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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

BioSentinel: Mission Development of a Radiation Biosensor to Gauge DNA Damage and Repair Beyond Low Earth Orbit on a 6U Nanosatellite.

We are designing and developing a "6U" (10 x 22 x 34 cm; 14 kg) nanosatellite as a secondary payload to fly aboard NASA's Space Launch System (SLS) Exploration Mission (EM) 1, scheduled for launch in late 2017. For the first time in over forty years, direct experimental data from biological studies beyond low Earth orbit (LEO) will be obtained during BioSentinel's 12- to 18- month mission. BioSentinel will measure the damage and repair of DNA in a biological organism and allow us to compare that to information from onboard physical radiation sensors. In order to understand the relative contributions of the space environment's two dominant biological perturbations, reduced gravity and ionizing radiation, results from deep space will be directly compared to data obtained in LEO (on ISS) and on Earth. These data points will be available for validation of existing biological radiation damage and repair models, and for extrapolation to humans, to assist in mitigating risks during future long-term exploration missions beyond LEO. The BioSentinel Payload occupies 4U of the spacecraft and will utilize the monocellular eukaryotic organism Saccharomyces cerevisiae (yeast) to report DNA double-strand-break (DSB) events that result from ambient space radiation. DSB repair exhibits striking conservation of repair proteins from yeast to humans. Yeast was selected because of 1) its similarity to cells in higher organisms, 2) the well-established history of strains engineered to measure DSB repair, 3) its spaceflight heritage, and 4) the wealth of available ground and flight reference data. The S. cerevisiae flight strain will include engineered genetic defects to prevent growth and division until a radiation-induced DSB activates the yeast's DNA repair mechanisms. The triggered culture growth and metabolic activity directly indicate a DSB and its successful repair. The yeast will be carried in the dry state within the 1-atm P/L container in 18 separate fluidics cards with each card having 16 independent culture microwells, with integral microchannels and filters to supply nutrients and reagents, confine the yeast to the wells, and enable optical measurement. The measurement subsystem will monitor each subgroup of culture wells continuously for several weeks, optically tracking DSBtriggered cell growth and metabolism. BioSentinel will also include physical radiation sensors based on the TimePix sensor, as implemented by JSC's RadWorks group, which record individual radiation events including estimates of their linear-energytransfer (LET) values. Radiation-dose and LET data will be compared directly to the rate of DSB-and-repair events measured by the S. cerevisiae biosentinels. The spacecraft bus will operate in a deep space environment with functions that include command and data handling, communications, power generation (via deployable solar panels) and storage, and attitude determination-and-control system with micropropulsion. Development of the BioSentinel spacecraft will mature and prove multiple nanosatellite advances in order to function well beyond LEO: Communications from distances of ≥ 500,000 km; Autonomous attitude control, momentum management, and safe mode of nanosatellites in deep space; Shielding-, hardening-, design-, and software-derived radiation tolerance for electronics; Reliable functionality for 12 - 18 months of key subsystems for biofluidics, memory, communications, power, etc.; Close integration of living biological radiation event monitors with miniature physical radiation spectrometers; Biological measurement of solar particle events beyond Earth orbit In addition to providing the first biological results from beyond LEO in over 4 decades, BioSentinel will provide an adaptable small-satellite instrument platform to perform a range of human-exploration-relevant measurements that characterize the biological consequences of multiple outer space environments. BioSentinel is being developed under NASA's Advanced Exploration Systems program.

DNA damage↗

Metal-organic frameworks as effective sensors and scavengers for toxic environmental pollutants

Abstract Metal-organic frameworks (MOFs) constructed from a rich library of organic struts and metal ions/clusters represent promising candidates for a wide range of applications. The unique structure, porous nature, easy tunability and processability of these materials make them an outstanding class of materials for tackling serious global problems relating to energy and environment. Among them, environmental pollution is one aspect that has increased at an alarming rate in the past decade or so. With rapid urbanization and industrialization, toxic environmental pollutants are constantly released and accumulated leading to serious contamination in water bodies and thereby having adverse effects on human health. Recent studies have shown that many toxic pollutants, as listed by the World Health Organization and the US Environmental Protection Agency, can be selectively detected, captured, sequestered and removed by MOFs from air and aquatic systems. Most of these sensing/capture processes in MOFs are quantifiable and effective for even a trace amount of the targeted chemical species. The functional sites (ligands and metals) play a critical role in such recognition processes and offer an extensive scope of structural tunability for guest (pollutants, toxic entities) recognition. Whereas on the one hand, the underlying mechanisms governing such sensing and capture are important, it is also crucial to identify MOFs that are best suited for commercial applications for the future. In this review article, we provide an overview of the most recent progress in the sensing, capture and removal of various common toxic pollutants, including neutral and ionic, inorganic and organic species, with brief discussions on the mechanism and efficacy of selected MOFs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Gene Fusion: A Genome Wide Survey

