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At least 55 records · Page 3

Decomposition of nitrous oxide and chloromethanes absorbed on particulate matter

The effect of pressure on the heterogeneous thermal and pyrolytic decomposition of nitrous oxides adsorbed on sand was studied. Results indicate that N20 adsorbed on certain sand surfaces can be decomposed by photons which nitrous oxide cannot absorb in the gas phase. There is also a thermal heterogeneous decomposition of nitrous oxide which also produces nitrogen. The photolysis of CC14, CFC13, CF2C12 adsorbed on fused quartz and on different types of sand was also investigated. There was no thermal heterogeneous reaction with any of these chloromethanes. Apparently the larger bond energy of approximately 74 kcal for the C-C1 bond compared to approximately 40 kcal for the N-O bond in N2O makes the thermal reaction inoperative for the chloromethanes.

Rebbert, R. E.

Suspended particulate matter in the Chesapeake Bay entrance and adjacent shelf waters

Approximately 400 samples were collected from the mouth of the Chesapeake Bay for various analyses, including 138 for suspended solids. Characteristics of suspended solids that were analyzed included: total suspended matter; total suspended inorganics, total suspended organics; percent organics; particle size distribution; and presence or absence of 11 of the most prominent particle types.

Gingerich, K. J.

Determination of the major groups of phytoplankton pigments from the absorption spectra of total particulate matter

The contributions of detrital particles and phytoplankton to total light absorption are retrieved by nonlinear regression on the absorption spectra of total particles from various oceanic regions. The model used explains more than 96% of the variance in the observed particle absorption spectra. The resulting absorption spectra of phytoplankton are then decomposed into several Gaussian bands reflecting absorption by phytoplankton pigments. Such a decomposition, combined with high-performance liquid chromatography data on phytoplankton pigment concentrations, allows the computation of specific absorption coefficients for chlorophylls a, b, and c and carotenoids. The spectral values of these in vivo absorption coefficients are then discussed, considering the effects of secondary pigments which were not measured quantitatively. We show that these coefficients can be used to reconstruct the absorption spectra of phytoplankton at various locations and depths. Discrepancies that do occur at some stations are explained in terms of particle size effect. These coefficients can be used to determine the concentrations of phytoplankton pigments in the water, given the absorption spectrum of total particles.

Hoepffner, Nicolas

A Particulate Matter

Technical Applications Unlimited, through a contract with Kennedy Space Center, developed the an activity sensor, called the TAU- N100A, which includes a microprocessor-controlled module that detects a particular on a sensor surface and converts this information into digital data. Its original purpose for development was to detect the accumulation of potentially damaging dust and fibers on sensitive payload components.

Source record

Method to Remove Particulate Matter from Dusty Gases at Low Pressures

Future human exploration of Mars will rely on local Martian resources to reduce the mass, cost, and risk of space exploration launched from Earth. NASA's In Situ Resource Utilization (ISRU) Project seeks to produce mission consumables from local Martian resources, such as atmospheric gas. The Martian atmosphere, however, contains dust particles in the 2-to-10 -micrometer range. These dust particles must be removed before the Martian atmospheric gas can be processed. The low pressure of the Martian atmosphere, at 5 to 10 mbars, prevents the development of large voltages required for a standard electrostatic precipitator. If the voltage is increased too much, the corona transitions into a glow/streamer discharge unsuitable for the operation of a precipitator. If the voltage is not large enough, the dust particles are not sufficiently charged and the field is not strong enough to drive the particles to the collector. A method using electrostatic fields has been developed to collect dust from gaseous environments at low pressures, specifically carbon dioxide at pressures around 5 to 10 mbars. This method, commonly known as electrostatic precipitation, is a mature technology in air at one atmosphere. In this case, the high voltages required for the method to work can easily be achieved. However, in carbon dioxide at low pressures, such as those found on Mars, large voltages are not possible. The innovation reported here consists of two concentric cylindrical electrodes set at specific potential difference that generate an electric field that produces a corona capable of imparting an electrostatic charge to the incoming dust particles. The strength of the field is carefully balanced so as to produce a stable charging corona at 5 to 10 mbars, and is also capable of imparting a force to the particles that drives them to the collecting electrode. There are only two possible ways that dust can be removed from Martian atmospheric gas intakes: with this electrostatic precipitator design, and with the use of filters. However, filters require upstream compression of the gas to be treated because the atmospheric pressure on Mars is too close to vacuum to use a vacuum pump downstream to the filter to draw the gas through the filter. The electrostatic precipitator is the best and more efficient solution for this environment. No other precipitator designs have been developed for the environment of Mars due to the challenges of the low atmospheric pressure. Dust particles are charged using corona generation around the high-voltage discharge electrode, which ionizes gas molecules. Since the atmospheric gas intakes for the ISRU processing chambers will likely be cylindrical, cylindrical precipitator geometry was chosen. The electrostatic precipitator design presented here removes simulated Martian dust particles in the required range in a simulated Martian atmospheric environment. The current-voltage (I-V) characteristic curves taken for the nine precipitator configurations at 9 mbars of pressure showed that a cylindrical collecting electrode 7.0 cm in diameter with a concentric positive high voltage electrode 100 m thick provides the best range of voltage and charging corona current. This precipitator design is effective for the size of the dust particles expected in the Martian atmosphere. Mass determination, as well as microscopic images and particle size distributions of dust collected on a silicon wafer placed directly below the precipitator with the field on and off, showed excellent initial results.

