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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Anomalous /C-13/H4:/C-12/H4 line strengths in 2 nu 3

Anomalous intensity ratios between 2 nu 3 singlet lines of C-13 methane and C-12 methane are reported. Absolute strengths of the Q1, R0 and R1 singlets were measured for essentially pure samples of (C-13)H4 and (C-12)H4 at a resolution of 0.035 kaysers at pressures of 10 and 20 Torr, using a computer controlled grating spectrometer. Line strength ratios between the isotopic species are presented which demonstrate a dramatic effect of isotopic substitution on line strengths. If this effect can be observed in the 3 nu 3 vibration-rotation band of methane, which is widely used in planetary atmosphere studies, revision of the (C-12)H4/(C-13)H4 abundance ratios of the outer planets will be necessary.

Fox, K.↗
NASA NTRS1985

Enhanced Raman spectroscopic study of the coordination chemistry of malononitrile on copper surfaces - Removal of nu(C=N) degeneracy through pi-coordination

Surface-enhanced Raman spectroscopy has been used to study the molecular interactions of malononitrile with copper electrode surfaces. The doubly degenerate CN stretching frequency at 2263/cm is removed when malononitrile adsorbs on copper. Two nu(CN) bands are observed at 2096 and 2204/cm at -0.6 V(SCE). The result shows that only one CN group is pi-coordinated with Cu, which contributes to the observed large shift (-167/cm) in nu(CN). The other CN group is not coordinated to the metal surface.

Loo, B. H.↗
NASA NTRS1988

Air-broadened Lorentz halfwidths and pressure-induced line shifts in the nu(4) band of C-13H4

Air-broadened halfwidths and pressure-induced line shifts in the nu(4) fundamental of C-13H4 were determined from spectra recorded at room temperature and at 0.01/cm resolution using a Fourier transform spectrometer. Halfwidths and pressure shifts were determined for over 180 transitions belonging to J-double prime values of less than or = to 16. Comparisons of air-broadened halfwidths and pressure-induced line shifts made for identical transitions in the nu(4) bands of C-12H4 and C-13H4 have shown that C-13H4 air-broadened halfwidths are about 5 percent smaller than the corresponding C-12H4 halfwidths, and the pressure shifts for C-13H4 lines are about 5-15 percent larger than those for C-12H4.

Devi, V. Malathy↗
NASA NTRS1996

Collisional Removal of OH (X (sup 2)Pi, nu=7) by O2, N2, CO2, and N2O

Collisional removal rate constants for the OH (X 2PI, nu = 7) radical are measured for the colliders O2, CO2, and N2O, and an upper limit is established for N2. OH(nu = 4) molecules, generated in a microwave discharge flow cell by the reaction of hydrogen atoms with ozone, are excited to v = 7 by the output of a pulsed infrared laser via direct vibrational overtone excitation. The temporal evolution of the P = 7 population is probed as a function of the collider gas partial pressure by a time-delayed pulsed ultraviolet laser. Fluorescence from the B 21 + state is detected in the visible spectral region.

Knutsen, Karen↗
NASA NTRS2000

The nu Andromedae System: Models and Stability

Radial velocity observations of the F8 V star nu Andromedae taken at Lick and at Whipple Observatories have revealed evidence of three periodicities in the line-of-sight velocity of the star. These periodicities have been interpreted as evidence for at least three low-mass companions (LMCs) revolving around nu Andromedae. The mass and orbital parameters inferred for these companions raise questions about the dynamical stability of the system. We report here results from our independent analysis of the published radial velocity data, as well as new unpublished data taken at Lick Observatory. Our results confirm the finding of three periods in the data. Our best fits to the data, on the assumption that these periods arise from the gravitational perturbations of companions in Keplerian orbits, are also generally in agreement but with some differences from the earlier findings. We find that the available data do not constrain well the orbital eccentricity of the middle companion in a three-companion model of the data. We also find that in order for our best-fit model to the Lick data to be dynamically stable over the lifetime of the star (approximately 2 billion years), the system must have a mean inclination to the plane of the sky greater than 13 deg. The corresponding minimum inclination for the best fit to the Whipple data set is 19 deg. These values imply that the maximum mass for the outer companion can be no greater than about 20 Jupiter masses. Our analysis of the stability of the putative systems also places constraints on the relative inclinations of the orbital planes of the companions. We comment on global versus local (i.e., method of steepest descent) means of finding best-fit orbits from radial velocity data sets.

