Results for “HfS” — Page 3

NASA NTRSDate not supplied

A Green’s Function Sensor Fusion Approach for Evaluating Spacecraft Entry Heating From on-Board Thermal Instrumentation

During atmospheric entry, distributed thermal measurements are critical to enable the evaluation of heat loads on spacecraft thermal protection systems (TPS). In recent space exploration missions, Schmidt-Boelter-type heat flux gauges have been integrated into the TPS alongside conventional temperature measurement instrumentation to measure total (convective and radiative) and radiative heat transfer rates1,2. While direct heat flux sensors (HFS) are able to provide valuable information detailing the thermal loads experienced by spacecraft, the interpretation of these measurements in unsteady, convective environments requires a correction factor to account for local heating augmentations at the cold wall HFS surface2,3. Current efforts to estimate cold wall correction factors, and thus recover the hot wall TPS heat flux, rely on time-marching computational fluid dynamics (CFD) simulations2. Simulation-based methods are susceptible to large uncertainties, however, as they require estimations of vehicle trajectory, gas kinetics, wall catalysis models, and other flight conditions as input parameters2,4. Furthermore, CFD simulations are computationally expensive and cannot efficiently survey all possible entry scenarios, exacerbating the uncertainty of reconstructed hot wall heat flux values. These drawbacks motivate the development of alternative hot wall heat flux reconstruction methods that are not reliant on CFD-based correction factors.

Kenneth McAfee↗

NASA NTRSDate not supplied

A Green’s Function Sensor Fusion Approach for Evaluating Spacecraft Entry Heating From on-Board Thermal Instrumentation

During atmospheric entry, distributed thermal measurements are critical to enable the evaluation of heat loads on spacecraft thermal protection systems (TPS). In recent space exploration missions, Schmidt-Boelter-type heat flux gauges have been integrated into the TPS alongside conventional temperature measurement instrumentation to measure total (convective and radiative) and radiative heat transfer rates1,2. While direct heat flux sensors (HFS) are able to provide valuable information detailing the thermal loads experienced by spacecraft, the interpretation of these measurements in unsteady, convective environments requires a correction factor to account for local heating augmentations at the cold wall HFS surface2,3. Current efforts to estimate cold wall correction factors, and thus recover the hot wall TPS heat flux, rely on time-marching computational fluid dynamics (CFD) simulations2. Simulation-based methods are susceptible to large uncertainties, however, as they require estimations of vehicle trajectory, gas kinetics, wall catalysis models, and other flight conditions as input parameters2,4. Furthermore, CFD simulations are computationally expensive and cannot efficiently survey all possible entry scenarios, exacerbating the uncertainty of reconstructed hot wall heat flux values. These drawbacks motivate the development of alternative hot wall heat flux reconstruction methods that are not reliant on CFD-based correction factors.

Kenneth McAfee↗

NASA NTRSDate not supplied

A Green’s Function Sensor Fusion Approach for Evaluating Spacecraft Entry Heating From on-Board Thermal Instrumentation

During atmospheric entry, distributed thermal measurements are critical to enable the evaluation of heat loads on spacecraft thermal protection systems (TPS). In recent space exploration missions, Schmidt-Boelter-type heat flux gauges have been integrated into the TPS alongside conventional temperature measurement instrumentation to measure total (convective and radiative) and radiative heat transfer rates1,2. While direct heat flux sensors (HFS) are able to provide valuable information detailing the thermal loads experienced by spacecraft, the interpretation of these measurements in unsteady, convective environments requires a correction factor to account for local heating augmentations at the cold wall HFS surface2,3. Current efforts to estimate cold wall correction factors, and thus recover the hot wall TPS heat flux, rely on time-marching computational fluid dynamics (CFD) simulations2. Simulation-based methods are susceptible to large uncertainties, however, as they require estimations of vehicle trajectory, gas kinetics, wall catalysis models, and other flight conditions as input parameters2,4. Furthermore, CFD simulations are computationally expensive and cannot efficiently survey all possible entry scenarios, exacerbating the uncertainty of reconstructed hot wall heat flux values. These drawbacks motivate the development of alternative hot wall heat flux reconstruction methods that are not reliant on CFD-based correction factors.

Kenneth McAfee↗

DOE OSTI2021

Thermodynamic modeling of hydrogen fueling process from high-pressure storage tank to vehicle tank

This study develops a hydrogen fueling station (HFS) thermodynamic model that simulates the actual fueling process in which hydrogen is supplied from a high-pressure (HP) storage tank into a fuel cell electric vehicle (FCEV) tank. To make the model as accurate as possible, we use the same components and specifications as in actual HFSs, such as a pressure control valve, a pre-cooling system, and an FCEV tank. After the components and their specifications are set, pressure and temperature profiles are set as the HP tank supply conditions. Based on the pressure and temperature profiles, the model solves for the temperature, pressure, and mass flow rate of hydrogen at each downstream position, including the inside of the vehicle tank. The values predicted by the model are compared with experimental data, and we show that the developed model makes it possible to accurately simulate those values at any position during the fueling process.

