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At least 55 records · Page 3

Experiments with the Mesoscale Atmospheric Simulation System (MASS) using the synthetic relative humidity

This study is intended to examine the impact of the synthetic relative humidity on the model simulation of mesoscale convective storm environment. The synthetic relative humidity is derived from the National Weather Services surface observations, and non-conventional sources including aircraft, radar, and satellite observations. The latter sources provide the mesoscale data of very high spatial and temporal resolution. The synthetic humidity data is used to complement the National Weather Services rawinsonde observations. It is believed that a realistic representation of initial moisture field in a mesoscale model is critical for the model simulation of thunderstorm development, and the formation of non-convective clouds as well as their effects on the surface energy budget. The impact will be investigated based on a real-data case study using the mesoscale atmospheric simulation system developed by Mesoscale Environmental Simulations Operations, Inc. The mesoscale atmospheric simulation system consists of objective analysis and initialization codes, and the coarse-mesh and fine-mesh dynamic prediction models. Both models are a three dimensional, primitive equation model containing the essential moist physics for simulating and forecasting mesoscale convective processes in the atmosphere. The modeling system is currently implemented at the Applied Meteorology Unit, Kennedy Space Center. Two procedures involving the synthetic relative humidity to define the model initial moisture fields are considered. It is proposed to perform several short-range (approximately 6 hours) comparative coarse-mesh simulation experiments with and without the synthetic data. They are aimed at revealing the model sensitivities should allow us both to refine the specification of the observational requirements, and to develop more accurate and efficient objective analysis schemes. The goal is to advance the MASS (Mesoscal Atmospheric Simulation System) modeling expertise so that the model output can provide reliable guidance for thunderstorm forecasting.

Chang, Chia-Bo

Trajectory Simulations of Upper Tropospheric Humidity

We present comparisons of simulations of upper tropospheric humidity at 215 and 146 hPa with satellite measurements. Our model uses diabatic trajectories to advect water vapor from an initial condition of 100% relative humidity to the final state. The model does not allow parcels' relative humidity to exceed 100%, and in this way crudely incorporates condensation. We find that this simple model does a good job of simulating the observations. Sensitivity studies suggest that one must have realistic wind velocities in order to accurately simulate the humidity distribution; microphysical parameterizations seem to be less important. Comparisions between simulations using UKMO and NCEP horizontal winds will be discussed.

Dessler, A. E.

Lidar Measurements of Relative Humidity and Ice Supersaturation in the Upper Troposphere

We compute upper tropospheric relative humidity profiles using water vapor profiles measured by an airborne DIAL and a ground-based Raman lidar. LASE water vapor and MTP temperature profiles acquired from the NASA DC-8 aircraft during the recent Pacific Exploratory Mission Tropics B (PEM Tropics B) field mission in the tropical Pacific and the SAGE-III Ozone Loss and Validation Experiment (SOLVE) in the Arctic as well as water vapor profiles derived from the ground-based DOE ARM Southern Great Plains (SGP) CART Raman lidar are used. Comparisons of the lidar water vapor measurements with available in situ measurements show reasonable agreement for water vapor mixing ratios above 0.05 g/kg. Relative humidity frequency distributions computed using LASE data indicate that ice supersaturation occurred about 5-11% of the time when temperatures were below -35 C. While a higher frequency of ice supersaturation was observed during SOLVE, higher peak values of relative humidity were observed during PEM Tropics B. The relative humidity fields associated with cirrus clouds are also examined.

Ferrare, Richard A.

Radiation Dry Bias of the Vaisala RS92 Humidity Sensor

The comparison of simultaneous humidity measurements by the Vaisala RS92 radiosonde and by the Cryogenic Frostpoint Hygrometer (CFH) launched at Alajuela, Cosla Rica, during July 2005 reveals a large solar radiation dry bias of the Vaisala RS92 humidity sensor and a minor temperature-dependent calibration error. For soundings launched at solar zenith angles between 10" and 30 , the average dry bias is on the order of 9% at the surface and increases to 50% at 15 km. A simple pressure- and temperature-dependent correction based on the comparison with the CFH can reduce this error to less than 7% at all altitudes up to 15.2 km, which is 700 m below the tropical tropopause. The correction does not depend on relative humidity, but is able to reproduce the relative humidity distribution observed by the CFH.

