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All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Perovskite-type oxides - Oxygen electrocatalysis and bulk structure

Perovskite type oxides were considered for use as oxygen reduction and generation electrocatalysts in alkaline electrolytes. Perovskite stability and electrocatalytic activity are studied along with possible relationships of the latter with the bulk solid state properties. A series of compounds of the type LaFe(x)Ni1(-x)O3 was used as a model system to gain information on the possible relationships between surface catalytic activity and bulk structure. Hydrogen peroxide decomposition rate constants were measured for these compounds. Ex situ Mossbauer effect spectroscopy (MES), and magnetic susceptibility measurements were used to study the solid state properties. X ray photoelectron spectroscopy (XPS) was used to examine the surface. MES has indicated the presence of a paramagnetic to magnetically ordered phase transition for values of x between 0.4 and 0.5. A correlation was found between the values of the MES isomer shift and the catalytic activity for peroxide decomposition. Thus, the catalytic activity can be correlated to the d-electron density for the transition metal cations.

Carbonio, R. E.↗
NASA NTRS1991

On magnetothermal instability in cluster cooling flows

Lagrangian techniques appropriate to a local calculation are used to show that a weak ordered magnetic field can result in a generic condensational mode in cluster cooling flows. However, thermal instability appears possible only if the conductivity is well below its Spitzer value, for all nonradial wavenumbers. Wavenumbers not subject to conductive damping are subject to buoyant oscillations. It is shown that when instability is present, lateral magnetic confinement of high thermal pressure regions in the plasma by radial magnetic field lines is responsible in at least equal measure with radially directed magnetic tension for the suppression of oscillations and the reappearance of local condensational modes. The general importance of even very modest magnetic fields for destabilizing thermal time scale perturbations is emphasized.

Balbus, Steven A.↗
NASA NTRS1991

Degradation of Fe-Mg silicates in hot CO2 atmospheres: Applications to Venus

Experiments demonstrated that oxidation of ferromagnesian silicates and magnetite occurs when these minerals are heated at 800 C in 1 atmosphere of CO2, under which conditions hematite is thermodynamically stable. The 30 ppm oxygen impurity in CO2 presumably facilitates the oxidation of some of the ferrous iron initially present in the crystal structures of the minerals. Mossbauer spectral measurements reveal, however, that only CO2 degraded olivine and pigeonite is hematite formed as a magnetically ordered phase at ambient temperatures. In orthopyroxene, some of the ferric iron produced by oxidation is present as nanophase hematite which, because it remains superparamagnetic until 4.2 K, must exist as particles less than or equal to 4 nm in diameter. In the calcic pyroxenes much of the oxidized ferrous iron may still remain as structural Fe3(+) in the host silicates. Some ferric iron may also be present as unit cell sized Fe2O3 inclusions in the pyroxenes, or be segregated along cleavage planes, or be coating mineral grains. In these states of aggregation, the Fe2O3 is unidentifiable by x ray diffraction and in low temperature Mossbauer spectra. Applications of this research to the surface of Venus are discussed.

Straub, Darcy W.↗
NASA NTRS1993

Circularly polarized radio emission from the T Tauri star Hubble 4

Multiwavelength VLA observations of the weak-lined T Tauri star (WTTS) Hubble 4, which is located in the nearby (about 140 pc) Taurus-Auriga star-forming region, are reported. The emission is characterized by a nearly flat spectral energy distribution with a spectral index of 0 (S sub nu varies as nu exp alpha). Right circular polarization was detected at both 3.6 and 6 cm at levels of 19 +/- 5 percent and 18 +/- 3 percent, respectively, with an upper limit of not more than 15 percent (3 sigma) at 20 cm. The star was in a state of low radio activity, with flux densities of 1.3-1.7 mJy and a radio luminosity of 10 exp 16.5 ergs/Hz s. The unambiguous detection of circularly polarized radio emission from Hubble 4 provides direct evidence for the existence of ordered magnetic fields in this WTTS.