Calle, Carlos

Particulate organic matter delta C-13 variations across the Drake Passage

Particulate organic matter (POM) was sampled during two cruise transects across the Drake Passage during March 1986 to investigate the unusual C-13 depletion in high-latitude Southern Ocean plankton. This POM delta C-13 transition from -23.2 o/oo at 53.3 deg S to values as low as -30.3 o/oo at above 62 deg S does not track previously reported abrupt changes in water chemistry and plankton species composition associated with the Polar Front Zone. The north-south isotopic trend is not accompanied by significant changes in POM carbon or nitrogen concentrations, or in POM C/N. Differences in plankton standing crop or biochemistry (e.g. lipid content) do not appear responsible for the isotopic trends observed. The latitudinal change in POM delta C-13 is highly correlated with water temperature and with the calculated concentration of CO2 (aq) at equilibrium with atmospheric CO2. These observations are consistent with the hypothesis that CO2 (aq) significantly influences POM delta C-13 in ocean surface waters.

Rau, G. H.

Development of an Indexing Media Filtration System for Long Duration Space Missions

The effective maintenance of air quality aboard spacecraft cabins will be vital to future human exploration missions. A key component will be the air cleaning filtration system which will need to remove a broad size range of particles including skin flakes, hair and clothing fibers, other biological matter, and particulate matter derived from material and equipment wear. In addition, during surface missions any extraterrestrial planetary dust, including dust generated by near-by ISRU equipment, which is tracked into the habitat will also need to be managed by the filtration system inside the pressurized habitat compartments. An indexing media filter system is being developed to meet the demand for long-duration missions that will result in dramatic increases in filter service life and loading capacity, and will require minimal crew involvement. These features may also benefit other closed systems, such as submarines, and remote location terrestrial installations where servicing and replacement of filter units is not practical. The filtration system consists of three stages: an inertial impactor stage, an indexing media stage, and a high-efficiency filter stage, packaged in a stacked modular cartridge configuration. Each stage will target a specific range of particle sizes that optimize the filtration and regeneration performance of the system. An 1/8th scale and full-scale prototype of the filter system have been fabricated and have been tested in the laboratory and reduced gravity environments that simulate conditions on spacecrafts, landers and habitats. Results from recent laboratory and reducegravity flight tests data will be presented.

Filtration

CARETS: A prototype regional environmental information system. Volume 7: Land use information and air quality planning

The pilot national land use information system developed by the U.S. Geological Survey in the Central Atlantic Regional Ecological Test Site project has provided an improved technique for estimating emissions, diffusion, and impact patterns of sulfur dioxide (S0 2 ) and particulate matter. Implementation of plans to control air quality requires land use information, which, until this time, has been inadequate. The pilot system, however, provided data for updating information on the sources of point and area emissions of S0 2 and particulate matter affecting the Norfolk--Portsmouth area of Virginia for the 1971-72 winter (Dec.-Jan.-Feb.) and the annual 1972 period, and for a future annual period--1985. This emission information is used as input to the Air Quality Display Model of the Environmental Protection Agency to obtain diffusion and impact patterns for the three periods previously mentioned. The results are: (1) During the 1971-72 winter, estimated SO 2 amounts over an area with a SW-NE-axis in the central section of Norfolk exceeded both primary and secondary levels; (2) future annual levels of SO 2 , estimated by anticipated residential development and point-source changes, are not expected to cause serious deterioration of the region's present air quality; and (3) for the 1971-72 winter and annual 1972 period the diffusion results showed that both primary and secondary standards for particulate matter are regularly exceeded in central Norfolk and Portsmouth. In additions on the bas is of current control programs, the 1985 levels of particulate matter are expected to exceed the presently established secondary air quality standards throughout central Norfolk and Portsmouth and in certain areas of Virginia Beach. The land use information can be used to estimate emissions for inputs to diffusion models and to interpret the implications of diffusion patterns for: (1) Implementing various control strategies (2) selecting sites of air sampling stations, and (3) predicting the effects that proposed changes in land use might have on emission patterns and air quality.

