Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Ultrasensitive”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

Ultrathin and Ultrasensitive Direct X‐ray Detector Based on Heterojunction Phototransistors

Abstract Most contemporary X‐ray detectors adopt device structures with non/low‐gain energy conversion, such that a fairly thick X‐ray photoconductor or scintillator is required to generate sufficient X‐ray‐induced charges, and thus numerous merits for thin devices, such as mechanical flexibility and high spatial resolution, have to be compromised. This dilemma is overcome by adopting a new high‐gain device concept of a heterojunction X‐ray phototransistor. In contrast to conventional detectors, X‐ray phototransistors allow both electrical gating and photodoping for effective carrier‐density modulation, leading to high photoconductive gain and low noise. As a result, ultrahigh sensitivities of over 10 5 μC Gy air −1 cm −2 with low detection limit are achieved by just using an ≈50 nm thin photoconductor. The employment of ultrathin photoconductors also endows the detectors with superior flexibility and high imaging resolution. This concept offers great promise in realizing well‐balanced detection performance, mechanical flexibility, integration, and cost for next‐generation X‐ray detectors.

Gao, Yuanhong↗

3D MoS 2 Aerogel for Ultrasensitive NO 2 Detection and Its Tunable Sensing Behavior

A high-performance NO 2 sensor based on the 3D MoS 2 aerogel is introduced. Compared to single- or few-layer MoS2, 3D assemblies of 2D MoS 2 provide more surface area per footprint with a simple and scalable synthesis. Integration of the 3D MoS 2 aerogel on a low-power microheater platform is demonstrated, and the sensing behavior of the 3D MoS 2 aerogel is investigated. A two-step sulfurization treatment is developed to obtain a high-quality MoS 2 aerogel with strong sensing performance. The aerogel exhibits low detection limit (50 ppb) toward NO 2 at room temperature, while after the two-step sulfurization treatment, it also exhibits fast response and recovery at low heater temperature of 200 °C, with no decrease in sensitivity. The observed p-type sensing behavior of MoS 2 aerogel is discussed and identified as being controlled by the defect state (as probed by the S:Mo ratio). Furthermore, annealing in a hydrogen environment changes the defect state of the MoS 2 aerogel by creating more sulfur vacancies; concomitantly, a transition from p-type sensing behavior to n-type sensing is observed

36 MATERIALS SCIENCE↗

Ultrasensitive and selective non-enzymatic electrochemical glucose sensor based on hybrid material of graphene nanosheets/graphene nanoribbons/nickel nanoparticle

Highlights: • Nickel nanoparticles incorporated graphene nanosheets/graphene nanoribbons (GS/GNR/Ni) composite was synthesized by in-situ chemical reduction route and the as prepared GS/GNR/Ni modified glassy carbon electrode (GCE) was applied to detect glucose. • The fabricated GS/GNR/Ni/GCE modified electrode exhibits outstanding performance for non-enzymatic glucose sensing with sensitivity (2.3 mA/mM cm{sup 2}), linear range (5 nM - 5 mM) and detection limit (2.5 nM). • GS/GNR/Ni/GCE modified electrode exhibited a high selectivity towards glucose against the interferents, such as ascorbic acid (AA), uric acid (UA), dopamine and sucrose. - Abstract: A fast, highly sensitive and selective non-enzymatic electrochemical glucose sensor based on graphene sheet/graphene nanoribbon/nickel nanoparticles (GS/GNR/Ni) hybrid material modified electrode was fabricated. The hybrid material was synthesized via facile in-situ chemical reduction and characterized by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The GS/GNR/Ni/GCE showed high electrochemical activity towards the oxidation of glucose in a 0.1 M NaOH solution. At an applied potential of +0.5 V, it displayed wide linear amperometric response towards glucose from the range of 5 nM–5 mM, with a detection limit of 2.5 nM and sensitivity of 2.3 mA/mM cm{sup 2}. Moreover, the modified electrode was relatively insensitive to commonly interfering species such as dopamine, ascorbic acid, sucrose, uric acid and Cl{sup −} ions. The fabricated sensor with better reproducibility, good long term stability, makes it a promising electrode for the development of effective glucose sensor.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

The quick and ultrasensitive determination of K in NaI using inductively coupled plasma mass spectrometry

A highly sensitive, novel and quick assay method utilizing inductively coupled plasma mass spectrometry was developed for the determination of K in NaI powders and NaI(Tl) scintillator crystals for use in ultralow background applications. The determination of K (viz. 40K), as well as Th and U and their daughters, is important in ultralow background detector materials to ensure incorporation of materials of sufficiently high radiopurity. Through the use of improved instrumentation, cool plasma operating conditions, and meticulously clean sample preparations, detection limits of 11 fg natK∙g-1 (or 341 pBq 40K∙kg-1) was attained for K in pure water. Detection limits in the sample matrix (i.e., NaI) were 0.529 ng natK∙g NaI-1 (or 16.4 Bq 40K∙kg NaI -1). A number of different precursor NaI powder samples and NaI(Tl) scintillator crystals were assayed for their K content. Determinations ranged from 0.757 – 31.4 ng natK∙g NaI-1. This method allows for the screening of materials to unprecedented levels in a fraction of the time compared to gamma counting techniques, providing a useful method for a more effective screening tool of K in ultralow background detector materials.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