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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Comparison of marine gravity from shipboard and high-density satellite altimetry along the Mid-Atlantic Ridge, 30.5-35.5 deg S

We compare new marine gravity fields derived from satellite altimetry with shipboard measurements over a region of more than 120,000 sq km in the central South Atlantic. Newly declassified satellite data were employed to construct free-air anomaly maps on 0.05 degree grids. An extensive gravity and bathymetry data set from four cruises along the Mid-Atlantic Ridge from 30.5-35.5 deg S provides a benchmark for testing the 2D resolution and accuracy of the satellite measurements where their crosstrack spacing is near their widest. The satellite gravity signal is coherent with bathymetry in this region down to wavelengths of 26 km, compared to 12.5 km for shipboard gravity. Residuals between the shipboard and satellite data sets have a roughly normal distribution. The standard deviation of satellite gravity with respect to shipboard measurements is nearly 7 mGal in a region of 140 mGal total variation, whereas the internal standard deviation at crossovers for GPS-navigated shipboard data is 1.8 mGal. The differences between shipboard and satellite data are too large to use satellite gravity to determine crustal thickness variations within a typical ridge segment.

Neumann, Gregory A.↗
DOE OSTI2025

Distinctive features of fluorescence and waveguides in magnesium aluminate spinel crystals driven by structural discrepancy

Transparent polycrystalline ceramics are of significant importance for a wide range of scientific and industrial applications. Developing a deeper understanding of their thermodynamic behavior is essential for achieving their maximum output performance in technological applications. This study provides a systematic investigation into the thermal excitation-induced fluorescence kinetics and waveguide characteristics of Magnesium Aluminate Spinel (MgAl 2 O 4 ) single crystals, with a focus on the intricate relationship between structure and properties. High-temperature extreme environments through irradiation with swift heavy ions 645.0 MeV Xe and 352.8 MeV Fe ions were created; the atomic deposition energy threshold (E th ) associated with disorder morphologies was assessed between 0.91 and 0.99 eV atom –1 . The track prediction model was developed to support the theoretical prediction of track formation. Electronic energy loss (E ele ) disrupts the balance of the initial structure through the thermal spike effect, leading to the formation of absorption-related F and F + color centers. These defects enhance photoluminescence in the visible spectrum and result in an effective modulation of the intrinsic bandgap. Moreover, as ion beams penetrate into the material, the uneven damage distribution induces the formation of waveguide structures. In conclusion, these findings provide valuable insights into the fabrication of functional devices through irradiation technologies and the structural changes of MgAl 2 O 4 at high temperatures within extreme environments.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Dry reforming of methane over Ni supported on LaMnO 3 thin films

Thin films of LaMnO 3 were deposited onto MgAl 2 O 4 by Atomic Layer Deposition (ALD) and studied as supports for Ni in the Dry Reforming of Methane (DRM). Scanning Transmission Electron Microscopy (STEM) with Energy-Dispersive X-ray Spectroscopy (EDS) demonstrated that LaMnO 3 covered the support uniformly, and X-ray diffraction (XRD) showed that the LaMnO 3 films maintained their perovskite structure after 5 redox cycles at 1073 K. The Ni also remained well dispersed after 5 redox cycles at 1073 K. The LaMnO 3 -supported catalyst was more active than Ni on the unmodified MgAl 2 O 4 and showed superior resistance against coke formation. Lastly, the results for Ni on the LaMnO 3 films are compared to previous results for Ni on LaFeO 3 , CaTiO 3 , SrTiO 3 , and BaTiO 3 films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Zinc aluminate (ZnAl 2 O 4 ) refractory aggregates: Dilatometric sintering studies and thermal expansion coefficient

ZnAl 2 O 4 has recently been reported to enhance thermomechanical properties and slag corrosion resistance of refractory castables. The pore generation and deleterious expansion during in situ ZnAl 2 O 4 formation can limit their amount in a refractory composition. A comprehensive dilatometric study is presented, identifying the optimum raw materials and processing conditions. Preformed ZnAl 2 O 4 refractory aggregates were synthesized from industrial ZnO and reactive Al 2 O 3 by two-stage firing at 1050 °C and 1700 °C resulting in 0% open porosity. The ZnAl 2 O 4 powder calcined at 1050 °C is also a good refractory matrix material as it has better sinterability than preformed refractory-grade MgAl 2 O 4 and calcined alumina. The thermal expansion coefficient of ZnAl 2 O 4 aggregate in the range of 70–1600 °C was found to be 10.7 × 10 –6 K –1 , which is similar to tabular Al 2 O 3 (10.3 × 10 –6 K –1 ) and MgAl 2 O 4 (10.3 × 10 –6 K –1 ), but lower than dead burned MgO (16.4 × 10 –6 K –1 ), creating the possibility of developing thermal shock resistant refractories by utilizing this mismatch.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Investigation of Rh–titanate (ATiO 3 ) interactions on high-surface-area perovskite thin films prepared by atomic layer deposition