Vomel, H.

Thrust Measurement of Dielectric Barrier Discharge (DBD) Plasma Actuators: New Anti-Thrust Hypothesis, Frequency Sweeps Methodology, Humidity and Enclosure Effects

We discuss thrust measurements of Dielectric Barrier Discharge (DBD) plasma actuators devices used for aerodynamic active flow control. After a review of our experience with conventional thrust measurement and significant non-repeatability of the results, we devised a suspended actuator test setup, and now present a methodology of thrust measurements with decreased uncertainty. The methodology consists of frequency scans at constant voltages. The procedure consists of increasing the frequency in a step-wise fashion from several Hz to the maximum frequency of several kHz, followed by frequency decrease back down to the start frequency of several Hz. This sequence is performed first at the highest voltage of interest, then repeated at lower voltages. The data in the descending frequency direction is more consistent and selected for reporting. Sample results show strong dependence of thrust on humidity which also affects the consistency and fluctuations of the measurements. We also observed negative values of thrust, or "anti-thrust", at low frequencies between 4 Hz and up to 64 Hz. The anti-thrust is proportional to the mean-squared voltage and is frequency independent. Departures from the parabolic anti-thrust curve are correlated with appearance of visible plasma discharges. We propose the anti-thrust hypothesis. It states that the measured thrust is a sum of plasma thrust and anti-thrust, and assumes that the anti-thrust exists at all frequencies and voltages. The anti-thrust depends on actuator geometry and materials and on the test installation. It enables the separation of the plasma thrust from the measured total thrust. This approach enables more meaningful comparisons between actuators at different installations and laboratories. The dependence on test installation was validated by surrounding the actuator with a grounded large-diameter metal sleeve. Strong dependence on humidity is also shown; the thrust significantly increased with decreasing humidity, e.g., 44 percent increase as relative humidity changed from 18 percent and dew point 33 degF to 50 percent and dew point of 57 degF.

Ashpis, David E.

Temperature and Humidity Profiles in the TqJoint Data Group of AIRS Version 6 Product for the Climate Model Evaluation

The Atmospheric Infrared Sounder (AIRS) mission is entering its 13th year of global observations of the atmospheric state, including temperature and humidity profiles, outgoing long-wave radiation, cloud properties, and trace gases. Thus AIRS data have been widely used, among other things, for short-term climate research and observational component for model evaluation. One instance is the fifth phase of the Coupled Model Intercomparison Project (CMIP5) which uses AIRS version 5 data in the climate model evaluation. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is the home of processing, archiving, and distribution services for data from the AIRS mission. The GES DISC, in collaboration with the AIRS Project, released data from the version 6 algorithm in early 2013. The new algorithm represents a significant improvement over previous versions in terms of greater stability, yield, and quality of products. The ongoing Earth System Grid for next generation climate model research project, a collaborative effort of GES DISC and NASA JPL, will bring temperature and humidity profiles from AIRS version 6. The AIRS version 6 product adds a new "TqJoint" data group, which contains data for a common set of observations across water vapor and temperature at all atmospheric levels and is suitable for climate process studies. How different may the monthly temperature and humidity profiles in "TqJoint" group be from the "Standard" group where temperature and water vapor are not always valid at the same time? This study aims to answer the question by comprehensively comparing the temperature and humidity profiles from the "TqJoint" group and the "Standard" group. The comparison includes mean differences at different levels globally and over land and ocean. We are also working on examining the sampling differences between the "TqJoint" and "Standard" group using MERRA data.

