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Quantum-State-Controlled Collisions of Ultracold Polyatomic Molecules

Collisions between ultracold calcium monohydroxide (CaOH) molecules are realized and studied. Inelastic collision rate constants are measured for CaOH prepared in ground and excited vibrational states, and the electric field dependence of these rates is measured for molecules in single quantum states of the parity-doubled bending mode. Theoretical calculations of collision rate coefficients are performed and found to agree with measured values. The lowest collisional loss rates are for states with repulsive long-range potentials that shield ultracold molecules from loss channels at short distance. These results unveil the collisional behavior of parity-doublet molecules in the ultracold regime and lay the foundation for future experiments to evaporatively cool polyatomic molecules to quantum degeneracy.

Vilas, Nathaniel B. [Harvard University, Cambridge

Predicted intensities of cosmic-ray-produced gamma-ray lines

The relative intensities of nuclear gamma-ray lines produced by inelastic collisions of low-energy cosmic ray nuclei with interstellar hydrogen have been calculated using assumed interstellar spectra which are power laws in kinetic energy. The intensity of the line at 511 keV produced by the annihilation of positrons emitted by radioactive nuclei resulting from similar collisions was also calculated. The 478 keV gamma-ray due to inelastic scattering of Li-7 is more intense than the positron line for spectral indicies Li-7 assuming that presently accepted cosmic ray abundances apply at low energies.

Rygg, T. A.

Dynamic interpretation of space shuttle photographs: Deepwater internal waves in the western equatorial Indian Ocean

Visible images of deep-ocean internal waves in the western equatorial Indian Ocean taken by the space shuttle Atlantis during mission STS 44 in 1991 are interpreted and analyzed. The internal waves occurred in the form of a multisoliton packet in which there are about a dozen solitons. The average wavelength of the solitons is 1.8 +/- 0.5 km, ranging from 1.1 to 2.6 km. The crest lines are mostly straight and reach as long as 100 km. The distance between two adjacent packets is about 66 km. Using the deepwater soliton theory, we derived that the mean amplitude of the solitons is 25 m, the nonlinear phase speed is 1.7 m/s, and the average period is 18 min. The internal semidiurnal tides are the principal generating mechanism. The oblique collision of two multisoliton packets shown on photograph STS 44-93-103 is examined. The results show that the deep-ocean internal waves obey the general properties of soliton collision. The leading solitons and a few followers exhibit some properties of inelastic collision characterized by a phase shift, and the rest of the solitons exhibits properties of elastic collision under resonance conditions.

Zheng, Quanan

Neutral cloud theory of the Jovian nebula: Anomalous ionization effect of superthermal electrons

The standard model of the Jovian nebula postulates that its particle source is the extended cloud of neutral sulfur and oxygen atoms that escape from the satellite Io and become ionized through electron impact from the corotating plasma. Its energy source is the gyroenergy acquired by newly formed pickup ions as they are swept up to corotation velocity by the planetary magnetic field. Elastic collisions between plasma ions and electrons cool the ions and heat the electrons, while inelastic collisions cool the electrons and excite the ions to radiate intense line emission, which is the primary energy-loss mechanism for the plasma. This neutral cloud theory of the Io plasma torus, as it has come to be known, has been the subject of recent critcism which asserts that the theory cannot account for the observed charge state of the plasma which features O(+) and S(2+) as the dominant ions. It is shown in this work that the inclusion of a small population of super-thermal electrons is required to achieve the correct ion partitioning among various charge states. It is also argued that the anomalous ionization effect of the superthermal electrons is responsible for the overall spatial bifurcation of the nebula into a hot multiply charged plasma region outside of 5.7 Jovian radii and a cool singly ionized plasma inside this distance.

Barbosa, D. D.