Skinner, Stephen L.↗
NASA NTRS1994

Implosive accretion and outbursts of active galactic nuclei

A model and simulation code have been developed for time-dependent axisymmetric disk accretion onto a compact object including for the first time the influence of an ordered magnetic field. The accretion rate and radiative luminosity of the disk are naturally coupled to the rate of outflow of energy and angular momentum in magnetically driven (+/- z) winds. The magnetic field of the wind is treated in a phenomenological way suggested by self-consistent wind solutions. The radial accretion speed u(r, t) of the disk matter is shown to be the sum of the usual viscous contribution and a magnetic contribution proportional to r(exp 3/2)(B(sub p exp 2))/sigma, where B(sub p)(r,t) is the poloidal field threading the disk and sigma(r,t) is the disk's surface mass density. An enhancement or variation in B(sub p) at a large radial distance leads to the formation of a soliton-like structure in the disk density, temperature, and B-field which propagates implosively inward. The implosion gives a burst in the power output in winds or jets and a simultaneous burst in the disk radiation. The model is pertinent to the formation of discrete fast-moving components in jets observed by very long baseline interferometry. These components appear to originate at times of optical outbursts of the active galactic nucleus.

Lovelace, R. V. E.↗
NASA NTRS2004

Developing Glassy Magnets from Simulated Composition of Martian Soil for Exploration Applications

The long-term exploration goals of NASA include developing human habitation on Mars and conducting scientific investigations on Mars and other planetary bodies. In situ resource processing is a key objective in this area We focus OR the possibility of making magnetic glasses in situ for potential applications development. The paper will focus on ongoing work at NASA Marshall Space Flight Center on making magnetic glass h m Mars soil simulants and its characterization. Analysis of the glass morphology, strength, chemistry and resulting magnetic properties will provide a fi.mdamenta1 understanding ofthe synthesized materiai that can be used for pomtiai appiications cieveiopment. In an effort to characterize the magnetic properbes of the Mars glasses, a series of tests were performed at NASA MSFC. Preliminary tests indicated that the glasses were attracted to a magnet and also had a small amount of residual magnetism. They were opaque (almost black in color). As the first step, a sample of Mars 1 glass (-lm x lmm x 5 mm length) was machined, weighed and its hysteresis curve was measured using a Vibration Sample Magnetometer 0. Next, a small furnace was designed and built and the sample was baked in a graphite (reducing agent) crucible at 800 C in an Argon atmosphere for 3 hours in the presence of a uniform, transverse (transverse to the 5mm length of the sample) magnetic field of 0.37 Tesla. The treated sample showed reddening on the outside and showed substantially increased residual magnetism. This sample was again analyzed in the VSM. The data clearly showed that some chemical change occurred during the heat treatment (color change) and that both the glasses have useful magnetic properties. Although no orientation effects of the magnetic field were considered, the data showed the following: 1. Both glass samples are primarily soft magnets and display ferromagnetic behavior (hysteresis, saturation, etc.) 2. The treated glass has improved saturation magnetism (order of magnitude increase), retentivity (factor of 6 increase) and susceptibility (order of magnitude increase) compared to the untreated glass 3. The untreated sample has higher coercivity (-50% that of Nickel) than the treated sample

Ramachandran, Narayanan↗
NASA NTRS2016

The Imaging X-Ray Polarimetry Explorer (IXPE)

The Imaging X-ray Polarimetry Explorer (IXPE) is an exciting international collaboration for a scientific mission that dramatically brings together the unique talents of the partners to expand observation space by simultaneously adding polarization measurements to the array of source properties currently measured (energy, time, and location). IXPE uniquely brings to the table polarimetric imaging. IXPE will thus open new dimensions for understanding how X-ray emission is produced in astrophysical objects, especially systems under extreme physical conditions-such as neutron stars and black holes. Polarization singularly probes physical anisotropies-ordered magnetic fields, aspheric matter distributions, or general relativistic coupling to black-hole spin-that are not otherwise measurable. Hence, IXPE complements all other investigations in high-energy astrophysics by adding important and relatively unexplored information to the parameter space for studying cosmic X-ray sources and processes, as well as for using extreme astrophysical environments as laboratories for fundamental physics.

