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Microscopic two-color infrared imaging of Ni Al reactive particles and pellets
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Pellet-Injector Technology—Brief History and Key Developments in the Last 25 Years
High-speed injection of solid fuel was first proposed in 1954 as a possible solution to the problem of transporting fresh fuel across the confining magnetic fields into the plasma of a fusion reactor. While it took a few decades, the use of cryogenic pellets (typically H 2 and D 2 ) on fusion experiments became common place; most tokamaks and stellarators are now equipped with a pellet injector(s). These devices operate at low temperatures (~10 to 20 K) and most often use a simple light gas gun to accelerate macroscopic-size pellets (~0.4- to 6-mm diameter) to speeds of ~100 to 1000 m/s. Before the advantages of pellet injection from the magnetic high-field side (HFS) of a tokamak were recognized in 1997, development focused on increasing the pellet speed to achieve deeper plasma penetration and higher fueling efficiency. The HFS injection technique typically dictates slower pellets (~100 to 300 m/s) to survive transport through the curved guide tubes that route the pellets to the plasma from the inside wall of the device. Two other key operating parameters for plasma fueling are the pellet-injection repetition rate and time duration—a single pellet is adequate for some experiments and a steady-state injection rate of up to ~50 Hz is appropriate for others. In addition to plasma fueling, cryogenic pellets have often been used for particle transport and impurity studies in fusion experiments (most often with neon pellets). During the past two decades, a few new applications for cryogenic pellets have been developed and used successfully in plasma experiments: (1) one for edge-localized mode mitigation, (2) one for plasma disruption mitigation (requires large pellets that are shattered before injection into the plasma), and (3) another in which pure argon pellets are used to trigger runaway electrons in the plasma for scientific studies. Here in this paper, a brief history and the key developments in this technology during the past 25 years are presented and discussed.
Modifications to the JET Shattered Pellet Injector to Optimize Disruption Mitigation Experiments for Supporting ITER’s DMS Design
Shattered pellet injection (SPI) experiments on Joint European Torus (JET) are an important element in determining the physics basis for mitigating disruptions in ITER. Here, the initial design of the JET SPI system included three barrels to produce pellets with diameters of 4.5, 8.1, and 12.5 mm. The variability of the pellet speed by operating with and without a mechanical punch was limited and led to poor pellet integrity, so the mechanical punch was removed. Fragment size distribution is a function of pellet speed and the desire to change the resulting fragment size distribution was not originally a requirement. After the first set of SPI experiments on JET, different pellet sizes were considered to enable dual injection experiments with identical pellet diameters. It was also determined that speed control is necessary to improve experimental repeatability and to determine how the fragment size distribution impacts mitigation performance. Two barrels were fabricated to form pellets of 10 mm diameter and a third to form an 8.1 mm diameter pellet. New propellant valves were also fabricated and characterized to improve repeatability and overall performance. To have fine control of pellet speed, inserts to reduce the breech volume were fabricated and installed. Laboratory testing was conducted to ensure pellet release and provide a comparison of propellant gas delivered versus pellet speeds for a range of pellet types and mixtures. This article will also discuss how lessons learned from the JET SPI modifications can be applied to other SPI systems, such as the ITER SPI system, as controlling pellet release with the least amount of propellant gas is essential for optimal SPI effectiveness.
