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At least 55 records · Page 3

High efficiency ion beam accelerator system

An ion accelerator system that successfully combines geometrical and electrostatic focusing principles is presented. This accelerator system uses thin, concave, multiple-hole, closely spaced graphite screen and focusing grids which are coupled to single slot accelerator and decelerator grids to provide high ion extraction efficiency and good focusing. Tests with the system showed a substantial improvement in ion beam current density and collimation as compared with a Pierce electrode configuration. Durability of the thin graphite screen and focusing grids has been proven, and tests are being performed to determine the minimum screen and focusing grid spacing and thickness required to extract the maximum reliable beam current density. Compared with present neutral beam injector accelerator systems, this one has more efficient ion extraction, easier grid alignment, easier fabrication, a less cumbersome design, and the capacity to be constructed in a modular fashion. Conceptual neutral beam injector designs using this modular approach have electrostatic beam deflection plates downstream of each module.

Aston, G.

A new approach to mass spectrometer measurements of thermospheric density

The gas sampling problem in satellite and high velocity probes was investigated by applying the theory of a drifting Maxwellian gas. A lens system using a free stream ion source was developed and experimentally evaluated over the pressure range of 0.00001 to 0.01 N/m sq (approx. 10 to the minus 7th power to 0.0001 torr). The source has high beam transparency, which minimizes gas-surface collisions within, or near, the ionization volume. It is shown that for high ion energy (60 eV), the extracted ion beam has an on-axis energy spread of less than 4 eV, and that 90 percent of the ions are within 2.5 deg of the beam axis. It is concluded that the molecular beam mass spectrometer concept, developed for gas density measurements in the upper atmosphere, substantially reduces gas-surface scattering and gas-surface reactions in the sample, and preserves the integrity of the gas sample during the analysis process. Studies show that both the Scout and Delta launch vehicles have adequate volume, control, velocity, and data acquisition capability necessary to obtain thermospheric number density in real time.

Melfi, L. T., Jr.

Fast extraction of nickel from aqueous media by using ionic metal-organic frameworks

As global demand for stainless steel rapidly increases, supply for minerals such as nickel, manganese, and chromium become more critical. To shift mineral peak production and delay scarcity of alloying minerals, recycling rate of the mineral needs to increase. Development of simple and cost-effective techniques for critical mineral production and recovery from industrial wastewater will lead to enhance the current recycling rate of the mineral and reduce potential hazards of industrial wastewater bearing high concentrations of minerals. Here, in this study, ionic metal-organic framework (iMOF)-based sorbents are successfully designed for critical metal ion extraction from aqueous solution. The iMOFs are highly stable in aqueous solution over wide pH ranges, indicating that they are suitable for use in industrial wastewater with harsh chemical environments. The sorption capacity of iMOFs towards Ni reaches 34.1 mg/g with a removal efficiency of >99.9%. Notably, complete extraction of Ni takes place within 5 min, which is much faster compared to other sorbents. Moreover, the iMOFs can simultaneously coextract multiple minerals, proving their effectiveness as general sorbents for critical mineral recovery.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Carbon/Carbon Grids For Ion Sources

Ion-extraction grids made of carbon/carbon composites used in spacecraft ion engines and industrial ion sources in place of molybdenum grids. In principle, carbon/carbon grids offer greater extraction efficiency and longer life. Grid fabricated by mechanical drilling, laser drilling, or electrical-discharge machining of array of holes in sheet of carbon/carbon. Advantages; better alignment and slower erosion.

Garner, Charles E.

Ion optics for high power 50-cm-diam ion thrusters

The process used at the NASA-Lewis to fabricate 30 and 50-cm-diameter ion optics is described. The ion extraction capabilities of the 30 and 50-cm diameter ion optics were evaluated on divergent field and ring-cusp discharge chambers and compared. Perveance was found to be sensitive to the effects of the type and power of the discharge chamber and to the accelerator electrode hole diameter. Levels of up to 0.64 N and 20 kW for thrust and input power, respectively, were demonstrated with the divergent-field discharge chamber. Thruster efficiencies and specific impulse values up to 79 percent and 5000 sec., respectively, were achieved with the ring-cusp discharge chamber.

Rawlin, Vincent K.

