Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “SiO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3

Vibration-rotation intensities of SiO

Dipole moment matrix elements have been computed for a large number of transitions of astrophysical interest for the more abundant isotopes of SiO. The wave functions utilized were obtained from a direct solution of the Schroedinger equation with an accurate RKR potential. The dipole moment function, in the form of a Pade approximant, was chosen to reproduce the experimental measurements near equilibrium, to have the proper united and separated atom limits, and to have the correct long-range asymptotic dependence on internuclear separation. Because of the large number of transitions involved, and to facilitate applications, the squares of the dipole moment matrix elements were fitted by a least-squares procedure to polynomials in v and J. In addition, Einstein A coefficients are given for observed maser transitions and for selected vibrational bands. These latter are compared with previous calculations, and it is concluded that for the higher Delta v transitions, the present results represent a significant improvement.

Tipping, R. H.↗

Sub-arc second 2 centimeter continuum and SiO spectral line observations of R Aquarii

VLA observations with a limiting spatial resolution of about 0.15 arcsec were attempted along with complementary observations of SiO emission using the three-element Hat Creek interferometer to determine an accurate position of the long-period variable (LPV) of the R Aquarii binary system. The observations indicate that the LPV wind is distorted by the photoionization of the hot campanion's accretion disk, that precession of the accretion disk may occur, and that the observed v = 1, J = 2-1 transition emanates from a circumbinary layer far removed from the position of the LPV itself.

Hollis, J. M.↗

SiO overcoating and polishing of CFRP telescope panels

Development of carbon fiber reinforces plastic (CFRP) panel overcoating and polishing is structured in two parts. The first part utilized a short series of experiments to determine the feasibility of overcoating and polishing CFRP panels, and the second part employes a systematic approach to optimize techniques learned. Questions which required answers in the initial investigation are summarized. Tests were performedin the Steward Observatory's 2.2 Meter Vacuum Coating Chamber and began with 3 cm square pieces of CFRP facesheet material. Next, a 10 cm square and one-inch-thick CFPR-Aluminum core panel was tested. Tests were then conducted on a 0.5-meter-square Dornier panel (QUAD 4) with CFRP facesheets on two-inch aluminum Flexcore. To complete the initial study, a previously characterized 0.5 m Dornier panel (QUAD 23) was coated and hand polished. The mirror's optical performance was not affected by the SiO coating.

Woida, Patrick↗

Tridymite and maghemite formation in an Fe-SiO smoke

Grains produced in porous Fe-SiO smoke are analyzed by means of electron microscopy to determine their crystallographical, morphological, and chemical properties. The nucleation of metal oxide condensates takes place as the vapor evolves in a condensation-flow apparatus, initially producing simple crystalline phases. Fe nucleation follows, and the subsequent heterogeneous nucleation of quenched mixed high-Fe silica grains exhibits associated Fe-depletion, eventually producing pure silica grains. The coalescence exhibited by the pure silica grains is compatible with the higher surface energy found in the pure silica phase. During coagulation the grains melt and anneal to a chemically pure mixture of alpha- and beta-tridymite, and the precipitation of amorphous silica material is observed. The settling of grains in evolving solar nebula is theorized to be related to the stickiness of this material, and maghemite is suggested to contribute to the Fe/Si fractionation in solar nebula.

Rietmeijer, F. J. M.↗

Spectral irradiance calibration in the infrared. III - The influence of CO and SiO

Efforts are described to establish a network of calibrated infrared spectra of 'standard stars' suitable for calibration of at least low-resolution infrared spectrometers using ground-based, airborne, and satellite-borne broadband sensors. Emphasis is given to the crucial 5-8 micron region in K and M giants, where the fundamental bands of CO and SiO cause substantial departures from featureless pseudocontinua. The invalidity of the blackbody assumption in the thermal infrared regime is pointed out by demonstrating the importance of these molecular features in cold giants stars in the airborne infrared regime and illustrating their influence on spectra calibrated using blackbody assumptions.

Cohen, Martin↗

The Low-Lying Electronic States of SiO

The singlet states of SiO that correlate with ground state atoms have been studied. The computed spectroscopic constants are in good agreement with experiment. The lifetime of the E state has been calculated to be 10.9 ns; this is larger than the results of previous computations and is in excellent agreement with the experimental value of 10.5 +/- 1.1 ns. The lifetime of the A state is about three times larger than found in experiment. We suggest that absorption from the X state to the (2)(exp 1) II state is responsible for the unidentified lines in the experiment of Hormes et al.

Charles W Bauschlicher↗

Bell Unmanned Aircraft Systems Integration and Operationalization (SIO) Demonstration: Final Report, Summary of Research

National Aeronautics and Space Administration (NASA) initiated the Unmanned Aircraft Systems Integration and Operationalization (SIO) demonstration as a partnership between NASA and Industry with the goal of accelerating routine unmanned aircraft systems (UAS) operations in the national airspace (NAS). In order to accomplish this goal, NASA partnered separately with Bell and two other industry teams each pioneering the development, integration, and testing of their UAS, with the intent to make progress towards type certification. The program culminated in flight demonstrations representing future commercial operations by each partner.

Flight Demonstration↗

Temperature Sensing to Above 1500 °C Using Y 2 SiO 5 :Er Phosphor Thermometry

A transition from metallic to ceramic turbine components that can operate at higher turbine engine temperatures will push component surface temperatures from below 1200 °C into a 1300 to 1500 °C temperature range that is much more challenging for phosphor thermometry measurements. To address this challenge, Y 2 SiO 5 :Er was selected for its high temperature sensing performance by both luminescence lifetime and luminescence intensity ratio (LIR) methods as well as its thermochemical compatibility with the current generation of rare earth silicate environmental barrier coatings (EBCs) that are required to protect SiC/SiC ceramic composite components. Lifetime measurements that monitor the Er3+ 4S3/2→4I15/2 emission decay at 542 nm exhibited a slow decrease in decay time with temperature up to 1300° C, above which the decay decreased steeply to provide good temperature sensitivity in the 1300 to 1500 °C range (Fig. 1). LIR images were obtained where each pixel represented the ratio I488/I561 (I488 and I561 are the detected 488 nm 4F7/2→4I15/2 and the 561 nm 4S3/2→4I15/2 emission band intensities, respectively). Good temperature sensitivity (Fig. 2) and signal-to-background ratios were observed to above 1500 °C. Contrary to conventional guidance on selecting phosphors for high temperature sensing, the detected emission band intensities and decay times exhibited remarkably slow decreases with temperature up into the 1300 to 1500 °C range despite high phonon energies (>900 cm-1) that allow the energy gap between the 4S3/2 emitting reservoir level and the 4F9/2 level below it to be bridged by as few as three phonons. The benefits of utilizing a thermographic phosphor at very high temperatures that exhibits strong nonradiative multiphonon relaxation even at room temperature is explained by a competition between spontaneous and stimulated multiphonon emission, and the more temperature-sensitive decay time above 1300 °C is explained by a transition from high to low effective phonon energies.

temperature measurement↗