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At least 55 records · Page 3

Equilibrium swelling of elastomers in solvents

Two proposed empirical equations, developed from Eilers-VanDijk equation to characterize relative modulus of filled elastomers as function of filler content, describe: (1) equilibrium swelling for cases where fillers are composed of permanent aggregates of primary particles; and (2) equilibrium swelling when filler material is composed of non-aggregated particles.

Fedors, R. F.

Detection and tracking of a low energy swell system off the U.S. East Coast with the Seasat SAR

It is noted that on the morning of September 28, 1978, at 1520 GMT, Seasat approached the East Coast of the U.S. with the 100 km swath of its synthetic aperture radar (SAR) running approximately parallel to the coast but displayed eastward by about 20 km. This pass is analyzed and the following conclusions are drawn: (1) the SAR can successfully detect low-energy swell systems with wave heights under 1 m (actually 0.65 + or - 0.25 m); (2) the refraction of low-energy but well-organized swells deriving from changes in the local depth of the ocean is clearly detectable in both wavelength and direction; and (3) the complexity of the ocean spectrum (whether composed of more than one system or spread in direction and wave number) appears to have little bearing on the threshold detection limits.

Beal, R. C.

The age and source of ocean swell observed in Hurricane Josephine

A simple kinematic model is applied to SIR-B observations in the far field of Hurricane Josephine in order to estimate the swell origin in space and time. The SIR data was obtained on October 12, 1984, and the geometry of the hurricane swell kinematic model is described. Estimates of the wavenumber and wave age and generation regions of the system are graphically presented and examined. The data reveal that the waves of Hurricane Josephine were generated 0-9 hours before the SIR-B overpass.

Gonzalez, Frank I.

Wind, current and swell influences on the ice extent and flux in the Grand Banks-Labrador sea area as observed in the LIMEX '87 experiment

This paper presents data collected by airborne and satellite instruments during the Labrador Ice Margin Experiment, that demonstrate the effects of oceanic and atmospheric processes on the ice conditions in the Grand Banks-Labrador sea area. Special consideration is given to the development of algorithms for extracting information from SAR data. It is shown that SAR data can be used to monitor ice extent, determine ice motion, locate shear zones, monitor the penetration of swell into the ice, estimate floe sizes, and establish the dimensions of the ice velocity zones. It is also shown that the complex interaction of the ice cover with winds, currents, swell, and coastlines is similar to the dynamics established for a number of sites in both polar regions.

Argus, Susan Digby

Swelling and Fission Gas Release of U-10Mo and U-17Mo Following Neutron Irradiation at 250 – 500°C

The performance of metallic fuel alloys, U-10Mo and U-17Mo, was examined using the MiniFuel test system in the High Flux Isotope Reactor. Approximately 0.8 mm thick disks were irradiated at target temperatures of 250°C, 350°C, 450°C, and 500°C up to three different fission densities, culminating at a maximum fission density of 6.8 × 10 20 cm −3 . Fission rates decayed from 3 – 6 × 10 13 cm −3 s −1 to 2 – 4 × 10 13 cm −3 s −1 over the course of the longest, eight cycle, irradiation as the 235 U was consumed and the 239 Pu concentration accumulated. Actual irradiation temperature on the last day of irradiation was measured via dilatometry using the SiC passive thermometry recovered from the MiniFuel subcapsules and compared favorably with the thermal calculations using as-built geometry and test conditions. Furthermore, average simulated temperatures were within 50°C of the target temperatures, except for the 500°C irradiation, for which the temperature variation was 62°C, 32°C, and 90°C in the in two, four, and eight cycle irradiations, respectively. Fission gas release (FGR) measurements showed no release above recoil for any U-17Mo fuels or for the U-10Mo fuel irradiated at 250°C. Finally, significant (40%–80%) FGR was found for the medium- to highest-burnup U-10Mo samples irradiated at target temperatures 350°C–500°C. Significant FGR correlated with sample thickness swelling, which was as high as 13%–35% for high-release samples and below 7% for all other (low–gas release) samples.

FGR

The Swelling and Destabilization of a Coronal Mass Ejection (abstract)

We will present and discuss data for a bugle that was particularly well observed. Apparently the swelling of the bugle and its destabilization were caused by the newly emerging flux and its interaction with the pre-existing active regions and coronal structures.

bugle destabilization coronal mass ejection swelli

Tuning the Mechanical Properties of Crosslinked Copolymers via Sequence and Solvent‐Selective Swelling for Vat Photopolymerization