Stepinski, Tomasz F.↗
NASA NTRS1995

Characterization of silicon-carbon clusters by infrared laser spectroscopy. The nu 1 band of SiC4

The nu 1 fundamental vibration of linear SiC4 has been observed by infrared diode laser spectroscopy of a supersonic cluster beam. Twenty-four rovibrational transitions were measured in the spectral region of 2094.6 to 2097.1 cm-1, the rotational temperature was 10 K. A combined least-squares fit of these transitions with previously reported microwave data yielded the following molecular constants: nu 1 = 2095.45806(37) cm-1, B" = 0.051161131(52) cm-1, and B' = 0.0509157(96) cm-1. These results are compared to vibrational spectroscopy measurements of SiC4 trapped in a solid Ar matrix and to ab initio calculations.

NASA Discipline Exobiology↗
NASA NTRS1994

Characterization of silicon-carbon clusters by infrared laser spectroscopy: the nu 3(sigma u) band of linear Si2C3

The nu 3(sigma u) fundamental vibration of 1 sigma g+ Si2C3 has been observed using a laser vaporization-supersonic cluster beam-diode laser spectrometer. Forty rovibrational transitions were measured in the range of 1965.8 to 1970.9 cm-1 with a rotational temperature of 10-15 K. A least-squares fit of these transitions yielded the following molecular constants: nu 3(sigma u)=1968.188 31(18) cm-1, B"=0.031 575 1(60) cm-1, and B'=0.031 437 4(57) cm-1. These results are in excellent agreement with recent Fourier transform infrared (FTIR) measurements of Si2C3 trapped in a solid Ar matrix [J. Chem. Phys. 100, 181(1994)] and with ab initio calculations [J. Chem. Phys. 100, 175 (1994)] which suggest cumulenic-like bonding for Si2C3, analogous to the isovalent C5 carbon cluster.

Non-NASA Center↗
NASA NTRS2008

Development of Lunar Highland REgolith Simulants, NU-LHT-1M,-2M

As part of a collaborative agreement between the U.S, Geological Survey (USGS) and NASA's Marshall Space Flight Center (MSFC) lunar highland simulants are being produced to support engineers and scientists in developing the technologies required to put a base on the moon by 2024. Two simulants have been produced to date: NU-LHT-1M and -2M (NASA/USGS-Lunar Highlands Type-l & 2 Medium-grained). Using starting material chiefly collected from the Stillwater Mine, Nye, MT, blending protocols were developed based on normative mineralogy calculated from average chemistry, for the Apollo 16 regolith. New technologies using a high temperature remotely coupled plasma melter were developed to generate both high quality and agglutinitic glasses that simulate the glassy components of the regolith. Detailed chemical, mineralogical and physical properties analysis of NU-LHT-1M indicate that it is overall a good surrogate for highlands lunar regolith (our new simulant LHT-2M has not be analyzed yet). The primary difference between 1M and 2M was the inclusion of trace mineralogy (phosphates and sulfide). Plans will also be presented on the future direction of the simulant project.

Stoeser, D. B.↗
NASA NTRS2011

Design and Impacts of Land-Biogenic-Atmosphere Coupling in the NASA-Unified WRF (NU-WRF) Modeling System

