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All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Assessment of Gravity Wave Momentum Flux Measurement Capabilities by Meteor Radars Having Different Transmitter Power and Antenna Configurations

Measurement capabilities of five meteor radars are assessed and compared to determine how well radars having different transmitted power and antenna configurations perform in defining mean winds, tidal amplitudes, and gravity wave (GW) momentum fluxes. The five radars include two new-generation meteor radars on Tierra del Fuego, Argentina (53.8 deg S) and on King George Island in the Antarctic (62.1 deg S) and conventional meteor radars at Socorro, New Mexico (34.1 deg N, 106.9 deg W), Bear Lake Observatory, Utah (approx 41.9 deg N, 111.4 deg W), and Yellowknife, Canada (62.5 deg N, 114.3 deg W). Our assessment employs observed meteor distributions for June of 2009, 2010, or 2011 for each radar and a set of seven test motion fields including various superpositions of mean winds, constant diurnal tides, constant and variable semidiurnal tides, and superposed GWs having various amplitudes, scales, periods, directions of propagation, momentum fluxes, and intermittencies. Radars having higher power and/or antenna patterns yielding higher meteor counts at small zenith angles perform well in defining monthly and daily mean winds, tidal amplitudes, and GW momentum fluxes, though with expected larger uncertainties in the daily estimates. Conventional radars having lower power and a single transmitting antenna are able to describe monthly mean winds and tidal amplitudes reasonably well, especially at altitudes having the highest meteor counts. They also provide qualitative estimates of GW momentum fluxes at the altitudes having the highest meteor counts; however, these estimates are subject to uncertainties of approx 20 to 50% and uncertainties rapidly become excessive at higher and lower altitudes. Estimates of all quantities degrade somewhat for more complex motion fields.

Fritts, D. C.↗
NASA NTRS2013

The NASA Meter Class Autonomous Telescope: Ascension Island

The Meter Class Autonomous Telescope (MCAT) is the newest optical sensor dedicated to NASA s mission to characterize the space debris environment. It is the successor to a series of optical telescopes developed and operated by the JSC Orbital Debris Program Office (ODPO) to monitor and assess the debris environment in (1) Low Earth Orbit (LEO), (2) Medium Earth Orbit (MEO), and (3) Geosynchronous Orbit (GEO), with emphasis on LEO and GEO altitudes. A joint NASA-Air Force Research Labs project, MCAT is a 1.3m optical telescope dedicated to debris research. Its optical path and sensor yield a large survey fence at the cutting edge of current detector performance. It has four primary operational observing modes, two of which were not computationally feasible a decade ago. Operations are supported by a sophisticated software suite that monitors clouds and weather conditions, and controls everything from data collection to dome rotation to processing tens of GB of imagery data nightly. With fainter detection limits, precision detection, acquisition and tracking of targets, multi-color photometry, precision astrometry, automated reacquisition capability, and the ability to process all data at the acquisition rate, MCAT is capable of producing and processing a volume and quality of data far in excess of any current (or prior) ODPO operations. This means higher fidelity population inputs and eliminating the multi-year backlog from acquisition-to-product typical of optical campaigns. All of this is possible given a suitable observing location. Originally planned for the island of Legan, part of the Kwajalein Atoll Islands, recent developments have led to a change in venue. Specifically, the Ground-based Electro-Optical Deep Space Surveillance, or GEODSS, System of telescopes is the United States major tracking system for deep space. This network consists of telescopes in Maui, Hawaii; Diego Garcia (Indian Ocean), and Socorro, New Mexico. A fourth optical telescope, though smaller in size, has been operating in conjunction with this effort until recently in M.ron, Spain. With the M.ron site closing, a significant gap in longitude exists between the New Mexico and Diego Garcia sites. This longitudinal gap is well covered by placing a telescope on Ascension Island (7degrees 58'20" S, 14degrees 24'4"W), in the Atlantic Ocean. Ascension Island offers the benefits of both location and weather. The near equatorial location affords the opportunity to access under-sampled low-inclination orbits and new GEO longitudes, while simultaneously filling in the GEODSS longitudinal gap. Ascension Island is a volcanic, desert island, receiving only 7" of rain per year on average. With consistent trade winds blowing from the SSE direction off Africa, the combination of an island location with consistent winds will create the smooth laminar flow sought after by all astronomical sites, which creates stable atmospheric ('seeing') conditions. Finally, this low population island has minimal lighting, resulting in very dark skies, ideal for an observatory.

