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New format presentation for infrared spectral emittance data. Infrared spectrometry studies, phase 5

Methods for infrared radiance measurements from geological materials were studied for airborne use over terrains with minimal vegetation. The tasks of the investigation were: (1) calculation of emittance ratios, (2) comparison of IR spectral emittance data with K-band scatterometer data over Pisgah Crater, and (3) standard infrared spectral file. Published papers reporting the research are included.

Lyon, R. J. P.

Low-background air-infrared telescope for balloon-borne infrared astronomy

The design and performance of a far-infrared telescope are discussed. The instrument is twenty centimeters in diameter and has excellent operating characteristics at 100 microns. The principal features of the telescope are summarized. A diagram of the system is provided. The telescope completed two sucessful balloon flights in which the planets Mars and Saturn were used as calibration sources. Observations were made of the H2 regions W 3, Orion A, NGC 2024, and the bright infrared galaxy M 82.

Low, F. J.

Infrared detector performance in the Shuttle Infrared Telescope Facility /SIRTF/

The limitations imposed on infrared detectors for SIRTF are quite different from those imposed on ground-based, balloon-borne, or aircraft-borne systems. The paper examines the limitations and provides performance predictions corresponding to SIRTF conditions. Detector parameters typical of an infrared camera are used. The detector size is taken to be of the order of the diffraction-limited spot, frequency response is taken to correspond to a fraction of a second or less time constant, and spectral definition is provided by multilayer dielectric filters, inductive or capacitive grids, intrinsic absorption, or a combination of these. A nominal 10-micron bandwidth is assumed. The discussion covers atmospheric absorption and emission, zodiacal dust radiance, Shuttle contaminants, telescope self-emission, charged particle radiation, clear environment detector performance, and trapped radiation effects. It is concluded that the SIRTF design and operating conditions will allow current and near-term state-of-the-art detectors to reach their performance limits with SIRTF at a temperature of 10-12 K.

Mccarthy, S. G.

Infrared photometry of the X-ray binary 2A 1822-371 - A model for the ultraviolet, optical, and infrared light curve

The X-ray source 2A 1822-371 may be prototypical of a class of accreting close binary systems in which the X-ray emission is diffused by a cloud of ionized material which is associated with the accretion disk. The present investigation provides a report on infrared photometry of 2A 1822-371 in the J (1.25 micrometer), H (1.65 micrometer), and K (2.2 micrometer) bands. A complete 5.57 hr light curve has been obtained at J which makes it possible to extend the investigations of the energy dependence of the ultraviolet and optical curve begun by Mason and Cordova (1982). The work conducted by White and Holt (1982) is extended to the long wavelength light curve by incorporating the influence of emission from the inner and outer rim of the disk and from the companion star. Including such effects, and assuming that reprocessed X rays are the major source of light at wavelengths greater than 1100 A, it is found possible to reproduce the morphology and energy dependence which is observed in the light curve of 2A 1822-371 from the far-ultraviolet to the near-infrared.

Mason, K. O.

Infrared and far-infrared laser magnetic resonance spectroscopy of the GeH radical - Determination of ground state parameters

The GeH radical has been detected in its ground 2 Pi state in the gas phase reaction of fluorine atoms with GeH4 by laser magnetic resonance techniques. Rotational transitions within both 2 Pi 1/2 and 2 Pi 3/2 manifolds have been observed at far-infrared wavelengths and rotational transitions between the two fine structure components have been detected at infrared wavelengths (10 microns). Signals have been observed for all five naturally occurring isotopes of germanium. Nuclear hyperfine structure for H-1 and Ge-73 has also been observed. The data for the dominant isotope (/Ge-74/H) have been fitted to within experimental error by an effective Hamiltonian to give a set of molecular parameters for the X 2 Pi state which is very nearly complete. In addition, the dipole moment of GeH in its ground state has been estimated from the relative intensities of electric and magnetic dipole transitions in the 10 micron spectrum to be 1.24(+ or - 0.10) D.

Brown, J. M.

Combined use of visible, reflected infrared, and thermal infrared images for mapping Hawaiian lava flows

The weathering of Hawaiian basalts is accompanied by chemical and physical changes of the surfaces. These changes have been mapped using remote sensing data from the visible and reflected infrared and thermal infrared wavelength regions. They are related to the physical breakdown of surface chill coats, the development and erosion of silica coatings, the oxidation of mafic minerals, and the development of vegetation cover. These effects show systematic behavior with age and can be mapped using the image data and related to relative ages of pahoehoe and aa flows. The thermal data are sensitive to silica rind development and fine structure of the scene; the reflectance data show the degree of oxidation and differentiate vegetation from aa and cinders. Together, data from the two wavelength regions show more than either separately. The combined data potentially provide a powerful tool for mapping basalt flows in arid to semiarid volcanic environments.