Land-Atmosphere coupling is typically designed and implemented independently for physical (e.g. water and energy) and chemical (e.g. biogenic emissions and surface depositions)-based models and applications. Differences in scale, data requirements, and physics thus limit the ability of Earth System models to be fully coupled in a consistent manner. In order for the physical-chemical-biological coupling to be complete, treatment of the land in terms of surface classification, condition, fluxes, and emissions must be considered simultaneously and coherently across all components. In this study, we investigate a coupling strategy for the NASA-Unified Weather Research and Forecasting (NU-WRF) model that incorporates the traditionally disparate fluxes of water and energy through NASA's LIS (Land Information System) and biogenic emissions through BEIS (Biogenic Emissions Inventory System) and MEGAN (Model of Emissions of Gases and Aerosols from Nature) into the atmosphere. In doing so, inconsistencies across model inputs and parameter data are resolved such that the emissions from a particular plant species are consistent with the heat and moisture fluxes calculated for that land cover type. In turn, the response of the atmospheric turbulence and mixing in the planetary boundary layer (PBL) acts on the identical surface type, fluxes, and emissions for each. In addition, the coupling of dust emission within the NU-WRF system is performed in order to ensure consistency and to maximize the benefit of high-resolution land representation in LIS. The impacts of those self-consistent components on' the simulation of atmospheric aerosols are then evaluated through the WRF-Chem-GOCART (Goddard Chemistry Aerosol Radiation and Transport) model. Overall, this ambitious project highlights the current difficulties and future potential of fully coupled. components. in Earth System models, and underscores the importance of the iLEAPS community in supporting improved knowledge of processes and innovative approaches for models and observations.

Tan, Qian↗
NASA NTRS2013

Air- and Self-Broadened Half Widths, Pressure-Induced Shifts, and Line Mixing in the Nu(sub 2) Band of (12)CH4

Lorentz self- and air-broadened half width and pressure-induced shift coefficients and their dependences on temperature have been measured from laboratory absorption spectra for nearly 130 transitions in the nu(sub 2) band of (12)CH4. In addition line mixing coefficients (using the relaxation matrix element formalism) for both self- and airbroadening were experimentally determined for the first time for a small number of transitions in this band. Accurate line positions and absolute line intensities were also determined. These parameters were obtained by analyzing high-resolution (approx. 0.003 to 0.01 per cm) laboratory spectra of high-purity natural CH4 and air-broadened CH4 recorded at temperatures between 226 and 297 K using the McMath-Pierce Fourier transform spectrometer (FTS) located at the National Solar Observatory on Kitt Peak, Arizona. A multispectrum nonlinear least squares technique was used to fit short (5-15 per cm) spectral intervals in 24-29 spectra simultaneously. Parameters were determined for nu(sub 2) transitions up to J" = 16. The variations of the measured broadening and shift parameters with the rotational quantum number index and tetrahedral symmetry species are examined. The present results are also compared with previous measurements available in the literature.

Smith, M. A. H.↗
NASA NTRS2015

High-Resolution NU-WRF Simulations of a Deep Convective-Precipitation System During MC3E: Comparisons Between Goddard Microphysics Schemes and Observations - Part 1

The Goddard microphysics scheme was recently improved by adding a 4th ice class (frozen dropshail). This new 4ICE scheme was implemented and tested in the Goddard Cumulus Ensemble model (GCE) for an intense continental squall line and a moderate,less-organized continental case. Simulated peak radar reflectivity profiles were improved both in intensity and shape for both cases as were the overall reflectivity probability distributions versus observations. In this study, the new Goddard 4ICE scheme is implemented into the regional-scale NASA Unified - Weather Research and Forecasting model (NU-WRF) and tested on an intense mesoscale convective system that occurred during the Midlatitude Continental Convective Clouds Experiment (MC3E). The NU42WRF simulated radar reflectivities, rainfall intensities, and vertical and horizontal structure using the new 4ICE scheme agree as well as or significantly better with observations than when using previous versions of the Goddard 3ICE (graupel or hail) schemes. In the 4ICE scheme, the bin microphysics-based rain evaporation correction produces more erect convective cores, while modification of the unrealistic collection of ice by dry hail produces narrow and intense cores, allowing more slow-falling snow to be transported rearward. Together with a revised snow size mapping, the 4ICE scheme produces a more horizontally stratified trailing stratiform region with a broad, more coherent light rain area. In addition, the NU-WRF 4ICE simulated radar reflectivity distributions are consistent with and generally superior to those using the GCE due to the less restrictive open lateral boundaries

Regional Scale Model↗
NASA NTRS2018

NU-WRF Development and Support at NASA GSFC

The NASA Unified WRF modeling system (NU-WRF) is an observation driven framework that combines WRF-ARW with Goddard developed radiation, microphysics, aerosols and land information system (LIS) packages. NU-WRF can be used for simulating aerosols and land use effects on a variety of weather events. This poster will present a description of the modeling system including updates and future plans.

