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Atomic bond rupture rate in rubber subjected to uniaxial tensile strain in ozone environment monitored by electron paramagnetic resonance measurements
Ag species paramagnetic relaxation in gamma- irradiated frozen aqueous solutions and in frozen methanol, relating spin-lattice relaxation to isotropic coupling
Electron paramagnetic resonance of Mn ions in single crystal and powder forsterite, testing heat treatment and proton irradiation effect on ordering
Apollo 11 lunar fines, rocks and breccias luminescence, electron paramagnetic resonance and optical properties, discussing reflection spectra, heating effects and dipole resonance
EPR study of two smectic A liquid crystals using vanadyl acetyl acetonate as paramagnetic probe
Electron paramagnetic resonance and optical absorption spectra of transition metal ions in zoisite crystal
Electron paramagnetic resonance spectral investigation of dynamic Jahn-Teller effect in La doped strontium chloride, discussing structural variations as function of temperature
Hydrogen atoms trapped in gamma irradiated calcium phosphates, studying radiation yields, electron paramagnetic resonance line widths, dose saturation and relaxation
Millimeter and submillimeter wave radiation detection by paramagnetic materials, noting noise equivalent power dependence on various parameters
Electron paramagnetic resonance spectroscopy was used to study the growth of S sub H centers on magnesium oxide powder which had hydrogen adsorbed on its surface. The centers were produced by ultraviolet radiation. The effects of both radiation intensity and hydrogen pressure were also studied. At constant hydrogen pressure and radiation dose, the initial S sub H center growth rate was found to be zero order. Beyond the initial region the growth rate deviated from zero order and finally approached saturation. The results are interpreted in terms of a model which assumes that the S sub H center is a hydrogen atom associated with a surface vacancy. Saturation appears to result from a limited supply of surface vacancies.
A model is presented for calculating the paramagnetic resonance (EPR) spectrum of vanadyl acetylacetonate (VAAC) dissolved in either a liquid crystal or isotropic solvent. It employs density matrix formulation in the rotating reference frame. The molecules occupy several discrete angles with respect to the magnetic field and can relax to neighboring positions in a characteristic time tau(theta). The form of tau(theta) is found from a diffusion approach, and the magnitude of tau(theta) is a measure of how freely the VAAC probe tumbles in the solvent. Spectra are predicted for values of tau between 10 to the minus 11th power sec and 10 to the minus 7th power sec. The EPR spectrum, in the isotropic case, is obtained be summing the contributions from the allowed angles weighted by the polar volume element, sin theta. When applying the model to the nematic liquid crystal case it is also necessary to multiply by the Saupe distribution function. For this case tau(theta) is obtained from the diffusion approach in which two diffusion constants are employed to reflect the difference in the parallel and perpendicular components of the viscosity.
Study of the molecular ordering in two smectic A liquid crystals using vanadyl acetylacetonate as a paramagnetic probe. The average hyperfine splitting of the spectrum in the smectic A mesophase is measured as a function of the orientation relative to the dc magnetic field of the spectrometer after alignment of the molecules of the liquid crystal.
The paramagnetic resonance spectrum of Vanadyl acetylacetonate (VAAC) dissolved in either a liquid crystal or isotropic solvent is calculated with the aid of a presented model. Density matrix formulation is employed in the rotating reference frame. The molecules occupy several discrete angles with respect to the magnetic field and can relax to neighboring positions in a characteristic time. The form of this characteristic time is found from a diffusion approach, and the magnitude of this time is a measure of how freely the VAAC probe tumbles in the solvent. Spectra are predicted for time values ranging from 10 picoseconds to 10 microseconds.
Using vanadyl acetylacetonate (VAAC) as a paramagnetic probe, the molecular ordering in two smectic-A liquid crystals that do not display nematic phases were studied. Reproducible alinement was attained by slow cooling throughout the isotropic smectic-A transition in dc magnetic fields of 1.1 and 2.15 teslas. The degree of order attained is small for a smectic-A liquid crystal. Measurements were made of the variation of the average hyperfine splitting of the alined samples as a function of orientation relative to the dc magnetic field of the spectrometer. This functional dependence is in agreement with the theoretical prediction except where the viscosity of the liquid crystal becomes large enough to slow the tumbling of the VAAC, as indicated by asymmetry in the end lines of the spectrum.
The ordering in a viscous, nematic, liquid crystal was studied using vanadyl acetyl acetonate and several nitroxides as paramagnetic probes. The ordering curve for VAAC at both K-band and X-band shows a slope discontinuity at a reduced temperature of 0.85. This discontinuity is caused by the tumbling time of the VAAC becoming comparable with the hyperfine splitting. The slope discontinuity is not present in the ordering curves of the nitroxides. The results are taken as evidence counter to the presence of a second-order phase transition.
The correlation between paramagnetism and the shake-up satellites in the X-ray photoelectron spectra of the 3d transition-metal compounds is examined and explained in terms of modified selection rules governing the shake-up transitions.
In the ilmenite-hematite solid solution series, compositions more ilmenite-rich than Ilm(73)Hem(27) are classically thought to be paramagnetic at room temperature. Ilm(80)Hem(20) samples have nevertheless been synthesized that acquire hard saturation remanent and thermoremanent moments. From analysis of AC demagnetization data, the source of the measured remanence is believed to be a single-domain (SD) like material within the IlM(80)Hem(20) grains themselves. On the basis of transmission electron microscope observations, it is suggested that transformation-induced domain boundaries, which in part are enriched in hematite component relative to the bulk composition of the grains, could act as the magnetic carrier of the SD-like remanence.
Addition of Mn to Ti/Nb superconducting alloy increases critical current. Adding Mn to Ti/Nb alloy has little effect on major superconducting phase, but confers strong paramagnetic susceptibility on alpha-phase particles. beta-phase particles become stronger flux pinners, resulting in increase in critical current.