Developing the Oxidation Kinetic Model for Magnetite Pellet
Oxidation is a vital phenomenon for magnetite pellets in their excursion through the furnace during induration. One of the pre-requisites for magnetite pellets to achieve homogeneously structured good quality pellets is to have complete oxidation before sintering begins. Partially oxidized magnetite pellets, upon sintering, might result in inhomogeneous structured pellets which could be detrimental to pellet quality. It is necessary to understand the mechanisms responsible for magnetite oxidation, and hence, it is intended in this study to investigate experimentally as well as develop a mathematical model based on oxidation kinetics. Oxidation of pellets is largely influenced by the oxidation kinetics of particles and hence should be studied at particle as well as at pellet scale. The principles of the Grain Model have been adopted to develop the Oxidation Model at pellet scale, whereas the particles’ oxidation follows the Avrami Kinetic Model. Isothermal oxidation experiments performed Thermogravimetric Analyzer showed that oxidation rate of magnetite at pellet scale contained two peaks. They were complemented well by oxidation rates predicted from the model. Further, the pellet was investigated microstructurally at pellet and particle scale to substantiate the findings from the experiments and the model. The oxidation model developed is used to predict the progression of oxidation in the magnetite pellet with respect to the reaction time at three different temperatures (873 K, 973 K, and 1073 K (600 °C, 700 °C, and 800 °C)) and at four levels of oxygen (0.21, 0.30, 0.60, and 1.00 atm) in the oxidizing gas.
Modeling Isothermal Reduction of Iron Ore Pellet Using Finite Element Analysis Method: Experiments & Validation
Iron ore pellet reduction experiments were performed with pure hydrogen (H2) and mixtures with carbon monoxide (CO) at different ratios. For direct reduction processes that switch dynamically between reformed natural gas and hydrogen as the reductant, it is important to understand the effects of the transition on the oxide reduction kinetics to optimize the residence time of iron ore pellets in a shaft reactor. Hence, the reduction rates were studied by varying experimental parameters such as the temperature (800, 850 & 900 °C), reactant gas flow rate (100, 150 & 200 cm3/min), pellet size and composition of the reactant gas mixture. The rate of reduction was observed to increase with an increase in temperature and reactant gas flow rate, but it decreased with an increase in pellet size. SEM greyscale analysis was performed to analyze the porosity and phase composition of partially reduced pellets. The porosity of the pellets was observed to increase from 0.3 for unreacted pellet to 0.42 for a completely reduced pellet. Energy-dispersive X-ray spectroscopy (EDAX) analysis was performed to identify the phases observed in the SEM images. The fraction of iron phase was observed to increase from the shell region of the pellet to the core region with an increase in the degree of reduction. A 2D-axisymmetric numerical model was developed on COMSOL Multiphysics, and it was validated using the conversion (X) vs. time curves obtained from each experiment. The model was able to accurately predict the total time needed for the complete conversion of a single iron ore pellet for multiple experiments. Effects of changes in the porosity and tortuosity of the pellet on the model were also studied and the rate of reduction was observed to be sensitive to changes in both porosity and tortuosity. The SEM analysis and the model results show that tortuosity is higher for pellets reduced with H2 than for pellets reduced with H2-CO gas mixtures.
ELM mitigation with pellet ELM triggering and implications for PFCs and plasma performance in ITER
The triggering of rapid small edge localized modes (ELMs) by high frequency pellet injection has been proposed as a method to prevent large naturally occurring ELMs that can erode the ITER plasma facing components (PFCs). Deuterium pellet injection has been used to successfully demonstrate the on-demand triggering of edge localized modes (ELMs) at much higher rates and with much smaller intensity than natural ELMs. The proposed hypothesis for the triggering mechanism of ELMs by pellets is the local pressure perturbation resulting from reheating of the pellet cloud that can exceed the local high-n ballooning mode threshold where the pellet is injected. Nonlinear MHD simulations of the pellet ELM triggering show destabilization of high-n ballooning modes by such a local pressure perturbation.A review of the recent pellet ELM triggering results from ASDEX Upgrade (AUG), DIII-D, and JET reveals that a number of uncertainties about this ELM mitigation technique still remain. These include the heat flux impact pattern on the divertor and wall from pellet triggered and natural ELMs, the necessary pellet size and injection location to reliably trigger ELMs, and the level of fueling to be expected from ELM triggering pellets and synergy with larger fueling pellets. The implications of these issues for pellet ELM mitigation in ITER and its impact on the PFCs are presented along with the design features of the pellet injection system for ITER.
