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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

UK-4 flight spacecraft magnetic tests

Magnetic tests conducted on the UK-4 spacecraft are discussed. The objectives of the test are: (1) to determine the permanent, induced, and stray magnetic moments of the spacecraft, (2) to assess its magnetic stability, (3) to determine the dipole moment produced by energizing the magnetorquer coil, (4) to measure the despin torque due to eddy current and magnetic hysteresis, and (5) to deperm, compensate, and make other adjustments necessary to achieve satisfactory magnetic characteristics for the spacecraft.

Pruett, W. E.↗
DOE OSTI2023

Strong Axiality in a Dysprosium(III) Bis(borolide) Complex Leads to Magnetic Blocking at 65 K

Substituted dysprosocenium complexes of the type [Dy(Cp R ) 2 ] + exhibit slow magnetic relaxation at cryogenic temperatures and have emerged as top-performing single-molecule magnets. The remarkable properties of these compounds derive in part from the strong axial ligand field afforded by the cyclopentadiene anions, and the design of analogous compounds with even stronger ligand fields is one promising route toward identifying new single-molecule magnets that retain a magnetic memory at even higher temperatures. Here, we report the synthesis and characterization of a dysprosium bis(borolide) compound, [K(18-crown-6)][Dy(BC 4 Ph 5 ) 2 ] (1), featuring the dysprosocenate anion [Dy(BC 4 Ph 5 ) 2 ] - with a pseudoaxial coordination environment afforded by two dianionic pentaphenyl borolide ligands. Variable-field magnetization data reveal open magnetic hysteresis up to 66 K, establishing 1 as a top-performing single-molecule magnet among its dysprosocenium analogues. Ac magnetic susceptibility data indicate that 1 relaxes via an Orbach mechanism above ~80 K with U eff = 1500(100) cm -1 and τ 0 = 10 -12.0(9) s, whereas Raman relaxation and quantum tunneling of the magnetization dominate at lower temperatures. Compound 1 exhibits a 100 s blocking temperature of 65 K, among the highest reported for dysprosium-based single-molecule magnets. Ab initio spin dynamics calculations support the experimental U eff and τ 0 values and enable a quantitative comparison of the relaxation dynamics of 1 and two representative dysprosocenium cations, yielding additional insights into the impact of the crystal field splitting and vibronic coupling on the observed relaxation behavior. Importantly, compound 1 represents a step toward the development of alternatives to substituted dysprosocenium single-molecule magnets with increased axiality.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Tunable structural and magnetic properties of NiAs-type Mn x Sb (1.00≤x≤1.30) compounds

Mn-based alloys can exhibit a variety of magnetic properties related to their tunable exchange interactions. Here, structural and magnetic properties of hexagonal NiAs-type Mn x Sb (1.00≤x≤1.30) compounds are studied with a combination of X-ray diffraction, neutron diffraction, and magnetic measurements. It is found that the magnetization, Curie temperature, and magnetocrystalline anisotropy of Mn x Sb compounds can be tuned by controlling Mn concentration and doping at interstitial (2d) sites. With increasing Mn concentration, magnetic moments of Mn atoms decrease and deviate gradually from the ab-plane to the c-axis for 1.20≤x≤1.22 at room temperature, which leads to a decrease of the Curie temperature T c and the spin reorientation temperature T SR . By doping with nonmagnetic elements, a substantial room-temperature magnetocaloric effect without magnetic hysteresis was achieved for Mn 1.12 Zr 0.1 Sb compound, which is highly beneficial to the practical magnetic refrigeration application.

36 MATERIALS SCIENCE↗
NASA NTRS1988

A new class of natural magnetic materials - The ordering alloys

It is shown that tetrataenite (approximately FeNi), found in many meteorites, and Josephinite (approximately FeNi3), found in many serpentinized peridotites and possibly in Allende, are atomically ordered alloys. Data are presented, showing magnetic hysteresis loops, coercivity-temperature behavior at cryogenic temperatures, and thermomagnetic curves, that show that these ordered magnetic materials have unique magnetic properties and do not fit the conventional rock magnetism paradigms represented by Fe3O4 serpentinites. The ordered state is characterized by induced magnetic anisotropy, reaching the extreme for the tetragonal truly uniaxial anisotropy in FeNi. It is suggested that these ordered magnetic alloys should be considered a new class of natural magnetic materials.