Ion optics for high power 50-cm-dia ion thrusters

The process used at the NASA Lewis Research Center to fabricate 30 and 50-cm-diameter ion optics is described. The ion extraction capabilities of the 30 and 50-cm diameter ion optics were evaluated on divergent field and ring-cusp discharge chambers and compared. Perveance was found to be sensitive to the effects of the type and power of the discharge chamber and to the accelerator electrode hole diameter. Levels of up to 0.64 N and 20 kW for thrust and input power, respectively, were demonstrated with the divergent-field discharge chamber. Thruster efficiencies and specific-impulse values up to 79 percent and 5000 seconds, respectively, were achieved with the ring-cusp discharge chamber.

Rawlin, Vincent K.

Advanced-technology 30-cm-diameter mercury ion thruster

An advanced-technology mercury ion thruster designed for operation at high thrust and high thrust-to-power ratio is described. The laboratory-model thruster employs a highly efficient discharge-chamber design that uses high-field-strength samarium-cobalt magnets arranged in a ring-cusp configuration. Ion extraction is achieved using an advanced three-grid ion-optics assembly which utilizes flexible mounts for supporting the screen, accel, and decel electrodes. Performance results are presented for operation at beam currents in the range from 1 to 5 A. The baseline specific discharge power is shown to be about 125 eV/ion, and the acceptable range of net-to-total accelerating-voltage ratio is shown to be in the range of 0.2-0.8 for beam currents in the range of 1-5 A.

Beattie, J. R.

Ion propulsion

An ion engine is a plasma thruster which produces thrust by extracting ions from the plasma and accelerating them to high velocity with an electrostatic field. The ions are then neutralized and leave the engine as high velocity neutral particles. The advantages of ion engines are high specific impulse and efficiency and their ability to operate over a wide range of input powers. In comparison with other electric thrusters, the ion engine has higher efficiency and specific impulse than thermal electric devices such as the arcjet, microwave, radiofrequency and laser heated thrusters and can operate at much lower current levels than the MPD thruster. However, the thrust level for an ion engine may be lower than a thermal electric thruster of the same operating power, consistent with its higher specific impulse, and therefore ion engines are best suited for missions which can tolerate longer duration propulsive phases. The critical issue for the ion engine is lifetime, since the prospective missions may require operation for several thousands of hours. The critical components of the ion engine, with respect to engine lifetime, are the screen and accelerating grid structures. Typically, these are large metal screens that must support a large voltage difference and maintain a small gap between them. Metallic whisker growth, distortion and vibration can lead to arcing, and over a long period of time ion sputtering will erode the grid structures and change their geometry. In order to study the effects of long time operation of the grid structure, we are developing computer codes based on the Particle-In-Cell (PIC) technique and Laser Induced Fluorescence (LIF) diagnostic techniques to study the physical processes which control the performance and lifetime of the grid structures.

Meserole, J. S.

Ion propulsion

An ion engine is a plasma thruster which produces thrust by extracting ions from the plasma and accelerating them to high velocity with an electrostatic field. The ions are then neutralized and leave the engine as high velocity neutral particles. The advantages of ion engines are high specific impulse and efficiency and their ability to operate over a wide range of input powers. In comparison with other electric thrusters, the ion engine has higher efficiency and specific impulse than thermal electric devices such as the arcjet, microwave, radio frequency, and laser heated thrusters and can operate at much lower current levels than the MPD thruster. However, the thrust level for an ion engine may be lower than a thermal electric thruster of the same operating power, consistent with its higher specific impulse, and therefore ion engines are best suited for missions which can tolerate longer duration propulsive phases. The critical issue for the ion engine is lifetime, since the prospective missions may require operation for several thousands of hours. The critical components of the ion engine, with respect to engine lifetime, are the screen and accelerating grid structures. Typically, these are large metal screens that must support a large voltage difference and maintain a small gap between them. Metallic whisker growth, distortion, and vibration can lead to arcing, and over a long period of time ion sputtering will erode the grid structures and change their geometry. In order to study the effects of long time operation of the grid structure, we are developing computer codes based on the particle-in-cell (PIC) technique and laser induced fluorescence (LIF) diagnostic techniques to study the physical processes which control the performance and lifetime of the grid structures.

Meserole, J. S.

Design and Performance of 40 cm Ion Optics

A 40 cm ion thruster is being developed at the NASA Glenn Research Center to obtain input power and propellant throughput capabilities of 10 kW and 550 kg. respectively. The technical approach here is a continuation of the "derating" technique used for the NSTAR ion thruster. The 40 cm ion thruster presently utilizes the NSTAR ion optics aperture geometry to take advantage of the large database of lifetime and performance data already available. Dome-shaped grids were chosen for the design of the 40 cm ion optics because this design is naturally suited for large-area ion optics. Ion extraction capabilities and electron backstreaming limits for the 40 cm ion optics were estimated by utilizing NSTAR 30 cm ion optics data. A preliminary service life assessment showed that the propellant throughput goal of 550 kg of xenon may be possible with molybdenum 40 cm ion optics. One 40 cm ion optics' set has been successfully fabricated to date. Additional ion optics' sets are presently being fabricated. Preliminary performance tests were conducted on a laboratory model 40 cm ion thruster.