Characterizing value-added pellets obtained from blends of miscanthus, corn stover, and switchgrass
The current pellet industry primarily relies on woody biomass. Inclusion of a diverse feedstock, such as herbaceous biomass, is necessary to meet the rising demand for pellets in heat and power generation, and for biofuel production. This study was motivated by the need to densify biomass, improving its naturally low energy density, to reach the required pellet standards for biofuel conversion. Here, we developed value-added miscanthus pellets blended with different ratios of corn stover and switchgrass and analyzed their chemical, physical, and mechanical properties. Pure miscanthus pellet durability index (PDI) was less than 85 %, well below the ISO 17225-6 standard for herbaceous pellets. While increasing switchgrass and corn stover ratios increases durability beyond 94 %, it also increases ash content from 1.6 % to 4.6 %, a quality unfavorable for biofuel conversion. The moisture content of the blended pellets varied from 7.12 % to 12.45 %, and positively correlated with the durability of the pellets. Pure miscanthus pellets had the highest bulk density, 633 kg/m 3 , while pellets containing 75 % miscanthus and 25 % corn stover had the lowest density, 564 kg/m 3 . The findings of this study also identified a decrease in the pellet bulk density with the increase in ash content and pellet diameter.
Development of Solenoid-Driven and Pneumatic Punches for Launching High- Z Cryogenic Pellets for Tokamak Disruption Mitigation Experiments
Mitigation of disruption events in future high energy density tokamaks is essential for machine longevity. The creation of runaway electrons, large electromagnetic forces, and high localized heat loads during a disruption can be devastating to machine components. Shattered pellet injection is currently the most effective method of disruption mitigation. Injection of cryogenically solidified deuterium, neon, or argon (or mixtures thereof) have been shown to efficiently radiate thermal energy of the plasma so that the heat load is distributed on the walls of the machine. Pellets are formed by desublimating gas in the barrel of a pipe gun and fired using a pulse of high-pressure light gas. Current gas gun designs cannot reach sufficient pressure to dislodge pure neon and argon pellets at low temperatures because the material strength is too high. Pellet temperatures must be kept low (to well below the triple-point temperature of the material) to ensure minimal gas flow into the machine due to vapor pressure of the pellet. A gas-driven punch device has been designed and tested to dislodge pure neon or argon pellets. The breakaway strength of a pellet is proportional to the surface area of the pellet in contact with the inner diameter of the barrel. As pellets get larger in diameter, the amount of force needed to dislodge them increases. To better understand the mechanics behind how a punch dislodges a pellet, a solenoid-operated punch was designed so that kinetic energy of the punch, when striking a pellet, can be varied by changing input current to the solenoid. This solenoid punch will be used to determine kinetic energy versus pellet surface area threshold for breakaway. These data will be used to design mechanical punches for use in a high-field tokamak environment. Furthermore, this paper outlines the modeling, design, experimental testing, and results of the punch development activities.
Issues in Formation of Cryogenic Pellets for Fusion Applications
Cryogenic pellets are used for injection into fusion plasmas to add fuel to build up density and replace the ions lost from fusion reactions and imperfect confinement in the plasma. These pellets are formed at cryogenic temperatures with pure hydrogenic isotopes or mixtures of the isotopes. Technology to make these pellets and inject them into plasmas has been under development for many years, and various methods using freezing or desublimation have been shown to produce high-quality solid pellets suitable for injection. The throughput needed and possible impurity content from the necessary recirculation of fusion exhaust gases are two of the key issues to overcome for fusion pellet fueling systems in long-pulse burning plasmas. Here, we describe the technical challenges associated with these issues and the capability of pellet formation extruders to overcome them.Cryogenic pellets of deuterium, neon, and argon are also used in fusion tokamak devices for disruption mitigation in the form of large pellets that can be injected on demand to quickly dissipate the plasma thermal energy through radiation and add significant density in order to prevent runaway electron formation. Here, the issue is not throughput as with the fueling pellets but rather is the time it takes to form pellets of the size needed and the ability to dislodge them immediately on demand when needed to mitigate a disruption. The method used to make these pellets by desublimation is described, and examples related to how pellet size and input gas parameters affect the formation time are provided.
