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At least 55 records · Page 3

Berkelium–carbon bonding in a tetravalent berkelocene

Interest in actinide–carbon bonds has persisted since actinide organometallics were first investigated for applications in isotope separation during the Manhattan Project. Transplutonium organometallics are rarely isolated and structurally characterized, likely owing to limited isotope inventories, a scarcity of suitable laboratory infrastructure, and intrinsic difficulties with the anaerobic conditions required. In this paper, we report the discovery of an organometallic “berkelocene” complex prepared from 0.3 milligrams of berkelium-249. Single-crystal x-ray diffraction shows a tetravalent berkelium ion between two substituted cyclooctatetraene ligands, resulting in the formation of berkelium–carbon bonds. The coordination in berkelocene resembles that of uranocene, and calculations show that the berkelium 5f orbitals engage in covalent overlap with the δ-symmetry orbitals of the cyclooctatetraenide ligand π system. Charge transfer from the ligands is diminished relative to uranocene and other actinocenes, which maximizes contributions from the stable, half-filled 5f 7 configuration of tetravalent berkelium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elmer Allen McKibbin Card

A McKibbin card for Elmer Allen, from the Manhattan Project. McKibbin cards verify employment at the laboratory.

99 GENERAL AND MISCELLANEOUS↗

A Valentine’s tribute to Lab love: Watch clips from 1943 wedding of two staff

She was a secretary for Director J. Robert Oppenheimer. He was a physicist who helped create the world’s first atomic bombs. And for 65 years they were Mr. and Mrs. Bradner. Hugh Bradner was the first person that Marjorie Hall met upon arrival to join the Lab’s clandestine war-time efforts. He happened to be in Dorothy McKibbin’s Santa Fe office when Marjorie walked in. It was love at first sight, Marjorie recalled years later in an interview. The Bradners were married in September 1943 at McKibbin’s home. It was one of many weddings there during the Manhattan Project era. Los Alamos was fenced and guarded during this time, as staff raced to secretly develop nuclear weapons to help end World War II. Most were young – the average age was late 20s – and many, like the Bradners, met their lifelong partners then. The Bradners left Los Alamos after the war ended in 1945. Hugh is credited with inventing the neoprene wetsuit in 1951. The couple had one daughter. Marjorie, 89, and Hugh, 92, died just a few weeks apart in 2008 in California. Many of their home movies from their time in Los Alamos are preserved at the Lab. They are part of the collections in the National Security Research Center, which is the Lab’s classified library and also houses unclassified artifacts.

99 GENERAL AND MISCELLANEOUS↗

Thirty Minutes Before the Dawn

The Trinity test of July 16, 1945, marked the scientific apex of the Manhattan Project. Often recognized as the symbolic birth of the nuclear age, Trinity’s multifaceted legacy remains just as captivating and complex today as it did 75 years ago. This paper examines why the test was necessary from a technical standpoint, shows how Los Alamos scientists planned the event, and explores the physical and emotional aftermaths of Trinity. The author also uses rarely accessed original records to reconstruct the story of Trinity’s health hazards, as seen through the eyes of radiation technicians and medical doctors as events unfolded. Trinity was conducted as the Potsdam Conference began, weeks after the collapse of Nazi Germany. It was considered necessary to let President Harry S. Truman know whether the United States possessed a nuclear capability ahead of his negotiations with Joseph Stalin, the Soviet premier. The author examines the competing priorities that drove the timetable for the test: international politics, security, and safety. Three weeks after Trinity, a gun-assembled enriched-uranium bomb called Little Boy was used against the Japanese city of Hiroshima. Three days later, Fat Man, a weaponized version of the imploding Trinity device, was dropped on Nagasaki. The author briefly examines these strikes and what impact they may have had on the Japanese surrender. The paper concludes by examining the legacy of the Trinity test 75 years into the age it helped usher in.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Trinity

The Manhattan Project was established in August 1942. Its mission: beat the Nazis to the atomic bomb. Los Alamos was selected as the site for the weapons design laboratory. J. Robert Oppenheimer served as the Laboratory’s director. In early summer 1944, Los Alamos scientists discovered plutonium would not work in a gun assembly. Thus, Oppenheimer reorganized the Laboratory to build an implosion bomb

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

A Birthday Tribute to Oppie. Listen to a rare interview from 1965, print a keepsake poster