Soulas, George C.

Ion accelerator system mounting design and operating characteristics for a 5 kW 30-cm xenon ion engine

Results from a series of experiments to determine the effect of accelerator grid mount geometry on the performance of the J-series ion optics assembly are described. Three mounting schemes, two flexible and one rigid, are compared for their relative ion extraction capability over a range of total accelerating voltages. The largest ion beam current, for the maximum total voltage investigated, is shown to occur using one of the flexible grid mounting geometries. However, at lower total voltages and reduced engine input power levels, the original rigid J-series ion optics accelerator grid mounts result in marginally better grid system performance at the same cold interelectrode gap.

Aston, Graeme

Single-Crystallization of O3-Type Layered Oxide Cathode for Na-Ion Battery

The development of high-energy-density Na-ion batteries places significant demands on single-crystal layered oxide cathodes, especially for further high-voltage, solid-state battery scenarios. In the O3-type structure, due to the original sluggish Na ion diffusion kinetics (approximately 1 order of magnitude lower than that of Li-ion), and further hindrance against diffusion kinetics caused by single-crystal architecture, these inherent defects lead to the decline in the electrochemical performance. Herein, we demonstrated that the single crystallization of O3-type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 cathode (d 50 = 5.04 μm) aggravates surface-to-bulk phase inhomogeneity distribution, which is attributed to the uneven Na ions extraction. Moreover, the Na-depletion of the surface/shell region not only aggravates Na ion diffusion resistance but also leads to a higher valence state of transition-metal elements (e.g., Ni/Fe) near the surface of the single-crystal particle, which further compromises the cathode-electrolyte interface stability. Furthermore, not limited to revealing the challenges, tuning the particle size and moderating quasi-single-crystal strategies have been proven to effectively mitigate the negative uneven distributions of Na ions, phases, and valence/oxidative states, resulting in efficient modification for single crystallization of Na-layered oxide cathodes.

36 MATERIALS SCIENCE

Recent work on an RF ion thruster

An experimental investigation of an rf ion thruster using an immersed coupler in an argon discharge is reported. The conical coil, used to couple rf power into the discharge, is placed inside the discharge vessel. The discharge was self-sustained by 100-150 MHz rf power at low environmental pressures. The ion extraction was accomplished by conventional accelerated grid optics from an unoptimized 8 cm diameter ion thruster.

Lee, R. Q.

Multi-Species Test of Ion Cyclotron Resonance Heating at High Altitudes

Observations of ion distributions and plasma waves obtained by the Dynamics Explorer 1 satellite in the high-altitude, nightside auroral zone are used to study ion energization for three ion species. A number of theoretical models have been proposed to account for the transverse heating of these ion populations. One of these, the ion cyclotron resonance heating (ICRH) mechanism, explains ion conic formation through ion cyclotron resonance with broadband electromagnetic wave turbulence in the vicinity of the characteristic ion cyclotron frequency. The cyclotron resonant heating of the ions by low- frequency electromagnetic waves is an important energy source for the transport of ions from the ionosphere to the magnetosphere. In this paper we test the applicability of the ICRH mechanism to three simultaneously heated and accelerated ion species by modelling the ion conic formation in terms of a resonant wave-particle interaction in which the ions extract energy from the portion of the broadband electromagnetic wave spectrum which includes the ion cyclotron frequency. Using a Monte Carlo technique we evaluate the ion heating produced by the electromagnetic turbulence at low frequencies and find that the wave amplitudes near the ion cyclotron frequencies are sufficient to explain the observed ion energies.

Persoon, A. M.