08 HYDROGEN↗

DOE OSTI2026

Improved nuclear-structure corrections to the hyperfine splitting of electronic and muonic deuterium

We calculate the nuclear-structure correction to the hyperfine splitting in both electronic and muonic deuterium using interactions from chiral effective field theory. We explore the sensitivity to different parameterizations of the nucleon-nucleon force, study the convergence pattern in the order-by-order chiral expansion, and estimate remaining uncertainties. Our results are consistent with earlier calculations from pionless effective field theory, offering new insights for a robust uncertainty quantification. Thanks to the order-of-magnitude reduction in uncertainty achieved with chiral effective field theory, the two-photon exchange contribution in electronic deuterium agrees with experimental extractions within 0.5σ, in contrast to the 2.6σ discrepancy observed in muonic deuterium. This study lays the groundwork for extending TPE calculations to HFS in heavier atomic systems.

Chiral effective field theory↗

DOE OSTI2021

High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

In this study, highly dispersed nickel (Ni) nanoparticles (NPs) with an average particle size of 4.3 nm were uniformly deposited on the outer surface, the inner channel surface, and inside the pores of 20-cm long 4-channel α-Al 2 O 3 hollow fibers (HFs) by atomic layer deposition (ALD) for dry reforming of methane (DRM). Cerium oxide (CeO 2 ) was added to promote the catalytic performance of Ni/Al 2 O 3 -HF catalysts. Rationally designed filling methods, by tuning the reactor size and inert fillings, can reduce the catalyst bed voidage in a fixed bed reactor for better reactant gas distribution, effectively utilize the Ni reactive sites, and achieve excellent catalytic performance. It was found that the CeO 2 -promoted Ni/Al 2 O 3 -HF catalyst was highly active and highly stable without deactivation during an overall 400-hr DRM test at 850 ºC. CeO 2 with reversible valence states could participate in surface reactions; especially, the formation of CeAlO 3 provided sufficient surface Ce 3+ for CO 2 activation and enhanced the stability and reusability of the HF catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Incommensurate transition-metal dichalcogenides via mechanochemical reshuffling of binary precursors

A new family of heterostructured transition-metal dichalcogenides (TMDCs) with incommensurate (“misfit”) spatial arrangements of well-defined layers was prepared from structurally dissimilar single-phase 2H-MoS 2 and 1T-HfS 2 materials. The experimentally observed heterostructuring is energetically favorable over the formation of homogeneous multi-principle element dichalcogenides observed in related dichalcogenide systems of Mo, W, and Ta. The resulting three-dimensional (3D) heterostructures show semiconducting behavior with an indirect band gap around 1 eV, agreeing with values predicted from density functional theory. Results of this joint experimental and theoretical study open new avenues for generating unexplored metal-dichalcogenide heteroassemblies with incommensurate structures and tunable physical properties.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Evaluation of DIII-D plasmas for Future Measurements of the Driven Current Density in the DIII-D High Field Side Lower Hybrid Experiment

High field side (HFS) lower hybrid current drive (LHCD) is a promising method for efficiently driving off-axis current in steady state tokamak power plants. The first test of this technology is underway at the DIII-D tokamak. The initial physics goal is to measure the LH-driven current density profile in order to validate the ray-tracing/Fokker-Plank codes GENRAY/CQL3D and gain confidence in their ability to predict LH deposition in future DIII-D experiments and fusion power plants. DIII-D’s motional Stark effect (MSE) diagnostic will be used to constrain the magnetic equilibrium reconstructions. From these reconstructions, the ohmic, bootstrap, and driven non-inductive components of the current density profile can be extracted. Several recent DIII-D plasmas have been identified in which GENRAY/CQL3D predict measurable amounts of current with only 100 kW of coupled power.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2026

Design, Manufacturing, and Installation of DIII-D Lower Hybrid Current Drive Outer Wall Waveguides and Expandable Vacuum Interface

High field side lower hybrid current drive (HFS LHCD) is promising method for efficient, off axis current drive. To operate this system, development of an expandable combination radio frequency (RF) and vacuum interface was necessary to allow the long (~2 m) waveguides to thermally expand with respect to the DIII-D 0 degree R-1 port extension without damage to the waveguide or excessive force on the vacuum seals which was previously observed when baking the waveguides during operations that were installed in 2024. Design of a custom bellows assembly with RF feedthrough that allows >20mm of waveguide thermal expansion is presented. Fabrication of this bellows assembly required simultaneously vacuum brazing multiple 304 stainless steel flanges to an oxygen free high conductivity copper waveguide section which required significant manufacturing development.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2022

