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At least 55 records · Page 3

Introduction of biotin or folic acid into polypyrrole magnetite core-shell nanoparticles

In order to contribute to the trend in contemporary research to develop magnetic core shell nanoparticles with better properties (reduced toxicity, high colloidal and chemical stability, wide scope of application) in straightforward and reproducible methods new core shell magnetic nanoparticles were developed based on polypyrrole shells functionalized with biotin and folic acid. Magnetite nanoparticles stabilized by sebacic acid were used as magnetic cores. The morphology of magnetite was determined by transmission electron microscopy TEM, while the chemical structure investigated by FT-IR.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Contributed Review: Nuclear magnetic resonance core analysis at 0.3 T

Nuclear magnetic resonance (NMR) provides a powerful toolbox for petrophysical characterization of reservoir core plugs and fluids in the laboratory. Previously, there has been considerable focus on low field magnet technology for well log calibration. Now there is renewed interest in the study of reservoir samples using stronger magnets to complement these standard NMR measurements. Here, the capabilities of an imaging magnet with a field strength of 0.3 T (corresponding to 12.9 MHz for proton) are reviewed in the context of reservoir core analysis. Quantitative estimates of porosity (saturation) and pore size distributions are obtained under favorable conditions (e.g., in carbonates), with the added advantage of multidimensional imaging, detection of lower gyromagnetic ratio nuclei, and short probe recovery times that make the system suitable for shale studies. Intermediate field instruments provide quantitative porosity maps of rock plugs that cannot be obtained using high field medical scanners due to the field-dependent susceptibility contrast in the porous medium. Example data are presented that highlight the potential applications of an intermediate field imaging instrument as a complement to low field instruments in core analysis and for materials science studies in general.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Coupled-inductor DC-DC power converter

A DC-to-DC power converter device has a common magnetic core structure that serves the functions of both transformer device and output inductor by integrating each into the common core. The transformer device has primary and secondary windings integrated into a first leg structure of the magnetic core, and the output inductor device has an output inductor winding integrated into a second leg structure of the magnetic core, the inductor winding structure for delivering output current to a load when a periodically switched input voltage is applied across the primary winding structure. The winding polarities of the transformer secondary winding structure and of the output inductor winding structure provide oppositely oriented polarities of electromotive force (EMF) to substantially reduce an output current ripple to an output load when delivering power through the transformer, through the output inductor and into the output load. A third leg structure of the common magnetic core allows magnetic flux passing through the transformer leg structure to partially magnetically couple to flux passing through the inductor leg structure, thereby allowing adjustment of the output voltage at which output current ripple is minimized.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Optical trapping of core-shell magnetic microparticles by cylindrical vector beams

Optical trapping of core-shell magnetic microparticles is experimentally demonstrated by using cylindrical vector beams. Second, we investigate the optical trapping efficiencies. The results show that radially and azimuthally polarized beams exhibit higher axial trapping efficiencies than the Gaussian beam. Finally, a trapped particle is manipulated to kill a cancer cell. The results make possible utilizing magnetic particles for optical manipulation, which is an important advantage for magnetic particles as labeling agent in targeted medicine and biological analysis.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Microwave-induced dynamic switching of magnetic skyrmion cores in nanodots

The nonlinear dynamic behavior of a magnetic skyrmion in circular nanodots was studied numerically by solving the Landau-Lifshitz-Gilbert equation with a classical spin model. We show that a skyrmion core reversal can be achieved within nanoseconds using a perpendicular oscillating magnetic field. Two symmetric switching processes that correspond to excitations of the breathing mode and the mixed mode (combination of the breathing mode and a radial spin-wave mode) are identified. For excitation of the breathing mode, the skyrmion core switches through nucleation of a new core from a transient uniform state. In the mixed mode, the skyrmion core reverses with the help of spins excited both at the edge and core regions. Unlike the magnetic vortex core reversal, the excitation of radial spin waves does not dominate the skyrmion core reversal process.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Helical superconducting undulator for 3rd and 4th generation of synchrotron light source and FELs

A helical superconducting undulator includes a cylindrical magnetic core through which a bore hole allows the passage of charged particles. A single superconducting wire wraps the magnetic core guided by helical flights and cylindrical protrusions, to create interleaved helical windings on the magnetic core. An electrical current may be supplied to the superconducting wire to generate a periodic helical magnetic field in the bore. The helical superconducting undulator also includes a strong-back enclosure that acts as an epoxy mold during epoxy impregnation, a structural support to ensure straightness of the undulator after epoxy impregnation, and assists in cooling and thermal control of the magnetic core and superconducting wire during device operation.