Lederer, S. M.↗
NASA NTRS2011

Mechanical Design of NESSI: New Mexico Tech Extrasolar Spectroscopic Survey Instrument

NESSI: the New Mexico Tech Extrasolar Spectroscopic Survey Instrument is a ground-based multi-object spectrograph that operates in the near-infrared. It will be installed on one of the Nasmyth ports of the Magdalena Ridge Observatory (MRO) 2.4-meter Telescope sited in the Magdalena Mountains, about 48 km west of Socorro-NM. NESSI operates stationary to the telescope fork so as not to produce differential flexure between internal opto-mechanical components during or between observations. An appropriate mechanical design allows the instrument alignment to be highly repeatable and stable for both short and long observation timescales, within a wide-range of temperature variation. NESSI is optically composed of a field lens, a field de-rotator, re-imaging optics, an auto-guider and a Dewar spectrograph that operates at LN2 temperature. In this paper we report on NESSI's detailed mechanical and opto-mechanical design, and the planning for mechanical construction, assembly, integration and verification.

exoplanet↗
NASA NTRS2016

SEACIONS During the 2012 Asian Monsoon: A Strategic Approach to Determining Convective Impacts on Tropospheric Ozone and TTL Gravity Waves

Purpose of making ozone and water vapor profiles measurements in SEAC4RS is to give consistent coverage of the vertical structure at fixed sites to (1) complement 2 campaign aircraft sampling; (2) ground-truth satellite measurements of H O and ozone; (3) provide profiles for model evaluation; (4) study processes responsible for day-to-day variability at each site. Revised objective for 2013, due to cancellation of the 2012 and 2013 plans to operate in Southeast Asia: rapidly re-configure the original "SEACIONS," Southeast Asian Consortium for Intensive Ozonesonde Network Study, to a SouthEast American plan (SEACIONS) for collecting daily ozonesonde data during DC-8 and ER-2 flights throughout the southeastern US. As in previous IONS (2004, 2006, 2008), students were trained at St Louis, Tallahassee, Houston, Penn State, Huntsville, Socorro. Images of the soundings and related flight-planning products were posted each day at NASA and Penn State (PSU) websites. With the aircraft based at Ellington Field (Houston), water CFH (cryogenic frost-point hygrometer) sondes in addition to ozonesondes, were to be taken launched at that site.

Thompson, Anne M.↗
NASA NTRS2016

The Caltech-NRAO Stripe 82 Survey (CNSS) Paper. I. The Pilot Radio Transient Survey in 50 Deg.(exp. 2)

We have commenced a multiyear program, the Caltech-NRAO Stripe 82 Survey (CNSS), to search for radio transients with the Jansky VLA in the Sloan Digital Sky Survey Stripe 82 region. The CNSS will deliver five epochs over the entire approx. 270 deg.(exp. 2) of Stripe 82, an eventual deep combined map with an rms noise of approx. 40 proper motion epoch y and catalogs at a frequency of 3 GHz, and having a spatial resolution of 3 inches. This first paper presents the results from an initial pilot survey of a 50 deg.(exp. 2) region of Stripe 82, involving four epochs spanning logarithmic timescales between 1 week and 1.5 yr, with the combined map having a median rms noise of 35 proper motion epoch y. This pilot survey enabled the development of the hardware and software for rapid data processing, as well as transient detection and follow-up, necessary for the full 270 deg.(exp. 2) survey. Data editing, calibration, imaging, source extraction, cataloging, and transient identification were completed in a semi-automated fashion within 6 hr of completion of each epoch of observations, using dedicated computational hardware at the NRAO in Socorro and custom-developed data reduction and transient detection pipelines. Classification of variable and transient sources relied heavily on the wealth of multiwavelength legacy survey data in the Stripe 82 region, supplemented by repeated mapping of the region by the Palomar Transient Factory. A total of 3.9(+0.5%/-0.9%) of the few thousand detected point sources werefound to vary by greater than 30%, consistent with similar studies at 1.4 and 5 GHz. Multiwavelength photometric data and light curves suggest that the variability is mostly due to shock-induced flaring in the jets of active galactic nuclei (AGNs). Although this was only a pilot survey, we detected two bona fide transients, associated with an RS CVn binary and a dKe star. Comparison with existing legacy survey data (FIRST, VLA-Stripe 82) revealed additional highly variable and transient sources on timescales between 5 and 20 yr, largely associated with renewed AGN activity. The rates of such AGNs possibly imply episodes of enhanced accretion and jet activity occurring once every approx. 40,000 yr in these galaxies. We compile the revised radio transient rates and make recommendations for future transient surveys and joint radio-optical experiments.

