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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Corrosion of 316H Stainless Steel in Flowing FLiBe (LiF-BeF 2 )

This milestone was originally envisioned for completion in FY21 and was delayed due to the COVID-19 response and difficulties in fabricating/obtaining fluoride salts. A monometallic type 316H stainless steel thermal convection loop (TCL) was operated for 1000 h with flowing LiFBeF 2 (i.e. FLiBe) salt and a peak temperature of 650°C. In general, the attack was minimal. However, classic mass transfer was not clearly observed with mass losses in both the hot and cold legs. There was an issue with cleaning the loop with water and specimens may have oxidized, which was not an issue with the previous FLiNaK TCL.

36 MATERIALS SCIENCE↗

Corrosion Testing Trade Study on Testing Methods in Molten Salts

In assessing molten salt compatibility with structural materials, static testing is often reported because it is easy to conduct. However, in order to assess mass transfer, where material dissolves in the salt in the hot section and may precipitate out of the liquid in colder regions, a flowing salt experiment in a temperature gradient is needed. While a forced convection or pumped loop produces prototypic flowing conditions, it also is a multi-million dollar investment. Among the less expensive dynamic testing options, the thermal convection loop (TCL) was favored during the 1960’s development of molten salt reactor technology. Because the workforce and core facilities are currently available to conduct TCL experiments, it is the least expensive strategy to evaluate candidate structural alloys in flowing molten salt conditions.

36 MATERIALS SCIENCE↗

Thematic Mapper geometric correction performance evaluation

The present paper provides a performance evaluation of geometric correction in the Thematic Mapper Image Processing System (TIPS). TIPS forms a part of NASA's Thematic Mapper (TM) data processing facility. During a TM Research and Development period which continues through 1984, the geometric accuracy of TIPS is currently being evaluated. A description is given of TIPS geometric correction system, taking into account a TIPS overview and the Thematic Mapper Control Point Library Build (TCL). TCL generates control point chips which are stored in a library for subsequent use in the Thematic Mapper Archive Generation (TAG). Methods for measuring accuracy are discussed, giving attention to error estimation and direct measurement. A temporal registration evaluation from error estimation is considered along with a temporal evaluation from direct measurement, and a geodetic correction evaluation.

Brooks, J.↗

Writing instrument interfaces with xf/tktcl

Tcl is an embedded control language written in C, running primarily under Unix and with an interpreted C look-and-feel. Tk is an X11 toolkit based on tcl. Xf is an application builder for tk. The entire package is public domain and available from sprite.berkeley.edu. This paper discusses the use of tk to develop a user interface for OSIRIS, an infrared camera/spectrograph now operational on the OSU Perkins 1.8m telescope. The good and bad features of the development process are described.

Henden, A. A.↗

NanoDesign: Concepts and Software for a Nanotechnology Based on Functionalized Fullerenes

Eric Drexler has proposed a hypothetical nanotechnology based on diamond and investigated the properties of such molecular systems. While attractive, diamonoid nanotechnology is not physically accessible with straightforward extensions of current laboratory techniques. We propose a nanotechnology based on functionalized fullerenes and investigate carbon nanotube based gears with teeth added via a benzyne reaction known to occur with C60. The gears are single-walled carbon nanotubes with appended coenzyme groups for teeth. Fullerenes are in widespread laboratory use and can be functionalized in many ways. Companion papers computationally demonstrate the properties of these gears (they appear to work) and the accessibility of the benzyne/nanotube reaction. This paper describes the molecular design techniques and rationale as well as the software that implements these design techniques. The software is a set of persistent C++ objects controlled by TCL command scripts. The c++/tcl interface is automatically generated by a software system called tcl_c++ developed by the author and described here. The objects keep track of different portions of the molecular machinery to allow different simulation techniques and boundary conditions to be applied as appropriate. This capability has been required to demonstrate (computationally) our gear's feasibility. A new distributed software architecture featuring a WWW universal client, CORBA distributed objects, and agent software is under consideration. The software architecture is intended to eventually enable a widely disbursed group to develop complex simulated molecular machines.