The coefficient of restitution of ice particles in glancing collisions: Experimental results for unfrosted surfaces

Both Saturn's rings and planetesimal disks are made up of particles in Keplerian orbits. Inelastic collisions between these particles regulate their dynamical evolution and possible aggregation. We present an experiment to simulate glancing collisions in Saturn's rings and in planetesimal disks and thus measure contributions to the energy loss for both normal and tangential velocity components. In this experiment, a spherical iceball mounted on a long-period, two dimensional pendulum is made to impact a flat ice surface in a low-temperature environment. This paper describes the experimental apparatus in detail and presents results for smooth unfrosted surfaces. The energy loss for tangential motion is suprisingly low, indicating that very little friction is present at low impact speeds for relatively smooth ice surfaces and temperatures near 100 K. We have also investigated room-temperature collisions of a rubber ball on a rough surface to understand the energy loss in situations where the tangential friction force is not small. In this analogous case, the energy loss is maximum for impact angles in the range 45 deg-60 deg.

Supulver, Kimberley D.

Capture of Planetesimals into a Circumterrestrial Swarm

The lunar origin model considered in this report involves processing of protolunar material through a circumterrestrial swarm of particles. Once such a swarm has formed, it can gain mass by capturing infalling planetesimals and ejecta from giant impacts on the Earth, although the angular momentum supply from these sources remains a problem. The first stage of formation of a geocentric swarm by capture of planetesimals from initially heliocentric orbits is examined. The only plausible capture mechanism that is not dependent on very low approach velocities is the mutual collision of planetesimals passing within Earth's sphere of influence. The dissipation of energy in inelastic collisions or accretion events changes the value of the Jacobi parameter, allowing capture into bound geocentric orbits. This capture scenario was tested directly by many body numerical integration of planetesimal orbits in near Earth space.

Weidenschilling, S. J.

Dynamical Models of the Solar System Formation and Evolution

Mark Lewis has extended his them is work by completing a series of N-body simulations of a narrow ring that: is in the location of Saturn's F-ring and is perturbed by a single satellite comparable to Prometheus, but on a circular orbit. We had previously shown how the satellite perturbations can cause a broadly distributed sparse population of ring particles to become concentrated into narrow rings that can be maintained outside of any resonance location. For low optical depths, the collisions between ring particles are highly localized in the peaks of the satellite wakes. The inelastic collisions therefore occur at a particular orbital phase angle so as to damp the azimuthal component of the relative velocities. Since particle positions are not changed by collisions, the semimajor axes of the particles are shifted toward the actual particle positions where the collisions occur. Thus, negative radial diffusion can occur while conserving orbital angular momentum so long as the forced eccentricity is continually re-excited by the satellite. We speculated that the separation between the final ringlets was largely determined by the magnitude of the forced eccentricities induced by the satellite at closest approach. We carried out a series of simulations with a variety of different satellite masses in order to vary the magnitude of the forced eccentricity. We found that indeed the final spacing of the ringlets does increase with the magnitude of the forced eccentricity (Lewis and Stewart 2002). This occurs because neighboring eccentric ringlets drift out of phase with one another due to Keplerian shear and eventually collide with one another, leading to a smaller number of more widely spaced ringlets, The time scale required to form narrow ringlets in these simulations is much shorter than one would expect from standard theories based upon the orbit-averaged torque produced by multiple passes by the satellite. We find that the initial ringlets form in less than two synodic periods and the final state is typically reached in 10 to 20 synodic periods. These studies move us closer to understanding the significantly more complex system of Saturn's F ring, where the perturbation magnitude varies over short temporal and spatial time scales due to the orbital eccentricities of the perturbing satellite. We are currently extending the simulation to allow for an eccentric orbit of the satellite.

Stewart, Glen R.

