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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Radiation Effects in Used Next Generation Nuclear Fuel Reprocessing Strategies

Given global commitments to significantly increase nuclear energy capacity, it is now more important than ever to develop efficient used nuclear fuel (UNF) management strategies to encourage widespread adoption of closed fuel cycles. To achieve this ambitious goal, a comprehensive understanding of radiation effects is essential for these next generation technologies, as radiolysis often limits longevity and performance. Here, we present new findings on: (i) the radiation robustness and performance of advanced sulfur chloride-based chlorination processes in the presence of nuclear materials (Fig. 1A); and (ii) the impacts of voloxidized uranium and rhenium complexation on monoamide-based UNF direct dissolution strategies (Fig 1B). These studies employed a combination of time-resolved electron pulse and dose accumulation gamma and electron beam irradiation techniques.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗
DOE OSTI2020

Simulations of coherent scattering experiments at storage ring synchrotron radiation sources in the hard x-ray range

Detailed simulations of experiments carried out at modern light sources are directly related to the most efficient and productive use of these facilities for research in multiple branches of science and technology. The “Synchrotron Radiation Workshop” computer code with its Python interface, and Sirepo web-browser-based graphical user interface, currently supports physical optics simulations of coherent X-ray scattering and imaging experiments on user-defined virtual samples. We present examples of simulations of coherent scattering experiments that are typically performed at the Coherent Hard X-ray beamline at Brookhaven National Laboratory’s (BNL) National Synchrotron Light Source II. We also present several comparisons of the simulations with the results of actual coherent X-ray scattering experiments with nano-fabricated test samples produced at BNL’s Center for Functional Nanomaterials.

36 MATERIALS SCIENCE↗
DOE OSTI2020

A Study of the Ultraviolet Radiation of Hybrid X-Pinches

The results of an experimental study of hybrid X-pinches (HXPs) as sources of vacuum ultraviolet (VUV) radiation within the wavelength range of λ < 2000 Å are presented here. A KING compact low-voltage generator (45 kV, 200 kA, 190 ns) was used to feed the X-pinches. The dynamics of forming the radiating plasma of HXPs of different materials were studied using pinhole cameras with radiation receivers based on microchannel plates with a time resolution of 5 ns and a spatial resolution of 150 µm. The time structure and energy characteristics of the radiation were studied using diamond photoconducting detectors (PCDs). The spectral composition of UV radiation was investigated using a spectrograph based on the transmission grating. It has been shown that the efficiency of conversion of the capacitor-stored energy to the VUV radiation may reach 5%, whereas the fraction of soft X-rays (SXR) with quanta energies above 800 eV is no more than 3%. In this case, the source brightness reaches 2 × 10 9 W/(sr cm 2 ).

plasma UV-spectroscopy↗
DOE OSTI2025

Effect of Gamma Radiation on TaOₓ ECRAM

Electrochemical random access memory (ECRAM) is an emerging three-terminal nonvolatile memory (NVM) with highly controllable channel conductance which is promising for use as an analog memory (or synapse) in analog in-memory computing (IMC) systems. Energy-efficient analog IMC computing is particularly desirable for power-constrained, high-radiation environments such as satellites. However, little is known about the suitability of ECRAM for use in a total ionizing dose (TID) environment. Here, this work investigates the effect of Co-60 gamma radiation on the channel conductance and noise—two properties critical for analog IMC systems—of a TaO x -based ECRAM up to 17.3 Mrad(SiO 2 ) for both low- and high-channel-conductance state devices. A transient increase in conductance is observed in response to radiation which consists of two elements: an immediate increase in conductivity due to photocurrent and a secondary increase in conductivity, which has a slower rise and saturation and can persist for hours after exposure. This secondary, persistent photoconductivity is attributed to charging caused by hole trapping. These transient effects would not likely occur in a space environment due to the low dose rate compared with this experiment. No permanent change is found in the low conductance state (LCS) following exposure and the minor shift in the high conductance change would be less significant than the regular retention decay in this state. A permanent increase in the random telegraph noise is observed, possibly due to increased traps created in the channel. This work demonstrates that TaO x -based ECRAM is suitable for use in spaceborne analog IMC systems that are subject to significant TID.