Gluskin, Efim↗

Gyrokinetic and kinetic particle-in-cell simulations of guide-field reconnection. I. Macroscopic effects of the electron flows

In this work, we compare gyrokinetic (GK) with fully kinetic Particle-in-Cell (PIC) simulations of magnetic reconnection in the limit of strong guide field. In particular, we analyze the limits of applicability of the GK plasma model compared to a fully kinetic description of force free current sheets for finite guide fields (b{sub g}). Here, we report the first part of an extended comparison, focusing on the macroscopic effects of the electron flows. For a low beta plasma (β{sub i} = 0.01), it is shown that both plasma models develop magnetic reconnection with similar features in the secondary magnetic islands if a sufficiently high guide field (b{sub g} ≳ 30) is imposed in the kinetic PIC simulations. Outside of these regions, in the separatrices close to the X points, the convergence between both plasma descriptions is less restrictive (b{sub g} ≳ 5). Kinetic PIC simulations using guide fields b{sub g} ≲ 30 reveal secondary magnetic islands with a core magnetic field and less energetic flows inside of them in comparison to the GK or kinetic PIC runs with stronger guide fields. We find that these processes are mostly due to an initial shear flow absent in the GK initialization and negligible in the kinetic PIC high guide field regime, in addition to fast outflows on the order of the ion thermal speed that violate the GK ordering. Since secondary magnetic islands appear after the reconnection peak time, a kinetic PIC/GK comparison is more accurate in the linear phase of magnetic reconnection. For a high beta plasma (β{sub i} = 1.0) where reconnection rates and fluctuations levels are reduced, similar processes happen in the secondary magnetic islands in the fully kinetic description, but requiring much lower guide fields (b{sub g} ≲ 3)

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Modeling of hot plasma in the solar active region core

Magnetically confined plasma with temperatures ⩾5 MK are a feature of hot coronal loops observed in the core of active regions. In this paper, using observations and MHD modeling of coronal loops, we investigate whether wave heating (Alternating Current) models can describe the high temperature loops observed in the active region of 2012 September 7. We construct three-dimensional MHD models for the Alfvén wave turbulence within loops with high temperature. We find that for the Alfvén waves to create enough turbulence to heat the corona, the rms velocity at the footpoints must be 5–6 km s{sup −1}. We conclude that the Alfvén wave turbulence model may be a candidate for explaining how the hot loops are heated, provided the loops have a high velocity at their photospheric footpoints.

79 ASTRONOMY AND ASTROPHYSICS↗

Flexible transformer system

A system includes conductive windings extending around a magnetic core and impedance-varying windings extending around the magnetic core. The impedance-varying windings include positive windings and negative windings. The conductive windings and the impedance-varying windings conduct electric current around the magnetic core. The system includes a first impedance tap changer that is electrically coupled with the positive windings of the impedance-varying windings and a second impedance tap changer electrically coupled with the negative windings of the impedance-varying windings. A controller controls the first impedance tap changer and the second impedance tap changer to change an impedance of the system by changing which portion of the positive windings and which portion of the negative windings are conductively coupled with the conductive windings, and which portion of the positive windings and which portion of the negative windings are disconnected from the conductive windings.

Ndiaye, Ibrahima↗

Extraction of Rare Earth Elements using Magnetite@MOF Composites

Magnetic core-shell microspheres were developed to extract rare earth elements (REEs) from aqueous and brine solutions with up to 99.99% removal efficiency. The shell, composed of a thermally and chemically stable functionalized metal-organic framework (MOF), is grown over a synthesized Fe3O4 magnetic core (magnetite@MOF). The composite particles can be removed from the mixture under an applied magnetic field, offering a practical, and efficient REE-removal process.

Elsaidi, Sameh K.↗

Additive manufacturing of amorphous metal soft magnetic composites

Soft magnet alloys are used as magnetic cores for electric motors, transformers, wind turbines and other power generation systems. Soft magnetic cores are expensive and time consuming to manufacture in the complex shapes required for next-generation devices using conventional press and sinter powder metallurgy. The objective of this effort is to additively manufacture high performance soft magnets, with reduced cost and reduced material waste and 10x lower energy (core) loss at the high operating frequencies of many electric machines. Laser powder bed fusion additive manufacturing is used as the fabrication method. Electrical steel and amorphous alloys atomized powders are used as a feedstock materials. Magnetic cores are printed in topology optimized structures such as the Hilbert curve because this has been shown to reduce energy losses by minimizing the eddy currents that circulate within the magnet at high frequencies. In our project, we succeed in printing FeSi 3.5wt% and FeSi 6.5wt% electrical steels, and iron-based soft magnetic amorphous alloys in the shape of Hilbert and Peano curve topology optimized structures. We found that the Peano curve has a higher cut-off frequency than the Hilbert curve, and that amorphous alloys have high cut-off frequencies and higher mechanical hardness than electrical steels. Processing conditions such as laser power, scan speed, and hatching pattern were optimized to achieve high density prints, and optimize magnetic performance. We find that the printing of amorphous alloy soft magnetic cores may be technoeconomically feasible for large scale applications such as transformers, for which supply chain issues and the labor costs of manual fabrication of magnetic cores is prohibitive in some cases.