Thin, ~1 nm films of CaTiO 3 , SrTiO 3 , and BaTiO 3 were deposited onto MgAl 2 O 4 by Atomic Layer Deposition (ALD) and studied as catalyst supports for Rh. Scanning Transmission Electron Microcopy (STEM) and X-Ray Diffraction (XRD) demonstrated that the films had the perovskite structure and formed uniform coatings stable up to 1073 K. Rh, added by ALD, interacted strongly with CaTiO 3 and somewhat less strongly with SrTiO 3 , while Rh on BaTiO 3 was similar to Rh on unmodified MgAl 2 O 4 . STEM measurements of Rh on CaTiO 3 films showed Rh remained well dispersed after repeated oxidations and reductions at 1073 K; however, the Rh was inactive for CO-oxidation. Rh formed small particles on SrTiO 3 films and was active for CO oxidation after reduction at 1073 K. The reducibility and catalytic activity of Rh/BaTiO 3 /MgAl 2 O 4 were similar to that of Rh/MgAl 2 O 4 . Evidence from CO-TPR, FTIR, and XPS all indicated that the degree of interaction between Rh and the three perovskite films can be ranked in the following order: Rh/CaTiO 3 /MgAl 2 O 4 > Rh/SrTiO 3 /MgAl 2 O 4 > Rh/BaTiO 3 /MgAl 2 O 4 . Here, bulk ex-solution catalysts, synthesized by reduction of ATi 0.98 Rh 0.02 O 3 (A = Ca, Sr, and Ba), were also examined for comparison.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

DyFe 2 O 4 : A new trigonal rare-earth ferrite grown by molecular-beam epitaxy

Using epitaxial stabilization, we synthesized single-phase (001)-oriented thin films of DyFe 2 O 4+x on (111) MgAl 2 O 4 substrates by molecular-beam epitaxy. The metastable DyFe 2 O 4 polymorph formed is isostructural to known trigonal ferrimagnetic RFe 2 O 4 phases with space group $R\bar{3}m$, where R = Ho to Lu. The epitaxial DyFe 2 O 4 thin films have two in-plane orientation relationships: [100] DyFe 2 O 4 || [$2\bar{1}1$] MgAl 2 O 4 plus a twin variant related by a 60° in-plane rotation. DyFe 2 O 4 is not bulk stable and has never been synthesized before. Indeed, it has been predicted to be on the edge energetically of what may be possible to stabilize. The fact that the RFe 2 O 4 phase is stable for all elements leading up to dysprosium (Ho–Lu) leads us to believe that DyFe 2 O 4 could be a “remnant metastable phase,” one which, given the right thermodynamic conditions, could become the lowest free energy phase. We find that although we are able to get structurally very close to $R\bar{3}m$ DyFe 2 O 4 , the films are not stoichiometric as they have an increased c lattice parameter, indicative of extra oxygen as is sometimes seen in other RFe2O4 phases. The unintended surplus oxygen opens questions regarding what may be achievable using such tricks as epitaxial stabilization to access metastable phases and whether this indeed constitutes “remnant metastability.”

36 MATERIALS SCIENCE↗
DOE OSTI2023

Mg and Al-induced phase transformation and stabilization of Ga 2 O 3 -based $\gamma$-phase spinels