X-ray astronomy x-ray polarimetry↗
NASA NTRS2018

Imaging X-Ray Polarimetry Explorer Mission Attitude Determination and Control Concept

The goal of the Imaging X-Ray Polarimetry Explorer (IXPE) Mission is to expand understanding of high-energy astrophysical processes and sources, in support of NASA's first science objective in Astrophysics: "Discover how the universe works." X-ray polarimetry is the focus of the IXPE science mission. Polarimetry uniquely probes physical anisotropies-ordered magnetic fields, aspheric matter distributions, or general relativistic coupling to black-hole spin-that are not otherwise measurable. The IXPE Observatory consists of Spacecraft and Payload modules. The Payload includes three polarization sensitive, X-ray detector units (DU), each paired with its corresponding grazing incidence mirror module assemblies (MMA). A deployable boom provides the correct separation (focal length) between the DUs and MMAs. These Payload elements are supported by the IXPE Spacecraft. A star tracker is mounted directly with the deployed Payload to minimize alignment errors between the star tracker line of sight (LoS) and Payload LoS. Stringent pointing requirements coupled with a flexible structure and a non-collocated attitude sensor-actuator configuration requires a thorough analysis of control-structure interactions. A non-minimum phase notch filter supports robust control loop stability margins. This paper summarizes the IXPE mission science objectives and Observatory concepts, and then it describes IXPE attitude determination and control implementation. IXPE LoS pointing accuracy, control loop stability, and angular momentum management are discussed.

Attitude Determination and Contro↗
NASA NTRS1992

Nonlinear restrictions on dynamo action

Astrophysical dynamos operate in the limit of small magnetic diffusivity. In order for magnetic reconnection to occur, very small magnetic structures must form so that diffusion becomes effective. The formation of small-scale fields is accompanied by the stretching of the field lines and therefore by an amplification of the magnetic field strength. The back reaction of the magnetic field on the motions leads to the eventual saturation of the dynamo process, thus posing a constraint on the amount of magnetic flux that can be generated by dynamo action, It is argued that in the limit of small diffusivity only a small amount of flux, many orders of magnitude less than the observed fluxes, can be created by dynamo processes.

Vainshtein, Samuel I.↗
NASA NTRS1987

Magnetic fields in the overshoot zone: The great escape

In order that magnetic flux be confined within the solar interior for times comparable to the solar cycle period it has been suggested that the bulk of the solar toroidal field is stored in the convectively stable overshoot region situated beneath the convection zone proper. Such a magnetic field, though, is still buoyant and is therefore subject to Rayleigh-Taylor type instabilities. The model problem of an isolated region of magnetic field embedded in a convectively stable atmosphere is considered. The fully nonlinear evolution of the two dimensional interchange of modes is studied, thereby shedding some light on one of the processes responsible for the escape of flux from the solar interior.

Cattaneo, F.↗
NASA NTRS1996

Computational Modeling of Magnetically Actuated Propellant Orientation

Unlike terrestrial applications where gravity positions liquid at the "bottom" of the tank, the location of liquid propellant in spacecraft tanks is uncertain unless specific actions are taken or special features are built into the tank. Some mission events require knowledge of liquid position prior to a particular action: liquid must be positioned over the tank outlet prior to starting the main engines and must be moved away from the tank vent before vapor can be released overboard to reduce pressure. It may also be desirable to positively position liquid to improve propulsion system performance: moving liquid away from the tank walls will dramatically decrease the rate of heat transfer to the propellant, suppressing the boil-off rate, thereby reducing overall mission propellant requirements. The process of moving propellant to a desired position is referred to as propellant orientation or reorientation. Propulsive reorientation relies on small auxiliary thrusters to accelerate the tank. The inertia of the liquid causes it to collect in the aft-end of the tank if the acceleration is forward. Liquid Acquisition Devices (LAD's) rely on surface tension to hold the liquid within special geometries, (i.e. vanes, wire-mesh channels, start-baskets), to positively position propellants. Both of these technologies add significant weight and complexity to the spacecraft and can be limiting systems for long duration missions. The subject of the present research is an alternate technique for positively positioning liquid within spacecraft propellant tanks: magnetic fields. LOX is paramagnetic (attracted toward a magnet) and LH2 is diamagnetic (repelled from a magnet). Order-of-magnitude analyses, performed in the 1960's to determine required magnet size, concluded that the magnets would be prohibitively massive and this option has remained dormant during the intervening years. Recent advances in high-temperature superconducting materials hold the promise of electromagnets with sufficient performance to support cryogenic propellant management tasks. In late 1992, NASA MSFC began a new investigation in this technology commencing with the design of the Magnetically-Actuated Propellant Orientation (MAPO) experiment. A mixture of ferrofluid and water is used to simulate the paramagnetic properties of LOX and the experiment is being flown on the KC-135 aircraft to provide a reduced gravity environment. The influence of a 0.4 Tesla ring magnet on flow into and out of a subscale Plexiglas tank is being recorded on video tape. The most efficient approach to evaluating the feasibility of MAPO is to compliment the experimental program with development of a computational tool to model the process of interest. The goal of the present research is to develop such a tool. Once confidence in its fidelity is established by comparison to data from the MAPO experiment, it can be used to assist in the design of future experiments and to study the parameter space of the process. Ultimately, it is hoped that the computational model can serve as a design tool for full-scale spacecraft applications.