The Lab’s first Director and brilliant physicist shied away from the spotlight, particularly after leaving Los Alamos following the end of World War II in 1945. But when J. Robert Oppenheimer spoke, his words commanded attention. In commemoration of what would’ve been Oppenheimer’s 117th birthday on April 22, the National Security Research Center (NSRC), the lab’s classified library, is sharing a rare interview from the Voices of the Manhattan Project and an original poster that can be printed and displayed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Plutonium and poetry: Where Trinity and Oppenheimer's reading habits met Literary inspirations, correcting misinterpretation of his famous quote

The Lab’s first director, J. Robert Oppenheimer, was a man of sonnets and scientific synthesis. Oppenheimer’s work at Los Alamos was defined not only by physics and administrative skill, but also by a life philosophy inspired, in part, by literature. The Trinity test, which took place 76 years ago on July 16th in the New Mexico desert, epitomizes this. Known as one of the greatest scientific achievements ever, the successful detonation of the world’s first nuclear weapon marked the dawn of the Atomic Age. Created in just 27, albeit harrowing, months, Oppenheimer and his team at the Los Alamos Lab worked nonstop on this clandestine effort to help end World War II. As he had done throughout his life, Oppenheimer continued to foster his love of literature during the Manhattan Project. Two of his influences were John Donne and the Hindu scripture Bhagavad-Gita. Oppenheimer recalled both during the Trinity test.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Sights of summer from Lab’s earliest days digitization preserves images from 1940s, features early staff enjoying Los Alamos

Working at the Lab during World War II was serious business, but even these world-changing scientists and staff found time to play during the summer months. The National Security Research Center (NSRC), which is the Lab’s classified library and also houses unclassified artifacts from Los Alamos history, recently rescanned candid footage from two of contributors to the Manhattan Project.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Commuting again to work on-site? Lab’s first drivers faced their own challenges decades ago

After a long pause in commuting, more and more Lab staff are filling travel mugs, topping off their tanks, and heading up the hill for on-site work. As long as the Lab has existed, workers have snaked through tight mountain roads to get to their jobs. And, back in the early 1940s, drivers faced even more challenges. In the Lab’s earliest years, drivers likely worried about getting stuck in the mud, navigating intense switchbacks, or making sure important equipment, such as a disassembled power plant, didn’t fall off the back of the truck that was hauling it. Creative solutions could go a long way to get out of a jam. As many of us return onsite and get reacquainted with commuting, we look back at how transportation has changed since the Manhattan Project, the U.S. government’s top secret effort at Los Alamos to create the first atomic bombs to help end World War II. These stories and photos are part of the collections in the National Security Research Center, which is the Lab’s classified library and also houses unclassified artifacts from our past.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

ADAM Program Execution Plan LANL Inputs (FY2022)

The National Security Research Center (NSRC) is Los Alamos National Laboratory’s classified library. There are two groups associated with the NSRC, both of who work for LANL’s Weapons Research Services (WRS) division (WRS-SIS and WRS-WMT). These groups are funded in part by the NNSA Archives Program. The NSRC’s collections include tens of millions of documents from the Manhattan Project era through today. It is staffed with an expert, highly trained staff of librarians, archivists, digitizers, historians, and communications specialists. The NSRC traces its lineage to the wartime Technical Library created by J. Robert Oppenheimer during in 1943. Today, it supports a broad range of researchers within the LANL Weapons Program and beyond. The NSRC also has customers across other National Nuclear Security Administration labs and sites, and partners in the Department of Defense. This report highlights LANL accomplishments through NSRC.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Be like Oppenheimer: Donate your weapons information for the next generation of LANL researchers

You can follow the Lab’s first physicists, J. Robert Oppenheimer, Richard Feynman, Hans Bethe, and so many others through the years, plus know your information is helping future researchers — just like our first scientists did for you. How? Donate your physical or digital classified weapons records to the Lab’s National Security Research Center (NSRC), said Riz Ali, NSRC Director. The NSRC houses 80 years’ worth of one-of-kind records, which total in the millions and include nearly every medium imaginable. It is the Laboratory’s largest collection of research materials and the largest classified library of any Department of Energy lab. It all started with Oppenheimer, our first Lab director, and his Technical Library that was established during the Manhattan Project, which was the U.S. government’s top-secret effort to create the first atomic bombs to help end World War II. “Few NSRC patrons are aware that most of its vital materials come from the Lab’s own workforce,” said Chris C’de Baca, the NSRC’s Group Leader. “A significant portion of our critical material — which today’s researchers access regularly — is a direct contribution from research scientists. If people don’t contribute, then we won’t have the information we need when people come to the NSRC for research.”

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Why didn’t Oppenheimer ever win a Nobel Prize?