Remote sensing

Review of the metallographic cooling rates of meteorites and a new model for the planetesimals in which they formed

The cooling rates of meteorites through approximately 900 -650 K, as read from their metal alloy compositions, are reviewed. Metallographic cooling rates are compared with the cooling rates that appear to be required by the K/Ar and Ar-40/Ar-39 ages of five meteorite classes, and discrepancies are found in all cases. Either (1) the metallographic cooling rates (and also Pu-244 fission cooling rates) are systematically in error, being too slow by a factor of approximately 6; or (2) the traditional thermal model for parent meteorite planets (having constant dimension and uniform physical properties) is oversimplified and the Ar closure temperatures for chondrites derived by Turner et al. (1978) are too low. An alternative parent planet model is proposed and numerically modeled, in which accretion of thermally insulating particulate matter, heat generation by Al-26 decay, melting or sintering of the particulate matter into conductive rock, and establishment of the properties of the meteorites occurred concurrently. Meteorite chronologies are somewhat easier to understand in this context, since the initially small, hot (thus sintered and conductive) bodies would have cooled rapidly to isotopic closure, but later cooling might have been much slower as a result of the continued accretion of insulating particulate matter.

Wood, J. A.

Particulate organic matter (POM) transport and transformation at the terrestrial-aquatic interface (Final Report)

This project investigates the input, transport, and degradation of particulate organic matter (POM) in near-surface riverbed sediments at the Hanford 300 Area of the Columbia River, a dynamic, regulated river system influenced by upstream dam operations. Riverbed sediments are biogeochemical hot spots where organic carbon inputs stimulate intense microbial activity, affecting nutrient cycling and redox transformations in the hyporheic zone (HZ). While dissolved organic matter (DOM) cycling has been studied extensively, little is known about the infiltration and transformation of POM—particularly under variable flow regimes common in large, regulated rivers.

54 ENVIRONMENTAL SCIENCES

Using MODIS Terra 250 m Imagery to Map Concentrations of Total Suspended Matter in Coastal Waters

High concentrations of suspended particulate matter in coastal waters directly effect or govern numerous water column and benthic processes. The concentration of suspended sediments derived from bottom sediment resuspension or discharge of sediment-laden rivers is highly variable over a wide range of time and space scales. Although there has been considerable effort to use remotely sensed images to provide synoptic maps of suspended particulate matter, there are limited routine applications of this technology due in-part to the low spatial resolution, long revisit period, or cost of most remotely sensed data. In contrast, near daily coverage of medium-resolution data is available from the MODIS Terra instrument without charge from several data distribution gateways. Equally important, several display and processing programs are available that operate on low cost computers.

Miller, Richard L.

Soil Particulate Organic Matter is Related to Ericoid Mycorrhizal Shrubs, not Ectomycorrhizal Trees, in a Temperate Forest

Mycorrhizal associations are key drivers of soil biogeochemistry, but previous studies have focused almost exclusively on ectomycorrhizal (EcM) and arbuscular mycorrhizal (AM) associations. Ericoid mycorrhizal (ErM) shrubs frequently occur in forest understories and are expanding in response to disturbance, but are rarely considered in biogeochemical frameworks. We investigated the relationships of understory ErM shrubs and overstory trees on carbon (C) and nitrogen (N) in soil organic matter fractions in a southern Appalachian temperate forest. We sampled the 0–10 cm mineral soil layer from 43 plots at the Coweeta Hydrologic Laboratory, across gradients in overstory EcM dominance and understory ErM shrub biomass. Soil C:N ratios increased with both increasing EcM dominance and increasing ErM shrub biomass. However, total particulate organic matter (POM) C, and the proportion of C and N held in POM increased with increasing ErM shrub biomass, but not with increasing EcM dominance. In contrast, mineral-associated organic matter (MAOM) C and N were negatively associated with EcM dominance, but were not related to ErM shrubs. Our findings suggest that ErM shrubs facilitate POM formation while AM trees promote MAOM formation. Because ErM shrub biomass represents a small fraction of total forest biomass, our work provides evidence that ErM shrubs have an outsized effect on soil organic matter, which advocates for their inclusion in mechanistic studies and biogeochemical frameworks.

Bonilla, Kayla A. [University of Georgia, Athens,

Fine particulate capture device

To capture fine particulate matter in a gas such as air, a dielectric fluid is directed to the center of whichever face of a rotating disc is exposed to the air flow. The disc is comprised of two or more segments which bear opposite electrostatic potentials. As the dielectric fluid is centrifuged towards the periphery of the rotating disc, the fluid becomes charged to the same potential as the segment over which it is passing. Particulate matter is attracted to the charged segment and is captured by the fluid. The fluid then carries the captured particulate matter to a collection device such as a toroidal container disposed around the periphery of the disc. A grounded electrically-conductive ring may be disposed at the outer periphery of the disc to neutralize the captured particles and the fluid before they enter the container.