Gas puff imaging on the TCV tokamak

We present the design and operation of a suite of Gas Puff Imaging (GPI) diagnostic systems installed on the Tokamak à Configuration Variable (TCV) for the study of turbulence in the plasma edge and Scrape-Off-Layer (SOL). These systems provide the unique ability to simultaneously collect poloidal 2D images of plasma dynamics at the outboard midplane, around the X-point, in both the High-Field Side (HFS) and Low-Field Side (LFS) SOL, and in the divertor region. We describe and characterize an innovative control system for deuterium and helium gas injection, which is becoming the default standard for the other gas injections at TCV. Extensive pre-design studies and the different detection systems are presented, including an array of avalanche photodiodes and a high-speed CMOS camera. First results with spatial and time resolutions of up to ≈2 mm and 0.5 µs, respectively, are described, and future upgrades of the GPI diagnostics for TCV are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2020

RNA‐Seq analysis revealed the molecular mechanisms of photobiomodulation effect on human fibroblasts

Abstract Background The photobiomodulation (PBM) effect has been applied to various clinical therapy for a long time. However, the mechanism related to the PBM effect in terms of wavelengths has been lack of in‐depth study, except that ultraviolet radiation has attracted much attention due to its strong cell‐killing effect. Purpose To clarify the principle behind PBM and the main mechanism of improvement. Methods To carry on this study, we created light equipment using three LED chips, which emit 390 nm ultraviolet radiation, 415 nm blue light and 660 nm red light, respectively. We choose human fibroblasts (HF) to be irradiated by three different wavelengths for PBM test. In this study, we used cell counting kit (CCK‐8) test to show the cell proliferation roughly and reported on a systematic RNA sequencing (RNA‐seq) analysis at transcriptional expression levels from HF, which accepted PBM of different wavelengths of light. Results We found that 415 nm blue light inhibited cell proliferation and 660 nm red light stimulated cell proliferation while 390 nm ultraviolet radiation has little influence on cell proliferation. Furthermore, RNA‐seq results showed that CSF1R, PPP3CC, ITGAL, ITGAM, IL2RB, and several other differentially expressed genes (DEGs) are involved in the cell proliferation. Relative DEGs values for matrix metalloproteinases (MMPs) gene family have shown a great difference in blue and red light radiation especially on MMP25, MMP9, MMP21, and MMP13. Conclusion Taken together, the results provide a valuable resource to describe the variation of HFs under PBM of different light at gene level.

Li, Wenqi↗

DOE OSTI2023

Development of a Pre-Combustion CO 2 Capture Process Using High-Temperature PBI Hollow-Fiber Membranes

The overall objective of this project was to evaluate the advantages of transformational polybenzimidazole (PBI) polymer hollow-fiber membrane (HFM)-based, carbon dioxide (CO 2 ) capture and purification technology at bench-scale using an actual coal-derived syngas stream from a coal gasification facility. The project was carried out over two budget periods. The technical objectives in Budget Period 1 (BP1) included preparing HFs and modules and upgrading the available skid for field testing. The technical objectives for BP2 were to field-test the skid unit with actual coal-derived syngas from an oxygen-blown gasifier to obtain performance data, update the Techno-Economic Analysis (TEA) that would assist with future process scale-up, and provide information on the design of a small pilot-scale test unit. The goal was to advance the PBI-HFM CO 2 capture and gas separation system for pre-combustion applications beyond second-generation economic performance predictions and make progress toward meeting overall fossil energy performance goals of CO 2 capture with 95% CO 2 purity at a cost of electricity (COE) 30% less than baseline capture approaches. The research program was designed with progressive technical tasks leading to both dynamic and steady-state testing of the PBI-HFM skid with actual coal-derived syngas. The work plan was to: (1) fabricate sufficient Generation-2 (GEN-2) fibers for module fabrication; (2) upgrade the fiber skid to accommodate large fiber modules for bench-scale field testing; (3) conduct dynamic and steady-state testing with coal-derived syngas from an oxygen-blown gasifier and obtain system performance data; (4) perform a TEA and environmental, health, and safety (EH&S) assessment; (5) update the State-Point Data Table, Technology Gap Analysis (TGA), and Technology Maturation Plan (TMP); (6) uninstall and return the test skid to the Recipient’s facilities; and (7) submit a Final Report that describes the results and analysis of the project research effort.