DESIGN AND COMMISSIONING OF A THREE-BARREL SHATTERED PELLET INJECTOR FOR DIII-D DISRUPTION MITIGATION STUDIES
Disruptions are sudden unplanned terminations of tokamak plasmas that can lead to high thermal loads and runaway electrons (RE). Unmitigated disruptions in ITER are predicted to dissipate hundreds of MJ of thermal energy and generate multi-MeV runaway electrons. This intense heat and energetic particle beams can cause localized melting of the plasma facing components. Reliable and fast acting disruption mitigation (DM) techniques are therefore a critical requirement for ITER to safeguard the machine from damage. The proven method for DM centers on injecting a large quantity of impurity particles into the plasma to quickly increase density and radiate the thermal energy to mitigate thermal effects. Additionally, if the particle injection can achieve a critical density, it can create collisional drag which suppresses the formation of REs. The particle injection methods attempted have been shell pellet injection, massive gas injection, and shattered pellet injection (SPI). The SPI technique has been successfully used on DIII-D [1] to study thermal mitigation using a single-barrel SPI system that can more efficiently reach the critical density required for successful disruption mitigation than the other injection approaches. Recently, a new three-barrel second SPI (SPI-II) system has been developed for use on DIII-D to study injection effects from multiple toroidal locations and pellet timing. The SPI-II system is a liquid helium cooled pipe gun that has two 7 mm and one 8.5 mm pellet sizes. The pellet sizes are determined by the inner diameter of the pipe gun barrels which can easily be changed for different pellet sizes. The three pellets can be formed and fired individually or simultaneously. The SPI-II has provisions for making and firing pure species pellets with deuterium, neon, or argon and also deuterium layered pellets with a core of neon. The pellets are fired into a bent tube near the plasma edge which shatters them from the impact. This paper will describe the design and commissioning of the SPI-II system. Measured pellet speeds and shattered pellet fragment sizes will be reported.
Effect of pelleting process variables on physical properties and sugar yields of ammonia fiber expansion pretreated corn stover
Pelletization process variables including grind size (4, 6 mm), die speed (40, 50, 60 Hz), and preheating (none, 70 degrees C) were evaluated to understand their effect on pellet quality attributes and sugar yields of ammonia fiber expansion (AFEX) pretreated biomass. The bulk density of the pelletized AFEX corn stover was three to six times greater compared to untreated and AFEX-treated corn stover. Also the durability of the pelletized AFEX corn stover was >97.5% for all pelletization conditions studied except for preheated pellets. Die speed had no effect on enzymatic hydrolysis sugar yields of pellets. Pellets produced with preheating or a larger grind size (6 mm) had similar or lower sugar yields. Pellets generated with 4 mm AFEX-treated corn stover, a 60 Hz die speed, and no preheating resulted in pellets with similar or greater density, durability, and sugar yields compared to other pelletization conditions.
Pellet fueling experiments in Wendelstein 7-X
During the two most recent experimental campaigns in the advanced stellarator Wendelstein 7-X (W7-X) (Klinger et al 2017 Plasma Phys. Control. Fusion 59 014018; Bosch et al 2017 Nucl. Fusion 57 116015; Wolf et al 2017 Nucl. Fusion 57 102020; Pedersen et al 2017 Phys. Plasmas 24 0555030) hydrogen ice pellet injection was performed for the first time. In order to investigate the potential of pellet fueling in W7-X and to study the particle deposition in a large stellarator, a blower-gun system was installed with 40 pellets capability. The experience gained with this system will be used for the specification of a future steady-state pellet injector system. One important motivation for a pellet injector (Dibon 2014 Master-Thesis Technical University Munich, Max-Planck Institut IPP) on W7-X is the mitigation of hollow density profiles expected in case of predominant neoclassical transport. For long-pulse operation of up to 30 min, only electron cyclotron resonance heating is available on W7-X. Hence, pellet injection will be the only source for deep particle fueling. Deep particle fueling by pellets in tokamaks is supported by a grad-B drift, if the pellets are injected from the magnetic high-field-side. This approach was tested in W7-X, as well. The injection of series of pellets was also tested. Here, deep fueling is supported for later pellets in the series by the plasma cooling following the initial pellets in the same series. As in earlier experiments in the heliotron LHD (Takeiri et al 2017 Nucl. Fusion 57 102023), deep and rapid fueling could be achieved successfully in W7-X.