Self-, N2- and Ar-broadening and line mixing in HCN and C2H2

Self-, N2- and Ar-broadening coefficients were measured for the stretch-bend infrared combination bands nu-1 + nu-1/2 (4004/cm) of HCN and nu-1 + nu-1/5 (4091/cm) of C2H2, using a tunable difference-frequency laser. At atmospheric pressures, the Q branches of these bands exhibit significant rotational narrowing or line mixing. The broadening coefficients are fit with empirical rotationally inelastic collision rate laws, which are then used to model the line mixing in the overlapped Q-branch profiles. Simple energy gap fitting laws appear to be suitable for the shorter-range intermolecular quadrupole-quadrupole and induction forces, whereas an energy-corrected-sudden scaling law works better for the longer-range dipole-dipole and dipole-quadrupole collision partners. In all cases, the line-coupling coefficients are substantially reduced from the rotationally inelastic rates fit to the broadening coefficients, indicating that 35-70 percent of the broadening may be due to other collisional mechanisms such as cross-relaxation to the degenerate H state vibrational level.

Pine, A. S.

Shielding materials for highly penetrating space radiations

Interplanetary travel involves the transfer from an Earth orbit to a solar orbit. Once outside the Earth's magnetosphere, the major sources of particulate radiation are solar cosmic rays (SCR's) and galactic cosmic rays (GCR's). Intense fluxes of SCR's come from solar flares and consist primarily of protons with energies up to 1 GeV. The GCR consists of a low flux of nuclei with energies up to 10(exp 10) GeV. About 70 percent of the GCR are protons, but a small amount (0.6 percent) are nuclei with atomic numbers greater than 10. High energy charged particles (HZE) interact with matter by transferring energy to atomic electrons in a Coulomb process and by reacting with an atomic nucleus. Energy transferred in the first process increases with the square of the atomic number, so particles with high atomic numbers would be expected to lose large amounts of energy by this process. Nuclear reactions produced by (HZE) particles produce high-energy secondary particles which in turn lose energy to the material. The HZE nuclei are a major concern for radiation protection of humans during interplanetary missions because of the very high specific ionization of both primary and secondary particles. Computer codes have been developed to calculate the deposition of energy by very energetic charged particles in various materials. Calculations show that there is a significant buildup of secondary particles from nuclear fragmentation and Coulomb dissociation processes. A large portion of these particles are neutrons. Since neutrons carry no charge, they only lose energy by collision or reaction with a nucleus. Neutrons with high energies transfer large amounts of energy by inelastic collisions with nuclei. However, as the neutron energy decreases, elastic collisions become much more effective for energy loss. The lighter the nucleus, the greater the fraction of the neutron's kinetic energy that can be lost in an elastic collision. Thus, hydrogen-containing materials such as polymers are most effective in reducing the energy of neutrons. Once neutrons are reduced to very low energies, the probability for undergoing a reaction with a nucleus (the cross section) becomes very high. The product of such a reaction is often radioactive and can involve the release of a significant amount of energy. Thus, it is important to provide protection from low energy neutrons during a long duration space flight. Among the light elements, lithium and boron each have an isotope with a large thermal neutron capture cross section, Li-6 and B-10. However, B-10 is more abundant in the naturally-occurring element than Li-6, has a thermal neutron capture cross section four times that of Li-6, and produces the stable products, He-4 and Li-7 in the interaction while Li-6 produces radioactive tritium (H-3). Thus, boron is the best light-weight material for thermal neutron absorption in spacecraft. The work on this project was focused in two areas: computer design where existing computer codes were used, and in some cases modified, to calculate the propagation and interactions of high energy charged particles through various media, and materials development where boron was incorporated into high performance materials.

Kiefer, Richard L.

Lambda-doublet transfer and propensities in collisions of OH (X2Pi/i/, v = 2) with H2O

The present work is concerned with the changes in electronic parity (e/f states) during rotationally elastic and inelastic collisions. In the OH X2Pi(i) molecule considered in the study, the differences in the e/f state production in the photodissociation of both H2O and HONO1, in the H + O2 reaction, and in the initial-state-unselected H2-OH collisions, have been experimentally examined.

Copeland, R. A.