Abrams, Michael

Comparison of column water vapor measurements using downward-looking near-infrared and infrared imaging systems and upward-looking microwave radiometers

Remote soundings of precipitable water vapor from three systems are compared with each other and with ground truth from radiosondes. Ancillary data from a mesoscale network of surface observing stations and from wind-profiling radars are also used in the analysis. The three remote-sounding techniques are: (a) a reflectance technique using spectral data collected by the Airborne Visible-Infrared Imaging Spectrometer; (b) an emission technique using Visible-Infrared Spin Scan Radiometer Atmospheric Sounder (VAS) data acquired from the NOAA's GOES; and (c) a microwave technique using data from a limited network of three ground-based dual-channel microwave radiometers. The data were taken over the Front Range of eastern Colorado on 22-23 March 1990. The generally small differences between the three types of remote-sounding measurements are consistent with the horizontal and temporal resolutions of the instruments. The microwave and optical reflectance measurements agreed to within 0.1 cm; comparisons of the microwave data with radiosondes were also either as good or explainable. The largest differences between the VAS and the microwave radiometer at Elbert were between 0.4 and 0.5 cm and appear to be due to variable terrain within the satellite footprint.

Gao, Bo-Cai

Near- and far-infrared observations of interplanetary dust bands from the COBE diffuse infrared background experiment

Data from the Diffuse Infrared Background Experiment (DIRBE) instrument aboard the Cosmic Background Explorer Satellite (COBE) spacecraft have been used to examine the near and far infrared signatures of the interplanetary dust (IPD) bands. Images of the dust band pairs at ecliptic latitudes of +/- 1.4 deg and +/- 10 deg have been produced at DIRBE wavelengths from 1.25 to 100 micrometers. The observations at the shorter wavelengths provide the first evidence of scattered sunlight from particles responsible for the dust bands. It is found that the grains in the bands and those in the smooth IPD cloud have similar spectral energy distributions, suggesting similar compositions and possibly a common origin. The scattering albedos from 1.25 to 3.5 micrometers for the grains in the dust bands and those in the IPD cloud are 0.22 and 0.29, respectively. The 10 deg band pair is cooler (185 +/- 10 K) than the smooth interplanetary dust cloud (259 +/- 10 K). From both parallactic and thermal analyses, the implied location of the grains responsible for the peak brightness of the 10 deg band pair is 2.1 +/- 0.1 AU the Sun A parallactic distance of 1.4 +/- 0.2 AU is found for the peak of the 1.4 deg band pair.

Spiesman, William J.

The Mid-Infrared Spectrometer on the Infrared Telescope in Space (IRTS) mission

The Mid-Infrared Spectrometer (MIRS) is one of the four focal plane instruments on the Infrared Telescope in Space (IRTS) mission. The instrument has been constructed, tested, and calibrated in the laboratory and is presently scheduled to be launched by a Japanese expendable launch vehicle as part of the Space Flyer Unit-1 mission in early 1995. The wavelength coverage of the MIRS ranges from 4.5 to 11.7 microns, with a spectral resolution of 0.23 to 0.36 microns. With the cryogenically cooled optics of the IRTS telescope assembly, the MIRS will be able to make an extremely sensitive survey of both point-source and extended objects over an estimated 10% of the sky.

Roellig, Thomas L.

The Far-Infrared Photometer on the Infrared Telescope in Space

We describe the design and calibration of the Far-Infrared Photometer (FIRP), one of four focal plane instruments on the Infrared Telescope in Space (IRTS). The FIRP will provide absolute photometry in four bands centered at 150, 250, 400, and 700 microns with spectral resolution wavelength/wavelength spread is approximately 3 and spatial resolution delta theta = 0.5 degrees. High sensitivity is achieved by using bolometric detectors operated at 300 mK in an AC bridge circuit. The closed-cycle He-3 refrigerator can be recycled in orbit. A 2 K shutter provides a zero reference for each field of view. More than 10% of the sky will be surveyed during the 3 week mission lifetime with a sensitivity of less than 10(exp -13) W per sq cm per sr per 0.5 degree pixel.

Lange, A. E.

A Far Infrared Photometer (FIRP) for the infrared telescope in space (IRTS)

We describe the design and calibration of the Far-Infrared Photometer (FIRP), one of four focal plane instruments on the Infrared Telescope in Space (IRTS). The FIRP will provide absolute photometry in four bands centered at 150, 250, 400, and 700 micrometers with spectral resolution lambda/(Delta lambda) approx. = 3 and spatial resolution Delta theta = 0.5 degrees. High sensitivity is achieved by using bolometric detectors operated at 300 mK in an AC bridge circuit. The closed-cycle He-3 refrigerator can be recycled in orbit. A 2 K shutter provides a zero reference for each field of view. More than 10% of the sky will be surveyed during the approximately 3 week mission lifetime with a sensitivity of less than 10(exp -13) W/((sq cm)(sr)) per 0.5 degree pixel.