climate model evaluation

A42F-03: Small-Scale Variability in Tropical Tropopause Layer Humidity

Recent advances in statistical parameterizations of cirrus cloud processes for use in global models are highlighting the need for information about small-scale fluctuations in upper tropospheric humidity and the physical processes that control the humidity variability. To address these issues, we have analyzed high-resolution airborne water vapor measurements obtained in the Airborne Tropical TRopopause EXperiment (ATTREX) over the tropical Pacific between 14 and 20 km. Using accurate and precise 1-Hz water vapor measurements along approximately-level aircraft flight legs, we calculate structure functions spanning horizontal scales ranging from about 0.2 to 50 km, and we compare the water vapor variability in the lower (about 14 km) and upper (16-19 km) Tropical Tropopause Layer (TTL). We also compare the magnitudes and scales of variability inside TTL cirrus versus in clear-sky regions. The measurements show that in the upper TTL, water vapor concentration variance is stronger inside cirrus than in clear-sky regions. Using simulations of TTL cirrus formation, we show that small variability in clear-sky humidity is amplified by the strong sensitivity of ice nucleation rate to supersaturation, which results in highly-structured clouds that subsequently drive variability in the water vapor field. In the lower TTL, humidity variability is correlated with recent detrainment from deep convection. The structure functions indicate approximately power-law scaling with spectral slopes ranging from about minus 5 divided by 3, to minus 2.

water vapor

Development of an Additively Manufactured Capacitive Humidity Sensor for the International Space Station

The ability to measure humidity on the International Space Station and other long-duration spaceflight missions is a crucial part of the onboard systems. For example, the Environmental Control and Life Support System (ECLSS) needs to know the amount of humidity in the air to make decisions about whether it should spend power to run the dehumidifier systems to attempt to reclaim that water. Other issues can arise if the humidity reaches too high of levels and condensation builds up on electrical components. With that in mind, it is vital that the spacecraft keeps spare sensors on board or has the ability to manufacture new sensors on demand. An additively manufactured sensor would be additionally beneficial because it would save space onboard that would normally be taken up by spares, save money from costly resupply missions, and allow the sensor to be constantly updated with the most effective design. This Technical Memorandum outlines a development process carried out to design, manufacture, and test an additively manufactured humidity sensor.

Chang, K. T.

Cloud Uniformity Measurement from NASA's 2nd Fundamental Ice Crystal Icing Test - Part 2 (Temperature and Humidity)

This paper provides a characterization of the temperature and humidity variations within icing cloud flows generated during the second Fundamental Ice Crystal Icing Physics test conducted in NASA’s Propulsion Systems Laboratory, in June of 2018. The tests were conducted at airflow velocities of 85, 135, and 185 m/s, a static pressure of 44.8 kPa, and a total temperature of 7.2 ⁰C. A custom rearward facing probe and commercial total air temperature probe were used to obtain temperature and humidity profiles of the icing cloud flow leaving the exit duct plane. Additional background humidity measurements were also obtained from a commercial total water content probe. The probes captured the changes in temperature and humidity that took place at the test section after the cloud was activated. As the main altitude airflow interacts with the icing cloud, their thermodynamic properties undergo substantial changes. Due to the particle nature of the icing cloud, the droplets and ice crystals tend to redistribute within the cloud as it propagates with the main flow. Data will be presented that shows how these factors affect the thermodynamic property distribution within the icing cloud. A discussion is given of the thermal balances in the icing cloud, between the evaporating spray droplets and the airflow, as a basis for interpreting the measured results.

Crystal Icing

An Algorithm to Derive Temperature and Humidity Profile Changes Using Spatially and Temporally Averaged Spectral Radiance Differences

A linear inversion algorithm to derive changes of surface skin temperature and atmospheric temperature and specific humidity vertical profiles using spatially and temporally averaged spectral radiance differences is developed. The algorithm uses spectral radiative kernels, which is the top-of-atmosphere spectral radiance change caused by perturbations of skin temperature and air temperature and specific humidity in the atmosphere, and is an improved version of the algorithm used in earlier studies. Two improvements are the inclusion of the residual and cloud spectral kernels in the form of eigenvectors of principal components. Three and six eigenvectors are used for, respectively, the residual and cloud spectral kernels. An underlying assumption is that the spectral shape of the principal components is constant and their magnitude varies temporally and spatially. The algorithm is tested using synthetic spectral radiances with the spectral range of the Atmospheric Infrared Sounder averaged over 16 days and over a 10° × 10° grid box. Changes of skin temperature, air temperature, and specific humidity vertical profiles are derived from the difference of nadir-view all-sky spectral radiances. The root-mean-square difference of retrieved and true skin temperature differences is 0.59 K. The median of absolute errors in the air temperature change is less than 0.5 K above 925 hPa. The median of absolute errors in the relative specific humidity changes is less than 10% above 825 hPa.

