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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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44 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Practical benzylation of N,N -substituted ethanolamines related to chemical warfare agents for analysis and detection by Electron Ionization Gas Chromatography-Mass Spectrometry

The benzylation of three, low-molecular weight N,N-disubstituted ethanolamines related to chemical warfare agents (CWAs) to furnish derivatives with improved Gas Chromatography-Mass Spectrometry (GC-MS) profiles is described. Due to their low molecular weight and polar nature, N,N-disubstituted ethanolamines are notoriously difficult to detect by routine GC-MS analyses during Organisation for the Prohibition of Chemical Weapons (OPCW) proficiency tests (PTs), particularly in scenarios when they are present at low levels (~1-10 ppm) amidst more abundant interferences. Our studies revealed that the optimal derivatization conditions involved the treatment of the ethanolamine with benzyl bromide in the presence of an inorganic base (e.g., Na 2 CO 3 ) in dichloromethane at 55 °C for 2 hours. This optimized set of conditions were then successfully applied to the derivatization of N,N-dimethylethanolamine, N,N-diethylethanolamine and N,N-diisopropylethanolamine present separately at 1 and 10 μg/mL concentrations in a glycerol-rich matrix sample featured in the 48 th OPCW PT. The benzylated derivatives of the three ethanolamines possessed retention times long enough to clear the massive glycerol-containing matrix interferences. In conclusion, the protocol herein is introduced as an alternative method for derivatization of these CWA and pharmaceutically important species and should find broad applicability in laboratories where their routine forensic analysis is carried out.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Joint Actinide Shock Physics Experimental Research (JASPER): System Design Requirements: Trigger Unit

One of the key systems required for the Joint Actinide Shock Physics Experimental Research (JASPER) facility is the timely triggering of the Prompt System (PS). The Trigger Unit (TU) is the critical component that determines when the PS is to be triggered. There are two redundant TUs within the JASPER system, and each TU creates three redundant triggers for the PS. In this fashion, the Prompt Trigger System (PTS) can suffer the loss of one sensor, as well as the loss of one TU, and still function correctly. The TU is designed to receive signals from five separate sensors along the flight of the projectile on its way to the target. The TU uses three pairs of these detectors to create a trigger pulse at the appropriate time, based on the actual velocity of the projectile as it passes between the two sensors.

42 ENGINEERING↗
DOE OSTI2020

Substation Secondary Asset Health Monitoring and Management System (SSHM)

Electric Power Group, LLC (EPG) was awarded DOE OE0000850 to design, develop, and demonstrate a real-time software application for substation secondary equipment health monitoring and management at host utility American Electric Power (AEP), a cost share partner. This project addresses the need for monitoring substation equipment health and providing operators with tools to identify and take pre-emptive action to avoid catastrophic equipment failure. By monitoring synchrophasor data in real time, data anomalies that indicate potential asset failure can be detected and alerts can be sent to operators in time to take corrective actions. EPG developed two data driven algorithms to identify abnormal equipment signature patterns as well as a method using substation linear state estimation (SLSE). The software has been deployed on hardened PC’s and tested and validated for cost share partner AEP’s substations - 138kV and 765 kV. The SSHM software has been accepted by AEP and final demonstration of DOE - OE0000850 for AEP and DOE was successfully completed on March 17th, 2020. EPG developed the Substation Secondary Asset Health Monitoring (SSHM) Platform to analyze equipment failure signatures in PMU data and alert substation personnel when pre-emptive inspection, repairs and other actions are warranted to prevent potential catastrophic failures. This is the first system that automatically monitors the health of substation secondary assets and alerts users to emerging failures using synchrophasor measurements. SSHM uses high resolution PMU data from PTs, CTs, and CCVTs to analyze equipment signatures and identify anomalies that are precursor indicators of potential equipment failure. When an anomaly is detected, there is a likelihood of potential failure of monitored equipment, the system alerts the user with visual alarms including alarm trend charts and indicator lights on a oneline diagram of the substation.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Outdoor Test Bed Performance of a Power Line Sensor Using a Real-Time Event Simulator

This report summarizes the design and application of an outdoor power line sensor testbed (OPLST) with a real-time simulator and power meter to compare a potential transformer (PT) and current transformer (CT) versus an advanced line-post sensor. The OPLST was created to validate advanced medium-voltage (20/34.5 kV) outdoor power line sensors used in electrical distribution systems. Electrical utilities have installed metering and relay-protection transformers like PTs and CTs for several decades. The PTs/CTs are iron core measurement transformers based on the electromagnetic induction principle and provide reliable data in normal grid operation. However, new outdoor power line sensors (OPLS) using other technologies like voltage divider, Rogowski coil and optical principles have become available and may have favorable performance and costs compared to PTs/CTs. Therefore, the importance of testing these technologies with the PT/CT, to compare the measured phase voltage/current at different power grid scenarios is crucial to understand the performance of these new OPLS. For this study a G&W Electric Model CVS-36-O power line sensor was chosen as the OPLS to test with voltage/current signals. An OPAL-RT Technologies Model OP4510 real-time simulator and Schweitzer Engineering Laboratories Model SEL-735 power meter were installed with the 20/34.5 kV OPLST to compare the measured transient events collected from an advanced OPLS and the PT/CT. This system is installed at the Distributed Energy Communications and Control (DECC) lab, Oak Ridge National Laboratory (ORNL). The simulator generated different power grid scenarios (electrical faults, capacitor bank operation, service restoration, etc.), and its analog-output signals were connected to the voltage/current amplifiers that feed the 20/34.5 kV aerial cable loop through the PT/CT devices. Additional PT/CT devices were also wired with the medium voltage aerial cable loop to measure the phase current/voltage signals and server as references. After each test, common format for transient data exchange (COMTRADE) files were collected from the SEL-735 power meter and used to compare the performance of the OPLS with the PT/CT. The behavior of analog signals, harmonic components, total harmonic distortion and crest factors were assessed and found favorable for the G&W sensor as compared to the reference PT/CT.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2022

