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At least 55 records · Page 3

Enhancement of surface area and wettability properties of boron doped diamond by femtosecond laser-induced periodic surface structuring

We demonstrate the formation of laser-induced periodic surface structures (LIPSS) in boron-doped diamond (BDD) by irradiation with femtosecond near-IR laser pulses. The results show that the obtained LIPSS are perpendicular to the laser polarization, and the ripple periodicity is on the order of half of the irradiation wavelength. The surface structures and their electrochemical properties were characterized using Raman micro-spectroscopy, in combination with scanning electron and atomic force microscopies. The textured BDD surface showed a dense and large surface area with no change in its structural characteristics. The effective surface area of the textured BDD electrode was approximately 50% larger than that of a planar substrate, while wetting tests showed that the irradiated area becomes highly hydrophilic. Lastly, our results indicate that LIPSS texturing of BDD is a straightforward and simple technique for enhancing the surface area and wettability properties of the BDD electrodes, which could enable higher current efficiency and lower energy consumption in the electrochemical oxidation of toxic organics.

36 MATERIALS SCIENCE↗

Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

36 MATERIALS SCIENCE↗

Total-internal-reflection elastic metasurfaces: Design and application to structural vibration isolation

This letter presents the concept of the Total Internal Reflection metasurface (TIR-MS) which supports the realization of structure-embedded subwavelength acoustic shields for elastic waves propagating in thin waveguides. The proposed metasurface design exploits extreme phase gradients, implemented via locally resonant elements, in order to achieve operating conditions that are largely beyond the critical angle. Such artificial discontinuity is capable of producing complete reflection of the incoming waves regardless of the specific angle of incidence. From a practical perspective, the TIR-MS behaves as a sound hard barrier that is impenetrable to long-wavelength modes at a selected frequency. The TIR metasurface concept is first conceived for a flat interface embedded in a rectangular waveguide and designed to block longitudinal S 0 -type guided modes. Then, it is extended to circular plates in order to show how enclosed areas can be effectively shielded by incoming waves. Given the same underlying physics, an equivalent dynamic behavior was also numerically and experimentally illustrated for flexural A 0 -type guided modes. This study shows numerical and experimental evidence that, when the metasurface is excited at the target frequency, significant vibration isolation can be achieved in the presence of waves having any arbitrary angle of incidence. Furthermore, these results open interesting paths to achieve vibration isolation and energy filtering in certain prototypical structures of interest for practical engineering applications.

42 ENGINEERING↗

Capacitive micromachined ultrasonic transducer arrays as tunable acoustic metamaterials

Capacitive Micromachined Ultrasonic Transducers (CMUTs) operating in immersion support dispersive evanescent waves due to the subwavelength periodic structure of electrostatically actuated membranes in the array. Evanescent wave characteristics also depend on the membrane resonance which is modified by the externally applied bias voltage, offering a mechanism to tune the CMUT array as an acoustic metamaterial. The dispersion and tunability characteristics are examined using a computationally efficient, mutual radiation impedance based approach to model a finite-size array and realistic parameters of variation. The simulations are verified, and tunability is demonstrated by experiments on a linear CMUT array operating in 2-12 MHz range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bending of electromagnetic waves in all-dielectric particle array waveguides

We propose and demonstrate experimentally an alternative approach for realizing subwavelength photonic structures, exploiting the waveguiding properties of chains of high-index dielectric disks with both electric and magnetic dipole resonances. We reveal that the electromagnetic energy can be efficiently guided through sharp corners by means of the mode polarization conversion at waveguide bends. We confirm experimentally the guidance through a 90° bend in the microwave frequency range.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enhancement of the transverse magneto-optical Kerr effect via resonant tunneling in trilayers containing magneto-optical metals

We propose a way to enhance the transverse magneto-optical Kerr effect, by the excitation of resonant tunneling modes, in subwavelength trilayer structures featuring a dielectric slab sandwiched between two magneto-optical metallic layers. Depending on the magneto-optical layer widths, the proposed system may exhibit an extraordinary transverse magneto-optical Kerr effect, which makes it very attractive for the design and engineering of thin-film magneto-optical-based devices for future photonic circuits or fiber optical-communication systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Near-field phase singularity in subwavelength metallic microstructures