galaxies: active – radio continuum: galaxies –↗
NASA NTRSDate not supplied

Impact of DORISx Post Seismic Deformation and Seasonal Corrections on the DPOD2020 Solution

As one of the tracking systems used for the altimeter missions (such as TOPEX/Poseidon, Envisat, Jason-1/-2/-3, CryoSat-2, Saral/AltiKa, Sentinel-3A/-3B, HY-2A/C/D, Jason-CS/Sentinel-6A, SWOT), the position of the DORIS tracking stations provides a fundamental reference for the estimation of the precise orbits and so, by extension is fundamental for the quality of the altimeter data analysis and derived products. Due to the time evolution of the DORIS ground network, stations included in ITRF2020 may have been decommissioned and stations that were added to the tracking network after 2021.0 are, by definition, not part of ITRF2020. Therefore, to satisfy operational requirements for precise orbit determination and routine delivery of geodetic products, the International DORIS Service maintains the DORIS terrestrial reference frame for Precise Orbit Determination (DPOD) solutions. Since 2016, the DPOD products are computed by the IDS Combination Center (CC) as a DORIS cumulative position and linear velocity solution aligned to the latest available ITRF and using the latest IDS weekly combined series. Mid-2023, the IDS CC started the computation of the second version of the DPOD2020 based on the IDS 20 weekly solutions from 1993.0 to 2023.0. With that new solution, the IDS CC will include Post Seismic Deformation (PSD) corrections for some DORIS sites such as Socorro Island. These DPOD PSD corrections are determined from the analysis of DORIS coordinate time series only. The second version will also include optional annual and semi-annual station corrections. The presentation will describe the analysis used for extracting the PSD and seasonal DORIS station corrections, compare such corrections to those derived for ITRF2020, and evaluate the impact these new corrections have on station positioning and satellite POD.

Guilhem Moreaux↗
NASA NTRSDate not supplied

Mineralogical Characterization of a Potential Mars-Analog Field Site: Gypsum- and Carbonate-Bearing Formations in the Quebradas Back Country, New Mexico, USA

The Quebradas Back Country field site is located approximately six miles east of Socorro, NM, USA and provides access to Pennsylvanian and Permian age sedimentary formations that record environments ranging from lacustrine to hypersaline supratidal mudflats in deposits of carbonate, sulfate, and clay minerals. These deposits demonstrate a critical climate transition from cold and wet to largely arid conditions, which may parallel the drying of ancient Mars. The Quebradas sulfate and carbonate deposits can provide insight into the formation and weathering of Mars-relevant sulfates and elucidate potential causes for the prevalence of calcium sulfate and paucity of calcium carbonate on Mars. Deciphering the environmental cues held within evaporites is particularly timely now with mounting evidence for sulfate-rich fluids in Jezero crater and the Curiosity rover analyzing the sulfate-bearing unit in Gale crater.

S J Ralston↗
DOE OSTI2025

Southwest Regional Partnership on Carbon Sequestration: Phase III (Final Scientific/Technical Report)

