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DOE OSTI2025

Enhancing Biopolyester Backbone Rigidity with an Asymmetric Furanic Monomer

Biobased furanic polyesters can exhibit performance advantages over petroleum-derived polyesters, primarily due to their rigid furan-containing backbones. Herein, we develop two strategies to polymerize methyl 5-hydroxymethyl furanoate to poly(5-hydroxymethyl furanoate) (PHMF), a furan-based polyester with even greater backbone rigidity than poly(ethylene furanoate). Thermal, spectroscopic, and computational investigations of PHMF alongside analogous furan-based and phenyl-based polyesters suggest that the high furan content of PHMF leads to its high glass transition temperature, slow crystallization kinetics, and low amorphous mobility. Molecular dynamics simulations suggest that while the backbone of PHMF is exceptionally rigid, its amorphous phase is denser than its phenyl analog due to noncovalent interchain interactions. Together, these results highlight how asymmetric furan-based monomers can modulate key properties in biobased polyesters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1972

Noise from interaction of flow with rigid surfaces: A review of current status of prediction techniques

A brief review of some fundamental aspects of sound arising from turbulent boundary layers, noise due to flow past a single discontinuity (trailing edge), noise from airfoils operating in turbulent flow, and noise due to rigid flow discontinuities (spoilers) immersed in rigid ducts is presented. Emphasis is on dipole-like sound fields associated with turbulent flow past a trailing edge, rigid bodies in turbulence and in-duct spoilers. Representative available data are reviewed and evaluated in terms of theoretical considerations and, where possible, empirical prediction techniques are given in terms of convenient aerodynamic and geometric parameters. Limitations on current knowledge are discussed.

Hayden, R. E.↗

NASA NTRS1974

Dynamic analysis of a system of hinge-connected rigid bodies with nonrigid appendages

Equations of motion are derived for use in simulating a spacecraft or other complex electromechanical system amenable to idealization as a set of hinge-connected rigid bodies of tree topology, with rigid axisymmetric rotors and nonrigid appendages attached to each rigid body in the set. In conjunction with a previously published report on finite-element appendage vibration equations, this report provides a complete minimum-dimension formulation suitable for generic programming for digital computer numerical integration.

Likins, P. W.↗

NASA NTRS1973

Dynamic analysis of a system of hinge-connected rigid bodies with nonrigid appendages

Equations of motion are derived for use in simulating a spacecraft or other complex electromechanical system amenable to idealization as a set of hinge-connected rigid bodies of tree topology, with rigid axisymmetric rotors and nonrigid appendages attached to each rigid body in the set. In conjunction with a previously published companion paper on finite-element appendage vibration equations, this paper provides a complete minimum-dimension formulation suitable for generic programming for digital computer numerical integration.

Likins, P. W.↗

NASA NTRS1974

Rigid and differential rotation driven by oscillations within the sun

Long-period oscillations involving the entire mass of the sun rotate like rigid bodies, and their oscillatory power is distributed nonuniformly across the solar surface. A mostly qualitative theory is constructed showing how the oscillations drive convective flows of global scale, which then organize photospheric and coronal magnetic fields into patterns which rotate rigidly. The convection rises along long graceful curves, creating the magnetic-arcade structures in the corona and unipolar photospheric regions on each side by dynamo action. These are thought to be the origin of the sector structure in the solar wind. The rigid patterns of convective upwelling also force nonrigid horizontal winds on the solar surface. Under the action of the Coriolis force, the main horizontal motions are converted into polar and equatorial wind currents which have the proper directions to drive the differential rotation long observed on the sun's surface.

Wolff, C. L.↗

NASA NTRS1975

Attitude dynamics simulation subroutines for systems of hinge-connected rigid bodies with nonrigid appendages

Three computer subroutines designed to solve the vector-dyadic differential equations of rotational motion for systems that may be idealized as a collection of hinge-connected rigid bodies assembled in a tree topology, with an optional flexible appendage attached to each body are reported. Deformations of the appendages are mathematically represented by modal coordinates and are assumed small. Within these constraints, the subroutines provide equation solutions for (1) the most general case of unrestricted hinge rotations, with appendage base bodies nominally rotating at a constant speed, (2) the case of unrestricted hinge rotations between rigid bodies, with the restriction that those rigid bodies carrying appendages are nominally nonspinning, and (3) the case of small hinge rotations and nominally nonrotating appendages. Sample problems and their solutions are presented to illustrate the utility of the computer programs.

