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At least 55 records · Page 3

Sensitive Procedures for Determining the Permeation Resistance of Chlorinated Polyethylene Against Liquid Propellants

The permeation resistance of chlorinated polyethylene (CPE) used in totally encapsulating chemical protective suits against the aerospace fuels hydrazine, monomethylhydrazine, and uns-dimethylhydrazine was determined by measuring the breakthrough time (BT) and time-averaged vapor transmission rate (VTR) using procedures consistent with ASTM F 739 and ASTM F 1383. Two exposure scenarios were simulated: a 2 hour (h) fuel vapor exposure, and a liquid fuel "splash" followed by a 2 h vapor exposure. To simulate internal suit pressure during operation, a positive differential pressure of 0.3 in. water (75 Pa) on the collection side of the permeation apparatus was used. Using the available data, a model was developed to estimate propellant concentrations inside an air-line fed, totally encapsulating chemical protective suit. Concentrations were calculated under simulated conditions of fixed vapor transmission rate, variable breathing air flow rate, and variable splash exposure area. Calculations showed that the maximum allowable permeation rates of hydrazine fuels through CPE were of the order of 0.05 to 0.08 ng/sq cm min for encapsulating suits with low breathing air flow rates (of the order of 5 scfm or 140 L min-1). Above these permeation rates, the 10 parts-per-billion (ppb) threshold limit value time-weighted average could be exceeded. To evaluate suit performance at 10 ppb threshold-limiting value/time-weighted average level concentrations, use of a sensitive analytical method such as cation exchange high performance liquid chromatography with amperometric detection was found to be essential. The analytical detection limit determines the lowest measurable VTR, which in turn governed the lowest per meant concentration that could be calculated inside the totally encapsulating chemical protective suit.

Waller, Jess M.↗

Aviation turbine fuel properties and their trends

This paper is an examination of published Jet A inspection data covering selected property distributions, averages, and trends for the period from 1969 to 1979. Yearly median values of aromatics, mercaptan sulfur content, 10-percent distillation temperature, smoke point, and freezing point are changing with time, approaching their specification limit values, particularly in the last three years. A near-specification property is defined as one within a stated tolerance band around the specification limit. On this basis, most fuel samples have one to three near-specification properties, the most common being aromatics, smoke point, and freezing point.

Friedman, R.↗

Thermal detectors for X-ray astronomy

The characteristics of an 'ideal' spectrometer for X-ray astronomy are discussed. Special attention is given to the development of new thermal detectors (calorimeters) for the AXAF, which are based on the conversion of the energy of a single X-ray photon entirely into heat. The results obtained so far yielded the FWHM value of 17 eV at 100 mK, but the values for each of the contributing noise components measured separately were less than 10 eV, suggesting that the limiting value for AXAF will be better than 10 eV. A summary of the expected parameters for an AXAF calorimeter is presented.

Holt, Stephen S.↗

Sunlight absorption by aerosols in Jupiter's upper atmosphere

The amount of sunlight deposited in the Jovian upper atmosphere is estimated from reflectivity measurements at 2400 A by the Voyager 2 Photopolarimeter experiment and at visible and near-IR wavelengths observed by Pioneer 10 and ground-based instruments. Zero to about one percent of the incident energy is absorbed at altitudes above the 100 mbar level in models with mean values for haze optical depth and single scattering albedo. Several percent of the incident energy could be absorbed, if limiting values are used, and if an additional absorbing layer is incorporated below the high altitude haze in Pioneer models. Maximum absorption occurs at the edge of the polar regions near + or - 65 deg latitude. Most of the absorbed energy is derived from visible and near-IR radiation rather than UV radiation.

West, R. A.↗

The limits of palaeontological knowledge: finding the gold among the dross

Palaeontological interpretation rests on two interwoven sets of comparisons with the modern world. Palaeobiological interpretation relies on the placement of fossils within a phylogenetic and functional framework based primarily on the comparative biology of living organisms. Analogy to currently observable chemical, physical and taphonomic processes enables palaeoenvironmental inferences to be drawn from geological data. In older rocks, comparisons with the modern Earth can become tenuous, limiting palaeontological interpretation. The problem reaches its apogee in Archaean successions, yet pursuit of multiple lines of evidence establishes that complex microbial communities, fuelled by autotrophy and, likely, photoautotrophy, existed 3500 million years ago. Although Archaean palaeontology has to date focused on silicified coastal sediments, improved understanding of Earth's earliest biosphere may depend on the development of alternative environmental and taphonomic analogies. Spring precipitates and hydrothermal metal deposits are promising candidates. Terrestrial organisms may be of limited value in interpreting such fossils as may be found on Mars, although some points of comparison could prove general. Given limited opportunities for exploration, proper choice of environmental analogy is critical. Spring precipitates constitute excellent deposits for addressing questions of biology on another planet.