The Southwest Regional Partnership on Carbon Sequestration (SWP) is one of 7 regional partnerships formed in 2003 under the U.S. Department of Energy’s (DOE) Regional Carbon Sequestration Partnerships (RCSPs) initiative. The overall purpose of the initiative was to help determine and implement the technology, infrastructure, and regulations most appropriate to promote carbon storage in different regions of the country. Covering Arizona, Colorado, New Mexico, Oklahoma, Utah, and parts of Texas, Wyoming, and Kansas, the SWP evaluated regional carbon storage and utilization potential and focused on technologies and sites that could complement the region’s strong position in energy production. The project progressed through three phases: • Phase I (2003–2005): Characterized regional geologic formations and CO 2 sources, assessed sequestration potential, and identified pilot test sites. • Phase II (2005–2013): Conducted small-scale field tests to validate sequestration methods, including geologic and terrestrial projects. • Phase III (2008–2022): Demonstrated large-scale CO 2 injection at a commercial oil field to test monitoring, verification, and long-term storage strategies. This report covers Phase III. The final project site, the Farnsworth Unit (FWU) in Texas, provided real-world testing of reservoir characterization, monitoring, and risk evaluation tools and processes that could be used in any commercial scale carbon capture, utilization, and storage (CCUS) project. Extensive data collection and analysis helped refine best practices for reservoir characterization, injection monitoring, and storage verification. The SWP contributed to national databases, DOE best practice manuals, and regional geological assessments to support future sequestration efforts. Key lessons learned include the importance of robust data management, strategic site selection, regulatory navigation, and effective industry collaboration. The project’s findings will inform ongoing and future carbon storage initiatives. Task 1 (Regional Characterization) • The SWP continued to participate in national outreach efforts and NATCARB. • The SWP evaluated multiple potential sites before selecting the FWU as the primary field test location. Task 2 (Public Outreach and Education) • The SWP contributed to national databases, DOE best practice manuals, and regional geological assessments to support future sequestration efforts. Task 3 (Permitting and Regulatory Compliance) • The SWP ensured compliance with federal and state regulations, including National Environmental Policy Act (NEPA) requirements. • The SWP obtained all necessary permits for drilling, injection, and monitoring activities. Task 4 (Site Characterization and Planning) • The SWP developed work plans for four key activities: characterization, simulation, monitoring and verification, and risk evaluation. • The SWP collected and synthesized legacy data from multiple sources to build initial static geological models and dynamic reservoir models demonstrating project feasibility. • The SWP conducted an initial risk evaluation and developed mitigation plans. Task 5 (Field Operations and Data Collection) • The SWP drilled, logged, and cored three characterization wells to gather critical subsurface data. • The SWP conducted multiple geophysical surveys, including 3D seismic, crosswell seismic, and vertical seismic profiling, to improve reservoir characterization. Task 6 (Monitoring and Verification) • The SWP performed extensive geological characterization using data from characterization wells and seismic surveys. • The SWP established a surface monitoring network to track CO 2 flux in soil gas, groundwater chemistry, and near-surface atmospheric CO 2 levels. • The SWP built and refined reservoir models to study the effects of relative permeability on simulation behavior and improve calibration with experimental data. Task 7 (Risk Assessment and Model Refinement) • The SWP conducted multiple studies to evaluate reservoir integrity, predict CO 2 plume behavior and improve predictive modeling capabilities. • The SWP refined geological models and used them to enhance the accuracy of simulation models. • The SWP continued quantitative risk assessment of top-ranked risks and strengthened the link between qualitative and quantitative risk methodologies.

02 PETROLEUM↗
DOE OSTI2025

Demonstration of Complete Recycling Processes of Reversible Epoxies Using Solar Energy Conversion

Reversible epoxies using the Diels–Alder chemistry enables recycling processes through depolymerizing the polymer at higher temperature and then repolymerizing upon cooling. Compared to conventional bulk heating, photothermal heating can save time and resource and, consequently, reduce costs to reach an elevated temperature for recycling processes of the reversible epoxies. In previous studies, self‐healing of cracks and reattachments of two broken pieces have been presented using a laser; however, recycling of a sample as a whole is not feasible by using such a point light source. Herein, complete recycling processes are demonstrated utilizing an area light source, i.e., sunlight. Reversible epoxies are incorporated with carbon black and refractory plasmonic titanium nitride nanoparticles (NPs). Under concentrated (10 times) sunlight, they can generate sufficient heat (≈140 °C) to completely liquefy, reprocess, and reshape the samples multiple times. Recycling processes are validated by evaluation of mechanical properties for each cycle. Using an integrated experimental and theoretical approach, photothermal performance is investigated in terms of the dispersion and loading of photothermal NPs in the matrix, as well as the sample thickness. In this study, an insight is provided into the design of polymer/photothermal nanomaterial composites which can be sustainably recycled using abundant solar energy.