36 MATERIALS SCIENCE↗

The Effect of Ligands on FePt–Fe 3 O 4 Core–Shell Magnetic Nanoparticles

FePt–Fe 3 O 4 core–shell nanoparticles functionalized with 3,4-dihydroxyphenylacetic acid (DOPAC) and dimercaptosuccinic acid (DMSA) ligands were synthesized and characterized. We also found that the DOPAC ligand enhances the magnetic properties of the FePt–Fe 3 O 4 particles, in comparison with the DMSA ligand, which induces the oxidation of the shell layer that causes a significant reduction of the saturation magnetization. We evaluated the synthesized magnetic nanoparticles for applications in magnetic hyperthermia and magnetic resonance imaging contrast enhancement.

3,4-dihydroxyphenylacetic acid (DOpAC)↗

Numerical and Analytical Modeling of the Effect of Cracks on the Self-Inductance of a COTS YJ-41003-TC Toroid

COTS inductors and transformers often contain partial cracks whose effect on inductance, a key performance parameter, have not been carefully studied. In this report, the effects of both partial and complete cracks on the self-inductance of a 100 turn square cross section COTS YJ-41003-TC toroid comprised of J Material was comprehensively investigated using both analytically derived closed form expressions and 3D computational techniques employing commercial codes. Both partial (half-penny) and complete (air gap) cracks of 10 and 25 μm were investigated. The crack is defined as the physical distance between two faces of the toroid's magnetic core, such that the surface normal of either face is along the Φ-direction, in alignment with the B-field. For the purposes of validation, two different approaches were incorporated for both the analytical and numerical models. The two analytical methods are comprised of a first principles approach based on the physics of electromagnetics, as well as linear circuit theory. The former directly utilizes the integral form of Maxwell's equations while the latter exploits the interchangeable relationship between electric and magnetic circuits. Validation within the computational scheme is realized through a code-to-code comparison between commercial solvers, COMSOL Multiphysics and CST, with the former employing the Finite Element Method (FEM) and the latter the Finite Difference Time Domain (FDTD) technique. Sound agreement between all four methods (ie., two analytical and two numerical) is observed, with results indicating that only a perturbation in self-inductance occurs for the half-penny cracks, while a substantial reduction takes place for the case of complete cracks. It is important to note that even though a static μ r is applied, representing the linear region of the BH curve (based on manufacturer specifications), the complete crack results still place a lower conservative bound on the inductance. This follows from the fact that even in the case of a half-penny crack, if the magnetic core portion of the crack approaches saturation, the crack begins to behave like an air gap, or complete crack. When an air gap is introduced into a magnetic core, a substantial reduction in inductance can occur due to the significant difference in permeabilities between the two mediums (ie., μ core >> μ air ). The once intact bulk magnetic core of the toroid essentially begins to behave like an air core.

36 MATERIALS SCIENCE↗

Magnetically separable core–shell ZnFe{sub 2}O{sub 4}@ZnO nanoparticles for visible light photodegradation of methyl orange

Highlights: • Phase pure, magnetic ZnFe{sub 2}O{sub 4}@ZnO nanoparticles synthesized with excellent yield. • ZnFe{sub 2}O{sub 4}@ZnO displayed higher UV photocatalytic efficiency than ZnO nanoparticles. • First report on visible light photodegradation of methyl orange by ZnFe{sub 2}O{sub 4}@ZnO. • Excellent reusability of ZnFe{sub 2}O{sub 4}@ZnO nanoparticles observed for azo dye removal. - Abstract: Visible light photodegradation of aqueous methyl orange using magnetically separable core–shell ZnFe{sub 2}O{sub 4}@ZnO nanoparticles is reported. A combination of low temperature (190 °C) microwave synthesis and hydrothermal method were used to prepare phase pure material with excellent yield (95%). The magnetic separability, surface area of 41 m{sup 2}/g and visible light absorption make ZnFe{sub 2}O{sub 4}@ZnO nanoparticles a good solar photocatalyst. ZnFe{sub 2}O{sub 4}@ZnO displayed greater UV photocatalytic efficiency than ZnO owing to the generation of large number of electron-hole pairs. Visible light photodegradation of MO using ZnFe{sub 2}O{sub 4}@ZnO nanoparticles is reported for the first time. Higher first order rate constants under both UV and visible light for core-shell nanoparticles suggested their superiority over its individual oxides. The ZnFe{sub 2}O{sub 4}@ZnO showed excellent reusability with high photocatalytic efficiencies suggesting its suitability for solar photocatalytic applications.