NASA Discipline Exobiology↗

Efficiency of tandem solar cell systems as function of temperature and solar energy concentration ratio

The results of a comprehensive theoretical analysis of tandem photovoltaic solar cells as a function of temperature and solar concentration ratio are presented. The overall efficiencies of tandem cell stacks consisting of as many as 24 cells having gaps in the 0.7 to 3.6 eV range were calculated for temperatures of 200, 300, 400, and 500 K and for illumination by an AMO solar spectrum having concentration ratios of 1, 100, 500, and 1000 suns. For ideal diodes (A = B = 1), the calculations show that the optimized overall efficiency has a limiting value eta sub opt of approximately 70 percent for T = 200 K and C = 1000; for T = 300 K and C = 1000, this limiting efficiency approaches 60 percent.

Gokcen, N. A.↗

Conditionally Active Min-Max Limit Regulators

A conditionally active limit regulator may be used to regulate the performance of engines or other limit regulated systems. A computing system may determine whether a variable to be limited is within a predetermined range of a limit value as a first condition. The computing system may also determine whether a current rate of increase or decrease of the variable to be limited is great enough that the variable will reach the limit within a predetermined period of time with no other changes as a second condition. When both conditions are true, the computing system may activate a simulated or physical limit regulator.

Garg, Sanjay↗

Occupational safety considerations with hydrazine fuels

A simple pharmacokinetic model and a specially designed dermal vapor exposure chamber which provides respiratory protection were used to determine the rate of penetration of hydrazine and 1,1-dimethylhydrazine (UDMH) vapor through the skin of rats. Parameters for the pharmacokinetic model were determined from intravenous and inhalation exposure data. The model was then used to estimate the skin permeation coefficient for hydrazine or UDMH vapor from the dermal-vapor exposure data. This analysis indicates that UDMH vapor has a relatively high permeability through skin (0.7 cm/hr), a value somewhat higher than was obtained for hydrazine by the same procedure (0.09 cm/hr). Based on these skin permeability results, a skin-only vapor exposure limit giving protection equivalent to the inhalation Threshold Limit Value (TLV) could be calculated. The current TLV's for UDMH and hydrazine are 0.5 and 0.1 ppm, respectively. The corresponding skin-only TLV equivalents, for personnel wearing respiratory protection, are 32 ppm for UDMH and 48 ppm for hydrazine. Should the proposed lowering to the TLV's for these compounds to 0.01 ppm be adopted, the equivalent skin-only TLV's would become 0.64 ppm for UDMH and 4.8 for hydrazine.

Clewell, H. J.↗

On the limit of field-aligned current intensity in the polar magnetosphere

Field-aligned current (FAC) is here defined by 4 pi j = alpha B, where alpha is constant along a magnetic field line. The upper limit value of alpha in the polar magnetosphere, possible source regions of the strongest FAC and the relationship of them to some auroral and ionospheric irregularity cross-field scale sizes are discussed. Cross-field dimensions of the strongest FAC are related to the gyroradii of source particles (O(+), He(2+), He(+), H(+), e) in the current-generating region. It is suggested that experimental determination, and mapping of the values of alpha, may assist with the search for the generators of such currents in near-earth space including in the nearby solar wind. The upper limit of alpha is associated with the breakup of FAC systems.

Cole, Keith D.↗

A study of the usefulness of Skylab EREP data for earth resources studies in Australia

The author has identified the following significant results. In subhumid, vegetated areas, S190B photography: (1) has a potentially operational role in detecting lineaments in 1:100,000 scale geological mapping and in major civil engineering surveys; (2) is of limited value for regional lithological mapping at 1:500,000 scale; and (3) provided much useful synoptic information and some detailed information of direct value to the mapping of nonmineral natural resources such as vegetation, land soil, and water. In arid, well exposed areas, S190B photography could be used: (1) with a limited amount of field traverses, to produce reliable 1:500,000 scale geological maps of sedimentary sequences; (2) to update superficial geology on 1:250,000 scale maps; and (3) together with the necessary field studies, to prepare landform, soil, and vegetation maps at 1:1,000,000 scale. Skylab photography was found to be more useful than LANDSAT images for small scale mapping of geology and land types, and for the revision of topographic maps at 1:100,000 scale, because of superior spatial resolution and stereoscopic coverage.

Lambert, B. P.↗

Dual-polarization airborne lidar observations of polar stratospheric cloud evolution

Dual-polarization 0.532 micron lidar data show systematic polar stratospheric cloud (PSC) evolution along a portion of the Airborne Arctic Stratospheric Expedition DC-8 flight of January 31, 1989. This flight leg was roughly aligned with air parcel motion on isentropic surfaces from 400-500 K, where the local adiabatic cooling rate was about 20 K/day. Type 1 PSCs show low depolarization ratios and scattering ratios which approach intermediate limiting values as ambient temperature decreases. These data suggest that Type 1 particles formed by rapid cooling may be nearly spherical and are restricted in size by partitioning of a limited HNO3 vapor supply among many competing growth sites. Type 2 PSCs appear at temperatures below estimated local frost points with increases in depolarization and scattering typical of larger ice crystals.