14 SOLAR ENERGY↗
DOE OSTI2026

Measurements of excitation functions and photoneutron cross sections of 96,98,99,104 Ru and 100 Mo

Photoneutron cross sections were extracted for isotopes of ruthenium and molybdenum on natural abundance targets via a reduced chi-squared analysis on excitation functions, or activation yields, as function of electron beam energy. Bremsstrahlung photons were produced via an electron linear accelerator and a tungsten radiator at the Idaho Accelerator Center. A total of 16 irradiations were performed with electron beam energies ranging from approximately 8 MeV to 23 MeV. Induced radioactivity was measured using a high purity germanium detector. The cross sections were extracted assuming a three parameter Lorentzian fit with a smooth truncated rise at reaction threshold.

07 - ISOTOPES AND RADIATION SOURCES↗
DOE OSTI2026

Recyclability of reversible polymer networks over a Dozen reprocessing cycles

Reversible polymer networks capable of reversible reactions along their backbone provide a promising strategy for addressing waste management challenges associated with conventional thermoset products. However, reversible polymer networks cannot be recycled infinitely. Unavoidable side reactions eventually cause significant degradation of mechanical properties or loss of recyclability. This study aims to answer a simple yet critical question on reversible polymer network systems: how many reprocessing cycles can be achieved before profound mechanical degradation or a loss of recyclability? The recyclability of Diels–Alder (DA) network samples was evaluated by repeating consistent reprocessing cycles until they were no longer reprocessable. To enhance their recyclability, the chemical structure of the maleimide precursor was tailored to mitigating side reactions by maleimide homopolymerization. Remarkably, by employing a maleimide precursor with alkyl substitutions on its phenyl group, the DA network system attained 12 reprocessing cycles using injection molding at 160 °C without significant degradation of mechanical properties. However, the 13th reprocessing cycle did not succeed. Rheological analysis revealed the accumulation of non-reversible bonds within the network structure during repeated reprocessing, despite fairly consistent mechanical properties under operating conditions. This study demonstrates that the rational design of the maleimide precursor is an effective means to enhance the reprocessability of DA networks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Understanding and promoting the reaction kinetics of photothermally driven Diels–Alder reaction with minimized side reactions

The thermoreversible Diels–Alder (DA) reaction involving furan and maleimide precursors has been extensively exploited to develop reversible thermosets for circular economy and additive manufacturing. Recently, applications of photothermal nanoparticles, which can absorb light and generate nanoscale heat, have gained significant attention in driving the Diels–Alder (DA) reaction more efficiently. This approach can be utilized by various applications, for example, solar light-enhanced recycling, self-healing at targeted area, and photothermal 3-D printing. Here, in this work, we address an important fundamental question on the photothermal approach: how does the reaction kinetics of the photothermally driven DA reaction compared to that of the conventional heat driven one? We found that the forward DA reaction kinetics varies dramatically depending on a type of heat sources, i.e., light-induced photothermal heat or conventional heat, despite of a similar bulk temperature. We observed that the light-induced photothermal heat significantly enhances the DA reaction rate in comparison to the bulk heating in an inert environment. On the contrary, the photothermally driven forward DA reaction is significantly slower than that of the heat driven reaction in the presence of oxygen. This is attributed to the photoexcited electrons in photothermal nanoparticles that can generate singlet oxygen ( 1 O 2 ) in the presence of visible light. This singlet oxygen may facilitate an endoperoxide side reaction on the furan group, ultimately, retard the DA reaction from the furan group. These results reveal the effectiveness of photothermal nanoparticles in accelerating DA reaction while underscoring the need to minimize oxygen exposure to prevent unfavorable side reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Observational Evidence for Wind‐Driven Low‐Pass Filtering of Infrasound at Short Range

Infrasound from controlled explosions provides a unique opportunity to isolate atmospheric effects on propagation. We report observations from two campaigns in May and October 2024, each featuring 10‐ton TNT‐equivalent controlled surface chemical explosions recorded by a dense network of 31 single‐sensor stations within 23 km. Despite identical sources, the observed wavefields were very different. October signals followed a near‐unimodal period–distance trend, whereas May signals exhibited a pronounced azimuthal bifurcation in both period and celerity. Downwind paths largely preserved the short‐period baseline observed in October, while upwind paths showed systematically longer periods caused by wind‐driven low‐pass filtering. This study provides the first direct observational evidence that tropospheric winds can impose azimuth‐dependent low‐pass filtering at local ranges, without the influence of measured temperature inversions. Thus, the structure of the atmosphere can modify the spectral characteristics of low‐frequency acoustic waves even at a distance of only a few kilometers.