Silicon Tetrafluoride Vapor Pressure Study

The vapor pressure (VP) of silicon tetrafluoride (SiF4) was evaluated using three different cryogenic cold baths and multiple pressure transducers (PTs). Through this experiment, the known range of VP has been extended to a low temperature of 122 K. A functional relationship for the VP has been developed for the range between 122 and 159.6 K. This relationship was also used to estimate a VP value at 88 K, which was below observable levels with a 0.1 torr gauge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Medium Voltage Testbed for Comparing Advanced Power Line Sensors vs. Transformers with Electrical Grid Events

Electrical utilities have relied upon potential transformers (PTs) and current transformers (CTs) for very accurate metering and to provide reliable signals for protective relays. These devices measure phase voltages and currents and are commissioned by electrical engineers. PTs/CTs can detect and react to various electrical anomalies that could adversely affect electrical grid operations. Less expensive alternative sensing technologies offer the possibility of wider deployment, particularly in grids that employ distributed energy resources. In this work, the performance of an advanced medium-voltage sensor is compared with that of a reference PT and a CT and experimentally evaluated for different power grid scenarios on an advanced outdoor power line sensor testbed at the U.S. Department of Energy’s Oak Ridge National Laboratory. The sensor is based on a capacitive divider for voltage monitoring and a Rogowski coil with an integrator for current monitoring. This study simulated a power grid model based on a utility circuit at the Riverside EPB of Chattanooga. The simulation circuit was created with MATLAB/Simulink software and was integrated into an RT-LAB project to run with the OP4510 real-time simulator at the OPLST. During the tests, the real-time simulations were run for 40 s, and the signal to record the test event with the power meter was set at 30 s for the event-trigger circuit. The advanced outdoor power line sensor testbed has a real-time simulator that is used to generate transient scenarios (e.g., electrical faults, capacitor bank operation, and service restoration), while the analog signals are recorded by the same high-resolution power meter. The behaviors of analog signals, harmonic components, total harmonic distortion, and crest factors are assessed for this power line sensor and compared with those of the reference PT/CT because of the absence of testing standards for advanced outdoor power line sensors. The results showed that this OPLS technology responded identically to the PT and CT under all conditions.

Piesciorovsky, Emilio [ORNL]↗
DOE OSTI2020

Fifth-degree elastic energy for predictive continuum stress-strain relations and elastic instabilities under large strain and complex loading in silicon

Materials under complex loading develop large strains and often phase transformation via an elastic instability, as observed in both simple and complex systems. Here, we represent a material (exemplified for Si I) under large Lagrangian strains within a continuum description by a 5th-order elastic energy found by minimizing error relative to density functional theory (DFT) results. The Cauchy stress—Lagrangian strain curves for arbitrary complex loadings are in excellent correspondence with DFT results, including the elastic instability driving the Si I → II phase transformation (PT) and the shear instabilities. PT conditions for Si I → II under action of cubic axial stresses are linear in Cauchy stresses in agreement with DFT predictions. Such continuum elastic energy permits study of elastic instabilities and orientational dependence leading to different PTs, slip, twinning, or fracture, providing a fundamental basis for continuum physics simulations of crystal behavior under extreme loading.

Levitas, Valery↗
DOE OSTI2020

Hawthorne Nevada Deep Direct-Use Feasibility Study - Data Used for Geothermal Resource Conceptual Modeling and Power Capacity Estimates

This data submission includes several data components that were used to develop a conceptual model and power capacity-estimates of two low-temperature geothermal resources that define geothermal prospect A at Hawthorne, Nevada. Data are sourced from a combination of legacy publicly-available data and more recent data acquisition conducted by the US Navy Geothermal Program Office (2008-2013) and the Great Basin Center for Geothermal Energy at the University of Nevada, Reno (2008-2010). Data sets include compiled fluid geochemistry data, down-hole temperature logs for wells in the vicinity of prospect A, 2 meter temperature survey data, temperature-spinner logs acquired in well HWAAD-2A, fracture picks from image log data acquired in wells HWAAD-2 and HWAAD-3, and X-Ray Diffraction (XRD) analyses on cuttings from wells HWAAD-2A and HWAAD-3. These data have been reviewed for errors and inconsistencies, but it is possible that few errors could still remain. The resource conceptual model and power capacity estimates are included in the final report to the US Department of Energy, and are presented in a manuscript by Ayling and Hinz. A link to the manuscript published in Geothermics is linked below in this submission.

15 GEOTHERMAL ENERGY↗