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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Analytical Determination of Radioactive Strontium and Cesium by Thermal Ionization Mass Spectrometry

Thermal ionization mass spectrometry (TIMS) has been evaluated for the detection of the radioactive isotopes of strontium and cesium. The instrument was investigated for the analysis of isotopic ratios of 89Sr to 90Sr and 135Cs to 137Cs in the presence of atomic isobars (Y and Zr for Sr analysis and Ba for Cs analysis). Signicant discrimination using TIMS was found for both Sr and Cs through evaluation using stable isotopes. Fusion procedures with different flux were evaluated for preparation of sample matrices. Chemical separations were developed and used after fusion to isolate the Sr and Cs from a prepared background matrix (i.e., Montana Soil). A graded approach, increasing in stable background isotopes, was performed to monitor the chemistry and instrument response. A thermal neutron irradiation was performed to produce a sample that contained the radioisotopes of Sr and Cs. Even though the irradiated sample was not a certified standard it does provide accurate expectation values via published, well understood cumulative fission yield data. The results presented in this work correlate extremely well with the published data. Furthermore, a significant decrease in uncertainty (by a factor of 5 { 10) was found for the isotopic ratios measured with TIMS compared to the published values.

TIMS, environmental contamination, radiostrontium,↗
DOE OSTI2020

Characterization of Spent Purolite A530E Resin with Implications for Long-Term Radioactive Contaminant Removal

Direct removal of pertechnetate anion (TcO4-) from the subsurface contaminated plumes at legacy nuclear weapons production sites, is effective remediation strategy to prevent their spread to adjacent aquifers but is also challenging because TcO4- is a trace component of the contaminated groundwater typically containing large access of other anionic constituents, such nitrate, sulfate, chloride and others. It can be achieved through ion exchange treatment using Purolite A530E resin which to date however has only been evaluated under laboratory conditions and many questions regarding its long-term operational performance remain. To address this need, here we report comprehensive characterization of the spent Purolite A530E resin which processed over 5.38x109 L of contaminated groundwater and successfully removed about 3.78 Ci of Tc-99 during four years of operation at the 200 West Pump & Treat facility at the US DOE Hanford site. This Tc-99 loading constitutes however only about 0.034% of the theoretical capacity of the resin which retained significant amounts of sulfate. Among other radioactive contaminants, small quantities of U-238, Co-60, and I-129 were retained by the resin. The total loading of iodine (combined 1-127 and I-129) on the spent resin exceeded that of Tc-99. To elucidate the mechanism of iodine retention, ion exchange behavior of iodide and iodate was investigated. Purolite A530E resin exhibited highly efficient uptake of iodide and only moderate affinity for iodate in accord with their Gibbs energy of hydration. Sorption isotherms for both anions obeyed Freundlich model.

Levitskaia, Tatiana G.↗
DOE OSTI2020

Ultra-low radioactivity Kapton and copper-Kapton laminates

Polyimide-based materials, like Kapton, are widely used in flexible cables and circuitry due to their unique electrical and mechanical characteristics. This study is aimed at investigating the radiopurity of Kapton for use in ultralow background, rare-event physics applications by measuring the 238U, 232Th, and natK levels using inductively coupled plasma mass spectrometry. Commercial-off-the-shelf Kapton varieties, mea- sured at approximately 950 and 120 pg/g 238U and 232Th (1.2×104 and 490 µBq/kg), respectively, can be a significant background source for many current and next-generation ultralow background detectors. This study has found that the dominant contamination is due to the use of dicalcium phosphate (DCP), a nonessential slip additive added during manufacturing. Alternative Kapton materials were obtained that did not contain DCP and were determined to be significantly more radiopure than the commercially- available options with 12 and 19 pg/g 238U and 232Th (150 and 77 µBq/kg), respectively. The lowest radioactivity version produced (Kapton ELJ, which contains an adhesive) was found to contain single digit pg/g levels of 238U and 232Th, two-to-three orders of magnitude cleaner than commercial-off-the- shelf options. Moreover, copper-clad polyimide laminates employing Kapton ELJ as the insulator were obtained and measured and showed to be very radiopure at 8.6 and 22 pg/g 238U and 232Th (110 and 89 µBq/kg), respectively.

Arnquist, Isaac J.↗
DOE OSTI2018

Charge Breeding of Radioactive Isotopes at the CARIBU Facility

An Electron Beam Ion Source Charge Breeder (EBIS-CB) has been developed at Argonne National Laboratory as part of the californium rare ion breeder upgrade. For the past year, the EBIS-CB has been undergoing commissioning as part of the ATLAS accelerator complex. It has delivered both stable and radioactive beams with A/Q < 6, breeding times < 30 ms, low background contamination, and charge breeding efficiencies > 18% into a single charge state. The operation of this device, challenges during the commissioning phase, and future improvements will be discussed. Published by AIP Publishing.