Cruz, Carlos A.↗
NASA NTRS2021

Cold Season Performance of the NU-WRF Regional Climate Model in the Great Lakes Region

As Earth’s largest collection of freshwater, the Laurentian Great Lakes have enormous ecological and socio-economic value. Their basin has become a regional hotspot of climatic and limnological change, potentially threatening its vital natural resources. Consequentially, there is a need to assess the current state of climate models regarding their performance across the Great Lakes region and develop the next generation of high-resolution regional climate models to address complex limnological processes and lake-atmosphere interactions. In response to this need, the current paper focuses on the generation and analysis of a 20-member ensemble of 3-km National Aeronautics and Space Administration (NASA)-Unified Weather Research and Forecasting (NU-WRF) simulations for the 2014-2015 cold season. The study aims to identify the model’s strengths and weaknesses; optimal configuration for the region; and the impacts of different physics parameterizations, coupling to a 1D lake model, time-variant lake-surface temperatures, and spectral nudging. Several key biases are identified in the cold-season simulations for the Great Lakes region, including an atmospheric cold bias that is amplified by coupling to a 1D lake model but diminished by applying the Community Atmosphere Model radiation scheme and Morrison microphysics scheme; an excess precipitation bias; anomalously early initiation of fall lake turnover and subsequent cold lake bias; excessive and overly persistent lake ice cover; and insufficient evaporation over Lakes Superior and Huron. The research team is currently addressing these key limitations by coupling NU-WRF to a 3D lake model in support of the next generation of regional climate models for the critical Great Lakes Basin.

Michael Notaro↗
NASA NTRS1973

3 nu sub 3 band of C-12H4 at 1.1 micron.

The 3 nu sub 3 absorption band of C-12H4 has been measured using a high-resolution vacuum infrared spectrometer. A technique is described which allows an extension of the use of the absorption standards available at 4.7 microns to the photomultiplier region of the spectrum. The new measurements indicate a shift of about 0.18 per cm from the most recently published measurements of this band.

Pugh, L. A.↗
NASA NTRS1974

Abundance and rotational temperature of telluric methane as determined from the 2 nu 3 band

The rotational temperature of the 2 nu 3 methane absorptions in the solar/telluric spectrum and the methane abundance in the earth's atmosphere have been measured and are found to be 243.4 plus or minus 5.3 K and 1.137 plus or minus 0.117 cm-atm (STP) in a vertical column, respectively. The data were reduced using the results of laboratory measurements with proper allowance for the fine-structure of the methane absorption manifold and the effects of vibration-rotation interaction (which causes an enhancement of the R-branch of this band).

Margolis, J. S.↗
NASA NTRS1974

Measurement of multiplet intensities and noble gas-broadened line widths in the nu 3 fundamental of methane

Presented integrated intensity data at 300 K for J multiplets between P(11) and R(11) in the nu-3 fundamental of C-12 methane are shown to be in good agreement with most previously published pertinent values. Also, line widths measured at 100 K, 130 K, 190 K, 250 K, and 300 K for R(0), R(1), and R(2) broadened by He, Ne, and Ar are presented, and the line-width temperature dependence is discussed for the three cases of broadening.

Varanasi, P.↗
NASA NTRS1974

The nu sub 9 fundamental of ethane - Integrated intensity and band absorption measurements with application to the atmospheres of the major planets

Measurements of the absolute intensity and integrated band absorption have been performed for the nu sub 9 fundamental band of ethane. The intensity is found to be about 34 per sq cm per atm at STP, and this is significantly higher than previous estimates. It is shown that a Gaussian profile provides an empirical representation of the apparent spectral absorption coefficient. Employing this empirical profile, a simple expression is derived for the integrated band absorption, which is in excellent agreement with experimental values. The band model is then employed to investigate the possible role of ethane as a source of thermal infrared opacity within the atmospheres of Jupiter and Saturn, and to interpret qualitatively observed brightness temperatures for Saturn.

Varanasi, P.↗