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Polarized fluorescence spectroscopy of O2(+)

Polarized fluorescence measurements involving the A 2Pi(u) - X 2Pi(g) and b 4Sigma(g)(-) - a 4Pi(u) transitions in O2(+) following narrow-band photoexcitation of O2/X 3Sigma(g)(-)/ are reported. The analysis, based on the conventional high-J limit, involves deducing the quadrupole alignment factor from which the relative strengths of degenerate photoexcitation channels responsible for the population distribution in the A 2Pi(u) and b 4Sigma(g)(-) states of O2(+) can be estimated. The measured A-channel polarization exhibits pronounced structure which correlates well with the known positions of Rydberg states, whereas the polarization signal in the b channel has broad and less prominent features. Discrepancies between theoretical and measured results can largely be accounted for by additional configuration mixing and autoionization considerations.

Keller, J. W.↗

Fluorescence yields from photodissociative excitation of HCOOH, HCOOCH3, and CH3COOH in the vacuum-ultraviolet region

The photoexcitation processes of HCOOH, HCOOCH3, and CH3COOH were studied in the vacuum-ultraviolet region by using synchroton radiation and a pulsed discharge lamp as light sources. The absorption and fluorescence cross sections of these molecules were measured in the 106-250-nm region. Fluorescences were detected from photoexcitation of HCOOH and HCOOCH3, but not from CH3COOH. Fluorescence produced at 123.9 nm was dispersed and identified as the excited OH and HCOO radicals. Fluorescence quantum yields of HCOOH and HCOOCH3 increase with decreasing excitation wavelengths with maxima of 5 and 0.3 percent at 106 nm, respectively.

Suto, Masako↗

The Fe XI-excited fluorescent cascade in Ne IV

A theoretical spectroscopic investigation of the fluorescent cascade to be expected in nitrogen-like Ne IV, when it is resonantly photoexcited by Fe XI in the solar atmosphere, symbiotic stars, or novae, is described. Primary and secondary cascade intensities are obtained as functions of photoexcitation rate, and expected absolute intensities in the solar atmosphere are derived on the basis of observed Fe XI and Ne EUV emission. Comparisons between the spatially resolved solar situation and spatially unresolved stellar cases of cataclysmic variables, in which these ions have been found to coexist, are made. An interesting possibility of periodic time-dependent fluorescence exists for the binary cataclysmics.

Bhatia, A. K.↗

3.3 micron emission from ultraviolet excitation of some aromatic molecules

Infrared emissions are observed from photoexcitation of benzene, naphthalene, phenanthrene, anthracene, pyrene, and their methyl derivatives in the gas phase at 193 nm using an ArF laser as a light source. An emission band with peak at 3.3 microns is observed from all the molecules studied. This band is attributed to the aromatic C-H stretching vibrational modes. In addition to the 3.3-microns band, an emission band at 3.4-3.6 microns is observed from photoexcitation of the methyl derivatives, which is attributed to the C-H stretching vibrational modes of the CH3 group. The observed spectra are compared with the IR emission bands observed in many astronomical objects. The current laboratory data lend support to a model in which PAH molecules are responsible for the 'unidentified' interstellar IR emissions. IR emissions from the 193-nm excitation of several interstellar molecules other than PAHs are also observed, but they are quite different from the interstellar IR bands.

Shan, Jun↗

Laser power transmission

An overview of previous studies related to laser power transmission is presented. Particular attention is given to the use of solar pumped lasers for space power applications. Three general laser mechanisms are addressed: photodissociation lasing driven by sunlight, photoexcitation lasing driven directly by sunlight, and photoexcitation lasing driven by thermal radiation.

Conway, Edmund J.↗

Photochemistry of porphyrins: a model for the origin of photosynthesis

A series of porphyrins and catalysts has been prepared as a model for the origin of photosynthesis on the primordial earth. These compounds have been used to test the hypotheses that (1) the biosynthetic pathway to chlorophyll recapitulates the evolutionary history of photosynthesis, and (2) the proto-photosythetic function of biogenetic porphyrins (biosynthetic chlorophyll precursors) was the oxidation of organic molecules by photoexcited porphyrins with the attendant emission of molecular hydrogen. This paper describes experiments in which photoexcited biogenetic porphyrins oxidize ethylenediamine tetraacetic acid (EDTA). The concomitant reduction of protons to hydrogen gas occurs in the presence of a colloidal platinum catalyst. The addition of methyl viologen, a one-electron shuttle, increases the amount of molecular hydrogen generated during long irradiations and the quantum yield of hydrogen production. When the porphyrin and catalyst are held in association by molecular complexes, the increased efficiency of electron transfer produces higher yields of hydrogen gas.