Geosciences↗
DOE OSTI2025

The Nature of Standing Plasma Waves Following Fast Breakdown in Thunderstorms

Narrow bipolar events (NBEs) are produced by large-scale systems of streamer corona discharges that occur inside thunderstorms and radiate intensely at very-high frequencies. Here we examine 14 high-power NBEs recorded in Florida which are followed by a lasting oscillatory signal. We isolate the dominant frequencies of the oscillations using empirical mode decomposition methods, and cross-reference this information with the radiator size inferred from broadband interferometry. We conclude that the oscillations are evidence of a standing electromagnetic wave in the plasma cavity created by the preceding streamer system, that is, the cavity's fundamental mode with wavelength equal to twice the radiator length. Contrasting the dispersive and attenuation properties of these waves across several different events allows us to conclude that the cavity is filled with ions resulting in an average conductivity of 0.01–0.1 mS/m, which are left behind after the streamers decay via electron attachment to oxygen molecules.

58 GEOSCIENCES↗
DOE OSTI2025

Cutoff and Emergence of Dart Leaders in an Unbranched Positive Leader Simulation

Channel cutoff is the process by which an active lightning channel cools down, goes dark, and loses its ability to effectively conduct electricity. Current cutoff precedes several lightning phenomena, notably dart leaders and return strokes, but the process by which a hot, highly‐conducting leader channel can undergo current cutoff is poorly understood. In this work, we present self‐consistent simulations of positive leader propagation, which include coupled treatment of electrodynamics and plasma physics. The unstable positive leader spontaneously undergoes channel cutoff and creates the conditions for the emission of dart leaders, that is, it accumulates a packet of negative charge at the intersection between cutoff and conducting channel segments. A residual conductivity in the cutoff section facilitates the conversion of the electric field enhancement into a traveling wave, which retraces and reionizes the channel. This is critical for allowing the frail positive leader to keep propagating.

58 GEOSCIENCES↗
DOE OSTI2025

Rapid and Temporary Deployment of Fiber-Optic Arrays to Measure Surface Chemical Explosion Series with Distributed Acoustic Sensing

Rapid and temporary distributed acoustic sensing (DAS) deployments are crucial for accurately capturing the seismic wavefield following major events, such as earthquakes, or in anticipation of known events of interest, such as chemical explosions. We provide an overview of two DAS campaigns conducted in May and October 2024 to record the seismoacoustic waves generated by two series of surface chemical explosions in New Mexico, United States, involving 1- and 10-ton trinitrotoluene-equivalent charges. In both campaigns, we deployed approximately 2 km of fiber-optic cables in a dry riverbed, about 12 km east of the explosion sites. For the October campaign, seven geophones and two anemometers were collocated with the fiber. We describe the field deployments and present preliminary results from the recorded signals. Specifically, we cross analyze the data recorded in May and October, validate the DAS data with geophone measurements, and highlight the benefits of burying fibers to reduce wind noise and improve signal-to-noise ratios. This study demonstrates the potential of DAS to record the seismoacoustic waves generated by surface chemical explosions of varying sizes at distances of approximately 10 km from the source.

58 GEOSCIENCES↗
DOE OSTI2026

Mobility of heavy rare earth elements in magmatic-hydrothermal systems: Experimental determination of DyPO 4 solubility in supercritical fluids