36 MATERIALS SCIENCE↗

Transformer system

A flexible transformer system includes conductive windings extending around a magnetic core of a transformer phase and impedance-varying windings extending around the magnetic core of the transformer phase. The conductive windings and the impedance-varying windings are configured to conduct electric current around the magnetic core of the transformer phase. The system includes an impedance switch coupled with the impedance-varying windings and with the conductive windings. The impedance switch is configured to change an impedance of the system by changing which impedance-varying winding of the impedance-varying windings is conductively coupled with the conductive windings and which impedance-varying winding of the impedance-varying windings is disconnected from the conductive windings.

Premerlani, William James↗

Formation of magnetized prestellar cores with ambipolar diffusion and turbulence

We investigate the roles of magnetic fields and ambipolar diffusion during prestellar core formation in turbulent giant molecular clouds, using three-dimensional numerical simulations. Our simulations focus on the shocked layer produced by a converging large-scale flow and survey varying ionization and the angle between the upstream flow and magnetic field. We also include ideal magnetohydrodynamic (MHD) and hydrodynamic models. From our simulations, we identify hundreds of self-gravitating cores that form within 1 Myr, with masses M ∼ 0.04-2.5 M {sub ☉} and sizes L ∼ 0.015-0.07 pc, consistent with observations of the peak of the core mass function. Median values are M = 0.47 M {sub ☉} and L = 0.03 pc. Core masses and sizes do not depend on either the ionization or upstream magnetic field direction. In contrast, the mass-to-flux ratio does increase with lower ionization, from twice to four times the critical value. The higher mass-to-flux ratio for low ionization is the result of enhanced transient ambipolar diffusion when the shocked layer first forms. However, ambipolar diffusion is not necessary to form low-mass supercritical cores. For ideal MHD, we find similar masses to other cases. These masses are one to two orders of magnitude lower than the value M {sub mag,} {sub sph} = 0.007B {sup 3}/(G {sup 3/2}ρ{sup 2}) that defines a magnetically supercritical sphere under post-shock ambient conditions. This discrepancy is the result of anisotropic contraction along field lines, which is clearly evident in both ideal MHD and diffusive simulations. We interpret our numerical findings using a simple scaling argument that suggests that gravitationally critical core masses will depend on the sound speed and mean turbulent pressure in a cloud, regardless of magnetic effects.

79 ASTRONOMY AND ASTROPHYSICS↗

SXR-XUV Diagnostics for Edge and Core of Magnetically Confined Plasmas

The present report summarizes the results obtained during a one-year extension of DoE grant “SXR-XUV Diagnostics for Edge and Core of Magnetically Confined Plasmas”, at Johns Hopkins University, aimed at completing the development of a new type of magnetic fusion plasma diagnostic, the XUV Transmission Grating Imaging Radiometer (TGIR). The TGIR enables simultaneous spatially and spectrally resolved measurements of the XUV/VUV radiated power from impurities in fusion plasmas, with high speed. The instrument was successfully developed and qualified in the laboratory and in experiments on a tokamak. Its future applications will be diagnostic of the impurity content and transport in the divertor and edge of advanced magnetic fusion experiments, such as NSTX Upgrade.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Faraday-effect polarimeter diagnostic for internal magnetic field fluctuation measurements in DIII-D

Motivated by the need to measure fast equilibrium temporal dynamics, non-axisymmetric structures, and core magnetic fluctuations (coherent and broadband), a three-chord Faraday-effect polarimeter-interferometer system with fast time response and high phase resolution has recently been installed on the DIII-D tokamak. A novel detection scheme utilizing two probe beams and two detectors for each chord results in reduced phase noise and increased time response [δb ∼ 1G with up to 3 MHz bandwidth]. First measurement results were obtained during the recent DIII-D experimental campaign. Simultaneous Faraday and density measurements have been successfully demonstrated and high-frequency, up to 100 kHz, Faraday-effect perturbations have been observed. Preliminary comparisons with EFIT are used to validate diagnostic performance. Principle of the diagnostic and first experimental results is presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