Poole, L. R.↗

Recent progress in the application of satellite altimetry to observing the mesoscale variability and general circulation of the oceans

The application of GEOS-3 and Seasat altimeter data to the study of mesoscale variability and general circulation in the oceans is discussed in a survey of recent investigations. Seasat provided much more accurate measurements, but lasted only 3.5 months (compared to 3.5 years for GEOS-3). General-circulation studies are shown to be strongly dependent on an accurate geoid, which has not yet been developed; hence even large-wave-length (7000-km) mapping is of limited value. Geoid-independent methods allow the global mapping of mesoscale sea-surface height and geostrophic current and the analysis of their distribution in wavenumber space, at least to the limits allowed by the accuracy of the instruments. These studies demonstrate the feasibility of future satellite-altimeter measurements of variability over a wide range of periods and wavelengths, which if combined with improved mapping of the earth's gravity field) would permit the determination of the general circulation on scales as small as 200 km.

Fu, L.-L.↗

Step Bunch Evolution on Vicinal Faces of KDP

For in-situ studies of the formation and evolution of step patterns in solution growth, we have assembled an experimental setup based on Michelson interferometry with the growing crystal surface as one of the reflective surfaces. The device allows data collection over a relatively large area (approximately 4 sq. mm) in situ and in real time during growth. The depth resolution is improved over traditional interferometry using phase-shifted images combining by a suitable algorithm. We achieve a depth resolution of approximately 50 Angstroms. Lateral resolution, dependent on the degree of magnification, is around 0.3 to 5 microns. The crystal chosen as a model in this work is potassium dihydrogen phosphate (KDP), the optically non-linear material widely used in frequency doubling applications. Kinetics of KDP crystallization is well studied so that KDP can serve as a benchmark for our investigations. We present quantitative results on the onset, initial stages and development of instabilities in moving step trains on vicinal crystal surfaces at varying supersaturation, flow rate, and flow direction. The kinetics data suggest that at low supersaturations, step bunching is caused by impurity retardation of the steps, while at higher supersaturations, we link the non-linearity during growth to interdependence of the velocity and density of the steps evidenced in independent experiments. The behavior on the surface is very dynamic, small bunches both merge and split from larger bunches as they travel across the facet. We present evidence that despite these dynamics, under steady conditions there exists a limiting value to step bunch height. This height is reached at distances between 600 and 1000 microns from the step source. In our experiments, we observed the retention of this step bunch height limit up to the path of 1500 microns.

Booth, N. A.↗

Elastic moduli of precompressed pyrophyllite used in ultrahigh pressure research

The propagation of ultrasonic pulses in pyrophyllite specimens was studied to determine the effect of specimen precompression on the measured elastic moduli. Measurements were made at room pressure and, for the precompressed specimens, to pressures of 3 kbar. Pyrophyllite was found to be elastically anisotropic, apparently the result of the fabric present in our material. The room pressure adiabatic bulk modulus as measured on specimens made of isostatically compacted powered pyrophyllite was determined to be 96.1 kbar. The wave speeds of ultrasonic pulses in pyrophyllite were found to decrease with increasing specimen precompression. A limiting value of precompression was found, above which no further decrease in wave speed was observed. For the shear wave speeds this occurs at 10 kbar while for the longitudinal wave at 25 kbar. In the limit, the shear waves propagate 20% slower than in the unprecompressed samples; for the longitudinal wave the difference is 30%.

Sachse, W.↗

Universal characteristics of transverse momentum transfer in intermediate energy heavy ion collisions

A microscopic optical model formalism for estimating momentum transfer in intermediate energy heavy ion collisions predicts universal behavior of the transverse component. In particular, for symmetric systems heavier than niobium, it appears that values of P(perpendicular)/A are independent of the mass and charge of the colliding nuclei and vary only with impact parameter and incident beam energy. This suggests that momentum transfer per nucleon saturates to some limiting value with increasing mass.

Khan, F.↗

Flow field characteristics and performance limitations of quasi-steady magnetoplasmadynamic accelerators

Measurements of terminal voltage, exhaust velocity, current and potential distributions in a quasi-steady MPD arc operating over a range of currents from 3 to 25 kA countervene previous indications of basic limitations on MPD performance. Terminal voltage fluctuations, previously used as an indicator of a unique limiting value of the parameter current squared over mass flow, are shown to be related to cathode surface area rather than to interelectrode plasma phenomena. With improved electrodes and insulators, satisfactory arc operation at specific impulses somewhat beyond previously proposed limits has been demonstrated, and the significant thrust producing mechanisms in such arcs have been identified.

Boyle, M. J.↗

On the correlation between objective measurements and subjectively felt disturbance from traffic

Measurements of traffic noise during the day were taken at 90 measurement points over the urban area of Vienna; in addition, the vehicle frequency ascertained at the individual measurement points was also noted. Results of these objective measurements or various characteristic single values derived from them are compared with the results of the environmental survey of 1973 on the subjective noise stress experienced within buildings but caused by outside factors. Suggestions for suitable measures to describe the traffic noise and to derive limit values are given considering the relationship between number of vehicles and noise and annoyance.

Lans, J.↗