Prediction of pellet mass thresholds for ELM triggering in low-collisionality, ITER-like discharges
Abstract In ITER, pellets are calculated to require more than 8 times the mass than currently planned to reliably trigger edge-localized modes (ELMs). Unmitigated heat flux impulses from ELMs are intolerable in ITER at full power and current. Therefore, ITER operation relies on multiple approaches to control ELM heat fluxes. One method is pellet ELM pacing to instigate small rapid ELMs with low heat flux. Predicting the performance of pellet pacing is critical for ITER, which is expected to operate in a regime with a low-collisionality, peeling-limited pedestal. However, to trigger ELMs the local pressure increase in the expanding pellet cloud pushes the equilibrium over the ballooning stability limit. In this work, linear and nonlinear M3D-C1 simulations are used to predict pellet mass thresholds in DIII-D discharges and ITER scenarios with peeling-limited pedestals. It is found that the distance of the equilibrium’s operational point from the ballooning branch of the pedestal stability boundary strongly changes thresholds. Linear M3D-C1 simulations find a strong dependence of the pellet mass threshold on the poloidal injection location for ITER’s 15 MA, Q = 10 scenario. The required pellet mass at the planned injection locations is 8 to 17 times larger than currently considered. However, such linear simulations do not include pellet ablation physics or time evolution of density and temperature. A new scheme of 2D nonlinear simulations, coupled with linear stability analysis at various steps throughout the nonlinear time evolution, was developed to include such physics and improve on the linear results. These new nonlinear-to-linear simulations confirm previous findings. This result suggests that pellet ELM triggering in ITER could require pellets much larger than those currently planned, which makes ELM-pacing operationally challenging. On the other hand, fueling pellets injected from the high-field side will likely not unintentionally trigger ELMs in an otherwise ELM-stable plasma.
Simulation of pellet ELM triggering in low-collisionality, ITER-like discharges
3D nonlinear, as well as 2D linear M3D-C1 simulations are used to model ELM triggering by small pellets in DIII-D discharges in the ITER relevant, peeling-limited pedestal stability regime. A critical pellet size threshold is found in both experiment and modeling depending on pedestal conditions, pellet velocity and injection direction. Using radial injection at the outboard midplane, the threshold is determined by M3D-C1 for multiple time slices of a DIII-D low-collisionality discharge that has pellet ELM triggering. Experimental observations show that a larger pellet size than the standard 1.3 mm diameter is necessary for ELM triggering; 1.8 mm pellets triggered several ELMs in cases where a smaller pellet failed. The M3D-C1 simulations are in good agreement with these observations. While the 2D linear simulations give insight into the change of growth rates for various toroidal modes with pellet size, the 3D nonlinear simulations apply a pellet ablation model that mimics the actual injection with good match to the experiment. The 3D nonlinear simulation confirms the pellet ELM triggering for a pellet size larger than the threshold found by the linear simulations.