Wasilewski, Peter↗
NASA NTRS1981

Magnetization of small iron-nickel spheres

Magnetic properties of small iron-nickel alloy spheres, having compositions which cover the entire Fe-Ni binary, are presented. The spheres were formed during solidification in free fall following the melting of electropolished wires of appropriate composition. The spheres with Ni not greater than 25% acquired a martensitic thermal remanence while those with Ni not less than 30% acquired a thermoremanent magnetization. A magnetic remanence-composition diagram and a coercive force-composition diagram are constructed. Magnetic hysteresis loops and derived parameters demonstrate the difference between metal-bearing and oxide-bearing natural samples. The magnetic remanence varies as the sphere size in conjunction with the microstructure. These results help to explain why coercive force is generally low, remanent coercive force is generally high, and their ratio (R/C) is always large in fine metal dispersions, such as lunar samples and chondrite meteorites.

Wasilewski, P.↗
NASA NTRS1972

Magnetic coercivity and ferromagnetic species in lunar materials

Lunar samples have reduced coercive force, high values of R sub H (ratio of remanent coercive force to coercive force), and constriction in their magnetic hysteresis loops due to the presence of superparamagnetic and multidomain iron grains. The high R sub H values are also attributable to the magnetic shape effects of the iron grains. Spheres, cubes, and needles, as well as more irregular metal grains were observed. The coercive force values are quite meaningless unless the size and shape distributions are determined. The R sub H and the ratio of saturation remanence to saturation magnetization values can be considered characteristic of the size and shape modes of the ferromagnetic grains in a natural sample, and a classification of natural materials based on their hysteresis characteristics is presented with special reference to lunar samples.

Wasilewski, P.↗
DOE OSTI2024

A Nanosized {Ni II 18 } Cluster with a ‘Flying Saucer’ Topology Exhibiting Slow Relaxation of Magnetisation Phenomena at Both 15 K and 1.3 K

A high-nuclearity {Ni 18 } complex (1) with a unique ‘flying saucer’ motif has been prepared from the organic chelate, α-methyl-2-pyridine-methanol (mpmH), in conjunction with bridging azido (N 3 - ) and peroxido (O 2 2- ) ligands. Magnetic susceptibility measurements revealed the presence of both ferro- and antiferromagnetic exchange interactions between the metal centres in 1, and the stabilization of spin states with appreciable S values at two different temperature regimes. The end-on bridging azido and alkoxido groups are in all likelihood the ferromagnetic mediators, while the η 3 :η 3 :μ 6 -bridging peroxides most likely promote the antiparallel alignment of the metals’ spin vectors, yielding an overall non-zero spin ground state for the centrosymmetric compound 1. Furthermore, the {Ni 18 } nanosized cluster behaves as a single-molecule magnet, exhibiting magnetic hysteresis at low temperatures and two relaxation processes at 15 K and 1.3 K, a very rare phenomenon in polynuclear magnetic 3d-metal clusters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Direct evidence of ferromagnetism in MnSb 2 Te 4

We report the magnetic imaging of ferromagnetic domains in the van der Waals single crystal MnSb 2 Te 4 from two different sources using cryogenic magnetic force microscopy. The magnetic field dependence of the domains reveals very weak pinning of domain walls in MnSb 2 Te 4 , resulting in a negligibly small magnetic hysteresis loop. Furthermore, the temperature dependence of the domain contrast reveals a mean field like behavior, in good agreement with that of bulk magnetization measurements.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Structural, magnetic, and magnetocaloric properties of (Nd 0.7 Ce 0.3 )YFe 17

Structural, magnetic, and magnetocaloric properties of iron-deficient (Nd 1-x Ce x )YFe 17 alloys in the rhombohedral Th 2 Zn 17 –type crystal structure prepared by arc-melting and vacuum annealing have been investigated. Among the investigated alloys, (Nd 0.7 Ce 0.3 )YFe 17 shows the highest values of magnetic entropy change and relative cooling power, namely 5.45 J kg -1 K -1 and 504 J kg -1 for a magnetic field change of 5 T. The Curie temperature and saturation magnetization of the (Nd 0.7 Ce 0.3 )YFe 17 alloy are 301 K and 162 emu/g, respectively. The absence of thermal and magnetic hysteresis with relatively high cooling capacity near room temperature suggests that Fe-deficient (Nd 0.7 Ce 0.3 )YFe 17 carries significant potential for room-temperature magnetic refrigeration.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Facile integration of giant exchange bias in Fe 5 Ge Te 2 / oxide heterostructures by atomic layer deposition