As a well known fact, organisms form larger and complex multimodular (composite or chimeric) and mostly multi-functional proteins through gene fusion of two or more individual genes which have independent evolution histories and functions. We call each of these components a module. The existence of multimodular proteins may improves the efficiency in gene regulation and in cellular functions, and thus may give the host organism advantages in adaptation to environments. Analysis of all gene fusions in present-day organisms should allow us to examine the patterns of gene fusion in context with cellular functions, to trace back the evolution processes from the ancient smaller and uni-functional proteins to the present-day larger and complex multi-functional proteins, and to estimate the minimal number of ancestor proteins that existed in the last common ancestor for all life on earth. Although many multimodular proteins have been experimentally known, identification of gene fusion events systematically at genome scale had not been possible until recently when large number of completed genome sequences have been becoming available. In addition, technical difficulties for such analysis also exist due to the complexity of this biological and evolutionary process. We report from this study a new strategy to computationally identify multimodular proteins using completed genome sequences and the results surveyed from 22 organisms with the data from over 40 organisms to be presented during the meeting. Additional information is contained in the original extended abstract.

Liang, Ping↗

In vivo visualization of butterfly scale cell morphogenesis in Vanessa cardui

Many organisms exhibit functional micro- and nanoscale materials with structural definition and performance that challenge synthetic fabrication techniques, yet we know little about the processes that enable their formation. Using butterfly scales as a model system for functional biomaterials, we establish a timeline of scale formation and quantify relevant structural parameters for developing painted lady butterflies. We overcome challenges of previous efforts by imaging structure formation directly in living organisms, which allows us to continuously observe the evolving wing tissue and the fine details of individual scale cells. Visualization of scale structure formation in live butterflies forms the basis for modeling the underlying biomechanical processes and opens avenues for their translation into advanced fabrication strategies.

59 BASIC BIOLOGICAL SCIENCES↗

The Clementine Mission: Initial Results from lunar mapping

Clementine was a mission designed to test the space-worthiness of a variety of advanced sensors for use on military surveillance satellites while, at the same time, gathering useful scientific information on the composition and structure of the Moon and a near-Earth asteroid. Conducted jointly by the Ballistic Missile Defense Organization (BMDO, formerly the Strategic Defense Initiative Organization) of the US Department of Defense and NASA, Clementine was dispatched for an extended stay in the vicinity of Earth's moon on 25 January 1994 and arrived at the Moon on 20 February 1994. The spacecraft started systematic mapping on 26 February, completed mapping on 22 April, and left lunar orbit on 3 May. The entire Clementine project, from conception through end-of-mission, lasted approximately 3 years.

Spudis, P. D.↗

Implementing an Applied Science Program

The work implied in the NASA Applied Science Program requires a delicate balancing act for the those doing it. At the implementation level there are multiple tensions intrinsic to the program. For example each application of an existing product to a decision support process requires deep knowledge about the data and deep knowledge about the decision making process. It is highly probable no one person has this range of knowledge. Otherwise the decision making process would already be using the data. Therefore, a team is required. But building a team usually requires time, especially across agencies. Yet the program mandates efforts of relatively short duration. Further, those who know the data are scientists, which makes them essential to the program. But scientists are evaluated on their publication record. Anything which diverts a scientist from the research for his next publication is an anathema to him and potential death to their career. Trying to get another agency to use NASA data does not strike most scientists as material inherently suitable for publication. Also, NASA wishes to rapidly implement often substantial changes to another agency's process. For many reasons, such as budget and program constraints, speed is important. But the owner of a decision making process is tightly constrained, usually by law, regulation, organization and custom. Changes when made are slow, cautious, even hesitant, and always done according a process specific to the situation. To manage this work MSFC must balance these and other tensions. Some things we have relatively little control over, such as budget. These we try to handle by structural techniques. For example by insisting all of our people work on multiple projects simultaneously we inherently have diversification of funding for all of our people. In many cases we explicitly use some elements of tension to be productive. For example the need for the scientists to constantly publish is motivation to keep tasks short and to the immediate point. As another example, the DSS agency and it personnel are treated as integral to the effort at every step. Thus, their ways of doing things, their problems and their assets become part of the solution. MSFC also manages the Applied Science work' within a strategic framework.' First, the scientists are necessarily at the core of all of this work as well as all of the work within the larger' organization. We therefore strive to keep a roughly 50-50 balance between the work done on tasks funded directly by the research side of NASA's Science Mission Directorate and funding from the applied side. Done at both the organization level and the level of the individual, this keeps the scientist both happy and productive over the long term. We also try diligently to remove as much burden from the scientist as practical by employing people such as the authors and others to do tasks not requiring; scientific knowledge. We also have designed our effort to take full use of external partners. We actively seek and support, including fund, people from multiple organizations to join us as committed collaborators. In this we use today's money and today's problem to help us diversify and strengthen for tomorrow. MSFC also considers the Applied Science work holistically. Each element is viewed as a step in a larger process. At a management level we can chose to emphasize or encourage certain areas which service long term goals. Thus, if we think work in a particular area should be developed, we can start with the smaller, less costly elements and grow.