ECRAM↗
DOE OSTI2026

Impacts of Dual-Use Solar (Agrivoltaics) on Crop Productivity and the Agricultural Economy in Massachusetts and Beyond

This project contributes applied research to better understand the impacts of agrivoltaics on farm microclimates, crop productivity, and economics at the farm and sector level. The site trial research is divided into two sets of site trials integrated into commercial farm and agrivoltaic operations – one set on annual vegetable and hay crops and one on perennial cranberry bog operations. The economic research developed methods for recording and evaluating changes in farm operations and costs, and on the public perception of and willingness-to-accept agrivoltaics.

14 SOLAR ENERGY↗
DOE OSTI2024

Unraveling radiation damage and healing mechanisms in halide perovskites using energy-tuned dual irradiation dosing

Perovskite photovoltaics have been shown to recover, or heal, after radiation damage. Here, we deconvolve the effects of radiation based on different energy loss mechanisms from incident protons which induce defects or can promote efficiency recovery. We design a dual dose experiment first exposing devices to low-energy protons efficient in creating atomic displacements. Devices are then irradiated with high-energy protons that interact differently. Correlated with modeling, high-energy protons (with increased ionizing energy loss component) effectively anneal the initial radiation damage, and recover the device efficiency, thus directly detailing the different interactions of irradiation. We relate these differences to the energy loss (ionization or non-ionization) using simulation. Dual dose experiments provide insight into understanding the radiation response of perovskite solar cells and highlight that radiation-matter interactions in soft lattice materials are distinct from conventional semiconductors. These results present electronic ionization as a unique handle to remedying defects and trap states in perovskites.

14 SOLAR ENERGY↗
DOE OSTI2025

Comparative study of crystallization kinetics and phase segregation of triple cation and methylammonium lead iodide perovskites on moisture probing using synchrotron X-ray based radiation

3D mixed perovskites have achieved substantial success in boosting solar cell efficiency, but the complicated perovskite crystal formation pathway remains mysterious. Here we present detailed crystallization kinetics of mixed perovskites FA 0.83 MA 0.17 Pb(I 0.83 Br 0.17 ) 3 , where FA is formamidinium and MA is methylammonium, with the addition of Cs + to form a triple cation perovskite (3-CAT), in a comparison with the perovskite building block MAPbI 3 (MAPI) via static grazing-incidence wide-angle X-ray scattering (GIWAXS) and micro-diffraction measurements. Spin-coated films produced α-perovskite peaks with no PbI 2 or δ-intermediate phases, which was a promising result for the 3-CAT perovskite from micro-diffraction measurements. However, the 3-CAT did not remain stable on probing with varied relative humidity (RH) conditions as segregation back to the δ-intermediate and PbI 2 phase after 10 s of exposure to an RH value of 11% was found to occur from the GIWAXS results. When RH levels were elevated to over 100%, segregation peaks of PbI 2 and δ-intermediate (2H, 4H and 6H) became conspicuous as the α-phase intensity diminished, unlike for MAPI that remains relatively stable. The possible cause of this is hydrophilic bonds that form between the 3-CAT crystals and the small annealing window of the best composition perovskite (5% Cs + ) film.

Shatsala, Miller (ORCID:0009000927230192)↗
DOE OSTI2024

Water use and radiation balance of miscanthus and corn on marginal land in the coastal plain region of North Carolina

Abstract Miscanthus is a perennial grass that can yield substantial amounts of biomass in land areas considered marginal. In the Coastal Plain region of North Carolina, marginal lands are typically located in coarse‐textured soils with low nutrient retention and water‐holding capacity, and high erosivity potential. Little is known about miscanthus water use under these conditions. We conducted a study to better understand the efficiency with which miscanthus uses natural resources such as water and radiant energy to produce harvestable dry biomass in comparison to corn, a typical commodity crop grown in the region. We hypothesized that under non‐limiting soil water conditions, miscanthus would have greater available energy and water use rates owing to its greater leaf area, thus leading to greater agronomic yields. Conversely, these effects would be negated under drought conditions. Our measurements showed that miscanthus intercepted more radiant energy than corn, which led to greater albedo (by 0.05), lower net radiation (by 4% or 0.4 MJ m −2 day −1 ), and lower soil heat flux (by 69% or 1.0 MJ m −2 day −1 ) than corn on average. Consequently, miscanthus had greater available energy (by 7% or 0.6 MJ m −2 day −1 ) and water use rates (by 14% or 0.5 mm day −1 ) than corn throughout the growing season on average, which partially confirmed our hypothesis. Greater water use rates and radiation interception by miscanthus did not translate to greater water‐use (1.5 g kg −1 vs. 1.6 g kg −1 ) and radiation‐use (0.9 g MJ −1 vs. 1.1 g MJ −1 ) efficiencies than corn. Compared to literature values, our data indicated that water and radiation availability were not limiting at our study site. Thus, it is likely that marginal land features present at the Coastal Plain region such as low soil fertility and high air temperatures throughout the growing season may constrain agronomic yields even if soil water and radiant energy are non‐limiting.