Freund, M. M.

Infrared Space Observatory Observations of Far-Infrared Rotational Emission Lines of Water Vapor Toward the Supergiant Star VY Canis Majoris

We report the detection of numerous far-infrared emission lines of water vapor toward the supergiant star VY Canis Majoris. A 29.5-45 micron grating scan of VY CMa, obtained using the Short-Wavelength Spectrometer (SWS) of the Infrared Space Observatory at a spectral resolving power lambda/delat.lambda of approximately 2000, reveals at least 41 spectral features due to water vapor that together radiate a total luminosity of approximately 25 solar luminosity . In addition to pure rotational transitions within the ground vibrational state, these features include rotational transitions within the (010) excited vibrational state. The spectrum also shows the (sup 2)product(sub 1/2) (J = 5/2) left arrow (sup 2)product(sub 3/2) (J = 3/2) OH feature near 34.6 micron in absorption. Additional SWS observations of VY CMa were carried out in the instrument's Fabry-Perot mode for three water transitions: the 7(sub 25)-6(sub 16) line at 29.8367 micron, the 4(sub 41)-3(sub 12) line at 31.7721 micron, and the 4(sub 32)-3(sub 03) line at 40.6909 micron. The higher spectral resolving power lambda/delta.lambda of approximately 30,000 thereby obtained permits the line profiles to be resolved spectrally for the first time and reveals the "P Cygni" profiles that are characteristic of emission from an outflowing envelope.

Neufeld, David A.

Exploring the Saturn System in the Thermal Infrared: The Composite Infrared Spectrometer

The Composite Inbred Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer on the Cassini orbiter that measures thermal radiation over two decades in wave number, from 10 to 1400 cm (1 mm to 7pm), with a spectral resolution that can be set from 0.5 to 20 cm. The far in portion of the spectrum (10 - 600 cm) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view. The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600 - 1100cm, 1100-1400 cm). Each focal plane is composed of a 1x10 array of HgCdTe detectors, each detector having a 0.3-mrad field of view. CIRS observations will provide three-dimensional maps of temperature, gas composition, and aerosols/condensates of the atmospheres of Titan and Saturn with good vertical and horizontal resolution, from deep in their tropospheres to high in their mesospheres. CIRS ability to observe atmospheres in the limb viewing mode (in addition to nadir) offers the opportunity to provide accurate and highly resolved vertical profiles of these atmospheric variables. The ability to observe with high-spectral resolution should facilitate the identification of new constituents. CIRS will also map the thermal and compositional properties of the surfaces of Saturn's icy satellites. It will similarly map Saturn's rings, characterizing their formation and evolution. The combination of broad spectral range, programmable spectral resolution, the small detector fields of view, and an orbiting spacecraft platform will allow CIRS to observe the Saturnian system in the thermal infrared at a level of detail not previously achieved.

Flasar, F. M.

Peripherally hydrogenated neutral polycyclic aromatic hydrocarbons as carriers of the 3 micron interstellar infrared emission complex: results from single-photon infrared emission spectroscopy

Infrared emission spectra of five gas-phase UV laser-excited polycyclic aromatic hydrocarbons (PAHs) containing aliphatic hydrogens are compared with the main 3.3 microns and associated interstellar unidentified infrared emission bands (UIRs). We show that neutral PAHs can account for the majority of the 3 microns emission complex while making little contribution to the other UIR bands; peripherally hydrogenated PAHs produce a better match to astrophysical data than do those containing methyl side groups; 3.4 microns plateau emission is shown to be a general spectral feature of vibrationally excited PAHs containing aliphatic hydrogens, especially those containing methyl groups; and finally, hot-band and overtone emissions arising from aromatic C-H vibrations are not observed in laboratory emission spectra, and therefore, in contrast to current assignments, are not expected to be observed in the UIRs.

NASA Discipline Exobiology

Infrared Spectroscopic Analyses of Sulfate, Nitrate, and Carbonate-bearing Atacama Desert Soils: Analogs for the Interpretation of Infrared Spectra from the Martian Surface

The Atacama Desert of northern Chile is the driest desert on Earth, receiving only a few mm of rain per decade. The Mars climate may, in the past, have been punctuated by short-lived episodes of aqueous activity. The paleo-Martian environment may have had aqueous conditions similar to the current conditions that exist in the Atacama, and Mars soils may have formed with soil chemistry and mineralogy similar to those found in the Atacama. Remote and in-situ analysis of the Martian surface using infrared technology has a long heritage. Future investigations of the subsurface mineralogy are likely to build upon this heritage, and will benefit from real life lessons to be learned from terrestrial analog studies. To that end, preliminary results from a near- and mid-infrared spectroscopic study of Atacama soil profiled at a range of depths are presented.

Dalton, J. B.