Rickman, Doug↗

Climate Change, Nutrition and Food Security in Sub-Saharan Africa

Food security and nutrition in sub-Saharan Africa have long been affected by variations in the weather. Vulnerability to these hazards, along with economic shocks and an adverse political environment, is often uneven in a community. Some individuals and households are more susceptible to emergencies or crises than others, and thus determining who is most vulnerable are and how they are responding to a shock or crises is essential to understand the impact on food security. Daily, quantitative and global observations derived from satellite remote sensing instruments can contribute to understanding how food production has declined due to drought, flood or other weather-related hazard, but it can say nothing about the likelihood that the people living in that area are suffering food insecurity as a result. As Amartya Sen argued, a famine can occur even when there is an absolute surplus of food in a region. Thus organizations like the US Agency for International Development's Famine Early Warning Systems Network (FEWS NET) work to integrate biophysical and socio-economic indicators together with on-the ground assessments to estimate the food security consequences of a variety of events. Climate change is likely to restructure local, regional and global agricultural systems and commodity markets. Although remote sensing information has been used to identify seasonal production declines for the past two decades, new ways of using the data will need to be developed in order to understand, document and respond to the impact of climate change on food security as it is manifested in shorter term shocks. In this article, the contribution of remote sensing is explained, along with the other factors that affect food security

Brown, Molly E.↗

Overview of the 2015 Algodones Sand Dunes Field Campaign to Support Sensor Intercalibration

Several sites from around the world are being used operationally and are suitable for vicarious calibration of space-borne imaging platforms. However, due to the proximity of these sites (e.g., Libya 4), a rigorous characterization of the landscape is not feasible, limiting their utility for sensor intercalibration efforts. Due to its accessibility and similarities to Libya 4, the Algodones Sand Dunes System in California, USA, was identified as a potentially attractive intercalibration site for space-borne, reflective instruments such as Landsat. In March 2015, a 4-day field campaign was conducted to develop an initial characterization of Algodones with a primary goal of assessing its intercalibration potential. Five organizations from the US and Canada collaborated to collect both active and passive airborne image data, spatial and temporal measurements of spectral bidirectional reflectance distribution function, and in-situ sand samples from several locations across the Algodones system. The collection activities conducted to support the campaign goal is summarized, including a summary of all instrumentation used, the data collected, and the experiments performed in an effort to characterize the Algodones site.

McCorkel, Joel↗

DEVELOP: Building Capacity in Early Career Individuals to Apply NASA Earth Observations in Health and Air Quality

The NASA DEVELOP National Program builds capacity to use and apply NASA Earth observations to address environmental concerns around the globe. The DEVELOP model builds capacity in both participants (students, recent graduates, and early and transitioning career professionals), who conduct the projects, and partners (decision and policy makers), who are recipients of project methodologies and results. While projects focus on a spectrum of thematic topics, health and air quality related topics made up more than a quarter of DEVELOP’s FY2023 project portfolio. These projects worked in collaboration with over 30 partner organizations throughout the US and internationally to explore how Earth observations could support decision making in areas such as health and air quality, wildland fires, climate, urban development, and transportation and infrastructure. This presentation provides an overview of the DEVELOP model of building capacity to use Earth observation data, environmental decision-making needs identified in health and air quality relevant projects, DEVELOP project case studies, commonly utilized data sources, and lessons learned. Key takeaways include best practices for project development and execution, how to balance learning with delivering impactful results for partners, and water resource relevant decisions guided by project end products.