Fleischer, G. E.↗

NASA NTRS1976

Rigid rotators

The two-particle, steady-state Schroedinger equation is transformed to center of mass and internuclear distance vector coordinates, leading to the free particle wave equation for the kinetic energy motion of the molecule and a decoupled wave equation for a single particle of reduced mass moving in a spherical potential field. The latter describes the vibrational and rotational energy modes of the diatomic molecule. For fixed internuclear distance, this becomes the equation of rigid rotator motion. The classical partition function for the rotator is derived and compared with the quantum expression. Molecular symmetry effects are developed from the generalized Pauli principle that the steady-state wave function of any system of fundamental particles must be antisymmetric. Nuclear spin and spin quantum functions are introduced and ortho- and para-states of rotators, along with their degeneracies, are defined. Effects of nuclear spin on entropy are deduced. Next, rigid polyatomic rotators are considered and the partition function for this case is derived. The patterns of rotational energy levels for nonlinear molecules are discussed for the spherical symmetric top, for the prolate symmetric top, for the oblate symmetric top, and for the asymmetric top. Finally, the equilibrium energy and specific heat of rigid rotators are derived.

Source record↗

NASA NTRS1977

Specifying spacecraft flexible appendage rigidity

As a method for specifying the required degree of rigidity of spacecraft flexible appendages, an analytical technique is proposed for establishing values for the frequency, damping ratio, and modal gain (deflection) of the first several bending modes. The shortcomings of the technique result from the limitations associated with the order of the equations that can be handled practically. An iterative method is prescribed for handling a system whose structural flexibility is described by more than one normal mode. The analytical technique is applied to specifying solar panel rigidity constraints for the NASA Space Telescope. The traditional nonanalytic procedure for specifying the required degree of rigidity of spacecraft flexible appendages has been to set a lower limit below which bending mode frequencies may not lie.

Seltzer, S. M.↗

NASA NTRS1977

Addition of rigid elements to NASTRAN

Four rigid elements, namely, a rigid rod element (CRIGDR) and three rigid body elements (CRIGD1, GRIGD2 and CRIGD3), have recently been added to NASTRAN and will be available in the next public release of the program. The theoretical formulation, the bulk data information and the programming details pertaining and realistic problems are illustrated by employing them in the solution of two helicopter structural analysis problems.

Pamidi, P. R.↗

NASA NTRS1979

Coupled motion of rigid bodies about their center of mass

Nontrivial analytical solutions for the coupled motion of two rigid bodies about their center of mass are obtained on the assumptions that the rigid bodies are coupled by a massless rigid boom and that no external forces are acting on the system. Both relative rotational and translational motions of the two bodies are considered. General equations of motion are derived by regarding the two bodies as consisting of two distinct systems of particles and by applying the principle of conservation of angular momentum. It is shown that a basic nontrivial solution can be obtained for the translational problem if an assumption is made concerning the relative orientation of one principal axis of inertia of each body and that fundamental nontrivial solutions are readily obtained for the rotational problem if an additional assumption is made with respect to the symmetry of one body. Certain stability criteria are found for some of these motions by defining regions of constraint for the relative translational and rotational elements.

Jezewski, D. J.↗

NASA NTRS1978

The proton and helium rigidity spectra from 10 to 100 GV

An airborne superconducting magnet spectrometer was used to obtain measurements on 700,000 protons and 50,000 helium nuclei of rigidity greater than about 4 GV. The rigidity spectra of protons and helium nuclei in the 9-100 GV range are determined. In the cited range, the proton and helium nuclei can be represented by a power law in rigidity, with an index of 2.78 + or - 0.03 and 2.80 + or - 0.03 respectively. An upper limit on H-2/p of 10% at 35 GeV/nucleon is established

Badhwar, G. D.↗

NASA NTRS1983

Docking of a rigid spacecraft with unrestrained orbiting flexible structure

A methodology for producing simulations of the docking of a rigid spacecraft with any unrestrained flexible structure was studied. A detailed algorithm for the simulation of the docking of a rigid body with a nonuniform unrestrained beam was sought. The values acquired during docking by the variables characterizing the motions of the rigid body and the unrestrained beam were sought.

