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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Rapid solidification of high-conductivity copper alloys

The main objective was to develop improved copper alloys of high strength and high thermal and electric conductivity. Chill block melt spinning was used to produce binary alloys of Cu-Cr and Cu-Zr, and ternary alloys of Cu-Cr-Ag. By quenching from the liquid state, up to 5 atomic percent of Cr and Zr were retained in metastable extended solid solution during the rapid solidification process. Eutectic solidification was avoided and the full strengthening benefits of the large volume fraction of precipitates were realized by subsequent aging treatment. The very low solid solubility of Cr and Zr in Cu result in a high conductivity Cu matrix strengthened by second phase precipitates. Tensile properties on as-cast and aged ribbons were measured at room and elevated temperatures. Precipitate coarsening of Cr in Cu was studied by changes in electrical resistance during aging. X-ray diffraction was used to measure the lattice parameter and the degree of supersaturation of the matrix. The microstructures were characterized by optical and electron microscopy.

Bloom, Theodore Atlas↗
DOE OSTI2023

Influence of Molybdenum on Rapid Solidification Microstructure and Microsegregation in Primary Ferrite Solidified Stainless Steel

Due to the widespread use and familiarity of austenitic stainless steels in many industries these alloys are often the first materials used when adapting new processing techniques. The rapid cooling and solidification rates that occur during fusion based additive manufacturing processes like powder bed fusion cause a fundamental shift in the solidification behavior of the material. While the effects that Cr and Ni have on the microstructure have been fairly well documented across a range of solidification conditions, the impact of alloying elements like Mo are not as well understood at rapid solidification rates. For this study, four custom stainless steel alloy feedstocks were made with targeted modification of the Cr and Mo concentrations to maintain a constant Cr/Ni eq ratio of ~1.7. Two-piston splat quenching was used to produce rapidly solidified samples and the solidification mode, phase, and cell size were investigated. Solidification rates were estimated to be between 0.4 and 1.5m/s. A comparison of the microsegregation and partitioning behavior of Cr, Ni and Mo in ferrite solidified material was also performed for the different alloy compositions. Variations of the Mo concentration between each feedstock showed no measurable influence on the solidification/cooling rates, solidification morphology, or the partitioning of Mo. Furthermore, higher concentrations of Mo were found to significantly increase the amount of ferrite phase in the microstructure by suppressing the ferrite to austenite massive transformation.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Rapid-Solidification Processing Facility

Microstructural changes enhance properties of alloys. Major feature of process is rapid quenching of alloys or intermetallic compounds from liquid to solid state at cooling rates of 10 to the 6th power C/s.

Glasgow, Thomas K.↗
NASA NTRS1988

Dispersion strengthened NiAl alloys produced by rapid solidification processing

Initial experimental results are presented concerning the relationship between microstructure and properties in rapidly solidified NiAl alloys whose melting point is of the order of 1900 K. When the dispersoid content of NiAl alloys is increased, the dispersoids begin to populate the grain boundaries, rendering them weak, so that failure must propagate intergranularly. It is concluded that NiAl alloys' strength can be significantly increased through dispersoid additions without sacrifice of high temperature ductility.

Jha, S. C.↗
NASA NTRS1988

Dispersion strengthening of precipitation hardened Al-Cu-Mg alloys prepared by rapid solidification and mechanical alloying

Several Al-4Cu-1Mg-1.5Fe-0.75Ce alloys have been processed from either rapidly solidified or mechanically alloyed powder using various vacuum degassing parameters and consolidation techniques. Strengthening by the fine subgrains, grains, and the dispersoids individually or in combination is more effective when the alloys contain shearable precipitates; consequently, the strength of the alloys is higher in the naturally aged rather than the artificially aged condition. The strengths of the mechanically alloyed variants are greater than those produced from prealloyed powder. Properties and microstructural features of these dispersion strengthened alloys are discussed in regards to their processing histories.

Gilman, P. S.↗
NASA NTRS1984

Rapid solidification and dynamic compaction of Ni-base superalloy powders

A Ni-base superalloy containing 13Al-9Mo-2Ta (in at. percent) has been characterized in both the rapidly solidified condition and after dynamic compaction. Dynamically compacted specimens were examined in the as-compacted condition and observations related to current theories of interparticle bonding. In addition, the recrystallization behavior of the compacted material at relatively low temperature (about 0.5-0.75 Tm) was investigated.

Field, R. D.↗
DOE OSTI2025

Evolution of dislocations during the rapid solidification in additive manufacturing

Materials processed by fusion-based additive manufacturing (AM) typically exhibit relatively high dislocation densities, along with cellular structures and elemental segregation. This representative structural feature significantly influences material performance; however, post-mortem microstructure characterizations of AM materials cannot capture the dynamic evolution of dislocations during the manufacturing process, thereby offering limited mechanism-based guidance for further advancing AM techniques and facilitating the qualification and certification of AM products. In this study, we conduct operando high-energy synchrotron X-ray diffraction experiments on wire-laser directed energy deposition of 316 L stainless steel. Through a unique configuration, our operando synchrotron experiments semi-quantitatively probe the dislocation density in solid phases and their dynamic changes during solidification and subsequent cooling. By integrating this advanced synchrotron technique with multi-physics simulation, in-situ neutron diffraction, and multi-scale electron microscopy characterization, our mechanistic study aims to elucidate the effects of rapid cooling and subsequent thermal cycling on the dislocation generation and evolution.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Rapid solidification of highly undercooled liquids

Melt undercooling is considered as a fundamental processing parameter for powders and for melt-spun and surface-melted samples. With reference to experimental results for Mn, Al, Al-Be, Al-Fe, and InSb-Sb powders, it is shown that the undercooling behavior in droplets is influenced by powder size, coating, melt superheat, and cooling rate. Droplet sample microstructures can be compared directly with those of rapidly quenched powders to establish the application of laboratory-scale studies to large-scale processing.