Globus, Al↗

MSAP Hardware Verification: Testing Multi-Mission System Architecture Platform Hardware Using Simulation and Bench Test Equipment

The Multi-Mission System Architecture Platform (MSAP) project aims to develop a system of hardware and software that will provide the core functionality necessary in many JPL missions and can be tailored to accommodate mission-specific requirements. The MSAP flight hardware is being developed in the Verilog hardware description language, allowing developers to simulate their design before releasing it to a field programmable gate array (FPGA). FPGAs can be updated in a matter of minutes, drastically reducing the time and expense required to produce traditional application-specific integrated circuits. Bench test equipment connected to the FPGAs can then probe and run Tcl scripts on the hardware. The Verilog and Tcl code can be reused or modified with each design. These steps are effective in confirming that the design operates according specifications.

Crossin, Kent R.↗

Real-Time Path Planning for Multi-copters flying in UTM -TCL4

NASA's UAS Traffic management (UTM) -TCL-4 focuses on safely enabling large scale small UAS oper- ations in low altitude airspace in dense urban regions. This paper presents an operational architecture of an autonomous unmanned aerial vehicle operating in TCL4. An on-line path planning scheme is proposed which can effectively plan for feasible paths in real time with TCL-4 constraints. An end to end system is designed and tested in high fidelity Reflection architecture which demonstrates the feasibility of the approach.

Chakrabarty, Anjan↗

Science-based HRA: experimental comparison of operator performance to IDAC (Information-Decision-Action Crew) simulations

Information-Decision-Action Crew (IDAC) operator model simulations of a Steam Generator Tube Rupture are compared to student operator performance in studies conducted in the Ohio State University’s Nuclear Power Plant Simulator Facility. This study is presented as a prototype for conducting simulator studies to validate key aspects of Human Reliability Analysis (HRA) methods. Seven student operator crews are compared to simulation results for crews designed to demonstrate three different decision-making strategies. The IDAC model used in the simulations is modified slightly to capture novice behavior rather that expert operators. Operator actions and scenario pacing are compared. A preliminary review of available performance shaping factors (PSFs) is presented. After the scenario in the NPP Simulator Facility, student operators review a video of the scenario and evaluate six PSFs at pre-determined points in the scenario. This provides a dynamic record of the PSFs experienced by the OSU student operators. In this preliminary analysis, Time Constraint Load (TCL) calculated in the IDAC simulations is compared to TCL reported by student operators. We identify potential modifications to the IDAC model to develop an “IDAC Student Operator Model.” This analysis provides insights into how similar experiments could be conducted using expert operators to improve the fidelity of IDAC simulations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Using scripting languages in optical interferometry

We discuss client-side CORBA scripts implemented in Tcl, Perl, and Python. These are all technologies that are either currently being used on testbeds at JPL or being evaluated for future use. Finally, a Python example demonstrating implementation of a simple CORBA server is presented.

CORBA↗

Assessing Stainless Steel Compatibility in Flowing FLiBe Salt

To address the considerable interest in LiF-BeF 2 (FLiBe) compatibility for fission and fusion reactor applications, static and flowing compatibility experiments were conducted to assess the compatibility with type 316H stainless steel. In static testing at 550° and 650 °C, small mass changes were measured and posttest characterization of the FLiBe showed increased levels of Fe, Cr, Ni and Mn in the salt. Adding Be in the static salt test reduced the dissolution of Fe and Ni. Further, an initial assessment of mass transfer in flowing FLiBe without a Be addition was conducted using a monometallic 316H thermal convection loop (TCL) operated for 1000 h with a peak temperature of 650 °C. Similar to prior results in flowing FLiNaK salt, the 316H specimens exhibited small mass losses in the hot leg. Posttest characterization of the 316H specimens suggested Cr surface depletion in the hot and cold legs and possibly Fe deposition in the cold leg. To further understand this behavior, Cr and Fe dissolution was measured in static FLiBe at 550–650 °C.