03 NATURAL GAS↗

DOE OSTI2026

Studying f-Electron Contributions in Thorium and Uranium Containing Molecules

The pure rotational spectra of several actinide-containing compounds have been improved upon and, in two cases, been recorded for the first time. The diatomic molecules HfS and ThS have been studied in their ground electronic states but high vibrationally excited states. The results have yielded very accurate locations of the minima of the potential energy curves. The asymmetric molecules OThS and UO2S have been prepared by laser ablation synthesis and their pure rotational spectra recorded for the first time. Precise information pertinent to the geometric and electronic structure of these molecules has been obtained and is compared with other, newly recorded and related species such as OCeS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1973

Hyperfine structure of furan.

The hfs of five rotational transitions of furan (C4H4O) has been resolved with a beam maser spectrometer with a resolution of about 500 Hz. All significant details of the observed structure are accounted for by the spin-spin and spin-rotation interactions of the four protons, and the coupling constants for these interactions have been determined to high precision. In particular, the diagonal elements of the spin-rotation tensors have been determined to about 10 Hz.

Tomasevich, G. R.↗

NASA NTRS1983

Laboratory and astronomical measurement of the millimeter wave spectrum of the ethynyl radical CCH

The N = 0 yields 1 and 1 yields 2 rotational transitions of CCH at 87 and 174 GHz, respectively, have been detected in a laboratory glow discharge in a mixture of He and C2H2. The spectroscopic constants of CCH derived from measurements of the hfs of the transitions agree well with those derived from astronomical observations, confirming the astronomical detection of CCH. As the CCH lines in the Orion Nebula are narrower than the laboratory lines but less certain in rest frequency owing to uncertainty in the radial velocity, the most accurate values for the spectroscopic constants of CCH are obtained from a simultaneous fit of both the laboratory and astronomical data. For the rotation, centrifugal distortion, spin-rotation, and hyperfine constants, respectively, the values found are within 0.006 of 43674.534 MHz, within 0.0008 of 0.1071 MHz, within 0.004 of -62.606 MHz, b = within 0.019 MHz of 40.426, and c is within 0.026 of 12.254 MHz.

Gottlieb, C. A.↗

NASA NTRS1985

Astronomical identification of the C3H radical

The C3H radical has been identified in the millimeter-wave spectra of IRC +10216 and TMC-1. In IRC +10216, four rotational transitions have been observed, three in the lower fine-structure ladder (2Pi1/2) and one in the upper (2Pi3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2-1/2 transition of the 2Pi1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216, the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2Pi1/2 ladder is low (8.5 K), because of rapid radiative decay, while Trot across the ladders is high (about 52 K), because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84 arcsec is 2.8 x 10 to the 13th/sq cm, an order of magnitude less than that of C2H and C4H.

Thaddeus, P.↗

NASA NTRS1985

Laboratory detection of the C3H radical

Millimeter-wave lines of the C3H radical, including six of the lines observed in space, were detected in a laboratory glow discharge through a flowing mixture of C2H2, He, and CO. Each of the 10 rotational transitions measured, five between 98 and 185 GHz in the 2Pi1/2 ladder and five between 80 and 194 GHz in the 2Pi3/2 ladder, is split by lambda-type doubling, and all but three possess resolved hyperfine structure. The excellent agreement between the fine-structure, rotation, lambda-doubling, and hyperfine constants derived from the laboratory data and from the astronomical observations conclusively confirms the identifications in IRC +10216 and TMC-1 by Thaddeus and colleagues (1985). An accurate set of spectroscopic constants, which allow calculation of the entire radio spectrum of C3H to a radial velocity of 0.1 km/s, was derived from a simulataneous fit to the laboratory frequencies and to the well-resolved hfs observed in the narrow-line astronomical source TMC-1.

Gottlieb, C. A.↗

NASA NTRS1991

Formation of Apollo 14 aluminous mare basalts by replenishment fractional crystallization and assimilation of precursor crust

Apollo 14 aluminous mare basalts (AMB) have been the subject of considerable controversy. These basalts were divided into 5 distinct groups on the basis of RE and HFS element abundances. The groups are similar in major element compositions but display an 8 fold variation in REE abundances. Open-system processes were explored which are common on Earth: combined replenishment fractional crystallization (RFC); and assimilation fractional crystallization (AFC), where the assimilant is a partial melt of precursor crust. RFC often produces decoupled major and trace element variations, while AFC can produce significant variation in incompatible trace element ratios. A model was envisioned by which magmas of Group 5 composition were emplaced in shallow chambers. The Apollo 14 AMB was modeled by RFC using a parental magma of Group 5 composition with the fractionating assemblage consisting of 60 pct. Px, 30 pct. Plag, and 3 pct. Il.

Dickinson, Tammy L.↗