Remote sensing↗

Search for Presolar Materials and Isotopically Anomalous Diffuse Insoluble Organic Matter in Samples From Asteroid 101955 Bennu

Carbonaceous asteroids allow us to study the original materials that formed the planets in the protoplanetary disk. They contain organic matter and (sub-)micrometer-size dust grains, called presolar grains, that condensed in the circumstellar envelopes of evolved stars and the ejecta of stellar explosions, such as novae and supernovae, before the formation of our Solar System. The isotopically anomalous organics are thought to have formed in the interstellar medium and the early Solar System. Whereas presolar grains provide insight into the building blocks of our Solar System, studying organics can help us understand the origin of life on Earth. These organics might have contributed to ingredients that helped life emerge. The return of samples from asteroid 101955 Bennu by NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission gives us a new opportunity to elucidate the formation mechanism(s) and evolution of organics, as well as the abundance and distribution presolar grains in carbonaceous asteroids. Here, we report on our ongoing work to characterize the isotopic and chemical compositions, microstructure, distribution, and abundance of insoluble organic matter (IOM) and presolar grains in Bennu samples. This work supports hypotheses 2 and 3 of the OSIRIS-REx Sample Analysis Plan.

P. Haenecour↗

Average Versus High Surface Ozone Levels over the Continental USA: Model Bias, Background Influences, and Interannual Variability

US background ozone (O3) includes O3 produced from anthropogenic O3 precursors emitted outside of the USA, from global methane, and from any natural sources. Using a suite of sensitivity simulations in the GEOS-Chem global chemistry transport model, we estimate the influence from individual background sources versus US anthropogenic sources on total surface O3 over 10 continental US regions from 2004 to 2012. Evaluation with observations reveals model biases of +0-19ppb in seasonal mean maximum daily 8h average (MDA8) O3, highest in summer over the eastern USA. Simulated high-O3 events cluster too late in the season. We link these model biases to excessive regional O3 production (e.g., US anthropogenic, biogenic volatile organic compounds (BVOCs), and soil NOx, emissions), or coincident missing sinks. On the 10 highest observed O3 days during summer (O3_top10obs_JJA), US anthropogenic emissions enhance O3 by 5-11ppb and by less than 2ppb in the eastern versus western USA. The O3 enhancement from BVOC emissions during summer is 1-7 ppb higher on O3_top10obs_JJA days than on average days, while intercontinental pollution is up to 2ppb higher on average versus on O3_top10obs_JJA days. During the summers of 2004-2012, monthly regional mean US background O3 MDA8 levels vary by up to 15ppb from year to year. Observed and simulated summertime total surface O3 levels on O3_top10obs_JJA days decline by 3ppb (averaged over all regions) from 2004-2006 to 2010-2012, reflecting rising US background (+2ppb) and declining US anthropogenic O3 emissions (6ppb) in the model. The model attributes interannual variability in US background O3 on O3_top10obs days to natural sources, not international pollution transport. We find that a 3-year averaging period is not long enough to eliminate interannual variability in background O3 on the highest observed O3 days.

Guo, Jean J.↗

Assessing the Effect of a Deep‐Rooted Grass on Belowground Carbon Storage in Cultivated Land: Insights From a Multi‐Site US Study

Agriculture depletes soil organic carbon (SOC), partly due to the exclusion of deep-rooted perennials. Reintroducing deep-rooted perennials to cultivated land may help to mitigate SOC loss. We quantified the effect of deep roots on SOC by comparing 8 to 30 year-old stands of switchgrass ( Panicum virgatum L .) with paired annual row crop fields at 12 sites across the central and eastern USA. We hypothesized that switchgrass would store more root C and SOC than neighboring shallow-rooted annual crops, and that these effects would extend deeper than 30 cm. We also evaluated whether switchgrass stimulates decomposition of SOC at depth using radiocarbon ( 14 C). Finally, we explored whether the effect of switchgrass on SOC is moderated by soil chemical and physical properties. While the effect of switchgrass on SOC in the surface 100 cm was positive at most sites, the average effect was not statistically significant (difference in SOC = 0.6 kg C m −2 [95% CI −0.8 to +1.9 kg C m −2 ]). By contrast, we found that root C was consistently more abundant under switchgrass, yielding an estimated additional 0.6 kg C m −2 in the surface 100 cm of soil [95% CI +0.5 to +0.7 kg C m −2 ]. 14 C measurements suggested that root C inputs were adding to existing SOC without stimulating decomposition. The effect of switchgrass on belowground C was not strongly related to any of the soil properties that we evaluated. Our observations show that root C can contribute substantially to belowground C stocks when deep-rooted perennials replace shallow-rooted crops.