Exchange bias arises from the interfacial exchange coupling in ferromagnet-antiferromagnet bilayers and manifests as a horizontal shift of the magnetic hysteresis loop, constituting a critical component underpinning a broad range of magnetoresistive logic and memory devices. The facile implementation of exchange bias in van der Waals (vdW) magnets would be a key step towards practical devices for emerging vdW spintronics. Here, in this paper, we report an easy approach to establishing strong exchange bias in the vdW magnet Fe 5 GeTe 2 by a single-step process—atomic layer deposition (ALD) of oxides on Fe 5 GeTe 2 . We successfully created exchange bias of 300–1500 Oe in Fe 5 GeTe 2 /Al 2 O 3 , Fe 5 GeTe 2 /ZnO, and Fe 5 GeTe 2 /V 2 O 5 heterostructures, at 130 K. Control experiments showed that increasing the oxidant pulse duration in each ALD cycle or utilizing the stronger oxidant O 3 can enhance the exchange bias strength, revealing the key role of the ALD oxidants. Our systematic work elucidates the essential role of ALD-enabled oxidization of Fe 5 GeTe 2 in the formation of exchange bias, and establishes ALD of oxides as a facile, controllable, and generally effective approach to creating giant exchange bias in vdW magnets, representing an integral advance towards practical vdW spintronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Synthesis, Stability, and Magnetic Properties of Antiperovskite Co 3 PdN

Experimental synthesis and characterization of theoretically predicted compounds are important steps in the materials discovery pipeline. Here, we report on the synthesis of Co 3 PdN, which was recently predicted to be a stable magnetic antiperovskite. The Co 3 PdN thin films were grown by reactive sputtering and were confirmed to form in an antiperovskite crystal structure. The thermal stability of the compound is demonstrated up to 600 K by in situ X-ray diffraction, though the phase persists at slightly higher temperatures (700 K) in an air-free magnetometer. Both ab initio calculations and magnetization measurements find Co 3 PdN to be ferromagnetic with an experimentally determined Curie temperature of T C = 560 ± 5 K. The saturation magnetization of 1.2 μ B /Co found in the experiment is slightly lower than the 1.7 μ B /Co value expected by theory. A narrow magnetic hysteresis loop with a coercive field of 100 Oe at low temperature suggests that Co 3 PdN might be useful in electronic applications requiring fast switching of the magnetization vector. While prior prediction of Co 3 PdN showed a gapped electronic band structure for each spin channel, we show that this was due to incomplete sampling of Brillouin zone paths and that band crossings exist along R-X|M and X|M-R paths. The metallic nature of Co 3 PdN is further confirmed by temperature-dependent transport measurements, which also show a considerable anomalous Hall effect. Altogether, this work represents an appreciable step toward understanding the synthesis, structure, stability, and properties of a new magnetic material.

14 SOLAR ENERGY↗
DOE OSTI2022

Presence of Induced Weak Ferromagnetism in Fe-Substituted YFe x Cr 1–x O 3 Crystalline Compounds

Fe-substituted YFe x Cr 1–x O 3 crystalline compounds show promising magnetic and multiferroic properties. Here we report the synthesis and characterization of several compositions from this series. Using the autocombustion route, various compositions (x = 0.25, 0.50, 0.6, 0.75, 0.9, and 1) were synthesized as high-quality crystalline powders. In order to obtain microscopic and atomic information about their structure and magnetism, characterization was performed using room temperature X-ray diffraction and energy dispersion analysis as well as temperature-dependent neutron diffraction, magnetometry, and 57 Fe Mössbauer spectrometry. Rietveld analysis of the diffraction data revealed a crystallite size of 84 (8) nm for YFeO 3 , while energy dispersion analysis indicated compositions close to the nominal compositions. The magnetic results suggested an enhancement of the weak ferromagnetism for the YFeO 3 phase due to two contributions. First, a high magnetocrystalline anisotropy was associated with the crystalline character that favored a unique high canting angle of the antiferromagnetic phase (13°), as indicated by the neutron diffraction analysis. This was also evidenced by the high magnetic hysteresis curves up to 90 kOe by a remarkable high critical coercivity value of 46.7 kOe at room temperature. Second, the Dzyaloshinskii–Moriya interactions between homogenous and heterogeneous magnetic pairs resulted from the inhomogeneous distribution of Fe 3+ and Cr 3+ ions, as indicated by 57 Fe Mössbauer studies. Together, these results point to new methods of controlling the magnetic properties of these materials.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Magnetoelastic properties of multiferroic hexagonal ErMnO 3