316H stainless steel↗

Reduced Free Energy Perturbation/Hamiltonian Replica Exchange Molecular Dynamics Method with Unbiased Alchemical Thermodynamic Axis

We report that replica-exchange molecular dynamics (REMD) has been proven to efficiently improve the convergence of free energy perturbation (FEP) calculations involving considerable reorganization of their surrounding. We previously introduced the FEP/(λ,H)-REMD algorithm for ligand binding, in which replicas along the alchemical thermodynamic coupling axis λ were expanded as a series of Hamiltonian boosted replicas along a second axis to form a two-dimensional (2D) replica-exchange exchange map [Jiang, W.; Roux, B., J. Chem. Theory Comput. 2010, 6 (9), 2559-2565]. Aiming to achieve a similar performance at a lower computational cost, we propose here a modified version of this algorithm in which only the end-states along the alchemical axis are augmented by boosted replicas. The reduced FEP/(λ,H)-REMD method with one-dimensional (1D) unbiased alchemical thermodynamic coupling axis λ is implemented on the basis of generic multiple copy algorithm (MCA) module of the biomolecular simulation program NAMD. The flexible MCA framework of NAMD enables a user to design customized replica-exchange patterns through Tcl scripting in the context of a highly parallelized simulation program without touching the source code. Two Hamiltonian tempering boosting scheme were examined with the new algorithm: a first one based on potential energy rescaling of a pre-identified “solute”, and a second one via the introduction of flattening torsional free energy barriers. As two illustrative examples with reliable experiment data, the absolute binding free energies of pxylene and n-butylbenzene to the nonpolar cavity of the L99A mutant of T4 lysozyme were calculated. Lastly, the tests demonstrate that the new protocol efficiently enhances the sampling of torsional motions for backbone and side chains around the binding pocket and accelerates the convergence of the free energy computations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Characterization of Fe and Cr Dissolution and Reaction Product Formation in Molten Chloride Salts With and Without Impurities

There is considerable interest in molten chloride salts for several applications including thermal storage and next-generation molten salt reactors (MSRs). Several studies have concluded that Cl salts are highly corrosive to structural materials. Using Oak Ridge National Laboratory’s established methodology, Cl salt compatibility was assessed for candidate Ni-based alloys 230, 600 and 740 H at 600°–800°C in static welded capsules and in flowing thermal convection loop (TCL) salt experiments. Simply drying commercial Cl salt at 550°–650°C and adding~0.05 wt.%Mg was able to produce small specimen mass changes and limited surface attack after 100–1000 h exposures. Intentional additions of H 2 O, NiCl 2 and undried salt were used to better understand the role of impurities and achieve the>50 µm levels of attack reported in other studies. Further, characterisation of Cr depletion and oxide formation in conjunction with pre- and post-test salt chemistry measurements are being used to understand salt compatibility of structural materials.

36 MATERIALS SCIENCE↗

Compatibility of FeCrAlMo in Flowing Pb-Li at 600°C to 700°C

A series of monometallic thermal convection loops (TCLs) has been conducted to determine the maximum temperature where FeCrAl alloys have compatibility with eutectic lead lithium (Pb-Li) for a dual-coolant fusion blanket. Pre-oxidizing commercial alloy APMT (Fe-21Cr-5Al-3Mo) for 2 h at 1000°C to form a surface α-Al 2 O 3 layer was very effective in reducing the mass loss of specimens in the hot and cold legs of the most recent TCL that was operated for 1000 h with a peak temperature of 700°C. However, unlike previous experiments, the postexposure room temperature ductility of many of the APMT specimens was degraded to <10% total elongation, and many of the specimens at the highest temperature (>680°C) were severely damaged or were not recovered. Furthermore, wide-angle X-ray scattering found that the pre-formed α-Al 2 O 3 scale transformed to a mixture of trigonal and tetragonal LiAlO 2 . The overall results suggest that the maximum temperature for FeCrAl is limited to <700°C.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Short-range ferromagnetic order due to Ir substitutions in single-crystalline Ba(Co 1-x Ir x ) 2 As 2 (0 ≤ x ≤ 0.25)