Ga 2 O 3 films were deposited on (100) MgAl 2 O 4 spinel substrates at 550, 650, 750, and 850 °C using metal-organic chemical vapor deposition and investigated using x-ray diffraction and transmission electron microscopy. A phase-pure γ-Ga 2 O 3 -based material having an inverse spinel structure was formed at 850 °C; a mixture of the γ-phase and β-Ga 2 O 3 was detected in films grown at 750 °C. Only β-Ga 2 O 3 was determined in the films deposited at 650 and 550 °C. A β- to γ-phase transition occurred from the substrate/film interface during growth at 750 °C. The growth and stabilization of the γ-phase at the outset of film growth at 850 °C was affected by the substantial Mg and Al chemical interdiffusion from the MgAl 2 O 4 substrate observed in the energy-dispersive x-ray spectrum. Further, atomic-scale investigations via scanning transmission electron microscopy of the films grown at 750 and 850 °C revealed a strong tetrahedral site preference for Ga and an octahedral site preference for Mg and Al. It is postulated that the occupation of these atoms in these particular sites drives the β-Ga 2 O 3 to γ-phase transition and markedly enhances the thermal stability of the latter phase at elevated temperatures.

42 ENGINEERING↗
DOE OSTI2023

Impact on aggregate/matrix bonding when a refractory contains zinc aluminate instead of spinel and magnesia‐chrome

The high hot strength of MgO–Cr 2 O 3 refractory is often ascribed to its intimate aggregate/matrix bonding. For a fundamental comparison with it, ~2 mm aggregates of MgO and Al 2 O 3 were separately embedded in ZnAl 2 O 4 and MgAl 2 O 4 matrices, sintered at 1600°C, and examined. It was found that similarity of thermal expansion coefficient (TEC) between the aggregate and the matrix is critical to achieve good bonding and this is more important than the extent of interdiffusion. The TEC mismatch of ≥ 5.7 × 10 -6 K -1 caused significant undesirable debonding in MgO aggregate/MgAl 2 O 4 matrix sample and MgO/ZnAl 2 O 4 despite >736 μm Zn 2+ diffusion depth in the latter. Direct bonding, as inferred from a thicker interfacial reaction layer and a greater shift of the aggregate/matrix interface before and after firing, was better in MgAl 2 O 4 /ZnAl 2 O 4 combination, followed by tabular Al 2 O 3 /ZnAl 2 O 4 and Al 2 O 3 /MgAl 2 O 4 . Powder X-ray diffraction indicated that the volatilization of ZnAl 2 O 4 at 1600°C in air was negligible compared to MgO–Cr 2 O 3 .

36 MATERIALS SCIENCE↗
DOE OSTI2025

Microstructure and bonding between calcium aluminate cement‐containing gahnite–alumina matrix and refractory aggregates

Calcium aluminate cement enhances the thermomechanical properties of refractory castables through the formation of acicular calcium hexaluminate (CaO·6Al 2 O 3 ), Ca 2 Mg 2 Al 28 O 46 (CAM-I), and CaMg 2 Al 16 O 27 (CAM-II) phases in MgO- or MgAl 2 O 4 -containing castables. The compatibility of CA 6 with gahnite (ZnAl 2 O 4 ), and acicular Ca 2 Zn 2 Al 28 O 46 (CAZ-I) and CaZn 2 Al 16 O 27 (CAZ-II) phases formation have been previously reported. Here, in this work, the interaction between a CAC binder containing ZnAl 2 O 4 -Al 2 O 3 matrix with commonly used refractory aggregates such as tabular alumina (TA), alumina-rich (AR90, AR78) and stoichiometric (SM72) MgAl 2 O 4 spinels, and fused and dead-burned magnesia (FM, DBM, respectively) were investigated at 1650°C for 5 h. Microstructural analysis, using digital microscopy, scanning electron microscopy, and energy dispersive spectroscopy, revealed the formation of acicular CaZn 0.18 Al 11.82 O 18.91 , CAZ-I and CAZ-II grains, and strong interfacial bonding between the matrix and TA and spinel aggregates. FM and DBM were found to debond from the matrix. Thick interface layers were observed between the matrix and all the aggregates but TA. Null hypothesis significance testing (NHST) shows that the difference in the number of acicular grains between the interface zone and the bulk matrix (Z) is statistically significant for AR90/Z, SM72/Z, FM/Z, and DBM/Z interfaces, but not significant for TA/Z and AR78/Z. The role of the aggregates’ chemistry on the interfacial bonding and microstructure evolution is discussed.