Slicing Pomerons in ultraperipheral collisions using forward neutrons from nuclear breakup

We argue that measurements of forward neutrons from nuclear breakup in inclusive high energy photon-nucleus ( γ A ) scattering provide a novel way to study small- x dynamics of QCD in heavy-ion ultraperipheral collisions (UPCs). Using models for hadronic fluctuations of the real photon and neutron emission in nuclear fragmentation, we calculate the distribution over the number of evaporation neutrons produced in γ Pb collisions at the Large Hadron Collider. We show that it is correlated with the number of wounded nucleons (inelastic collisions) and, hence, can constrain the mechanism of nuclear shadowing and its x dependence. Published by the American Physical Society 2024

Physics

Forward production of protons in relativistic 12C-nucleus collisions

The production of protons in heavy ion collisions through the knockout mechanism (abrasion) is described using the Glauber model. The multiple knockouts from the projectile, including the inelastic collision series with the target, are considered using a closure approximation in treating energy conservation. Calculations for reactions of 12C projectiles with several targets at energies of 1 and 2A GeV arc compared to experiments. For large secondary proton momentum a strong dependence on the target mass is found and attributed to multiple scattering of the projectile knockouts.

NASA Discipline Radiation Health

Redistribution in astrophysically important hydrogen lines

Under typical solar chromospheric conditions for hydrogen radiators, strong collisions due to both electrons and ions are well separated in time, so that a binary collision theory for collisional redistribution is applicable. However, a simple impact approximation may not be used, but rather a unified type theory is required in which frequency dependent line shape parameters are used to describe both impact and quasi-static regions of the spectrum. In addition, correlated terms which describe absorption and emission during a collision are important, and, in fact, without correlated terms describing both transfer of excitation and emission during the same collision unphysical predictions (such as negative intensities) would be obtained. In this paper theory is specifically developed for the coupled Lyman-alpha, Lyman-beta, Hydrogen-alpha system, and equations of statistical equilibrium and absorption and emission coefficients are given. All correlated events are examined and emission during a collision is found to be important in the line wings. Stimulated emission and absorption is also included within a broadband approximation. The major approximation is to ignore lower state interaction. It is found that for Lyman-beta Raman-coupling with Hydrogen-alpha occurs and the overall scattering of radiation in the line wings is mostly coherent. In contrast, for Hydrogen-alpha, incoherent redistribution due to lower state radiative decay (which occurs even in the absence of collisions) is found to dominate the coherent scattering. Finally, in the Lyman series the dominant incoherent contribution is associated with cascade transitions and inelastic collisions between different principal quantum states.

Cooper, J.

Propagation and secondary production of low energy antiprotons in the atmosphere

Current theories, in which the observed antiproton component is attributed strictly to secondary production in high energy inelastic collisions of protons with the interstellar medium or the atmosphere, apparently fail to explain the relatively high p vertical intensities measured at mountain and balloon altitudes. Therefore, a more careful calculation of the theoretical secondary intensity spectra is required before more exotic sources for these excess p's can be explored. A one dimensional diffusion equation is used to calculate the expected vertical intensity of p's due only to secondary production in the atmosphere; any assumed primary p spectrum is also included. Two adjustable parameters, the inelasticity and charge exchange in nucleon-nucleus collisions, were included in the algorithm. In order to obtain an independent estimate of their values the proton vertical intensities in the atmosphere were calculated, adjusting the parameters until the curves fit the experimental proton data, and then assumed that these values were identical in antinucleon-nucleus collisions.

Bowen, T.

Electron-H2 Collisions Studied Using the Finite Element Z-Matrix Method

We have applied the Z-matrix method, using a mixed basis of finite elements and Gaussians, to study e-H2 elastic and inelastic collisions. Special attention is paid to the quality of the basis set and the treatment of electron correlation. The calculated cross sections are invariant, to machine accuracy, with respect to the choice of parameters a, b, d, e as long as they satisfy Equation (3). However, the log derivative approach, i.e., the choice a = -e = 1, b = d = 0 appears to converge slightly faster than other choices. The cross sections agree well with previous theoretical results. Comparison will be made with available experimental data.

Huo, Winifred M.