Hochstein, John I.↗
NASA NTRS1992

Magnetic interchange instability of accretion disks

The nonlinear evolution of the magnetic interchange or buoyancy instability of a differentially rotating disk threaded by an ordered vertical magnetic field is investigated. A 2D ideal fluid in the equatorial plane of a central mass in the corotating frame of reference is considered as a model for the disk. If the rotation rate of the disk is Keplerian, the disk is found to be stable. If the vertical magnetic field is sufficiently strong, and the field strength decreases with distance from the central object, and thus the rotation of the disk deviates from Keplerian, if is found that an instability develops. The magnetic flux and disk matter expand outward in certain ranges of azimuth, while disk matter with less magnetic flux moves inward over the remaining range of azimuth, showing a characteristic development of an interchange instability.

Kaisig, M.↗
NASA NTRSDate not supplied

VERNE: Revealing the Mysteries and Histories of Venus

Introduction: The three Venus missions that were recently selected for upcoming flight (VERITAS, DAVINCI+, and EnVision) will be incredibly valuable to our understanding of Venus’ history, geology, and atmosphere. However, even once completed, key gaps in our knowledge of Venus, and more generally the formation and active processes on rocky, Earth-like planets, will still persist. Remaining questions include 1) how global intrinsic magnetic fields might be maintained on rocky worlds, and how they could then go extinct, and 2) what role atmospheric sulfur chemistry plays in climates of Earth-like planets, which is an increasingly timely subject as Earth’s own atmospheric sulfur content is climbing due to human activity. These questions require in-situ observations from Venus’ cloud deck, at the altitudes at which the UV absorber exists. The Venus Environment Research and Novel Exploration (VERNE) mission will address these questions with an aerial platform that will drift around the equatorial region of the planet for 9 days. VERNE will collect data to determine the identity of the mysterious UV absorber, while also taking magnetic field measurements over the tesserae, the regions on Venus that are most likely to retain remanent crustal magnetization, in order to understand the potential role of a past intrinsically-generated global magnetic field on Venus. Mission Objectives: The two major science objectives that drive the VERNE mission are: 1) Determine the identity of the Venusian unknown ultraviolet absorber(s). First observed approximately a century ago [1], the composition of Venus’ ultraviolet (UV) absorber is one of the oldest mysteries in Venus atmospheric chemistry [2,3]. While several candidate UV absorbers (mostly sulfur species) have been proposed, no consensus has been reached on its composition and its specific interactions with the atmosphere. Determining the identity of the UV absorber will aid climate models by showing how and where incident solar energy is absorbed by the atmosphere and make progress towards understanding the chemical and energetic processes taking place above Venus’ upper cloud deck [4]. 2) Determine if Venus retains evidence of a past, internally-generated magnetic field. While Venus does not currently have an intrinsically-generated magnetic field, evidence for the existence of a past field on Venus and a timeline of its decay will fill in a more holistic picture of the evolution of Venus’ geological record and atmosphere. As the oldest geologic units on the surface, Venus’ tesserae may still have remanent crustal magnetization signatures within the rocky composition [5]. In any case, the signatures detected will provide insight into Venus’ past geological and core dynamo activity. Mission Summary: VERNE includes a 3-part flight system made up of 1) an entry system with a HEEET (Heatshield for Extreme Entry Environment Technology) aeroshell, 2) an orbiter for data relay, and 3) an in-situ balloon and gondola. After entry into Venus’ atmosphere, the balloon will be deployed within the upper cloud deck, at an altitude of 62 km, over a tesserae region. The in-situ data collection will last for the duration of 2 full circumnavigations of the planet, which