60 APPLIED LIFE SCIENCES↗

Risk Informed Philosophy: Using What We Fear to Lose to Guide Us to Success

When an organization sets out on a new effort, program, or project, one of the first steps undertaken is to understand the related requirements. Most often, these requirements come in the form of standards, directives, or other organizational processes, and are derived to meet a broad range of efforts, programs, and projects. The net result is that organizations or teams are forced to start with a maximum set of requirements and expend time and energy tailoring the set of requirements down to what is more appropriate for the effort, program, or project at hand. This presentation will present an alternate method for the application of requirements or best practices that is based upon the actual risks to the safety, performance, or success of the effort. This additive route for applying best practices and requirements also encourages an early exploration of the risks, thus yielding a better understanding of where resources should be applied. This presentation also extends this concept of risk-based application of best practices and requirements to the selection of organization-wide improvement or standardization efforts, such as Lean, Six Sigma, and Quality Management Systems.

Darpel, Scott↗

Exploring the impact of the local environment on charge transfer states at molecular donor-acceptor heterojunctions

This program explored a broad range of charge transfer (CT) states in organic solar cells with the goal of understanding how molecular energetics, structure, and morphology influence CT state energy and dynamics, and how this in turn influences solar cell performance. We identified new types of delocalized CT states at ordered molecular heterojunctions, determined the factors that dictate CT state energetic disorder in bulk heterojunctions, determined that hot CT state dissociation is negligible for most systems, that the occupation of CT states is generally non-thermal in disordered heterojunctions, and that quasi-equilibrium generally does not hold in organic solar cells. These findings allowed us to demonstrate the lowest loss in potential of any organic solar cell to date and provide valuable guidance for designing higher efficiency organic solar cells in the future.

14 SOLAR ENERGY↗

Nitrogen Fixation Symposium at ICCC 2024 (Final Report)

The symposium "Advances in Nitrogen Fixation" was part of the 45th International Conference on Coordinate Chemistry (ICCC45) in Fort Collins, Colorado. It was organized by Patrick Holland (US) and Sven Schneider (Germany). The symposium was one of four parallel sessions on the first full day of the conference (Monday July 29, 2024). There were also three posters associated with the symposium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Soil Candidate Phyla Radiation Bacteria Encode Components of Aerobic Metabolism and Co-occur with Nanoarchaea in the Rare Biosphere of Rhizosphere Grassland Communities

Here, we investigated overlooked microbes in soil, candidate phyla radiation (CPR) bacteria and Diapherotrites, Parvarchaeota, Aenigmarchaeota, Nanoarchaeota, and Nanohaloarchaeota (DPANN) archaea, by size fractionating small particles from soil, an approach typically used for the recovery of viral metagenomes. Concentration of these small cells (<0.2 μm) allowed us to identify these organisms as part of the rare soil biosphere and to sample genomes that were absent from non-size-fractionated metagenomes.

59 BASIC BIOLOGICAL SCIENCES↗

Interstellar Ice and Dust: The Feedstock of the Solar System

Studying the chemical and isotopic composition of interstellar ice and dust provides insight into the composition and chemical history of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to probe the composition of these microscopic interstellar particles (some hundreds of light years away), thanks to substantial progress in two areas: astronomical spectroscopic techniques in the middle-infrared, the spectral region most diagnostic of composition; and laboratory simulations which realistically reproduce the critical conditions in various interstellar environments. High quality infrared spectra of many different astronomical sources, some associated with dark molecular clouds, and others in the diffuse interstellar medium (DISM) are now available. What comparisons of these spectra with laboratory spectra tell us about the complex organic components of these materials is the subject of this talk. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by gas phase and dust grain surface reactions. Gaseous species (except H2) striking the cold (10K) dust will stick, forming an icy grain mantle. This accretion, coupled with energetic particle bombardment and UV photolysis, will produce a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. One can compare spectra of the diffuse and dense interstellar medium with the spectra of analogs produced in the laboratory under conditions which mimic those in these different environments. In this way one can determine the composition and abundances of the major constituents present and place general constraints on the types and relative abundances of organics coating the grains. Ices in dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, as well as nitriles and ketones or esters. There is some evidence that the later, more complex species, are also present on the grains in the DISM. The evidence for these materials, in addition to carbon rich materials such as amorphous carbon, microdiamonds, and polycyclic aromatic hydrocarbons will be reviewed and the possible connection with meteoritic organics will be discussed.

Allamandola, L. J.↗