Carvalho, Henrique D. R.↗
DOE OSTI2025

Radiation Effects on the Performance of Advanced Sulfur Monochloride Chlorination Processes

Advanced sulfur chloride-based chlorination technologies are being developed to enable efficient recycling of aluminum and zirconium-based materials used in the nuclear industry. However, the impacts of ionizing radiation on the performance of these sulfur chloride compounds are not well established, despite this being critical knowledge for assessing their feasibility and longevity under envisioned process conditions. Here, in the present article, we report on the effects of cobalt-60 gamma irradiation (≤ 5 MGy) on the aluminum alloy 6061 (AA6061-T6) chlorination yield in sulfur monochloride (S 2 Cl 2 ). Our findings indicate that, compared to nonirradiated solvent, radiation-induced changes in the chemical composition of S 2 Cl 2 —identified using Raman spectroscopy—afford an additional, dose-dependent exothermic process prior to the chlorination reaction’s typical thermodynamic behavior. We attribute this new process to reactions involving aluminum species (metal, oxide, or [oxy]hydroxides) and sulfur dichloride (SCl 2 ), an S 2 Cl 2 radiolysis product that accumulates with absorbed gamma dose, but is absent following an AA6061-T6 chlorination study. Despite the exothermicity of this new process, the overall yield of chlorination decreased with increasing preirradiation dose. Consequently, the chemical reactivity, specificity (aluminum metal vs aluminum passivation and corrosion layer constituents), and byproducts of SCl 2 must be more thoroughly evaluated to support the continued development of advanced S 2 Cl 2 chlorination technologies.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2024

Backend Nuclear Fuel Cycle Radiation Chemistry

Given global commitments to significantly increase nuclear energy capacity, it is now more important than ever to develop efficient used nuclear fuel management strategies to improve resource utilization, energy security, and waste minimization. Here, an overview of nuclear energy, backend fuel cycle challenges, and advances in used nuclear fuel reprocessing radiation chemistry will be presented. More specifically, the use of electron pulse irradiation techniques to explore radiation-induced reaction mechanisms in actinide containing solutions and solvent systems.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2025

The Efficiency of Water Vapor on Top‐of‐Atmosphere Radiation

Earth's climate sensitivity is greatly affected by the compensation between temperature feedback and water vapor (WV) feedback. Using abrupt 4xCO 2 experiments, we show that the global-mean WV feedback is nearly a linear function of the temperature feedback, the slope of which is explained by the longwave radiative efficiency of WV (ϵ). Although ϵ remains constant across models in the global mean, it exhibits substantial spatial variations and is particularly weak in Antarctica, where near-surface inversions decouple the surface from the free troposphere. We introduce a surface–free troposphere temperature difference (SFTD) metric, showing that positive SFTD (e.g., high lifting condensation level) amplifies ϵ, while negative SFTD (e.g., strong surface inversion) suppresses it. These findings provide a clear explanation of how local climate conditions modulate the radiative compensation between temperature and WV feedbacks.

climate feedback↗
DOE OSTI2021

Progress on the National Solar Radiation Data Base (NSRDB): A New DNI Computation

