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A Critical Review of the Circular Economy for Lithium-Ion Batteries and Photovoltaic Modules: Status, Challenges, and Opportunities

To meet net-zero emissions and cost targets for power production, recent analysis indicates that photovoltaic (PV) capacity in the United States could exceed 1 TW by 2050 alongside comparable levels of energy storage capacity, mostly from batteries. For comparison, the total U.S. utility-scale power capacity from all energy sources in 2020 was 1.2 TW (EIA 2022), of which solar satisfied approximately 3% (DOE 2021). With such massive scales of deployment, questions have arisen regarding issues of material supply for manufacturing, end-of-life management of technologies, environmental impacts across the life cycle, and economic costs to both individual consumers and society at large. A set of solutions to address these issues center on the development of a circular economy - shifting from a take-make-waste linear economic model to one that retains the value of materials and products as long as possible, recovering materials at end of life to recirculate back into the economy. With limited global experience, scholars and practitioners have begun to investigate circular economy pathways, focusing on applying novel technologies and analytical methods to fast-growing sectors like renewable energy. This critical review aims to synthesize the growing literature to identify key insights, gaps, and opportunities for research and implementation of a circular economy for two of the leading technologies that enable the transition to a renewable energy economy: solar PV and lithium-ion batteries (LIBs). We apply state-of-the-science systematic literature review procedures to critically analyze over 3,000 publications on the circular economy of solar PV and LIBs, categorizing those that pass a series of objective screens in ways that can illuminate the current state of the art, highlight existing impediments to a circular economy, and recommend future technological and analytical research. We conclude that while neither PV nor LIB industries have reached a circular economy, they are both on a path towards increased circularity. Based on our assessment of the state of current literature and scientific understanding, we recommend research move beyond its prior emphasis on recycling technology development to more comprehensively investigate other CE strategies, more holistically consider economic, environmental and policy aspects of CE strategies, increase leveraging of digital information systems that can support acceleration towards a CE, and to continue to study CE-related aspects of LIB and PV markets.

circular economy↗

Electricity from photovoltaic solar cells. Flat-Plate Solar Array Project of the US Department of Energy's National Photovoltaics Program: 10 years of progress

The objectives were to develop the flat-plate photovoltaic (PV) array technologies required for large-scale terrestrial use late in the 1980s and in the 1990s; advance crystalline silicon PV technologies; develop the technologies required to convert thin-film PV research results into viable module and array technology; and to stimulate transfer of knowledge of advanced PV materials, solar cells, modules, and arrays to the PV community. Progress reached on attaining these goals, along with future recommendations are discussed.

Christensen, Elmer↗

Photovoltaic system criteria documents. Volume 3: Environmental issues and evaluation criteria for photovoltaic applications

The environmental issues and evaluation criteria relating to the suitability of sites proposed for photovoltaic (PV) system deployment are identified. The important issues are defined, briefly discussed and then developed into evaluation criteria. System designers are provided with information on the environmental sensitivity of PV systems in realistic applications, background material which indicates the applicability of the siting issues identified, and evaluation criteria are defined to facilitate the selection of sites that maximize PV system operation.

Koenig, John C.↗

Overall Performance Losses and Activated Mechanisms in Double Glass and Glass-backsheet Photovoltaic Modules with Monofacial and Bifacial PERC Cells, under Accelerated Exposures

Commercial PV modules have various packaging choices nowadays, which influence their long-term reliability. This study compared the degradation behaviors of sixteen module variants from two brands with varying encapsulant materials (EVA or POE), encapsulant types, module architectures (GB or DG), and cell types (monofacial or bifacial) using null hypothesis testing to determine statistical significant findings. The modules were exposed for 2,520 hours under two accelerated exposures: modified damp heat (mDH) and modified damp heat with full-spectrum light (mDH+FSL). For both brands, two DG module variants with UV-Cutoff rear encapsulant are found to have significantly lower average power loss than the module variants of EVA+GB with opaque rear encapsulant after each accelerated exposure. Metallization interconnect corrosion is identified as the primary degradation mechanism. Furthermore, unsupervised hierarchical clustering finds that the degradation behaviors of modules from one brand with a more strict manufacturing quality control depends on module architectures only.

14 SOLAR ENERGY↗