Ramteke, Rajat Durgesh [Univ. of Alabama, Birmingh↗
DOE OSTI2022

Follow-on Report of Analysis of Approaches to Supplemental Treatment of Low-Activity Waste at the Hanford Nuclear Reservation (Vol. I)

The Hanford Site, in southeast Washington State, is preparing to disposition approximately 56,000,000 gallons (56 Mgal) of radioactive and chemically hazardous wastes currently stored in underground tanks at the site. Tank wastes will be divided into a high-activity fraction and a low-activity fraction for subsequent treatment and disposition. A waste processing and treatment facility, the Waste Treatment and Immobilization Plant (WTP), will include the high-level waste (HLW) vitrification facility (WTP HLW Vitrification Facility) for immobilizing the high-activity fraction and a low-activity waste (LAW) vitrification facility (WTP LAW Vitrification Facility) for immobilizing the low-activity fraction. Both facilities will use vitrification technology to immobilize the Hanford tank wastes in a glass waste form. The volume of LAW to be treated and disposed of following waste retrieval and WTP operations will exceed the planned processing capacity of the WTP LAW Vitrification Facility. ORP-11242,-River Protection Project System Plan, estimates a shortfall in LAW treatment capacity of approximately 56 Mgal, approximately 50% of the projected LAW volume. To maintain the planned tank waste processing mission schedule, the U.S. Department of Energy (DOE) will require additional LAW treatment capacity (termed “supplemental LAW”) external to the WTP process. LAW must be solidified by a treatment technology before the waste can be permanently disposed of in an approved DOE on-site disposal facility or a commercial (state or U.S. Nuclear Regulatory Commission [NRC-licensed]) off-site mixed low-level waste disposal facility. A decision on the approach to supplemental LAW treatment, processing, and disposal has not yet been made

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1973

Traverse gravimeter experiment

A semiautomatic self-leveling lunar gravimeter has been designed for the Apollo 17 mission. This traverse gravimeter, which is completely self-contained and powered by an internal battery, was used to measure gravity at predetermined stops along the route of the Lunar Rover Vehicle. The gravity sensor is a vibrating string accelerometer (VSA) enclosed in a temperature-controlled oven and gimballed leveling assembly. This instrument is capable of resolving gravity differences as small as 0.035 milligal (1 mgal = 0.001 cm/s) on the moon and yet also is able to measure the earth's gravity field of 980,000 milligals. Twenty-two measurements were taken on the moon during the Apollo 17 mission, during which the VSA temperature never varied more than 0.005 C. The flight results indicate an instrument accuracy of better than 2 mgal.

Buck, S. W.↗
NASA NTRS1976

On estimating gravity anomalies from gradiometer data

The Gravsat-gradiometer mission involves flying a gradiometer on a gravity satellite (Gravsat) which is in a low, polar, and circular orbit. Results are presented of a numerical simulation of the mission which demonstrates that, if the satellite is in a 250-km orbit, 3- and 5-degree gravity anomalies may be estimated with accuracies of 0.03 and 0.01 mm/square second (3 and 1 mgal), respectively. At an altitude of 350 km, the results are 0.07 and 0.025 mm.square second (7 and 2.5 mgal), respectively. These results assume a rotating type gradiometer with a 0.1 -etvos unit accuracy. The results can readily be scaled to reflect another accuracy level.

Argentiero, P.↗
NASA NTRS1976

Apollo 17 traverse gravimeter experiment /Preliminary results/

Preliminary results of the traverse gravimeter experiment successfully performed during the Apollo 17 mission are discussed. An earth-moon gravity tie was established. On the basis of several readings, a gravity value of 162,695 + or - 5 mgal was obtained at the lunar-module landing site in the Taurus-Littrow valley. Free-air and Bouguer corrections were applied to the gravity data. The resultant Bouguer anomaly, analyzed with a two-dimensional approximation, shows a relative gravity maximum of about 25 to 30 mgal over the Taurus-Littrow valley. This maximum is interpreted in terms of a 1-km-thick block of basalt flow with a positive density contrast of 0.8 g/cu cm relative to the highland material on either side.

Talwani, M.↗
NASA NTRS1979

Gravity anomaly and geoid undulation results in local areas from GEOS-3 altimeter data

The adjusted GEOS-3 altimeter data, taken as averages within a data frame, have been used to construct free air anomaly and geoid undulation profiles and maps in areas of geophysical interest. Profiles were constructed across the Philippine Trench (at a latitude of 6 deg) and across the Bonin Trench (at a latitude of 28 deg). In the latter case an anomaly variation of 443 mgals in 143 km was derived from the altimeter data. These variations agreed reasonably with terrestrial estimates, considering the predicted point accuracy was about + or - 27 mgals. An area over the Patton Sea mounts was also investigated with the altimeter anomaly field agreeing well with the terrestrial data except for the point directly over the top of the sea mount. It is concluded that the GEOS-3 altimeter data is valuable not only for determining 5 deg and 1 deg x 1 deg mean anomalies, but also can be used to describe more local anomaly variations.