This study introduces a new technique to compute direct normal irradiance (DNI) for improving the National Solar Radiation Data Base (NSRDB). A finite-surface integration algorithm is developed to compute solar radiation in differential solid angles and efficiently infer its contribution to a surface perpendicular to the solar direction. A lookup table of cloud bi-directional transmittance distribution function (BTDF) is developed by use of the discrete ordinates radiative transfer (DISORT) model for possible solar and observing directions and various cloud optical and microphysical properties. In each solar incident direction, DNI is given by the cloud BTDFs from approximately 200 differential solid angles. The simulated DNI is calibrated and evaluated using surface observations at the National Renewable Energy Laboratory's (NREL's) Solar Energy Research Laboratory (SRRL) and the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) facility.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2026

A Coincident CdTe Detector Array for Enhanced Nuclear Process Monitoring

Nuclear fuel cycle aqueous separation processes desire improved real-time material characterization and process monitoring techniques; gamma coincidence spectroscopy has the potential to meet this need in these high throughput and high radiation environments based on its ability to reduce background noise, thereby enhancing detection limits and improving isotopic identification accuracy. A detector array composed of three CdTe detectors was designed to surround a chemical processing pipe in a reprocessing facility and evaluate the feasibility of passively assaying the nuclear materials flowing though this measurement point. This array uses commercial off the shelf components that are radiation hard and highly efficiency at low energies relevant to actinide photon signatures. Detector efficiency characterizations, coincidence detection, and potential configuration improvements are presented here.

Good, Erin C.↗
DOE OSTI2022

Electromagnetic Fireworks: Fast Radio Bursts from Rapid Reconnection in the Compressed Magnetar Wind

One scenario for the generation of fast radio bursts (FRBs) is magnetic reconnection in a current sheet of the magnetar wind. Compressed by a strong magnetic pulse induced by a magnetar flare, the current sheet fragments into a self-similar chain of magnetic islands. Time-dependent plasma currents at their interfaces produce coherent radiation during their hierarchical coalescence. We investigate this scenario using 2D radiative relativistic particle-in-cell simulations to compute the efficiency of the coherent emission and to obtain frequency scalings. Consistent with expectations, a fraction of the reconnected magnetic field energy, f ~ 0.002, is converted to packets of high-frequency fast magnetosonic waves, which can escape from the magnetar wind as radio emission. In agreement with analytical estimates, we find that magnetic pulses of 10 47 erg s –1 can trigger relatively narrowband GHz emission with luminosities of approximately 10 42 erg s –1 , sufficient to explain bright extragalactic FRBs. The mechanism provides a natural explanation for a downward frequency drift of burst signals, as well as the ~100 ns substructure recently detected in FRB 20200120E.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Modeling the Fundamental Radiation Chemistry of the Organic Diluent, and the Effect of Metal Ion Complexation on the Radiochemical Behavior of Active Compounds

All used nuclear fuel (UNF) reprocessing technologies must operate efficiently in the presence of an intense, multi-component (predominantly alpha, beta, and gamma) radiation field. Consequently, radiation-induced degradation of reprocessing systems is of concern, as it negatively impacts process performance over time due to the destruction of both active compounds (ligands, phase modifiers, holdback agents, etc.) and the formation of degradation products. Reprocessing solvent system radiolysis has been linked to changes in separation efficiency and physical properties of solvent mixtures, solvent-recycle longevity, crud formation, and other unexpected outcomes that impact the efficient recovery of valuable materials (e.g., the actinides) and the volume of hazardous radioactive waste for final disposal, i.e., in a geological repository. Consequently, a fundamental understanding of radiolytic processes and their effects on reprocessing solvent system performance is critical for: (i) the cost-effective development and innovation of separation technologies; (ii) the design and implementation of predictive radiation chemical models for process monitoring and lifetimes; and (iii) potentially the ability to exploit radiolytic phenomenon to our benefit, e.g., strategic radiolysis of active molecules to liberate specific degradation products that aid subsequent process stages. Despite extensive investigation into the radiolytic behavior of active solvent system compounds, little attention has been given to understanding (i) the radiation chemical behavior and modification of the organic diluent and (ii) the effect of metal ion complexation on the radiochemical behavior of active compounds.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2024

High-yield implosion modeling using the Frustraum: Assessing and controlling the formation of polar jets and enhancing implosion performance with applied magnetization