will take ~9 days. Instrumentation Suite: The four instruments that comprise VERNE’s instrument payload will enable the identification of the unknown UV absorber and the detection of remanent crustal magnetization if it exists in the tesserae. The proposed instrument suite cycle during mission operations is shown in Fig. 1. The four instruments are described below: 1) Adams (ion neutral mass spectrometer) has a range of 18-257 AMU and will detect and distinguish the mixing ratios of O₂, H₂O, H₂SO₄, S, S₂, S₃, S₄, S₅, S₆, S₇, S₈, SO, SO₂, OSSO, SO₃, Cl₂, FeCl₃ and other trace sulfur and organic species. The spatial (longitudinal) and temporal (day/night) variations will be observed throughout 2 circumnavigations with a sample cadence of 12 minutes. 2) Shelley (nephelometer) will determine the size distribution of the aerosols (0.4 to 36 um) in the atmosphere. With a size resolution of <0.7 um, it can determine which mode of H2SO4 is present and characterize the large (>30 um) organic particles previously detected by the Venera and Galileo missions [6,7]. 3) Herbert (UV imager) will measure UV radiance at 283 nm (the wavelength of SO2 absorption) and 365 nm (the unknown part of the absorber). UV images will be taken concurrently with the INMS and nephelometer to correlate UV absorption with abundances of the UV absorber species. 4) Vonnegut (magnetometer) has a range of >600 nT and a precision and accuracy of 1 nT. If magnetized by a past field, the crust may have retained a magnetization of up to 3 A/m2 [5]. With a noise floor of 10 nT, the magnetometer will be able to detect RCM from an altitude of 62 km, even if the thickness of the magnetized crust is just 1 km (Fig. 2). Mission Concept Design: VERNE will be launched with a mass of 3300 kg in an intermediate-high performance class vehicle with a 4-m fairing. The 475-day mission includes 466 days for the cruise, coasting, and orbit initialization phases before entry, descent, and balloon deployment. During the 9-day science phase, the aerial platform will make 2 circumnavigations of the planet at an altitude of 62 km. The INMS and the nephelometer will acquire data for 2 hours during the daytime and nighttime during each circumnavigation, while the UV imager will be on for the duration of the daytime, and the magnetometer will be operational throughout the entirety of the science phase. Data will be stored and processed with the JPL-designed Sphinx command and data handling system. Data will be sent from the balloon to the orbiter using an S-band relay link, stored on the orbiter, and then forwarded to Earth where it will be received by the DSN. Conclusion: VERNE will fill key gaps in our understanding of the history and ongoing processes related to the geology and atmosphere of Venus and rocky worlds in general. Even with adequate flight system contingencies and expected costs below the $900M New Frontiers cost cap, VERNE is not without its risks and challenges. Further trade spaces to explore include 1) using solely battery power vs. including solar panels to increase the mission duration and 2) investigating the use of lightweight materials and 3D-printed structures to reduce the gondola mass, among others. Acknowledgments: We would like to thank the JPL Planetary Science Summer School, especially our mentors Troy Hudson, Karl Mitchell, and Leslie Lowes, as well as our Team-X study lead Al Nash and the members of Team-X. We’d additionally like to thank our review panel for asking insightful questions and providing valuable feedback. References: [1] Ross, F. E. (1928) Astrophysical J., 68, 57-92. [2] Rossow, W. B. et al. (1980) J. Geophysical Research, 85, 8107-8128. [3] Pinto, J. P. et al. (2021) Nature Communications, 12, 175. [4] Titov, D. V. et al. (2007) Cosmic Research, 21, 401. [5] O’Rourke, J. et al. (2019) Geophysical Research Lett., 46, 5768–5777. [6] Limaye, S. S. et al. (2018) Astrobiology, 18(9), 1181-1198. [7] Grinspoon, D. H. et al. (2013) Planetary and Space Sci., 41(7), 515-542. [8] Parker, R. L. (2003) J. Geophysical Research, 108, 5006. *The cost information contained in this document is of a budgetary and planning nature and is intended for informational purposes only. It does not constitute a commitment on the part of JPL and/or Caltech.

