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Results for “IONIZATION CROSS SECTION”

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At least 55 records · Page 3

Influence of Triply-Charged Ions and Ionization Cross-Sections in a Hybrid-PIC Model of a Hall Thruster Discharge

The sensitivity of xenon ionization rates to collision cross-sections is studied within the framework of a hybrid-PIC model of a Hall thruster discharge. A revised curve fit based on the Drawin form is proposed and is shown to better reproduce the measured crosssections at high electron energies, with differences in the integrated rate coefficients being on the order of 10% for electron temperatures between 20 eV and 30 eV. The revised fit is implemented into HPHall and the updated model is used to simulate NASA's HiVHAc EDU2 Hall thruster at discharge voltages of 300, 400, and 500 V. For all three operating points, the revised cross-sections result in an increase in the predicted thrust and anode efficiency, reducing the error relative to experimental performance measurements. Electron temperature and ionization reaction rates are shown to follow the trends expected based on the integrated rate coefficients. The effects of triply-charged xenon are also assessed. The predicted thruster performance is found to have little or no dependence on the presence of triply-charged ions. The fraction of ion current carried by triply-charged ions is found to be on the order of 1% and increases slightly with increasing discharge voltage. The reaction rates for the 0→III, I→III, and II→III ionization reactions are found to be of similar order of magnitude and are about one order of magnitude smaller than the rate of 0→II ionization in the discharge channel.

Hall Thrusters

Photoionization research on atomic beams. 2: The photoionization cross section of atomic oxygen

An experiment to determine the absolute value of the photo-ionization cross section of atomic oxygen is described. The atoms are produced in an electrical discharge in oxygen gas with 1% hydrogen added. In order to prevent recombination a crossed beam technique is employed. The ions formed are detected by a time-of-flight mass spectrometer. The concentration of oxygen atoms in the beam is 57%. The measured photoionization cross section of atomic oxygen is compared with theoretical data. The results show the participation of autoionization processes in ionization. The cross section at the autoionizing levels detected is considerably higher than the absorption due to the unperturbed continuum. Except for wavelengths where autoionization occurs, the measured ionization cross section is in fair agreement with theory. This holds up to 550 A whereas for shorter wavelengths the theoretical values are much higher.

Comes, F. J.

Calculation of photoionization cross section near auto-ionizing lines and magnesium photoionization cross section near threshold

The research performed is briefly reviewed. A simple method was developed for the calculation of continuum states of atoms when autoionization is present. The method was employed to give the first theoretical cross section for beryllium and magnesium; the results indicate that the values used previously at threshold were sometimes seriously in error. These threshold values have potential applications in astrophysical abundance estimates.

Moore, E. N.

Ionization cross-sections for the production of positive ions from H2O by electron impact

Water is present in the atmospheres of 6 of the 9 planets. Cross section values for the direct and partial ionization of H2O by electron impact have been measured and compared with previously published data. The present measurements have been carried out from thresholds to 1 KeV by utilizing a crossed electron beam and molecular beam collision geometry and an improved ion extraction technique.

planetary atmospheres

X-ray and gamma-ray line production by nonthermal ions

X-ray production was calculated at approximately 6.8 keV by the 2p to 1s transition in fast hydrogen- and helium-like iron ions, following both electron capture to excited levels and collisional excitation. A refinement of the OBK approximation was used to obtain an improved charge exchange cross section. This, and the corresponding ionization cross section were used to determine equilibrium charge fractions for iron ions as functions of their energy. The effective X-ray line production cross section was found to be sharply peaked in energy at about 8 to 12 MeV/amu. Because fast ions of similar energies can also excite nuclear levels, the ratio of selected strong gamma ray line emissivities to the X-ray line emissivity was also calculated. Limits set by this method on the intensity of gamma ray line emission from the galactic center and the radio galaxy Centaurus A are generally lower than those reported in the literature.

Bussard, R. W.

X-ray and gamma-ray line production by nonthermal ions

X-ray production at about 6.8 keV by the 2p to 1s transition in fast hydrogen- and helium-like iron ions is calculated, following both electron capture to excited levels and collisional excitation. A refinement of the Oppenheimer-Brinkman-Kramers (1930) approximation is used to obtain an improved charge-exchange cross-section. This, and the corresponding ionization cross section, were used to determine equilibrium charge fractions for iron ions as functions of their energy. The effective X-ray line production cross section was found to be sharply peaked in energy at about 8 to 12 MeV per amu. Since fast ions of similar energies can also excite nuclear levels, the ratio of selected strong gamma-rays line emissivities to the X-ray line emissivity is calculated. These calculations are employed to set limits on the intensity of gamma-rays line emission from the galactic center and the radio galaxy Cen A, and it is found that these limits are generally lower than those reported in the literature.

Bussard, R. W.