Multi-Species Test of Ion Cyclotron Resonance Heating at High Altitudes

Observations of ion distributions and plasma waves obtained by the Dynamics Explorer 1 satellite in the high-altitude, nightside auroral zone are used to study ion energization for three ion species. A number of theoretical models have been proposed to account for the transverse heating of these ion populations. One of these, the ion cyclotron resonance heating (ICRH) mechanism, explains ion conic formation through ion cyclotron resonance with broadband electromagnetic wave turbulence in the vicinity of the characteristic ion cyclotron frequency. The cyclotron resonant heating of the ions by low-frequency electromagnetic waves is an important energy source for the transport of ions from the ionosphere to the magnetosphere. In this paper we test the applicability of the ICRH mechanism to three simultaneously heated and accelerated ion species by modelling the ion conic formation in terms of a resonant wave-particle interaction in which the ions extract energy from the portion of the broadband electromagnetic wave spectrum which includes the ion cyclotron frequency. Using a Monte Carlo technique we evaluate the ion heating produced by the electromagnetic turbulence at low frequencies and find that the wave amplitudes near the ion cyclotron frequencies are sufficient to explain the observed ion energies.

Persoon, A. M.

Design and Preliminary Performance Testing of Electronegative Gas Plasma Thruster

In classical gridded electrostatic ion thrusters, positively charged ions are generated from a plasma discharge of noble gas propellant and accelerated to provide thrust. To maintain overall charge balance on the propulsion system, a separate electron source is required to neutralize the ion beam as it exits the thruster. However, if high-electronegativity propellant gases (e.g., sulfur hexafluoride) are instead used, a plasma discharge can result consisting of both positively and negatively charged ions. Extracting such electronegative plasma species for thrust generation (e.g., with time-varying, bipolar ion optics) would eliminate the need for a separate neutralizer cathode subsystem. In addition for thrusters utilizing a RF plasma discharge, further simplification of the ion thruster power system may be possible by also using the RF power supply to bias the ion optics. Recently, the PEGASES (Plasma propulsion with Electronegative gases) thruster prototype successfully demonstrated proof-of-concept operations in alternatively accelerating positively and negatively charged ions from a RF discharge of a mixture of argon and sulfur hexafluoride.i In collaboration with NASA Marshall Space Flight Center (MSFC), the Georgia Institute of Technology High-Power Electric Propulsion Laboratory (HPEPL) is applying the lessons learned from PEGASES design and testing to develop a new thruster prototype. This prototype will incorporate design improvements and undergo gridless operational testing and diagnostics checkout at HPEPL in April 2014. Performance mapping with ion optics will be conducted at NASA MSFC starting in May 2014. The proposed paper discusses the design and preliminary performance testing of this electronegative gas plasma thruster prototype.

Liu, Thomas M.

Design and Engineering of LUPIN: A Test-Bed Radio-Frequency Ion Source for Enhanced Neutral Beam Injection on DIII-D

The Large, Uniform Plasma for Ionizing Neutrals (LUPIN) is a radio-frequency (RF) inductively coupled plasma (ICP) chamber for demonstrating plasma performance of an RF ICP positive ion source upgrade for the DIII-D neutral beam injection (NBI) system. LUPIN will be used to investigate ion source physics, including neutral gas dynamics, plasma density uniformity, interactions with Faraday shields, and power coupling to novel RF antenna designs. LUPIN has an RF generator capable of delivering 20 kW of power at 2 MHz, which is coupled into a cylindrical quartz vessel measuring 20 cm in length and 10 cm in radius. This configuration matches the power density requirements for a full-scale ion source. Target hydrogen and deuterium plasma densities exceeding 10 18 m -3 would relate to extracted ion current densities of 2100 A/m 2 for 10s. Vacuum conductance and gas flow calculations predict a maximum achievable neutral gas flow rate of 1675 Pa ⋅ L/s at 5 Pa of He, which mimics the gas flow of the DIII-D NBI system. Designs have been developed for an internal Faraday shield to mitigate heat flux and ion sputtering on the dielectric vessel. Thermomechanical finite element simulations demonstrated the Faraday shield design to be capable of withstanding anticipated heat loads from worst-case operation scenarios. Finally, results of upcoming experimental investigations on LUPIN will guide the design of a full-scale prototype for DIII-D integration.

Faraday shield

Dry etching of metallization

The production dry etch processes are reviewed from the perspective of microelectronic fabrication applications. The major dry etch processes used in the fabrication of microelectronic devices can be divided into two categories - plasma processes in which samples are directly exposed to an electrical discharge, and ion beam processes in which samples are etched by a beam of ions extracted from a discharge. The plasma etch processes can be distinguished by the degree to which ion bombardment contributes to the etch process. This, in turn is related to capability for anisotropic etching. Reactive Ion Etching (RIE) and Ion Beam Etching are of most interest for etching of thin film metals. RIE is generally considered the best process for large volume, anisotropic aluminum etching.

Bollinger, D.