The ternary-arsenide compound BaCo 2 As 2 was previously proposed to be in proximity to a quantum-critical point where long-range ferromagnetic (FM) order is suppressed by quantum fluctuations. In this paper we report the effect of Ir substitutions for Co on the magnetic and thermal properties of Ba(Co 1-x Ir x ) 2 As 2 (0 ≤ x ≤ 0.25) single crystals. These compositions all crystallize in an uncollapsed body-centered-tetragonal ThCr 2 Si 2 structure with space group I4/mmm. Magnetic susceptibility measurements reveal clear signatures of short-range FM ordering for x ≥ 0.11 below a nearly composition-independent characteristic temperature T cl ≈ 13 K. The small variation of T cl with x, thermomagnetic irreversibility between zero-field-cooled and field-cooled magnetic susceptibility versus T, the occurrence of hysteresis in magnetization versus field isotherms at low field and temperature, and very small spontaneous and remanent magnetizations <0.01 μ B /f.u. together indicate that the FM response arises from short-range FM ordering of FM spin clusters as previously inferred to occur in Ca(Co 1–x Ir x ) 2–y As 2 . Heat-capacity Cp(T) data do not exhibit any clear feature around Tcl, consistent with the very small moments of the FM clusters. The Cp(T) in the paramagnetic temperature regime 25–300 K is well described by the sum of a Sommerfeld electronic contribution and Debye and Einstein lattice contributions where the latter lattice contribution suggests the presence of low-frequency optic modes associated with the heavy Ba atoms in the crystals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

On Market-Based Coordination of Thermostatically Controlled Loads With User Preference

This paper presents a market-based control framework to coordinate a group of autonomous Thermostatically Controlled Loads (TCL) to achieve the system-level objectives with pricing incentives. The problem is formulated as maximizing the social welfare subject to feeder power constraint. It allows the coordinator to affect the aggregated power of a group of dynamical systems, and creates an interactive market where the users and the coordinator cooperatively determine the optimal energy allocation and energy price. The optimal pricing strategy is derived, which maximizes social welfare while respecting the feeder power constraint. The bidding strategy is also designed to compute the optimal price in real time (e.g., every 5 minutes) based on local device information. The coordination framework is validated with realistic simulations in GridLab-D. Extensive simulation results demonstrate that the proposed approach effectively maximizes the social welfare and decreases power congestion at key times.

Li, Sen↗

A Geometric Approach to Aggregate Flexibility Modeling of Thermostatically Controlled Loads

Coordinated aggregation of a large population of thermostatically controlled loads (TCLs) presents a great potential to provide various ancillary services to the grid. One of the key challenges in coordination and control of TCLs is developing a simple and portable model to accurately extract their aggregate flexibility. In this paper, we propose a novel geometric approach to model the aggregate flexibility of TCLs. We show that the set of admissible power profiles of an individual TCL is a polytope, and their aggregate flexibility is the Minkowski sum of the individual polytopes. In order to represent their aggregate flexibility in an intuitive way and achieve a tractable approximation, we develop optimization-based algorithms to approximate the polytopes by the homothets of a given convex set. As a special application, this set is chosen as a virtual battery model and the corresponding optimal approximation problems are solved efficiently by equivalent linear programs. Numerical results show that our algorithms yield significant improvement in characterizing the aggregate flexibility over existing modeling methods. Finally, we also conduct case studies to demonstrate the efficacy of our approaches by coordinating TCLs to track a frequency regulation signal from the Pennsylvania-New Jersey-Maryland (PJM) Interconnection.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Optimal Load Ensemble Control in Chance-Constrained Optimal Power Flow

Distribution system operators (DSOs) world-wide foresee a rapid roll-out of distributed energy resources. From the system perspective, their reliable and cost effective integration requires accounting for their physical properties in operating tools used by the DSO. This work describes an decomposable approach to leverage the dispatch flexibility of thermostatically controlled loads (TCLs) for operating distribution systems with a high penetration level of photovoltaic resources. Each TCL ensemble is modeled using the Markov Decision Process (MDP). The MDP model is then integrated with a chance constrained optimal power flow that accounts for the uncertainty of PV resources. Since the integrated optimization model cannot be solved efficiently by existing dynamic programming methods or off-the-shelf solvers, this paper proposes an iterative Spatio-Temporal Dual Decomposition algorithm (ST-D2). Finally, we demonstrate the merits of the proposed integrated optimization and ST-D2 algorithm on the IEEE 33-bus test system.

24 POWER TRANSMISSION AND DISTRIBUTION↗