transports on an interannual basis. We proposed a modeling strategy based on an entropy extremum principle that could be used to separate the transports into oceanic and atmospheric components so as to better understand the effects of regional perturbations at the distinct atmospheric and oceanic time scales. The original focus was to consider the maintenance and year-to-year modulation of a large-scale, low-latitude North African-West Pacific Ocean net radiation dipole, which we had detected in the Nimbus 6 and 7 record of earth radiation budget measurements, and which necessitated significant cross-meridional energy transports to maintain global equilibrium. In addition, perturbations in the radiation balance term were to be partitioned into cloud-induced and surface-induced components to better understand the feedbacks between clouds and surface boundary conditions on interannual variability of the radiation balance.

Smith, Eric A.↗

X-ray Variability of the Magnetic Cataclysmic Variable V1432 Aql and the Seyfert Galaxy NGC 6814

V1432 Aquilae (=RX J1940.2-1025) is the X-ray bright, eclipsing magnetic cataclysmic variable approximately 37 (sup) away from the Seyfert galaxy, NGC 6814. Due to a 0.3% difference between the orbital (12116.3 s) and the spin (12150 s) periods: the accretion geometry changes over the approximately 50 day beat period. Here we report the results of an RXTE campaign to observe the eclipse 25 times, as well as of archival observations with ASCA and BeppoSAX. Having confirmed that the eclipse is indeed caused by the secondary, we use the eclipse timings and profiles to map the accretion geometry as a function of the beat phase. We find that the accretion region is compact, and that it moves relative to the center of white dwarf on the beat period. The amplitude of this movement suggest a low-mass white dwarf, in contrast to the high mass previously estimated from its X-ray spectrum. The size of the X-ray emission region appears to be larger than in other eclipsing magnetic CVs. We also report on the RXTE data as well as the long-term behavior of NGC 6814, indicating flux variability by a factor of at least 10 on time scales of years.

Mukai, K.↗

Beat to beat variability in cardiovascular variables: noise or music?

Cardiovascular variables such as heart rate, arterial blood pressure, stroke volume and the shape of electrocardiographic complexes all fluctuate on a beat to beat basis. These fluctuations have traditionally been ignored or, at best, treated as noise to be averaged out. The variability in cardiovascular signals reflects the homeodynamic interplay between perturbations to cardiovascular function and the dynamic response of the cardiovascular regulatory systems. Modern signal processing techniques provide a means of analyzing beat to beat fluctuations in cardiovascular signals, so as to permit a quantitative, noninvasive or minimally invasive method of assessing closed loop hemodynamic regulation and cardiac electrical stability. This method promises to provide a new approach to the clinical diagnosis and management of alterations in cardiovascular regulation and stability.

Non-NASA Center↗

Variable magnification variable dispersion glancing incidence imaging x-ray spectroscopic telescope

A variable magnification variable dispersion glancing incidence x-ray spectroscopic telescope capable of multiple high spatial revolution imaging at precise spectral lines of solar and stellar x-ray and extreme ultraviolet radiation sources includes a pirmary optical system which focuses the incoming radiation to a primary focus. Two or more rotatable carries each providing a different magnification are positioned behind the primary focus at an inclination to the optical axis, each carrier carrying a series of ellipsoidal diffraction grating mirrors each having a concave surface on which the gratings are ruled and coated with a mutlilayer coating to reflect by diffraction a different desired wavelength. The diffraction grating mirrors of both carriers are segments of ellipsoids having a common first focus coincident with the primary focus. A contoured detector such as an x-ray sensitive photogrpahic film is positioned at the second respective focus of each diffraction grating so that each grating may reflect the image at the first focus to the detector at the second focus. The carriers are selectively rotated to position a selected mirror for receiving radiation from the primary optical system, and at least the first carrier may be withdrawn from the path of the radiation to permit a selected grating on the second carrier to receive radiation.

Hoover, Richard B.↗

Long Term Variability of Cygnus X-1. VII. Orbital Variability of the Focused Wind in Cyg X-1/HDE 226868 System

Binary systems with an accreting compact object offer a unique opportunity to investigate the strong, clumpy, line-driven winds of early-type supergiants by using the compact object's X-rays to probe the wind structure. We analyze the two-component wind of HDE 226868, the O9.7Iab giant companion of the black hole Cyg X-1, using 4.77 Ms Rossi X-ray Timing Explorer (RXTE) observations of the system taken over the course of 16 years. Absorption changes strongly over the 5.6 d binary orbit, but also shows a large scatter at a given orbital phase, especially at superior conjunction. The orbital variability is most prominent when the black hole is in the hard X-ray state. Our data are poorer for the intermediate and soft state, but show signs for orbital variability of the absorption column in the intermediate state. We quantitatively compare the data in the hard state to a toy model of a focussed Castor-Abbott- Klein wind: as it does not incorporate clumping, the model does not describe the observations well. A qualitative comparison to a simplified simulation of clumpy winds with spherical clumps shows good agreement in the distribution of the equivalent hydrogen column density for models with a porosity length on the order of the stellar radius at inferior conjunction; we conjecture that the deviations between data and model at superior conjunction could either be due to lack of a focussed wind component in the model or to a more complicated clump structure.

binaries↗

Impact of Dust-Cloud-Radiation-Precipitation Dynamical Feedback on Subseasonal-to-Seasonal Variability of the Asian Summer Monsoon in Global Variable-Resolution Simulations With MPAS-CAM5

In this study, we investigate the effects of increased dust emission from the Middle East deserts on subseasonal-to-seasonal (S2S) variability of the Asian summer monsoon (ASM). Numerical experiments are performed using the Model for Prediction Across Scales (MPAS) coupled with the Community Atmosphere Model (CAM5) physics, with regional refinement at 30 km grid resolution over South Asia and the surrounding regions. Result shows that increased dust emission and transport from the Middle East/West Asia region induces a strong dust-cloud-radiation-precipitation-circulation feedback, resulting in a colder surface over the desert regions and the western Tibetan Plateau, but warmer and moister troposphere with enhanced cloudiness and precipitation over the Pakistan/Northwest India (PNWI) region. The latter changes are amplified by the dust aerosol induced Elevated Heat Pump (EHP) mechanism along the West Himalayas/Iranian Plateau foothill regions, most pronounced during May- June. During July-August, cloud radiation feedback further enhances the warming of the upper troposphere, and cooling of the land surface over the PNWI and adjacent regions overWest Asia. The upper tropospheric heating and increased precipitation over PNWI spur a large-scale anomalous Rossby wavetrain and a northward displacement of the subtropical jetstream, manifesting in a contraction of the South Asian High and westward shift of the Western Pacific Subtropical High. As a result, the entire ASM precipitation-cloud system is displaced westward. Precipitation and cloudiness are intensified over northwest and western India and west Asia, but suppressed over southern and central East Asia. Analyses of the S2S variability of the upper level vorticity balance suggests that heating by Middle East dust plays an important role in exciting, and anchoring a teleconnection pattern through interactions among dust cloud radiation, precipitation heating over the PNWI, the development of an upper level Rossby wavetrain, and the northward shift of the boreal summer jetstream over Eurasia.

Asian summer monsoon↗