Perepezko, J. H.↗
NASA NTRS1983

Rapid solidification of highly undercooled alloy droplets

Experimental work is described on undercooling and structure of tin-lead droplets emulsified in oil. The droplets, predominantly in the size range of 10-20 microns, were cooled at rates ranging from about 0.04 K/sec to 1,000,000 K/sec. The higher cooling rates were obtained by a newly developed technique of quenching the emulsified droplets in a cold liquid. Measured undercoolings (at the lower cooling rates) ranged up to about 100 C. Structures obtained depended strongly on undercooling, cooling rate before nucleation, droplet size, alloy composition and the rate of heat extraction after nucleation.

Chu, M. G.↗
NASA NTRS1985

Rapid solidification characteristics in melt spinning a Ni-base superalloy

The solidification kinetics involved in the process of melt spinning a Ni-base superalloy have been characterized. Through a correlation of ribbon thickness to melt puddle residence time, it was found that the solidification front velocity, V, is typically about 100 mm/sec at the ribbon surface not in contact with the spinning wheel. The rate of solidification varies within the ribbon, increasing with decreasing distance, S, from the wheel-contact surface as V = 3.65/s. Ribbon microstructure and texture characteristics are discussed in light of this kinetics result. The thickness-vs-time correlation was further analyzed to yield information about thermal history during ribbon formation. These thermal results are generally consistent with those deduced from dendrite arm spacing measurements.

Huang, S. C.↗
NASA NTRS1986

Transition from a planar interface to cellular and dendritic structures during rapid solidification processing

The development of theoretical models which characterize the planar-cellular and cell-dendrite transitions is described. The transitions are analyzed in terms of the Chalmers number, the solute Peclet number, and the tip stability parameter, which correlate microstructural features and processing conditions. The planar-cellular transition is examined using the constitutional supercooling theory of Chalmers et al., (1953) and it is observed that the Chalmers number is between 0 and 1 during dendritic and cellular growth. Analysis of cell-dendrite transition data reveal that the transition occurs when the solute Peclet number goes through a minimum, the primary arm spacings go through a maximum, and the Chalmers number is equal to 1/2. The relation between the tip stability parameter and the solute Peclet number is investigated and it is noted that the tip stability parameter is useful for studying dendritic growth in alloys.

Laxmanan, V.↗
NASA NTRS1985

Fundamentals of rapid solidification processing

An attempt is made to illustrate the continuous change that occurs in the solidification behavior of undercooled melts, as cooling rates increase from 0.0001 K/sec to about 1000 K/sec. At the higher cooling rates, more significant changes occur as the dendrite tip temperature begins to drop from the equilibrium liquidus. Discontinuous solidification behavior changes will occur if absolute stability is reached, or a metastable phase forms, or solidification proceeds to a glass rather than to a crystalline solid, or if there is significant undercooling prior to nucleation.

Flemings, Merton C.↗
NASA NTRS1989

Morphological transitions in the rapid solidification regime - A re-examination of the fundamental validity of the absolute stability concept of Mullins and Sekerka

The validity of the notion of absolute stability (AS) of a planar solid-liquid interface, proposed by Mullins and Sekerka (M-S, 1964), was tested using experimental data obtained for a number of dilute Ag-Cu and Sn-In alloys and for ultrahigh-purity succinonitrile. It is shown that the restriction applied by the M-S theory is satisfied during the steady-state planar solidification in an undercooled melt, provided the undercooling is quite small. The findings obtained on the Ag-Cu and Sn-In alloys are compared with early measurements by Davis and Fryzuk (1971) in dilute Sn-In alloys with 25 to 400 ppm additions of In.

Laxmanan, V.↗
NASA NTRS1991

Rapid solidification of polymorphic transition metals induced by nanosecond laser pulses

An Nd-YAG laser giving 5 ns, 266 nm pulses was used to melt and subsequently quench thin, pure metallic films on a liquid Al/Al2O3 substrate at 10 to the 10th - 10 to the 12th K/s. Transmission electron microscopy together with electron diffraction was used to study the competitive nucleation and growth behavior of the crystals from the undercooled melt. In the case of Fe and Co, the high-temperature bcc and fcc structures were retained after laser quenching. Ti and Zr in spite of the structural similarities exhibit different preferences for nucleation from the undercooled melt. In all the metals the solid-state transformations were completely suppressed and the crystal growth was found to be limited by the collisional frequency of the atoms onto the growing interface.

Vitta, Satish↗
NASA NTRS1990

Rotatable crucible for rapid solidification process

This invention relates to an apparatus for producing filament, fiber, ribbon or film from a molten material, comprising a preferably heat extracting crucible which contains a pool of molten material at a selected horizontal level in the pool. The crucible has an opening extending from above the free surface level to a bottom edge of the opening, the bottom edge being sufficiently below the free surface level so that the molten material cannot form and hold a meniscus by surface tension between the edge and the level of the free surface and further comprises a heat extracting substrate laterally disposed with respect to the crucible and which rotates about an axis of rotation. The substrate is positioned adjacent the edge of the opening which confines the molten material and prevents it from overflowing downwardly out of the crucible. The invention features rotating means which includes a first drive means for tiltably rotating the crucible about an axis of rotation which is coaxial with the axis of rotation of the substrate, so the crucible edge can be maintained a predetermined constant distance from the substrate. The distance chosen is suitable for depositing molten material on the substrate and the apparatus also has a second drive means which is drivingly connected to the substrate for continuously moving the surface of the substrate upwardly past the edge and a melt front formed at the interface of the molten material and the substrate surface.

Gaspar, Thomas↗