Here, the strength and dynamics of magnetoelastic coupling through the paramagnetic (PM) – antiferromagnetic (AFM) – ferrimagnetic (FIM) transitions in multiferroic hexagonal ErMnO 3 have been investigated by Resonant Ultrasound Spectroscopy. Elastic stiffening by up to 2% below the PM – AFM transition at 80 K arises from biquadratic coupling between strain and the magnetic order parameter with relaxation times longer than ~10 -6 s for the response of spins to changes in strain. In contrast with YMnO 3 , the PM – AFM transition in ErMnO 3 is accompanied by a peak in acoustic loss immediately below the Néel point which is interpreted in terms of strain relaxation accompanying ordering of spins of Er 3+ at 4b sites. Changes in the magnetic ordering scheme at the AFM – FIM transition near 3 K are accompanied by elastic softening of ~0.03 %. During poling of the low temperature ferrimagnetic structure round magnetic hysteresis loops, small changes in elastic stiffness which arise due to the contribution of piezomagnetic and/or piezoelectric moduli are detected. Contributions of piezoelectric moduli to acoustic resonance frequencies also permit changes in the configuration of ferroelectric domains to be detected in response both to cycling through this transition and to application of a magnetic field. A peak in acoustic loss in the vicinity of 250 K is attributed to strain-mediated pinning/freezing of some aspect of the domain microstructure with an activation energy of ~0.25–0.3 eV. A return to the original elastic properties on heating to temperatures above ~250 K is interpreted in terms of backswitching of domains to the configuration they had at the start. These observations confirm the existence of subtle variations in magnetoelastic coupling behaviour relating to both the magnetic order parameters and magnetic domain structures.

36 MATERIALS SCIENCE↗
NASA NTRS2009

Magnetic-Field-Tunable Superconducting Rectifier

Superconducting electronic components have been developed that provide current rectification that is tunable by design and with an externally applied magnetic field to the circuit component. The superconducting material used in the device is relatively free of pinning sites with its critical current determined by a geometric energy barrier to vortex entry. The ability of the vortices to move freely inside the device means this innovation does not suffer from magnetic hysteresis effects changing the state of the superconductor. The invention requires a superconductor geometry with opposite edges along the direction of current flow. In order for the critical current asymmetry effect to occur, the device must have different vortex nucleation conditions at opposite edges. Alternative embodiments producing the necessary conditions include edges being held at different temperatures, at different local magnetic fields, with different current-injection geometries, and structural differences between opposite edges causing changes in the size of the geometric energy barrier. An edge fabricated with indentations of the order of the coherence length will significantly lower the geometric energy barrier to vortex entry, meaning vortex passage across the device at lower currents causing resistive dissipation. The existing prototype is a two-terminal device consisting of a thin-film su - perconducting strip operating at a temperature below its superconducting transition temperature (Tc). Opposite ends of the strip are connected to electrical leads made of a higher Tc superconductor. The thin-film lithographic process provides an easy means to alter edge-structures, current-injection geo - metries, and magnetic-field conditions at the edges. The edge-field conditions can be altered by using local field(s) generated from dedicated higher Tc leads or even using the device s own higher Tc superconducting leads.

Sadleir, John E.↗
DOE OSTI2024

Quantum Barkhausen noise induced by domain wall cotunneling

Most macroscopic magnetic phenomena (including magnetic hysteresis) are typically understood classically. Here, we examine the dynamics of a uniaxial rare-earth ferromagnet deep within the quantum regime, so that domain wall motion, and the associated hysteresis, is initiated by quantum nucleation, which then grows into large-scale domain wall motion, which is observable as an unusual form of Barkhausen noise. We observe noncritical behavior in the resulting avalanche dynamics that only can be explained by going beyond traditional renormalization group methods or classical domain wall models. We find that this “quantum Barkhausen noise” exhibits two distinct mechanisms for domain wall movement, each of which is quantum-mechanical, but with very different dependences on an external magnetic field applied transverse to the spin (Ising) axis. These observations can be understood in terms of the correlated motion of pairs of domain walls, nucleated by cotunneling of plaquettes (sections of domain wall), with plaquette pairs correlated by dipolar interactions; this correlation is suppressed by the transverse field. Similar macroscopic correlations may be expected to appear in the hysteresis of other systems with long-range interactions.

