Mathematical simulation of solar-thermionic energy conversion systems.
Solar-thermionic energy conversion system design using mathematical simulation relating characteristics of solar collector and cavity absorber
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Solar-thermionic energy conversion system design using mathematical simulation relating characteristics of solar collector and cavity absorber
The work being carried out at the University of Florida Solar Energy and Energy Conversion Laboratory in converting solar energy, our only income, into other needed and useful forms of energy is described. A treatment such as this demonstrates, in proper perspective, how solar energy can benefit mankind with its many problems of shortages and pollution. Descriptions were given of the conversion processes, equipment, and performance. The testing of materials, solar water heating, space heating, cooking and baking, solar distillation, refrigeration and air-conditioning, work with the solar furnace, conversion to mechanical power, hot air engines, solar-heated sewage digestion, conversion to electricity, and other devices will be discussed.
Radiation resistant silicon cells for solar energy conversion
Recent parametric studies of alternate SPS design concepts have shown that the concept appears technically feasible. The parametric studies were based on the use of advanced technology silicon solar cells for solar energy conversion. Solar array blanket unit masses of 0.31 to 0.46 kg/sq m were investigated. Conversion efficiencies of 15 to 17 percent air mass zero (AMO at 247 K) with a concentration ratio of two were considered. The systems were sized for a ground power output of 10 GW. To the level of detail studied, no design or operational problems were encountered that did not appear amenable to solution; however, the economic viability of the SPS concepts studied is obviously dependent upon a combination of technology advancement and/or the costs of competitive sources.
Thermoelectric flat plates, thermionic systems, and uncooled silicon solar cells for solar direct-energy conversion
Mathematical model simulation of solar-thermal energy conversion systems and collectors
Results obtained from studies of a (1) solar concentrator, (2) solar energy receiver - thermionic converter system, and (3) solar thermionic topping system are described. Peripheral subsystems, which are required for any solar energy conversion system, are also discussed.
A photovoltaic device development plan is reported that considers technological as well as economical aspects of single crystal silicon, polycrystal silicon, cadmium sulfide/copper sulfide thin films, as well as other materials and devices for solar cell energy conversion systems.
Since the energy input to solar thermal conversion systems is both time variant and probabilistic, it is unlikely that simple steady-state methods for estimating lifetime performance will provide satisfactory results. The work described here uses dynamic modeling to begin identifying what must be known about input radiation and system dynamic characteristics to estimate performance reliably. Daily operation of two conceptual solar energy systems was simulated under varying operating strategies with time-dependent radiation intensity ranging from smooth input of several magnitudes to input of constant total energy whose intensity oscillated with periods from 1/4 hour to 6 hours. Integrated daily system output and efficiency were functions of both level and dynamic characteristics of insolation. Sensitivity of output to changes in total input was greater than one.
500-electrical-watt solar energy thermionic conversion system for a mars spacecraft
Analysis, design, and development of flat plate solar thermoelectric energy conversion panel
Analysis, design, and development of flat plate solar thermoelectric energy conversion panel
In recognition of the obstacles to solar-generated baseload power on earth, proposals have been made to locate solar power satellites in geosynchronous earth orbit (GEO), where solar energy would be available 24 hours a day during most of the time of the year. In an SPS, the electricity produced by solar energy conversion will be fed to microwave generators forming part of a planar phase-array transmitting antenna. The antenna is designed to precisely direct a microwave beam of very low intensity to one or more receiving antennas at desired locations on earth. At the receiving antenna, the microwave energy will be safely and efficiently reconverted to electricity and then be transmitted to consumers. An SPS system will include a number of satellites in GEO. Attention is given to the photovoltaic option for solar energy conversion in GEO, solar cell requirements, the availability of materials, the implication of large production volumes, requirements for high-volume manufacture of solar cell arrays, and the effects of concentration ratio on solar cell array area.
Photovoltaic devices have been fabricated for solar and short-wavelength laser energy conversion using the thin metal film-semiconductor (Schottky barrier) approach. Studies of the metal film optical characteristics and the voltage outputs were emphasized. Air mass zero efficiencies of 8 to 9% in GaAs and laser conversion efficiencies of 25% at 4880 A in GaAs(0.6)P(0.4) are presently measured, with projected efficiencies of 15 and 45%, respectively. The techniques, if applied successfully to semiconductor thin films, could have an impact in solar energy terrestrial application.
It is widely known that semiconductor-based solar energy conversion could power our planet. This is in part because high-quality semiconductor structures are unrivalled in their ability to separate photogenerated electrons and holes. One effective approach to achieving this photoinduced charge separation relies on a phenomenon known as “band bending”. But details to justify why band bending results in photoinduced charge separation are more complex than often appreciated. This underappreciation is an impediment to the rational, hypothesis-driven design of next-generation approaches to solar energy conversion. Herein we show, by means of derivations rooted in physical chemistry, that several phenomena – not just band bending – can facilitate photoinduced charge separation, and that each is influenced by nonequilibrium species concentration and a parameter, such as diffusion coefficient or rate coefficient, that introduces dynamics. To help visualize the impact of each phenomenon, we introduce plots that depict their contributions as free energy, force, flux, force constant, and rate. We reveal that spatial dopant distributions that define band bending are predictors of initial photogenerated species transport rates. But charge separation alone does not guarantee high-efficiency operation. A photogenerated change in energy that is freely available to do useful work is also essential, and is strongly dependent on semiconductor optical properties and reaction kinetics. Notably, this information reveals that specificity of interfacial chemical reactions – even when they are not preceded by charge separation elsewhere – can result in efficient solar energy conversion. We expect that this tutorial will guide researchers in their pursuit to uncover new mechanisms for light to perform useful work.
A key issue in solar energy conversion is the utilization of solar energy for the preparation of solar fuels. In this area, artificial photosynthesis offers promising approaches for the conversion of H 2 O and CO 2 into usable solar fuels. This review highlights both the design and characterization of surface molecular assemblies for the preparation of solar fuels. It includes mechanistic summaries of the details of the underlying surface chemical reactions including water oxidation and proton/water reduction. The surface mechanisms are shown to integrate molecular reactivity with surface electron transfer in integrated assemblies that lead to impressive efficiencies for water oxidation and proton or CO 2 reduction.
Mathematical model for solar flares formation based on magnetic/kinetic energy conversion, investigating plasma instability
Thin dielectric films for thermoelectrostatic solar energy conversion