Fang Pan

Global seasonal variations of the near-surface relative humidity levels on present-day Mars

We investigate the global seasonal variations of near-surface relative humidity and relevant attributes, like temperature and water vapor volume mixing ratio on Mars using calculations from modelled and measurement data. We focus on 2 AM local time snapshots to eliminate daily effects related to differences in insolation, and to be able to compare calculations based on modelling data from the Laboratoire de Météorologie Dynamique Mars General Circulation Model with the observations of Mars Global Surveyor Thermal Emission Spectrometer. We study the seasonal effects by examining four specific dates in the Martian year, the northern spring equinox, summer solstice, autumn equinox, and winter solstice. We identify three specific zones, where the near-surface relative humidity levels are systematically higher than in their vicinity regardless of season. We find that these areas coincide with low thermal inertia features, which control surface temperatures on the planet, and are most likely covered with unconsolidated fine dust with grain sizes smaller than ∼ 40 μm. By comparing the data of relative humidity, temperature and water vapor volume mixing ratio at three different heights (near-surface, ∼ 4m and ∼ 23m above the surface), we demonstrate that the thermal inertia could play an important role in determining near-surface humidity levels. We also notice that during the night the water vapor levels drop at ∼ 4m above the surface. This, together with the temperature and thermal inertia values, shows that water vapor likely condenses in the near-surface atmosphere and on the ground during the night at the three aforementioned regions. This condensation may be in the form of brines, wettening of the fine grains by adsorption or deliquescence. This study specifies areas of interest on the surface of present day Mars for the proposed condensation, which may be examined by in-situ measurements in the future.

Bernadett Pál

Regenerable Liquid Desiccants for High Efficiency Humidity Control in Microgravity

The NASA X-Hab project aims to design, manufacture, test, and prove functionality of an air humidity control subsystem to dehumidify and re-humidify air from a space cabin. The method of regulating cabin air humidity utilizes vortex phase separation, which uses an ionic liquid (IL) desiccant for air-water phase separation. This subsystem is intended to be integrated with a CO 2 removal system requiring de-humidified air to operate efficiently. The air humidity control subsystem is composed of a cold-desiccant or cold-side Vortex Phase Separator (VPS) that dehumidifies the cabin air. The dehumidified air exits the cold-side (CS) VPS chamber to flow into the CO 2 removal module, and the cold, water-laden liquid desiccant flows to a regenerative heat exchanger. From the heat exchanger the liquid desiccant continues to the heater. After heating, the desiccant flows into a hot-desiccant or hot-side (HS) VPS as the dehumidified air from CO 2 removal module enters through the HS VPS air inlet. The rehumidified air exits the HS VPS into the space cabin. One pump installed at the liquid exit of the CS VPS and one pump installed at the liquid exit of the HS VPS transport the fluid through the system. To evaluate the system’s efficiency and effectiveness, the temperature, pressure, flow rate and relative humidity are read, recorded, and analyzed at critical points along the module.