Peterson, V. S.

Spiral fluid separator

A fluid separator for separating particulate matter such as contaminates is provided which includes a series of spiral tubes of progressively decreasing cross sectional area connected in series. Each tube has an outlet on the outer curvature of the spiral. As fluid spirals down a tube, centrifugal force acts to force the heavier particulate matter to the outer wall of the tube, where it exits through the outlet. The remaining, and now cleaner, fluid reaches the next tube, which is smaller in cross sectional area, where the process is repeated. The fluid which comes out the final tube is diminished of particulate matter.

Robertson, Glen A.

Location generalizability of image-based air quality models

This paper is to be submitted at the IEEE/CVF Winter Conference on Applications of Computer Vision (WACV) Computer Vision for Earth Observation workshop. The full paper abstract is below: The ability to rapidly quantify atmospheric pollutants is important both for global emissions monitoring and for mitigating the adverse effects that follow a hazardous chemical release. In the aftermath of a chemical release, imagery is often the only available resource to assess local conditions. Recent work has demonstrated initial success in predicting particulate matter pollution from imagery; however, these results are tied to a specific site and do not generalize to new geographic locations. In this work, we seek to understand how easily deep learning models generalize to new locations in the context of image-based air quality assessments, targeting two distinct tasks: (1) broad measures of particulate matter pollution, and (2) the mass of a given chemical released in hazardous plumes. For the latter, we focus on sulfur dioxide, a toxic aerosol and a major component of particulate matter pollution caused by industrial fossil fuel consumption. To develop a model that operates in the widest possible range of environments, we test different training strategies, including the use of new geolocation foundation models. The best performing models achieve >80% accuracy when evaluating unseen imagery at previously seen sites, but we find significant drops in performance when evaluating imagery from unseen sites, at best 65%. Additionally, we present the public release of the National Parks Air Quality Index Dataset, a new medium-sized dataset that pairs imagery with sensor-based air quality measurements at 15 different national parks.

Byler, Eleanor B. [BATTELLE (PACIFIC NW LAB)]

NASA Lunar Dust Filtration and Separations Workshop Report

NASA Glenn Research Center hosted a 2.5-day workshop, entitled "NASA Lunar Dust Filtration and Separations Workshop" at the Ohio Aerospace Institute in Cleveland, Ohio, on November 18 to 20, 2008. The purpose of the workshop was to address the issues and challenges of particulate matter removal from the cabin atmospheres in the Altair lunar lander, lunar habitats, and in pressurized rovers. The presence of lunar regolith dust inside the pressurized volumes was a theme of particular interest. The workshop provided an opportunity for NASA, industry experts, and academia to identify and discuss the capabilities of current and developing air and gas particulate matter filtration and separations technologies as they may apply to NASA s needs. A goal of the workshop was to provide recommendations for strategic research areas in cabin atmospheric particulate matter removal and disposal technologies that will advance and/or supplement the baseline approach for these future lunar surface exploration missions.

Agui, Juan H.

Seasonal And Regional Differentiation Of Bio-Optical Properties Within The North Polar Atlantic

Using data collected during spring and summer seasons in the north polar Atlantic we examined the variability of the spectral absorption, a(lambda), and backscattering, b(sub b)(lambda), coefficients of surface waters and its relation to phytoplankton pigment concentration and composition. For a given chlorophyll a concentration (TChla), the concentrations of photosynthetic carotenoids (PSC), photoprotective carotenoids (PPC), and total accessory pigments (AP) were consistently lower in spring than in summer. The chlorophyll-specific absorption coefficients of phytoplankton and total particulate matter were also lower in spring, which can be partly attributed to lower proportions of PPC, PSC, and AP in spring. The spring values of the green-to-blue band ratio of the absorption coefficient were higher than the summer ratios. The blue-to-green ratios of backscattering coefficient were also higher in spring. The higher b(sub b) values and lower blue-to-green b(sub b) ratios in summer were likely associated with higher concentrations of detrital particles in summer compared to spring. Because the product of the green-to-blue absorption ratio and the blue-to-green backscattering ratio is a proxy for the blue-to-green ratio of remote-sensing reflectance, we conclude that the performance of ocean color band-ratio algorithms for estimating pigments in the north polar Atlantic is significantly affected by seasonal shifts in the relationships between absorption and TChla as well as between backscattering and TChla. Intriguingly, however, fairly good estimate of the particulate beam attenuation coefficient at 660 nm (potential measure of total particulate matter or particulate organic carbon concentration) can be obtained by applying a single blue-to-green band-ratio algorithm for both spring and summer seasons.

Stramska, Malgorzata