Investigation of the sensitivity of ionization-type vacuum gauges

A quantitative analysis of a large and representative sample of available data has been made to determine the best criteria for predicting the relative sensitivities of ionization-type vacuum gauges to different gases. The molecular property of the gas that correlates best with relative sensitivity is the ionization cross section (eV). For high-pressure ionization gauges, a cross section evaluated at 2/3 of the accelerating potential of the gauge is the best choice. For Bayard-Alpert and triode gauges, any of three choices are of approximately equal value. These are 100 eV cross section values, maximum cross section value for each gas, and a cross section evaluated at 2/3 of the accelerating potential for each gauge. For the Alphatron gauge, cross section values in the range 5000-10,000 eV provide the best correlation.

Holanda, R.

Double photoionization and doubly charged ions in the thermosphere

It is shown that a plausible cross section for the double photoionization of oxygen at wavelengths less than 254 A accounts for the observed concentration of O(2+) ions in the thermosphere. Due to the lack of laboratory measurements, double ionization cross sections for atomic oxygen were estimated from laboratory measurements of the ionization cross sections of other species. For altitudes between 150 and 400 km, where O(2+) is assumed to be in photochemical equilibrium, calculations reveal a significantly greater contribution to O(2+) production by double ionization of O atoms than by single ionization of O(+) ions. The concentration of O(2+) ions, assuming a double photoionization creation mechanism and a large sink by charge exchange with molecular nitrogen, is calculated to agree with that measured by AE-C down to altitudes of 250 km.

Victor, G. A.

Sensitivity of hot-cathode ionization vacuum gages in several gases

Four hot-cathode ionization vacuum gages were calibrated in 12 gases. The relative sensitivities of these gages were compared to several gas properties. Ionization cross section was the physical property which correlated best with gage sensitivity. The effects of gage accelerating voltage and ionization-cross-section energy level were analyzed. Recommendations for predicting gage sensitivity according to gage type were made.

Holanda, R.

Electrical structure and ionizable constituent measurements

In-situ stratospheric ions showed typical characteristics. A Krypton lamp created large numbers of additional ions of remarkably high mobility with a product of number density and ionization cross section of the ionizable constituent(s) greater than 10 cm to the 9th power per cm.

Hale, L. C.

Data analysis and theoretical studies for atmospheric Explorer C, D and E

The research concentrated on construction of a comprehensive model of the chemistry of the ionosphere. It proceeded by comparing detailed predictions of the atmospheric parameters observed by the instrumentation on board the Atmospheric Explorer Satellites with the measured values and modifying the chemistry to bring about consistency. Full account was taken of laboratory measurements of the processes identified as important. The research programs were made available to the AE team members. Regularly updated tables of recommended values of photoionization cross sections and electron impact excitation and ionization cross sections were provided. The research did indeed lead to a chemistry model in which the main pathways are quantitatively secure. The accuracy was sufficient that remaining differences are small.

Dalgarno, A.

Electron impact ionization and attachment cross sections for H2S

Experiments were performed to measure, by electron impact, appearance potentials and the cross sections for ionization, dissociative ionization, and electron attachment for H2S. Results are presented, and discussed individually, for both positive and negative ions. A schematic diagram of the experimental setup is included.

Rao, M. V. V. S.

Electron-impact ionization of laser-excited Ba-138 (... 5p6 6s 6p) and Ba-138 (... 5p6 6s 5d) atoms

Electron-impact ionization cross sections for laser-excited Ba-138 (... 5p6 6s 6p; 1P1, M = - 1) and cascade-populated Ba-138 (... 5p6 6s 5d; 1D + 3D) atoms were measured in the threshold to 10 eV energy range. The peak cross sections for the excited species are about a factor of 2 larger than that for ground-state Ba. In addition, it was demonstrated that ionization from individual magnetic substates of various hyperfine levels can be studied. The ionization cross sections in the case of Ba-138 (1P1) were found to be equal for the M = 0 and for the M = + or - 1 sublevels within the experimental error limit.

Trajmar, S.

Dissociative Recombination (DR) and Associative Ionization (AI) Cross Section Calculations for the NO+ + e yields N + O (2D+3P, 2P+3P, and 2D+1D) Reaction for Atmospheric Entry Modeling

During entry of a space craft into Earth atmosphere, the flow surrounding the vehicle becomes partially ionized leading to significant cation and free-electron production. Subsequently, electron impact excitation and dissociation form radiating excited state species that contribute to the heat load on the vehicle. While experimental data on selected total cross sections are available, few experiments address the need for accurate AI cross sections for metastable atomic states at the high temperatures realized in atmospheric re-entry. In order to maintain desired safety margins during atmospheric entry of a space vehicle, chemical reaction models need to accurately account for this process. For the present study, we have computed vibrationally resolved cross sections for the DR of NO+ for electron energies between 0.01 to 10 eV and apply microscopic reversibility to obtain the AI cross sections and rate coefficients. For the DR cross section calculations, we use state-of-the-art MRCI potential energy curves. The resulting adiabatic potential curves are transformed to a diabatic representation, which is used in time-dependent wave packet calculations to describe the nuclear motion of the dissociating cation upon collision with an electron. Based on the wave function evolution in time, these calculations provide T-matrix and cross sections for the DR including recombination into the low energy metastable atomic states. The DR and AI rate coefficients are compared with the available experimental data.

Ewa Papajak