Gerardo Castro

Springtime SEA Air Is Consistently Both Smoky and Humid, but This Relationship (and Its Radiative Effects) Varies Spatially and Seasonally

The atmosphere over the southeast Atlantic Ocean (SEA) sees a consistent springtime biomass burning (BB) smoke from widespread agricultural fires on the African continent. This smoke layer is initially lofted high in a continental mixed layer (~5-6km) and is then transported westward in the free troposphere, where it overlies and ultimately mixes into the SEA stratocumulus-topped oceanic boundary layer. Coincident with this smoke is an elevated humidity signal which is present from the time a given airmass is over the continental source region. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) was a NASA Earth Venture Suborbital mission with the goal of measuring aerosol, cloud, and atmospheric properties over this region during three deployments in September 2016, August 2017, and October 2018. A previous study discussed the spatial characteristics of the water vapor-BB plume observations in the September 2016 flight data and their degree of agreement with several atmospheric reanalyses and models. In the present work, we first discuss atmospheric chemistry, structure, and aerosol results from all three ORACLES deployments to place these results in a broader seasonal context. Despite the differing locations and season of each deployment, we show that there continues to be good agreement between the airborne ORACLES dataset and large-scale reanalyses, specifically the ECMWF ERA5 and CAMS reanalyses. Other reanalyses (specifically NASA's MERRA-2) preserved the observed correlation between meteorology and biomass burning conditions, but, as was seen for 2016, was frequently displaced spatially relative to the observations. The CAMS reanalysis performs better with water vapor than with CO. Results comparing CAMS column AOD to the field measurements show slight overestimates, consistent with previous analysis, but the good relationship observed between AOD and inlet-based aerosol extinction demonstrates this metric's utility to broader studies. The good ERA5/CAMS/ORACLES agreement allows us to next examine the multi-year seasonal patterns and trends beyond the three ORACLES deployment periods. Looking at seven years of reanalysis data for the BB season, we find distinct variations between each month/deployment in terms of vertical smoke distribution and correlation to atmospheric specific humidity, due to changing conditions through the BB season. Using k-means clustering of these climatological reanalysis, we identify six canonical atmospheric profile types of varying total atmospheric humidity and vertical structure and describe their changing incidence spatially and throughout the season, and six analogous profile types for carbon monoxide, allowing us to characterize the atmospheric structure of both vapor and BB over time throughout the SEA region. This classification will allow for a more complete analysis of the broader radiative and dynamical effects of humid aerosols overlying stratocumulus clouds.

Kristina Marie Myers Pistone

Mitigating humidity interference in chemiresistive hydrogen sensors through hydrophobic surface functionalization

Chemiresistive gas sensors based on semiconductor metal oxides, such as tin dioxide (SnO₂), are indispensable for detecting and monitoring toxic gases and pollutants, making them critical components in industrial and environmental applications. To enhance their performance, the metal oxides are loaded with noble metals such as palladium (Pd). However, ambient humidity poses a significant challenge to their performance. The presence of adsorbed water molecules on the oxide surface can considerably impair sensor sensitivity and overall performance. To address this issue, in this paper, we report on the application of an ultrathin, hydrophobic layer of hexamethyldisilazane to the surface of a Pd/SnO 2 sensor. This study investigates the influence of hydrophobic surface modifications on the metal oxide interface, focusing on their impact on sensor sensitivity and selectivity. The resulting sensor exhibits superior hydrogen sensing capabilities, operating effectively at low temperatures even in high humidity environments. Furthermore, the hydrophobic modification reduces the sensor’s susceptibility to interfering gases, thus enhancing its selectivity. The combined enhancements in moisture resistance and selectivity achieved through HMDS surface modification, along with the superior sensitivity of Pd/SnO₂ sensors, facilitate the development of gas sensors with enhanced humidity tolerance and broader applications.

Chemiresistive gas sensors

Brittle-to-Ductile Transitions of Polyelectrolyte Complexes: Humidity, Temperature, and Salt