Hydrogen/chemistry↗

Influence of the size and protonation state of acidic residue 85 on the absorption spectrum and photoreaction of the bacteriorhodopsin chromophore

The consequences of replacing Asp-85 with glutamate in bacteriorhodopsin, as expressed in Halobacterium sp. GRB, were investigated. Similarly to the in vitro mutated and in Escherichia coli expressed protein, the chromophore was found to exist as a mixture of blue (absorption maximum 615 nm) and red (532 nm) forms, depending on the pH. However, we found two widely separated pKa values (about 5.4 and 10.4 without added salt), arguing for two blue and two red forms in separate equilibria. Both blue and red forms of the protein are in the two-dimensional crystalline state. A single pKa, such as in the E. coli expressed protein, was observed only after solubilization with detergent. The photocycle of the blue forms was determined at pH 4.0 with 610 nm photoexcitation, and that of the red forms at pH 10.5 and with 520 nm photoexcitation, in the time-range of 100 ns to 1 s. The blue forms produced no M, but a K- and an L-like intermediate, whose spectra and kinetics resembled those of blue wild-type bacteriorhodopsin below pH 3. The red forms produced a K-like intermediate, as well as M and N. Only the red forms transported protons. Specific perturbation of the neighborhood of the Schiff base by the replacement of Asp-85 with glutamate was suggested by (1) the shift and splitting of the pKa for what is presumably the protonation of residue 85, (2) a 36 nm blue-shift in the absorption of the all-trans red chromophore and a 25 nm red-shift of the 13-cis N chromophore, as compared to wild-type bacteriorhodopsin and its N intermediate, and (3) significant acceleration of the deprotonation of the Schiff base at pH 7, but not of its reprotonation and the following steps in the photocycle.

Non-NASA Center↗

Eta Carinae: Orientation of The Orbital Plane

Evidence continues to build that Eta Carinae is a massive binary system with a hidden hot companion in a highly elliptical orbit. We present imaging and spectroscopic evidence that provide clues to the orientation of the orbital plane. The circumstellar ejecta, known as the Homunculus and Little Homunculus, are hourglass-shaped structures, one encapsulated within the other, tilted at about 45 degrees from the sky plane. A disk region lies between the bipolar lobes. Based upon their velocities and proper motions, Weigelt blobs B, C and D, very bright emission clumps 0.1 to 0.3" Northwest from Eta Carinae, lie in the disk. UV flux from the hot companion, Eta Car B, photoexcites the Weigelt blobs. Other clumps form a complete chain around the star, but are not significantly photoexcited. The strontium filament, a 'neutral' emission structure, lies in the same general direction as the Weigelt blobs and exhibits peculiar properties indicative that much mid-UV, but no hydrogen-ionizing radiation impinges on this structure. It is shielded by singly-ionized iron. P Cygni absorptions in Fe I I lines, seen directly in line of sight from Eta Carinae, are absent in the stellar light scattered by the Weigelt blobs. Rather than a strong absorption extending to -600 km/s, a low velocity absorption feature extends from -40 to -150 km/s. No absorbing Fe II exists between Eta Carinae and Weigelt D, but the outer reaches of the wind are intercepted in line of sight from Weigelt D to the observer. This indicates that the UV radiation is constrained by the dominating wind of Eta Car A to a small cavity carved out by the weaker wind of Eta Car B. Since the high excitation nebular lines are seen in the Weigelt blobs at most phases, the cavity, and hence the major axis of the highly elliptical orbit, must lie in the general direction of the Weigelt blobs. The evidence is compelling that the orbital major axis of Eta Carinae is projected at -45 degrees position angle on the sky. Moreover the milliarcsecond-scale extended structure of Eta Carinae, recently detected by VLTI, may be evidence of the binary companion in the disk plane, not necessarily of a single star as a prolate spheroid extending along the ejecta polar axis.

Gull, T. R.↗

Ejecta of Eta Carinae: What We Learn about N-Rich Chemistry

At least one member of the binary system, Eta Carinae, is in the late stages of CNO-cycle. At least ten solar masses of ejecta make up the Homunculus, a neutral bi-polar shell ejected in the 1840s and the Little Homunculus, an internal, ionized bi-polar shell ejected in the 1890s. HST/STIS and VLTAJVES high dispersion spectroscopy revealed absorptions of multiple elements and diatomic molecules in these shells, some, such as V II and Sr II have not been seen previously in the ISM. The skirt region between the bi-lobes includes the very bright Weigelt blobs, within 0.1 to 0.3" of the central source, and the more distant, unusual Strontium Filament, a neutral emission nebula photoexcited by Balmer continuum, but shielded by Fe II from Lyman radiation. The 600+ emission lines are due to metals usually tied up in dust, but underabundances of C and O prevent precipitation as oxides onto the dust grains. Indications are that Ti/Ni is 100X solar, likely due not to nuclear processing, but the very different photo-excitation environments coupled with N-rich, C-, O-poor chemistry. In the Homunculus, level populations of the molecules indicate 60K gas; the metal absorption lines, 760K; that of the Little Homunculus 6400K during the broad spectroscopic maximum, relaxing to 5000K for the few month long minimum. Lyman radiation, including both continuum and Lyman lines, is trapped across periastron. leading to temporary relaxation of the ejecta. These ejecta are a treasure trove of information on material thrown out of massive stars in the CNO-cycle, well before the helium burning phase. Curiously, spectra of three very recent SWIFT GRBs indicate the presence of warm, photoexcited ejecta in the vicinity of the protoGRBs, but obviously of very different abundances. However, the ejecta of Eta Carinae promise to be a nearby example of massive ejecta, the study of which should lead to increased insight of earlier, very distant massive stars.