Frustraums have a higher laser-to-capsule x-ray radiation coupling efficiency and can accommodate a large capsule, thus potentially generating a higher yield with less laser energy than cylindrical Hohlraums for a given Hohlraum volume [Amendt et al., Phys. Plasmas 26, 082707 (2019]. Frustraums are expected to have less m = 4 azimuthal asymmetries arising from the intrinsic inner-laser-beam geometry on the National Ignition Facility. An experimental campaign at Lawrence Livermore National Laboratory to demonstrate the high-coupling efficiency and radiation symmetry tuning of the Frustraum has been under way since 2021. Simulations benchmarked against experimental data show that implosions using Frustraums can achieve more yield with higher ignition margins than cylindrical Hohlraums using the same laser energy. Hydrodynamic jets in capsules along the Hohlraum axis, driven by radiation-flux asymmetries in a Hohlraum with a gold liner on a depleted uranium (DU) wall, are present around stagnation, and these “polar” jets can cause severe yield degradation. The early-time Legendre mode P4<0 radiation-flux asymmetry is a leading cause of these jets, which can be reduced by using an unlined DU Hohlraum because the shape of the shell is predicted to be more prolate. Magnetization can increase the implosion robustness and reduce the required hotspot ρR for ignition; therefore, magnetizing the Frustraum can maintain the same yield while reducing the required laser energy or increase the yield using the same laser energy—all under the constraint that the ignition margin is preserved. Reducing polar jets is particularly important for magnetized implosions because of the intrinsic toroidal hotspot ion temperature topology.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Tapering-enhanced high-efficiency THz waveguide oscillator

Using a waveguide in a THz FEL has been shown to maximize the coupling and enable efficient extraction of relativistic electron beam energy from a single passage through a tapered helical undulator. An oscillator configuration can further boost energy extraction above the single-pass limits and open the door toward very high average power THz sources. Embedding the undulator in an oscillator cavity is particularly useful in combination with high repetition rate electron sources, even if at reduced peak brightness, since recycling a fraction of the radiation as an intense seed can compensate for lower single-pass gain. In this paper, we investigate the efficiency scaling of a tapering-enhanced waveguide oscillator, showcasing its capability for frequency-tuning operation and high-efficiency operation at different wavelengths. Using a thermionic-driven beamline equipped with compression elements, numerical start-to-end simulation results indicate a 16% efficiency at 200 GHz and a 2.1% efficiency at 1.5 THz, resulting in kW-level average power out-coupled in radiation pulses with few hundred μ J energy and tens of MW peak power. Published by the American Physical Society 2024

Yang, Y. N. (ORCID:0009000849540151)↗
DOE OSTI2020

Wildfire‐Smoke Aerosols Lead to Increased Light Use Efficiency Among Agricultural and Restored Wetland Land Uses in California's Central Valley

Abstract There are few observational studies measuring the ecosystem‐scale productivity effects of changes in incident diffuse photosynthetically active radiation (PAR diffuse ), especially related to wildfire smoke. Climate change‐induced increases to the duration and intensity of fire conditions have made smoke a common occurrence across western North America, with largely unquantified ecosystem feedbacks. Under equivalent amounts of radiation, increased atmospheric particulate matter could lead to a boost in productivity as scattering redistributes photons throughout multilayer canopies. In this work, we leverage a meso‐network of eddy covariance measurement sites across a unique array of managed and restored C 3 and C 4 canopy types to understand how recent wildfire smoke affected ecosystem productivity during the summer of 2018, an especially smoky year in the agriculturally productive Central Valley. We find that diffuse PAR diffuse increased by more than a third compared to the previous growing season, while total PAR was only slightly diminished. These conditions caused nearly a doubling of light use efficiency over the range of diffuse fraction observed, with the highest sensitivity to diffuse fraction exhibited by corn and alfalfa crops. We utilized an empirical model to assess the trade‐off between enhanced diffuse fraction and reduced total PAR. Under mean radiation conditions, daily integrated gross ecosystem productivity increased by 1.2–4.2% compared to the previous growing season. Finally, we explore the potential negative effect of heightened ozone, a copollutant often associated with wildfire. In addition to the effects of wildfire smoke, the results of this natural experiment can help validate future predictions of aerosol‐productivity feedbacks.

Hemes, Kyle S.↗