Polyelectrolyte complexation is an entropically driven, associative phase separation that results in a polymer-rich polyelectrolyte complex (PEC) and a polymer-poor supernatant. PECs show promise as a new class of sustainable materials since they can be processed using aqueous solutions rather than organic solvents. Previous reports have looked at the mechanical properties and glass transitions of PECs as a function of temperature, relative humidity (rH), and salt concentration (CS), but establishing a universal understanding of how these parameters affect PEC mechanics has yet to be achieved. We examined the effects of temperature, rH, and CS on the mechanical properties of PECs formed from poly(methacrylic acid) and poly(trimethyl aminoethyl methacrylate) with a goal of establishing design rules for their mechanical response. Relative humidity was shown to have the most dramatic effect on the mechanical properties, with temperature and salt concentration having far less of an impact. Furthermore, we observed that the glass transition of PECs is tied to both temperature and relative humidity, creating a glass transition rH g /T g line that can be modulated by added salt. Finally, we looked at the thermodynamics behind the glass transition of PECs, which yielded similar energies as the condensation of water. Here, we propose the use of water and/or salt as a low energy and efficient method of processing PECs for various applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Insights into Sustainable Nitrogen Fixation by Gas-phase Spectroscopic Measurements and Global Modeling of Reaction Intermediates in Humid Nitrogen Plasma

In this article, there is growing interest in reacting molecular nitrogen and water to sustainably synthesize fixed forms of nitrogen such as ammonia. In particular, low-temperature plasmas can activate these relatively inert feedstocks at or near room temperature without a catalyst. However, because of the enhanced reactivity and nonequilibrium chemistry, a diverse range of products is formed, and the underlying reaction mechanisms are exceedingly complex. In this work, we studied a simplified reactor consisting of a gaseous plasma containing controlled mixtures of nitrogen gas and water vapor. Densities of key chemical species such as N, H, OH, NH, and NO were measured by emission and laser-based spectroscopy as a function of the relative humidity. A global model was constructed and the reaction network was validated by comparing calculated species densities with experiments. We discover that N, a key initial intermediate for ammonia, strongly decreases in the presence of water vapor, and as a result, ammonia formation becomes limited at high relative humidity. This decrease is surprisingly not because N itself reacts, but because one of its main sources, an excited molecular nitrogen state, is reacted away. In addition, oxidation pathways for nitrogen, which lead to NO and related products, are found to be favored over reduction pathways because the corresponding reverse reactions are less significant. Together, this understanding helps explain previously reported observations of selectivity toward nitrogen oxides over ammonia, particularly at higher relative humidities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Moisture Performance of Unvented Attics With Vapor Diffusion Ports and Buried Ducts in Hot, Humid Climates

Energy efficiency measures, such as cool roofs, radiant barriers, interior radiative control coatings, and buried ducts are increasing in popularity and are promoted by energy codes because of their energy-saving potential. However, these strategies can also pose moisture risks in attics by lowering surface temperatures and increasing condensation potential and moisture accumulation. Of particular concern in hot-humid climates is dripping condensation on cold air-conditioning ductwork in the summer - commonly referred to as duct "sweating" - which threatens the attic floor with conditions conducive to mold growth and rot. One strategy to mitigate these moisture issues is to wrap ductwork in thicker duct-wrap insulation with an integrated exterior vapor barrier, but thick duct wrap can be difficult to come by, expensive, and unwieldy to work with. This study explores an alternative strategy of reducing moisture issues while embracing energy efficiency by using unvented attics with vapor diffusion ports and buried ductwork in hot-humid climates. Vapor diffusion ports have been studied so far in a wide range of U.S. climates, mostly in the context of conditioned attics. In this study, the strategy is implemented in the novel context of hot-humid climates with ductwork sitting atop blown-in attic floor insulation in unconditioned attics. Using a combination of field experiments and hygrothermal modeling, the findings of this project indicate that an unvented attic with vapor diffusion ports and buried ducts may be a key part of a successful low-cost method for reducing the attic moisture load by venting excess moisture out of the attic, keeping duct-jacket surfaces above dew point temperature, and keeping the roof deck safe from winter moisture accumulation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI

Relative Humidity Measurement Assurance Program Results

During the summer of 1992, the National Conference of Standards Laboratories sponsored a relative humidity measurement assurance program (RHMAP) whose purpose was to enable each participating center to assess the quality of relative humidity calibrations being performed by their respective standards laboratories. This paper presents the data which was submitted by the participants during the first round of the program and shows the multi-laboratory comparisons of the 20%, 50%, and 80% relative humidity meaurements performed.

Humidity