Dysprosium (Dy) is part of the heavy rare earth elements (REE) and a critical component in the production of high-performance super magnets used in wind turbines, electric vehicles, and other green technologies. The HREE phosphate, xenotime, is commonly associated with hydrothermal systems, where the mobility, fractionation, and deposition of REE are controlled by the stability of aqueous complexes and solubility of REE minerals which depend on temperature, pressure, and fluid composition (salinity, pH, and ligand availability). Here, we conducted a series of synthetic DyPO 4 solubility experiments in NaCl-HCl-bearing aqueous solutions (pH of 2 at 25 °C) from 500 to 700 °C and 1.5 kbar using externally heated pressure vessels. DyPO 4 displays a strong prograde solubility with temperature across all studied fluid salinities (0–0.5 m NaCl). The DyPO₄ solubility isotherms at 500 °C, 600 °C, and 700 °C show a complex relationship with salinity where DyPO₄ solubility is highest (39.2–1552 ppm at 500–700 °C) in 0 m NaCl solutions, decreases strongly (21–331 ppm at 500–700 °C) in the 0.06 m NaCl solutions and remains relatively constant in the 0.25 m (42.8–248 ppm) and 0.5 m NaCl (40.2–124 ppm) solutions. Thermodynamic modeling suggests that pH increases as a function of temperature and salinity, and controls solubility due to the stability of chloride complexes (i.e., DyCl +2 and DyCl 2 + ) at 500–600 °C, transitioning to hydroxyl complexes (i.e., Dy(OH) 3 0 ) dominating at 700 °C and relatively alkaline pH. Comparison with NdPO 4 solubility data indicates that the light REE in monazite is significantly more soluble than the heavy REE in xenotime in saline fluids at high temperature (500–700 °C), implying efficient light/heavy REE fractionation in supercritical fluids. The lower solubility of DyPO 4 relative to NdPO 4 suggests that at high temperatures, acidic (pH 2–4), low-salinity (∼5 wt% NaCl) fluids will favor the precipitation of xenotime over monazite as it will cool from 700 °C to below 500 °C. These observations align with paragenetic mineral assemblages in NYF pegmatites (e.g., Baveno, Italy), where xenotime commonly immobilizes heavy REE during the high-temperature hydrothermal stages.

58 GEOSCIENCES↗
DOE OSTI2025

NdPO 4 solubility and aqueous Neodymium speciation in supercritical fluids: An experimental study at 500–700 °C and 1.7 kbar

A key aspect in the formation of rare earth elements (REE) deposits is the role of REE transport as aqueous REE complexes in supercritical hydrothermal solutions, where the nature of the aqueous complex is controlled by solution composition, temperature and pressure. Despite chloride being considered as one of the most abundant transporting ligands in magmatic-hydrothermal fluids, experimental investigations on the stability of aqueous REE chloride complexes are scarce above 300 °C. In this study, synthetic NdPO 4 crystals were reacted with non-saline and saline (0, 0.05 and 0.5 mNaCl), acidic (0.01 mHCl) aqueous solutions in a series of solubility experiments conducted at 500–700 °C and 1.7 kbar, where the solubilities were determined using a stable Nd isotope ( 145 Nd isotope spike) dilution technique. NdPO 4 solubility ranges between 28 ppm and 10,858 ppm, where solubility increases with both temperature and salinity. At 500 °C, log mNdPO 4 increases from –3.93 to –1.60 and there is a strong correlation between NdPO 4 solubility and NaCl concentrations (slope of 1.2 ± 0.3), indicating stabilization of the Nd chloride aqueous complexes with a stoichiometry corresponding to NdCl 2+ . At 600 °C, this correlation is weaker (slope of 0.4, log mNdPO 4 increases from –2.63 to –1.88) indicating the stabilization of both Nd chloride and hydroxyl species controlling solubility. At 700 °C, NdPO 4 solubility is largely independent of NaCl concentration indicating that solubility is controlled by Nd hydroxyl complexes, where stoichiometry suggests the neutral Nd(OH) 3 0 species is dominant. The solubility product (Ksp) of NdPO4 is derived from experimental data with the relation: log K sp = -41.81 – 0.057T – 20987/T, with T temperature in Kelvin. Comparison of the measured Nd phosphate solubility to thermodynamic predictions using the available Helgeson-Kirkham-Flowers equation of state parameters for aqueous Nd complexes indicate that predictions are up to three orders of magnitude lower compared to experimental observations. This discrepancy is most pronounced in saline solutions, suggesting that thermodynamic properties of the REE chloride species in supercritical fluids require revision. Numerical simulations of fluid-rock interaction between acidic, saline fluids and a Strange Lake felsic mineral assemblage demonstrates that NdPO 4 solubility predictions from models are four to six orders of magnitude lower than those calculated based on empirical fits from experiments, which suggests that acidic, saline fluids may play an important role in mobilizing large amounts of light REE from 450 to 700 °C.

58 GEOSCIENCES↗