The melting curves of lithium, sodium, potassium and rubidium to 80 kb
Melting point-pressure curves for lithium, sodium, potassium, and rubidium
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Melting point-pressure curves for lithium, sodium, potassium, and rubidium
Rubidium, Sr and Sr isotopic composition of normal gray hypersthene chondrite falls, noting Rb/Sr and Sr87/Sr86 ratio determination of Bath Furnace L chondrite isochron
Rubidium 87 atomic time and frequency reference system for manned space flight
The construction of a quartz bulb-quartz cavity type rubidium maser is described, and the results obtained with two of these masers are presented. The tuning characteristics, medium term stability, and short term stability are reported. It is concluded that the stability of the masers in the short term region is superior to any of the oscillators presently existing. On this basis it is believed that future development of the masers to reduce their size and improve their medium term stability is well justified.
The lunar mare basalt 15555 from the edge of Hadley Rille has been dated at 3.3 b.y. by both rubidium-strontium and potassium-argon techniques. Age and trace element abundances closely resemble those of the Apollo 12 mare basalts. Data from lunar basalts obtained thus far indicate that they cannot be derived by simple fractionation from a homogeneous source.
A description is given of the development of a compact rubidium-87 maser. Data cover the electronic control system for the maser itself and a superhetrodyne receiver capable of locking a crystal oscillator to the maser signal.
The characteristics of Efratom optically pumped rubidium frequency standards are discussed. The Efratom units were compared with cesium beam and hydrogen maser standards and showed a stability of approximately 5 times 10 to the minus 12th power over two one-week periods. Dependency of frequency upon the environmental parameters of pressure, magnetic field, temperature, supply voltage, and acceleration was measured. A package of three units with automatic phase comparison and recording was designed and constructed to allow a measurement of relativistic effects on time with high accuracy during space missions.
The design, development, and characteristics of a rubidium 87 maser are discussed. The design of a receiver capable of locking a crystal oscillator to the maser signal is reported. The subjects considered are: (1) maser construction, (2) maser control electronics, (3) the characteristics of the receiver, and (4) results of experimental maser tests.
Changes in the intensity of the light source in an optically pumped, rubidium, gas cell frequency standard can produce corresponding frequency shifts, with possible adverse effects on the long-term frequency stability. A pulsed optical pumping apparatus was constructed with the intent of investigating the frequency stability in the absence of light shifts. Contrary to original expectations, a small residual frequency shift due to changes in light intensity was experimentally observed. Evidence is given which indicates that this is not a true light-shift effect. Preliminary measurements of the frequency stability of this apparatus, with this small residual pseudo light shift present, are presented. It is shown that this pseudo light shift can be eliminated by using a more homogeneous C-field. This is consistent with the idea that the pseudo light shift is due to inhomogeneity in the physics package (position-shift effect).
Warm-up and size challenges to oscillator construction are presented as well as the problems involved in these tasks. The performance of M-100 military rubidium oscillator is compared to that of a subminiture rubididum oscillator (M-1000). Methods of achieving 1.5 minute warm-up are discussed as well as improvements in performance under adverse environmental conditions, including temperature, vibration, and magnetics. An attempt is made to construct an oscillator error budget under a set of arbitrary mission conditions.
The error signal which is used to control the frequency of the quartz crystal oscillator of a passive rubidium cell frequency standard is considered. The value of the slope of this signal, for an interrogation frequency close to the atomic transition frequency is calculated and measured for various phase (or frequency) modulation waveforms, and for several values of the modulation frequency. A theoretical analysis is made using a model which applies to a system in which the optical pumping rate, the relaxation rates and the RF field are homogeneous. Results are given for sine-wave phase modulation, square-wave frequency modulation and square-wave phase modulation. The influence of the modulation frequency on the slope of the error signal is specified. It is shown that the modulation frequency can be chosen as large as twice the non-saturated full-width at half-maximum without a drastic loss of the sensitivity to an offset of the interrogation frequency from center line, provided that the power saturation factor and the amplitude of modulation are properly adjusted.