A near-field phase singularity (NFPS) depending on the spin state of the incident electromagnetic (EM) radiation is very fascinating because it can enrich the functionality of the EM radiation in metamaterials. Here we present a microscopic dipole model to describe the NFPS effect under the time-harmonic quasistatic limit. The results reveal that NFPS exists for the longitudinal components of both electric and magnetic fields as well as the transverse component of time-averaged Poynting vector. The localized surface plasmon polariton in the subwavelength metallic structure contributes to enhance the generation efficiency of NFPS by introducing the resonance of the electric dipole. This effect not only is promising for microtrapping and manipulation but also enriches the functionality of the existing metamaterials.

36 MATERIALS SCIENCE↗

Experimental Demonstration of the Effect of Magnetic Polaritons on the Radiative Properties of Deep Aluminum Gratings

Despite the abundant theoretical studies of magnetic polaritons (MPs) in tailoring the radiative properties of nanostructures, experimental investigation of MPs in deep metal gratings is still lacking. This work experimentally demonstrates the excitation of MP from several microfabricated aluminum gratings in the mid-infrared region by measuring the specular reflectance (zeroth-order diffraction) of the specimen using a Fourier-transform infrared (FTIR) spectrometer. The rigorous coupled-wave analysis (RCWA) and an LC-circuit model are employed to elucidate the mechanism of various resonant modes and their coupling effect. The influence of incidence angle, plane of incidence, polarization, and the trench depth on the spectral reflectance is also discussed. Moreover, the MP dispersion for off-plane layout has been investigated and demonstrated for the first time. Finally, the insight gained from this work may facilitate future design and applications of subwavelength periodic structures with desired radiative properties.

36 MATERIALS SCIENCE↗

Infrared near-field spectroscopy of trace explosives using an external cavity quantum cascade laser

Utilizing a broadly-tunable external cavity quantum cascade laser for scattering-type scanning near-field optical microscopy (s-SNOM), we measure infrared spectra of explosives particles by probing characteristic nitro-group resonances in the 7.1-7.9 µm wavelength range. Measurements are presented with spectral resolution of 0.25 cm-1, spatial resolution of 25 nm, <100 attomolar sensitivity, and at a rapid acquisition time of 90 s per spectrum. We demonstrate high reproducibility of the acquired s-SNOM spectra with very high signal-to-noise ratios and relative noise of <0.02 in self-homodyne detection.

(140.5965) Semiconductor lasers, quantum cascade↗

Tailoring dielectric resonator geometries for directional scattering and Huygens’ metasurfaces

In this paper we describe a methodology for tailoring the design of metamaterial dielectric resonators, which represent a promising path toward low-loss metamaterials at optical frequencies. We first describe a procedure to decompose the far field scattered by subwavelength resonators in terms of multipolar field components, providing explicit expressions for the multipolar far fields. We apply this formulation to confirm that an isolated high-permittivity dielectric cube resonator possesses frequency separated electric and magnetic dipole resonances, as well as a magnetic quadrupole resonance in close proximity to the electric dipole resonance. We then introduce multiple dielectric gaps to the resonator geometry in a manner suggested by perturbation theory, and demonstrate the ability to overlap the electric and magnetic dipole resonances, thereby enabling directional scattering by satisfying the first Kerker condition. We further demonstrate the ability to push the quadrupole resonance away from the degenerate dipole resonances to achieve local behavior. These properties are confirmed through the multipolar expansion and show that the use of geometries suggested by perturbation theory is a viable route to achieve purely dipole resonances for metamaterial applications such as wave-front manipulation with Huygens’ metasurfaces. Our results are fully scalable across any frequency bands where high-permittivity dielectric materials are available, including microwave, THz, and infrared frequencies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Tunable dark modes in one-dimensional “diatomic” dielectric gratings