Block copolymers (BCPs) offer distinct advantages for vat photopolymerization by enabling mechanically programmable network structures through microphase-separated morphologies that can be kinetically trapped during curing, yielding properties unattainable in homogeneous resins. However, the respective roles of repeat-unit sequence and solvent environment, together with their interplay in directing network formation and mechanical performance, remain unclear. Here, we synthesize a series of CO 2 -based polycarbonate copolymers comprising a crosslinkable glassy poly(vinyl cyclohexene carbonate) (PVCHC, A block) and a non-crosslinkable soft poly(propylene carbonate) (PPC, B block). The polymer sequence is systematically varied (ABA, BAB, and statistical), and solvent choice controls block-selective swelling to jointly control gelation behavior, microphase morphology, and mechanical response through changes in the accessibility and local environment of photocrosslinkable vinyl groups during network formation, as revealed by photorheology and small angle x-ray scattering. By tuning polymer sequence and curing solvent, we transform nominally identical formulations from brittle to highly ductile materials, achieving a three-orders-of-magnitude range in toughness (0.003 to 9.1 MJ m −3 ). These results establish clear structure–processing–property relationships and identify polymer sequence and selective solvation as powerful strategies for programming both printability and performance of block copolymer resins for additive manufacturing.

additive manufacturing

Swelling of FK800

The report summarizes an assessment of the strain experienced by FK800 upon change in humidity and temperature of its surroundings. The FK800 samples were obtained from Laural Hargrove in the form of a disk that was 12 mm in diameter and 0.5 – 1 mm in thickness. The sample had a Lot # 05172301. For TMA testing, the sample was cut into a small film of dimensions 0.5 mm x 3.38 mm x 6.57 mm and tested under the tensile mode. A single set of swelling experiments were performed on the sample between November and December 2024.

36 MATERIALS SCIENCE

Thermal Expansion and Swelling of Cured Epoxy Resin Used in Graphite/Epoxy Composite

The thermal expansion and swelling of resin material as influenced by variations in temperature during moisture absorption is discussed. Comparison measurements using composites constructed of graphite fibers and each of two epoxy resin matrices are included. Polymer theory relative to these findings is discussed and modifications are proposed.

Adamson, M. J.

Analysis of a multisensor image data set of south San Rafael Swell, Utah

A Shuttle Imaging Radar (SIR-A) image of the southern portion of the San Rafael Swell in Utah has been digitized and registered to coregistered Landsat, Seasat, and HCMM thermal inertia images. The addition of the SIR-A image to the registered data set improves rock type discrimination in both qualitative and quantitative analyses. Sedimentary units can be separated in a combined SIR-A/Seasat image that cannot be seen in either image alone. Discriminant Analyses show that the classification accuracy is improved with addition of the SIR-A image to Landsat images. Classification accuracy is further improved when texture information from the Seasat and SIR-A images is included.

Evans, D. L.

SAR imagery of ocean-wave swell traveling in an arbitrary direction

The intensity wave like patterns observed in Synthetic Aperture Radar (SAR) are known to be caused by two mechanisms: the microwave radar cross sectional amplitude modulation due to tilt and hydrodynamic interaction of the long ocean waves, and intensity modulation due to the motion of the long ocean waves. Two dimensional closed form expressions of intensity wave patterns based on ocean wave swell are developed. They illustrate the relative importance of the amplitude and motion modulations; they also show that velocity bunching and a distortion due to the phase velocity of the ocean wave field are independent of the focus adjustment, provided that the second order temporal effects are neglected. Second order effects are small only over a limited range of ocean/radar parameters.

Rufenach, C. L.

Mechanical and swelling behaviour of well characterized polybutadiene networks

Endlinking of hydroxyl-terminated polybutadiene with the appropriate isocyanate has been used to prepare well characterized networks. Two networks have been studied with molecular weights of the prepolymers being 6100 and 2400 g/mole by g.p.c. Cylindrical specimens were prepared and the derivatives of the stored energy function with respect to the stretch invariants were determined by torque and normal force measurements in torsion. From these data the Valanis-Landel (1967) stored energy function derivatives w-prime(lambda) were determined for both networks. The stored energy function for the junction constraint model of Flory (1953, 1977, 1979, 1985) which is a special form of the Valanis-Landel function, has been fitted to that determined from the experiments. The contributions to the stored energy function from the phantom network and from the junction constraints respectively do not agree with predictions from the topologies of the networks. In spite of this, the form of w-prime(lambda) for the junction constraint model gives an excellent 'curve fit' to the data. Comparison is also made with equilibrium swelling.

Mckenna, Gregory B.

The dependence of sea surface slope on atmospheric stability and swell conditions

A tower-mounted optical device is used to measure the two-orthogonal components of the sea surface slope. The results indicate that an unstable stratification at the air-sea interface tends to enhance the surface roughness. The presence of a long ocean swell system steers the primary direction of shortwave propagation away from wind direction, and may increase or reduce the mean square slope of the sea surface.

Hwang, Paul A.

The swelling mechanism of cathodes in Li/(CFx)(sub n) cells

Active material particles spatial arrangement in combination with the nature of the electrochemical reduction mechanism were found to be the major cause of excessive swelling in cathodes in Li/(CF(x))n cells. A better understanding of the chemical reaction mechanism, a possible new role for the carbon, and a model for cathode growth are discussed.

Margalit, Nehemiah