Kane, T. R.↗

NASA NTRS1983

Service life evaluation of rigid explosive transfer lines

This paper describes a joint Army/NASA-sponsored research program on the service life evaluation of rigid explosive transfer lines. These transfer lines are used to initiate emergency crew escape functions on a wide variety of military and NASA aircraft. The purpose of this program was to determine quantitatively the effects of service, age, and degradation on rigid explosive transfer lines to allow responsible, conservative, service life determination. More than 800 transfer lines were removed from the U.S. Army AH-1G and AH-1S, the U.S. Air Force B-1 and F-111, and the U.S. Navy F-14 aircraft for testing. The results indicated that the lines were not adversely affected by age, service, or a repeat of the thermal qualification tests on full-service lines. Extension of the service life of rigid explosive transfer lines should be considered, since considerable cost savings could be realized with no measurable decrease in system reliability.

Bement, L. J.↗

NASA NTRS1981

On the rigid body motion and shape distortion evaluation for large flexible spacecraft

A procedure is described for evaluating and subtracting the contribution of the rigid body motion from the general displacement of a Large Space Structure. The shape distortions are thus exhibited and their root mean square calculated. It is well known that a rigid body motion is composed of a rotation and a translation. To evaluate the rotation matrix M, use is made of the fact that unitary matrices can be expressed as M = (I-B)/(I+B) where B is computed using the coordinates, before and after the displacement, of three rigidly attached points. The translation vector is then deduced from the same coordinates.

Hamidi, M.↗

NASA NTRS1985

Diurnal variations of cosmic ray geomagnetic cut-off threshold rigidities

The spectrographic global survey method was used to investigate the rigidity variations Rc of geomagnetic cut-off as a function of local time and the level of geomagnetic disturbance for a number of stations of the world wide network. It is shown that geomagnetic cut-off threshold rigidities undergo diurnal variations. The diurnal wave amplitude decreases with increasing threshold rigidity Rc, and the wave maximum occurs at 2 to 4 hr LT. The amplitude of diurnal variations increases with increasing geomagnetic activity. The results agree with those from trajectory calculations made for an asymmetric model of the magnetosphere during different geomagnetic disturbance conditions.

Dvornikov, V. M.↗

NASA NTRS1990

A rigid line inclusion at a bimaterial interface

A solution is presented for the plane elastostatics problem of a rigid line inclusion at a bimaterial interface. Explicit expressions are derived for the complex potentials. The complex stress intensity factors at the tip of the rigid line are compared with those for the corresponding crack problem. It is found that the nature of the singularities differ. Furthermore, unlike the crack problem, the singularity for the rigid line inclusion depends on the stresses parallel to the interface.

Ballarini, Roberto↗

NASA NTRS1991

A general purpose nonlinear rigid body mass finite element for application to rotary wing dynamics

The Second Generation Comprehensive Helicopter Analysis System employs the present formulation of the general-purpose nonlinear rigid body mass finite element, which represents the hub masses, blade tip masses, and pendulum vibration absorbers. The rigid body mass element has six degrees of freedom, and accounts for gravitational as well as dynamic effects. A consequence of deriving the element's equations from various physical principles is that, prior to the transformation which couples the rigid body mass element to the rotor blade finite element, the forces obtained for each element are fundamentally different; this is true notwithstanding the degrees-of-freedom of each element are parameterized using the same coordinates.

Hamilton, B. K.↗

NASA NTRS1992

A new pre-loaded beam geometric stiffness matrix with full rigid body capabilities

Space structures, such as the Space Station solar arrays, must be extremely light-weight, flexible structures. Accurate prediction of the natural frequencies and mode shapes is essential for determining the structural adequacy of components, and designing a controls system. The tension pre-load in the 'blanket' of photovoltaic solar collectors, and the free/free boundary conditions of a structure in space, causes serious reservations on the use of standard finite element techniques of solution. In particular, a phenomenon known as 'grounding', or false stiffening, of the stiffness matrix occurs during rigid body rotation. The authors have previously shown that the grounding phenomenon is caused by a lack of rigid body rotational capability, and is typical in beam geometric stiffness matrices formulated by others, including those which contain higher order effects. The cause of the problem was identified as the force imbalance inherent in the formulations. In this paper, the authors develop a beam geometric stiffness matrix for a directed force problem, and show that the resultant global stiffness matrix contains complete rigid body mode capabilities, and performs very well in the diagonalization methodology customarily used in dynamic analysis.

Bosela, P. A.↗