Recently researchers have demonstrated ultra high quality factor (Q) resonances in one-dimensional (1D) dielectric gratings. Here we theoretically investigate a new class of subwavelength 1D gratings, namely “diatomic” gratings with two nonequivalent subcells in one period, and utilize their intrinsic dark modes to achieve robust ultra high Q resonances. Such “diatomic” gratings provide extra design flexibility, and enable high Q resonators using thinner geometry with smaller filling factors compared to conventional designs like the high contrast gratings (HCGs). More importantly, we show that these high Q resonances can be efficiently tuned in situ, making the design appealing in various applications including optical sensing, filtering and displays.

42 ENGINEERING↗

Efficient dielectric metasurface collimating lenses for mid-infrared quantum cascade lasers

Light emitted from single-mode semiconductor lasers generally has large divergence angles, and high numerical aperture lenses are required for beam collimation. Visible and near infrared lasers are collimated using aspheric glass or plastic lenses, yet collimation of mid-infrared quantum cascade lasers typically requires more costly aspheric lenses made of germanium, chalcogenide compounds, or other infrared-transparent materials. We report mid-infrared dielectric metasurface flat lenses that efficiently collimate the output beam of single-mode quantum cascade lasers. The metasurface lenses are composed of amorphous silicon posts on a flat sapphire substrate and can be fabricated at low cost using a single step conventional UV binary lithography. Mid-infrared radiation from a 4.8 μm distributed-feedback quantum cascade laser is collimated using a polarization insensitive metasurface lens with 0.86 numerical aperture and 79% transmission efficiency. The collimated beam has a half divergence angle of 0.36° and beam quality factor of M² =1.02.

47 OTHER INSTRUMENTATION↗

Hybridized metamaterial platform for nano-scale sensing

Plasmonic/metamaterial sensors are being investigated for their high sensitivity, fast response time, and high accuracy. We propose, characterize and experimentally realize subwavelength bilayer metamaterial sensors operating in the near-infrared domain. We measure the figure-of-merit (FOM) and the bulk sensitivity (S) of the two fundamental hybridized modes and demonstrate both numerically and experimentally that the magnetic dipolar mode, degenerate with the electric quadrupolar mode, has higher sensitivity to a variation of the refractive index compared to the electric dipolar mode. In addition, the hybridized system exhibits a four fold increase in the FOM compared to a standard dipolar plasmonic system.

36 MATERIALS SCIENCE↗

Slow light Mach-Zehnder interferometer as label-free biosensor with scalable sensitivity

Our design, fabrication, and characterization of a label-free Mach–Zehnder interferometer (MZI) optical biosensor that incorporates a highly dispersive one-dimensional (1D) photonic crystal in one arm are presented. The sensitivity of this slow light MZI-based sensor scales with the length of the slow light photonic crystal region. The numerically simulated sensitivity of a MZI sensor with a 16 μm long slow light region is 115,000 rad/RIU-cm, which is sevenfold higher than traditional MZI biosensors with millimeter-length sensing regions. Moreover, the experimental bulk refractive index detection sensitivity of 84,000 rad/RIU-cm is realized and nucleic acid detection is also demonstrated.

47 OTHER INSTRUMENTATION↗

Glancing-angle-deposited magnesium oxide films for high-fluence applications

Here, Birefringent magnesium oxide thin films are formed by glancing angle deposition to perform as quarter-wave plates at a wavelength of 351 nm. These films are being developed to fabricate a large aperture distributed-polarization rotator for use in vacuum, with an ultimate laser-damage–threshold goal of up to 12 J/cm 2 for a 5-ns flat-in-time pulse. The laser-damage threshold, ease of deposition, and optical film properties are evaluated. While the measured large-area laser-damage threshold is limited to ~4 J/cm 2 in vacuum, initial results based on small-spot testing in air (>20 J/cm 2 ) suggest MgO may be suitable with further process development.

36 MATERIALS SCIENCE↗