The Rubidium Maser Frequency Standard is a precision frequency source with excellent short-term stability. A type PBR-II Rb maser frequency standard was developed by the Beijing Institute of Radio Metrology and Measurement (BIRMM). The time-domain frequency stability (two-sample variance) of this frequency standard is less than 1/5 times 10 to the 13th power for t=10ms yields 1.0s, fh=1.0 KHz. Two PBR-II frequency standards were used as reference frequency sources in a frequency stability measurement system. Some important system characteristics for the PBR-II Rb maser frequency standard such as phase noise and frequency stability transfer characteristics are discussed. Furthermore, the design of the frequency standard for optimum frequency stability of the output signal; the choice of a voltage controlled crystal oscillator for the frequency standard; the design of the phase-locked loop; and the frequency stability test results on the PBR-II are discussed.
Highly reliable timing system, such as used on board satellites, may incorporate a hot standby atomic clock besides the active one. RF couplings between them may affect the performance of the active clock. The effect of such couplings between two rubidium atomic clocks was investigated, and it was found that they will add an oscillatory term to the Allan Variance of the active clock, degrading its frequency stability, and that under certain circumstances they may also shift the active clock's operating frequency. These two effects are discussed in detail, and the level of isolation required to render them negligible is established.
Some interim results from the environmental testing program to evaluate the Engineering Design Model (EDM) of the EG and G Spaceborne Rubidium Clock are presented. This effort is in support of the Global Positioning System (GPS) BLOCK IIR program and is intended to characterize the performance of EG and G design for BLOCK IIR satellite applications. Two EG and G EDM units are currently under test at NRL's Clock Test Facility to measure the long-term frequency stability, drift, and frequency versus temperature characteristics.
It has been shown in previous studies that in some cesium frequency standards there exist certain C-field settings that minimize frequency changes that are due to variations in the microwave power. In order to determine whether similar results could be obtained with rubidium (Rb) frequency standards (clocks), we performed a similar study, using a completely automated measurement system, on a commercial Rb standard. From our measurements we found that changing the microwave power to the filter cell resulted in significant changes in frequency, and that the magnitude of these frequency changes at low C-field levels went to zero and decreased as the C-field was increased.
Amplified spontaneous emission, ASE, generated by a Ti:Al2O3 laser amplifier has been measured as a function of pump energy, and thus gain, using the atomic absorption of rubidium, Rb, gas at 0.780 micron. By tuning the Ti:Al2O3 laser, the Rb cell could selectively absorb the narrow spectral bandwidth laser radiation while transmitting the wide spectral bandwidth ASE. Transmission of laser amplifier pulses through a Rb absorption cell, measured at various temperatures, thus allows the measurement of the weak ASE in the vicinity of the strong laser pulse. A model for the transmission of Rb as a function of temperature and wavelength has been developed. The measured transmissions are in good agreement with the transmission model predictions.
The 82 Sr/ 82 Rb generator system has found use in positron emission tomography (PET) imaging of myocardial perfusion. 82 Sr is produced by proton irradiation of Rb metal/RbCl salt followed by chemical separation. Inorganic ion-exchangers were synthesized by hydrothermal methods and evaluated for the purification of accelerator-produced 82Sr from a RbCl target and co-produced impurities like 75 Se, Fe, Cr, and Ni. A process consisting of removal of bulk RbCl using sodium nonatitanate (SNT), then removal of remaining tracers of Rb and Se using poorly crystalline silicotitanate (pCST) is suitable for 82 Sr separation and achieves higher purity of 82 Sr vs. commonly used organic resins.
The Doppler Wind Experiment (DWE) is one of six investigations to be performed during the Titan atmospheric descent of the ESA Huygens Probe. The primary scientific objective is to measure the direction and strength of Titan's Zonal winds with an acuracy better than 1 m s-1.