Science & Technology - Other Topics↗
DOE OSTI2021

Magnetism and structure of Fe- and Co-substituted Mn 2 NiSn

Mn-containing Heuslers are important magnetic shape-memory alloys for fast and precise actuators in manufacturing, robotics, surgery, and other applications. Among the key requirements are a high magnetization and favorable thermal properties, especially a high Curie temperature. In this work, the effect of Fe and Co substitution on the structure and magnetism of Mn 2 NiSn alloys is investigated. The Heusler alloys have been produced by melt spinning and characterized by X-ray diffraction, magnetometry, and electron-transport measurements. It was found that Co substitution for Mn enhances the Curie temperature of Mn 2 NiSn and both Co and Fe substitution improve its magnetization. Further, these improvements are accompanied by reduced thermal and magnetic hysteresis losses and by interesting structural changes, namely improved chemical order and site occupancies characteristic of quaternary (Y-ordered) Heuslers.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Strongly Correlated Exciton-Magnetization System for Optical Spin Pumping in CrBr 3 and CrI 3 .

Ferromagnetism in van der Waals systems, preserved down to a monolayer limit, attracted attention to a class of materials with general composition CrX 3 (X=I, Br, Cl), which are treated now as canonical two-dimensional ferromagnets. Their diverse magnetic properties, such as different easy axes or varying and controllable character of in-plane or interlayer ferromagnetic coupling, make them promising candidates for spintronic, photonic, optoelectronic, and other applications. Still, significantly different magneto-optical properties between the three materials, have been presenting a challenging puzzle for researchers over the last few years. Herewith, we demonstrate that despite similar structural and magnetic configurations, the coupling between excitons and magnetization is qualitatively different in CrBr 3 and CrI 3 films. Through a combination of the optical spin pumping experiments with the state-of-the-art theory describing bound excitonic states in the presence of magnetization, we concluded that the hole-magnetization coupling has the opposite sign in CrBr 3 and CrI 3 and also between the ground and excited exciton state. Consequently, we demonstrate efficient spin pumping capabilities in CrBr 3 driven by magnetization via spin-dependent absorption and unraveled the different origins of the magnetic hysteresis in CrBr 3 and CrI 3 are unraveled

36 MATERIALS SCIENCE↗
DOE OSTI2025

Extended quantum anomalous Hall states in graphene/hBN moiré superlattices

Electrons in topological flat bands can form new topological states driven by correlation effects. The pentalayer rhombohedral graphene/hexagonal boron nitride (hBN) moiré superlattice was shown to host fractional quantum anomalous Hall effect (FQAHE) at approximately 400 mK, triggering discussions around the underlying mechanism and role of moiré effects. In particular, new electron crystal states with non-trivial topology have been proposed. Here, in this paper, we report electrical transport measurements in rhombohedral pentalayer and tetralayer graphene/hBN moiré superlattices at electronic temperatures down to below 40 mK. We observed two more fractional quantum anomalous Hall (FQAH) states and smaller R xx values in pentalayer devices than those previously reported. In the new tetralayer device, we observed FQAHE at moiré filling factors v = 3/5 and 2/3. With a small current at the base temperature, we observed a new extended quantum anomalous Hall (EQAH) state and magnetic hysteresis, where R xy = h/e 2 and vanishing R xx spans a wide range of v from 0.5 to 1.3. At increased temperature or current, EQAH states disappear and partially transition into the FQAH liquid. Furthermore, we observed displacement field-induced quantum phase transitions from the EQAH states to the Fermi liquid, FQAH liquid and the likely composite Fermi liquid. Our observations established a new topological phase of electrons with quantized Hall resistance at zero magnetic field and enriched the emergent quantum phenomena in materials with topological flat bands.

36 MATERIALS SCIENCE↗