For his scientific achievement, he would be forever known as the father of the atomic bomb – but never as a Nobel laureate. The pinnacle of global recognition, the Nobel Prize was bestowed on 18 of J. Robert Oppenheimer’s colleagues with whom he worked at the Manhattan Project site in Los Alamos. There, in just 27 months and in a perceived race with Nazi Germany, the scientists created the first nuclear weapons. Their efforts brought the world into the Atomic Age and helped end World War II. Several were awarded the prize before coming to work at the wartime lab, while most would go on to win later in life. Oppenheimer was nominated for the Nobel Prize for Physics three times: in 1946, in 1951, and in 1967. Colleagues, scholars, and surely Oppenheimer himself pondered why he was never bestowed the honor. “To understand this,” said James Kunetka, historian and author of The General and the Genius, “you have to first examine the man’s academic life before and after the war.”

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Weapons Active Repository for Radiographs and Film (WARF) [Slides]

NSRC’s lineages dates to the Technical Library formed by J. Robert Oppenheimer in 1943 as part of the Manhattan Project. Houses 75+ years of nuclear weapons research, designs, procedures, reports, etc. This is the largest collection of nuclear weapons information anywhere in the nation.

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Section 106 Recordation, Interpretation, and Documentation for the Demolition of Buildings 9201-5 and 9204-4, Y-12 National Security Complex, Oak Ridge, Tennessee

In 2019 and 2020, Cultural Resource Analysts, Inc. (CRA), began preparing recordation packages for 18 World War II and Cold War Era buildings slated for demolition at the request of Consolidated Nuclear Security, LLC (CNS), on behalf of the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA). The recordations for these 18 buildings, which are located within what is now known as the Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee, were prepared and submitted in two separate packages. The first report (EC-NP-004) was prepared as a mitigation measure to address adverse effects that will result from the proposed demolition of 16 support and ancillary buildings. The current report is the second of the two packages and addresses the last two of the 18 buildings slated for demolition (9201-5 and 9204-4), which are two of the large process buildings located at Y-12. All 18 of these buildings have previously been determined eligible for listing in the National Register of Historic Places (NRHP). The two buildings, Building 9201-5 and Building 9204-4, are located south of Bear Creek Road and west of the main Y-12 entrance gate. Both buildings were constructed as uranium enrichment facilities in support of the Manhattan Project, a top-secret World War II mission to develop the world’s first nuclear weapons. Building 9201-5, completed in October 1944, is the Alpha-5 process facility and Building 9204-4, completed in Fall 1945, is the Beta-4 process facility. Over the years, these facilities were repurposed for a number of different functions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Celebrate Valentine’s Day with Three Early Lab Love Stories

This Valentine’s Day revel in several remarkable relationships that occurred leading up to and during the Manhattan Project, the United States government’s effort to build the atomic bomb and help end World War II. Further details of the lives and work of early Lab staff can be found in the legacy collections housed at the National Security Research Center, LANL’s classified library and curator of unclassified legacy items.

99 GENERAL AND MISCELLANEOUS↗

Actinides and Correlated Electron Materials

The Actinides and Correlated Electron Materials area of leadership spans Los Alamos National Laboratory competency in actinide materials research dating to the Manhattan Project as articulated in the Integrated Plutonium Science and Research Strategy and competency in strongly correlated electron systems dating back to at least the early 1980s. This area of leadership focuses on the goals of discovering, understanding, and controlling emergent electronic states and predictive performance of actinide materials. They are quintessentially linked by the fact that the physics of actinides—and plutonium in particular—are governed by strong electronic correlations. Not only is the electronic structure of actinides dictated by fine details of electron correlations, but chemical bonding and physical structure are as well. Hence, by addressing the first goal of this leadership area we can significantly accelerate progress on the second goal. To understand such matter requires probing the intertwined spin, charge, orbital, and lattice degrees of freedom with greater precision and developing models that accurately predict the consequences of these coupled degrees of freedom, on multiple length and time scales and including acute reactivity and effects of self-irradiation phenomena in these materials.

36 MATERIALS SCIENCE↗

Nuclear Weapons Theater Experience_V1

The theater experience is driven by the big message of nuclear deterrence through successful stockpile stewardship. This job enables other national and global security work with roots going back to the capabilities developed during the Manhattan Project and honed through the history of this successor scientific laboratory. The story that unfolds uses a narrative (traditional film-type approach), although the theater setup would offer immersion and decision-making (audience participation). The idea is to demonstrate how and why the Laboratory continues its mission in maintaining the nation’s stockpile while concurrently enabling the ever-evolving multi-disciplinary science and technology innovations developed for that purpose to take other scientists along vibrant paths.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