H Alpert↗
NASA NTRS2008

Magnetic Compensation for Second-Order Doppler Shift in LITS

The uncertainty in the frequency of a linear-ion-trap frequency standard (LITS) can be reduced substantially by use of a very small magnetic inhomogeneity tailored to compensate for the residual second-order Doppler shift. An effect associated with the relativistic time dilatation, one cause of the second-order Doppler shift, is ion motion that is attributable to the trapping radio-frequency (RF)electromagnetic field used to trap ions. The second-order Doppler shift is reduced by using a multi-pole trap; however it is still the largest source of systematic frequency shift in the latest generation of LITSs, which are among the most stable clocks in the world. The present compensation scheme reduces the frequency instability of the affected LITS to about a tenth of its previous value. The basic principles of prior generation LITSs were discussed in several prior NASA Tech Briefs articles. Below are recapitulated only those items of basic information necessary to place the present development in context. A LITS includes a microwave local oscillator, the frequency of which is stabilized by comparison with the frequency of the ground state hyperfine transition of 199Hg+ ions. The comparison involves a combination of optical and microwave excitation and interrogation of the ions in a linear ion trap in the presence of a nominally uniform magnetic field. In the current version of the LITS, there are two connected traps (see figure): (1) a quadrupole trap wherein the optical excitation and measurement take place and (2) a 12-pole trap (denoted the resonance trap), wherein the microwave interrogation takes place. The ions are initially loaded into the quadrupole trap and are thereafter shuttled between the two traps. Shuttling ions into the resonance trap allows sensitive microwave interrogation to take place well away from loading interference. The axial magnetic field for the resonance trap is generated by an electric current in a finely wound wire coil surrounded by magnetic shields. In the quadrupole and 12-pole traps, the potentials are produced by RF voltages applied to even numbers (4 and 12, respectively) of parallel rods equally spaced around a circle. The polarity of the voltage on each rod is opposite that of the voltage on the adjacent rod. As a result, the amplitude of the RF trapping field is zero along the centerline and increases, with radius, to a maximum value near the rods.

Burt, Eric↗
NASA NTRS2022

A Regional Classification of Time Spectral Amplitudes in Total Electron Content: Southeastern United States During Solar Cycle 24

To investigate the meso-scale structure (100 s of km) of the ionosphere at mid-latitudes, the spectral properties in calculated total electron content (TEC) at a cluster of GPS receivers in and around Florida are analyzed. The ionosphere does not respond exactly the same to periodic solar driving at different locations around the planet, due to the complex electrodynamic interactions of the coupled magnetosphere-ionosphere system. Therefore, at each GPS receiver in the cluster we compare spatio-temporal variations of the spectral amplitudes for diurnal, solar rotation, and seasonal oscillations. The amplitudes for these dominant oscillations are organized with respect to magnetic latitude of the receiver. A low-latitude and high-latitude station are also included to put the mid-latitude ionospheric response into a global context. The amplitudes of diurnal, seasonal, and solar rotation signals are well ordered by magnetic latitude, superposed with meso-scale deviations between stations separated by ~100s of km. The results suggest that spatio-temporal variations of spectral amplitudes in the mid-latitude ionosphere are not dominated by a single process. This conclusion is based on our finding that at high latitude, the shape of the diurnal signal varies significantly less with solar activity compared to low- and mid-latitudes, and additionally, that the ratio of annual to semi-annual amplitudes fluctuates around 1 with time and from station-to-station only at mid-latitudes.

ionosphere↗
NASA NTRS1985

The detection of global convective wave flows on the Sun

Global convective flows in the solar convection zone have been predicted by theoretical interpretations of the global-scale ordering of magnetic fields and activity centers and by theoretical analyses of rotating convection zones. Direct evidence of these flows in the photosphere has not previously been found despite several long-term efforts. The signatures of such flows have now been detected by analyzing the daily series of low-resolution Dopplergrams obtained at the Wilcox Solar Observatory at Stanford University. The signatures are patterns of alternating east and west flows with amplitudes on the order of 25 m/s and longitudinal extent of about 30 degrees. The patterns move across the disc at approximately the solar rotation rate and have lifetimes of at least several rotations. Boundaries of the fast and slow flows are often associated with large magnetic active regions.

Scherrer, P. H.↗