Grain Size and Phase Purity Characterization of U 3 Si 2 Pellet Fuel
Characterization of U 3 Si 2 fresh fuel pellets is important for quality assurance and validation of the finished product. Grain size measurement methods, phase identification methods using scanning electron microscopes equipped with energy dispersive spectroscopy and x-ray diffraction, and phase quantification methods via image analysis have been developed and implemented on U 3 Si 2 pellet samples. A wide variety of samples have been characterized including representative pellets from an initial irradiation experiment, and samples produced using optimized methods to enhance phase purity from an extended fabrication effort. The average grain size for initial pellets was between 16 and 18 µm. The typical average grain size for pellets from the extended fabrication was between 20 and 30 µm with some samples exhibiting irregular grain growth. Pellets from the latter half of extended fabrication had a bimodal grain size distribution consisting of coarsened grains (>80 µm) surrounded by the typical (20-30 µm) grain structure around the surface. Phases identified in initial uranium silicide pellets included: U 3 Si 2 as the main phase composing about 80 vol. %, Si rich phases (USi and U 5 Si 4 ) composing about 13 vol. %, and UO 2 composing about 5 vol. %. Initial batches from the extended U 3 Si 2 pellet fabrication had similar phases and phase quantities. The latter half of the extended fabrication pellet batches did not contain Si rich phases, and had between 1-5% UO 2 : achieving U 3 Si 2 phase purity between 95 vol. % and 98 vol. % U 3 Si 2 . The amount of UO 2 in sintered U 3 Si 2 pellets is correlated to the length of time between U 3 Si 2 powder fabrication and pellet formation. These measurements provide information necessary to optimize fabrication efforts and a baseline for future work on this fuel compound.
A New Manufacturing Method of Bentonite Pellets as a Gap Filling Material for HLW Repository - 16110
In high-level waste (HLW) repositories in Japan, there is a need to properly deal with gaps that surround buffers made of bentonite-based material, which are inevitably generated during construction. Bentonite pellets are thought to be a candidate material for filling these gaps. To fill the gaps densely in order to ensure desired buffer quality, high-density pellets with spherical shape would be suitable, and we have developed a new method for manufacturing such bentonite pellets, which is different from conventional methods. The new method first produces spherical pellets by extrusion and spheronization by alternately using two commercially available pelletizing machines. Then, the pellets, which do not have a very high density because of their water content, are turned into high-density ones using dry shrinkage. For typical Japanese sodium bentonite, we confirmed that spherical pellets can be manufactured when the water content is relatively high within the range of 25 to 30%. We observed that proper dry shrinkage enables the wet spherical pellets with a low density of about 1,500 kg/m{sup 3} to turn into ones with a high dry density of about 2,000 kg/m{sup 3} . Drying slowly causes the proper dry shrinkage. We performed simple laboratory tests to evaluate the filling performance of pellets produced by the new manufacturing method. The maximum filling density obtained was 1,540 kg/m{sup 3} when large (20-mm diameter) and small (1-mm diameter) pellets were mixed in the proportion of 60 % to 40 %, which is considerably higher than the previously reported maximum filling density in Japan, which was about 1,300 kg/m{sup 3}. (authors)
The Role of Biomass Composition and Steam Treatment on Durability of Pellets
Steam treatment has been reported to improve the durability of wood pellet likely by changing the physical and chemical structures of wood particles, but published literature is inconclusive about which structure change is the major reason for enhanced durability. Here, in this paper, steam treatment was combined either with alkaline or with SO 2 to study. The solids obtained after steam treatments along with a control sample were dried and each was compacted into pellets. The pellets were then tested for durability. Steam treatment alone dominated improvements in durability. The pellet durability increased with the amount of xylose, but xylose performed better in the pellet from raw poplar than did in the pellet from treated poplar. Water-soluble components contributed a maximum 4% of the durability of poplar pellets. The addition of lignin and sugars to substrates after steam treatment did not improve durability significantly. The surface modification that took place as a result of size reduction during steam treatment was the major reason, contributing about 50% of the durability of the pellet from steam-treated poplar. The acidity of steam treatment slightly affected the relative contributions of these structure changes on the durability. Lastly, the new knowledge helps tailor the chemical and/or mechanical pretreatment involved in pelleting biomass to durable pellets.