Rapp, R. H.↗
NASA NTRS1982

A supersensitive accelerometer for spacecraft gradiometry

An exact knowledge of the earth's gravity field is needed for advanced studies related to solid earth and ocean physics. A study (GRAVSAT-A) is currently considered by NASA to determine the gravity field with an accuracy of 2-3 mgal change and a resolution of 100 km using satellite to satellite range rate tracking techniques. The present investigation has the objective to prepare the foundation of an advanced GRAVSAT-B mission in the 1990s with an accuracy of about 1 mgal and a resolution of about 50 km. It is possible that satellite to satellite tracking will not be able to satisfy these requirements. However, it appears that a new technology, called "high sensitivity gradient gradiometry", could be employed to achieve the aims of the GRAVSAT-B mission. Attention is given to a new type of gravity gradiometer using superconducting microwave cavity oscillator accelerometers.

Reinhardt, V. S.↗
NASA NTRS1987

Gravity field fine structure estimation techniques for a spaceborne gravity gradiometer

Use of standard estimation techniques to recover geopotential fine structure from gradiometer data requires the adjustment of small subsets of parameters while constraining others to their a priori values in order to minimize the computational load. Here, gravitational anomalies are selected as a parametrization of the gravity field which permits such an approach. Techniques coupled with numerical results for a spaceborne gravity gradiometer mission simulation are described which demonstrate that if a satellite is in a polar/circular orbit at an altitude of 160 km, 1 deg mean free air gravity anomalies can be recovered to an accuracy of 0.4 mgal, where 1 mgal = 0.001 cm/sq s.

Kahn, W. D.↗
NASA NTRS1989

Synopsis of early field test results from the gravity gradiometer survey system

Although the amount of data yielded by the initial airborne and surface tests was modest, it was sufficient to demonstrate that the full gravity gradient tensor was successfully measured from moving platforms both in the air and on the surface. The measurements were effectively continuous with spatial along-track resolution limited only by choice of integration lengths taken to reduce noise. The airborne data were less noisy (800 E squared/Hz typical) than were the Gravity Gradiometer Survey System (GGSS) measurements taken at the surface (5000 E squared/Hz typical). Single tracks of surface gravity disturbances recovered from airborne data were accurate to 3 to 4 mgal in each component of gravity when compared to 5 x 5 mean gravity anomalies over a 90 km track. Multitrack processing yielded 2 to 3 mgal when compared to 5 x 5 mean anomalies. Deflection of the vertical recovery over a distance of 150 km was about one arcsecond.

Brzezowski, S.↗
NASA NTRS1989

Satellite-to-satellite tracking experiment for global gravity field mapping

The satellite-to-satellite (STS) tracking concept for estimating gravitational parameters offers an attractive means to improve on regional and global gravity models in areas where data availability is limited. The extent to which the STS tracking measurements can be effectively utilized in global field models depends primarily on the satellite's altitude, number of satellites, and their orbit constellation. The estimation accuracy of the gravity field recovery also depends on the measurement accuracy of the sensors employed in the STS tracking concept. A comparison of the obtainable accuracies in the gravity field recovery using various STS tracking concepts was presented by Jekeli. The results of a feasibility study for a specific realization of the STS high-low tracking concept are summarized. In this realization, the high altitude satellites are the GPS satellites, and the low orbit satellite is the space shuttle. The GPS satellite constellation consists of 18 satellites in 6 orbital planes inclined at 55 deg. The shuttle orbit is at approximately 300 km, with an inclination of 30 deg. This specific configuration of high-low satellites for measuring perturbation in the gravity field is named the Air Foce STAGE (Shuttle GPS Tracking for Anomalous Gravitation Estimation) mission. The STAGE mission objective is to estimate the perturbations in gravity vector at the shuttle altitude to an accuracy of 1 mgal or better. Recent simulation studies have confirmed that the 1 mgal accuracy objective is near optimum for the STAGE mission.

Upadhyay, Triveni N.↗