Gull, Theodore↗

Fe xvii 2p–3s Line Ratio Diagnostic of Shock Formation Radius in O Stars

The 2p–3s lines of Fe xvii in the X-ray spectrum of the O-type star ζ Puppis exhibit an anomalous (3G + M2)/(3F) line ratio of ∼1.4, in comparison with ∼2.4 for almost all other collisionally excited astrophysical spectra. Based on the work of Mauche et al., we conjectured that the strong UV field of ζ Puppis produces the observed ratio by depopulation of metastable 3s excited states, and that the ratio can potentially be used as an independent diagnostic of plasma formation radius. We used the Flexible Atomic Code collisional-radiative model to model the effect of UV photoexcitation from O stars on the Fe xvii lines. We compared our model calculations to archival spectra of coronal and hot stars from the Chandra HETGS and XMM-Newton RGS to benchmark our calculations for various electron densities and UV field intensities. Our calculations show that UV photoexcitation does not produce a sufficiently large dynamic range in the 3F / (3F + 3G + M2) fraction to explain the difference in the observed ratio between coronal stars and ζ Pup. Thus, this effect likely cannot explain the observed line ratio of ζ Pup, and its origin is still unexplained.

Gabriel J. Grell↗

Fe XVII 2p–3s Line Ratio Diagnostic of Shock Formation Radius in O Stars

The 2p–3s lines of Fe xvii in the X-ray spectrum of the O-type star ζ Puppis exhibit an anomalous (3G + M2)/(3F) line ratio of ∼1.4, in comparison with ∼2.4 for almost all other collisionally excited astrophysical spectra. Based on the work of Mauche et al., we conjectured that the strong UV field of ζ Puppis produces the observed ratio by depopulation of metastable 3s excited states, and that the ratio can potentially be used as an independent diagnostic of plasma formation radius. We used the Flexible Atomic Code collisional-radiative model to model the effect of UV photoexcitation from O stars on the Fe xvii lines. We compared our model calculations to archival spectra of coronal and hot stars from the Chandra HETGS and XMM-Newton RGS to benchmark our calculations for various electron densities and UV field intensities. Our calculations show that UV photoexcitation does not produce a sufficiently large dynamic range in the 3F / (3F + 3G + M2) fraction to explain the difference in the observed ratio between coronal stars and ζ Pup. Thus, this effect likely cannot explain the observed line ratio of ζ Pup, and its origin is still unexplained.

Gabriel Grell↗

Photocapacitance effects at a Cu2S-CdS heterojunction.

The influence of trapped charge on the photovoltaic properties of an efficient Cu2S-CdS single-crystal heterojunction has been studied by a photocapacitance technique. For the nonheat-treated cell, a persistent increment in capacitance as high as 70% of the dark capacitance remained after illumination of the junction by band-gap light at 100 K. The additional capacitance is due to holes trapped in deep levels in the CdS depletion region near the interface. The trapped holes enhanced the 100 K photocurrent spectrum uniformly by a factor of 3 before heat treatment. After a 200 C heat treatment in air, the maximum trapped charge at 100 K enhanced the photocurrent by two orders of magnitude. The results are interpreted in terms of the tunneling through a conduction band spike of electrons photoexcited in the Cu2S.

Lindquist, P. F.↗

Laser scanner for testing semiconductor chips

Individual ''fingerprint'' signals are produced when system photoexcites chips. ''Fingerprints'' are analyzed for characteristics associated with defects, including many not visible to the naked eye. Electromagnetic radiation photogenerates free electrons and holes in semiconductor chip. These carriers produce electrical signals at terminals. Signals vary depending on what defects are present.

Hall, T. C.↗

Development of ultraviolet lasers

The pulsed electron accelerator selected for use in the development of ultraviolet laser capability suitable for use in photoexcitation and photoionization studies of the upper atmosphere is reported. Performance figures, installation specifications, and total cost of the equipment are briefly shown, and plans for further studies are outlined.

Walters, G. K.↗

Heat treatment effects in Cu2S-CdS heterojunction photovoltaic cells

The dependence of the short-circuit current on photon energy, temperature, and the state of optical degradation (or enhancement) is determined in a study of the photovoltaic properties of Cu2S-CdS single-crystal heterojunctions. A coherent formulation is proposed for the relationship between enhancement and optical degradation and for their effects on the transport of a short-circuit photoexcited current and dark forward-bias current in a photovoltaic cell. Optical degradation in a Cu2S-CdS cell is shown to be identical to the optical degradation of lifetime in a homogeneous CdS:Cd:Cu crystal.

Fahrenbruch, A. L.↗