Vondrasek, Richard↗
DOE OSTI2016

Results From the First Use of Low Radioactivity Argon in a Dark Matter Search

Liquid argon is a bright scintillator with potent particle identification properties, making it an attractive target for direct-detection dark matter searches. The DarkSide-50 dark matter search here reports the first WIMP search results obtained using a target of low-radioactivity argon. DarkSide-50 is a dark matter detector, using a two-phase liquid argon time projection chamber, located at the Laboratori Nazionali del Gran Sasso. The underground argon is shown to contain Ar39 at a level reduced by a factor (1.4±0.2)×103 relative to atmospheric argon. We report a background-free null result from (2616±43) kg d of data, accumulated over 70.9 live days. When combined with our previous search using an atmospheric argon, the 90% C.L. upper limit on the WIMP-nucleon spin-independent cross section, based on zero events found in the WIMP search regions, is 2.0×10-44 cm2 (8.6×10-44 cm2, 8.0×10-43 cm2) for a WIMP mass of 100 GeV/c2 (1 TeV/c2, 10 TeV/c2).

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1972

Study of extraterrestrial disposal of radioactive wastes. Part 2: Preliminary feasibility screening study of extraterrestrial disposal of radioactive wastes in concentrations, matrix materials, and containers designed for storage on earth

The results are reported of a preliminary feasibility screening study for providing long-term solutions to the problems of handling and managing radioactive wastes by extraterrestrial transportation of the wastes. Matrix materials and containers are discussed along with payloads, costs, and destinations for candidate space vehicles. The conclusions reached are: (1) Matrix material such as spray melt can be used without exceeding temperature limits of the matrix. (2) The cost in mills per kw hr electric, of space disposal of fission products is 4, 5, and 28 mills per kw hr for earth escape, solar orbit, and solar escape, respectively. (3) A major factor effecting cost is the earth storage time. Based on a normal operating condition design for solar escape, a storage time of more than sixty years is required to make the space disposal charge less than 10% of the bus-bar electric cost. (4) Based on a 10 year earth storage without further processing, the number of shuttle launches required would exceed one per day.

Hyland, R. E.↗
NASA NTRS1974

Study of extraterrestrial disposal of radioactive wastes. Part 1: Space transportation and destination considerations for extraterrestrial disposal of radioactive wastes

A feasibility study of extraterrestrial disposal of radioactive waste is reported. This report covers the initial work done on only one part of the NASA study, that evaluates and compares possible space destinations and space transportation systems. The currently planned space shuttle was found to be more cost effective than current expendable launch vehicles by about a factor of 2. The space shuttle requires a third stage to perform the waste disposal missions. Depending on the particular mission, this third stage could be either a reusable space tug or an expendable stage such as a Centaur.

Thompson, R. L.↗
DOE OSTI2017

Predictive modeling of crystal accumulation in high-level waste glass melters processing radioactive waste

The effectiveness of HLW vitrification is limited by precipitation/accumulation of spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr)2O4] in the glass discharge riser of Joule-heated ceramic melters during idling. These crystals do not affect glass durability; however, if accumulated in thick layer, they can clog the melter and prevent discharge of molten glass into canisters. To address this problem, an empirical model was developed that can predict thicknesses of accumulated layers as a function of glass composition. This model predicts well the accumulation of single crystals and/or small-scale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ~53.8 ± 3.7 µm/h determined for this glass will result in ~26 mm thick layer in 20 days of melter idling.

Crystal accumulation↗
DOE OSTI2019

Nuclear properties for astrophysical and radioactive-ion-beam applications (II)

We tabulate the ground-state odd-proton and odd-neutron spins and parities, proton and neutron pairing gaps, one- and two-neutron separation energies, quantities related to β-delayed one- and two-neutron emission probabilities, average energy and average number of emitted neutrons, β-decay energy release and half-life with respect to Gamow–Teller decay with a phenomenological treatment of first-forbidden decays, one- and two-proton separation energies, and α-decay energy release and half-life for 9318 nuclei ranging from {sup 16}O to {sup 339}136 and extending from the proton drip line to the neutron drip line. This paper is a new and improved version of Atomic Data And Nuclear Data Tables [66 131 (1997)]. The starting point of our present work is the new study (FRDM(2012)) of nuclear ground-state masses and deformations based on the finite-range droplet model and folded-Yukawa single-particle potential published in a previous issue of Atomic Data And Nuclear Data Tables [109–110, 1 (2016)]. The β-delayed neutron-emission probabilities and Gamow–Teller β-decay rates are obtained from a quasi-particle random-phase approximation with single-particle levels and wave functions at the calculated nuclear ground-state shapes as input quantities. A development since 1997 is we now use a Hauser–Feshbach approach to account for (n, γ) competition and treat first-forbidden decay in a phenomenological approach.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