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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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51 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

The impact of fuel and injection strategy on combustion characteristics, emissions and efficiency in gasoline compression ignition operation

Gasoline compression ignition in diesel engines has been proposed in order to meet increasingly stringent emission regulations without sacrificing efficiency. In this study, a six-cylinder heavy-duty diesel engine was operated in a mixing controlled gasoline compression ignition mode to investigate the influence of fuels and injection strategies on the combustion characteristics, emissions, and thermal efficiencies. Fuels, including ethanol (E), isobutanol (IB), and diisobutylene (DIB), were blended with a gasoline fuel to form E10, E30, IB30, and DIB30 based on volumetric fraction. These four blends along with gasoline formed the five test fuels. With these fuels, three injections strategies were investigated, including late pilot injection, early pilot injection, and port fuel injection/direct injection. The impact of moderate exhaust gas recirculation on nitrogen oxides and soot emissions was examined to determine the most promising fuel/injection strategy for emissions reduction. In addition, first and second law analyses were performed to provide insights into the efficiency, loss, and exergy destruction of the various gasoline fuel blends at low and medium load conditions. Overall, the emission output, thermal efficiency, and combustion performances of the five fuels were found to be similar and their differences are modest under most test conditions. E30 with the port/direct fuel injection strategy obtained the peak brake thermal efficiency (46.9%) and gross indicated thermal efficiency (52.2%) at 14 bar. At 7 bar, the peak brake thermal efficiency (44.2%) and gross indicated thermal efficiency (52.5%) also belonged to E30 with the late pilot injection strategy. The second law analysis revealed that exergy destruction was mostly influenced by the fuel type and not by the injection strategy for the 14 bar operating conditions. However, the opposite trend was observed for the 7 bar case. In addition, port fuel injection in combination with oxygenated fuel blends was found to be helpful to suppress soot emissions for operation with exhaust gas recirculation.

co-optima fuels↗
DOE OSTI2024

Unconventional fieldlike spin torques in CrPt 3

The topological semimetal CrPt 3 has potential for generating unconventional spin torques due to its ferrimagnetic ordering, topological band structure, and high anomalous Hall effect. CrPt 3 exhibits ferrimagnetic behavior only in its chemically ordered phase and is paramagnetic in its chemically disordered phase. By controlling the growth and annealing temperatures, we prepare epitaxial films of both chemically ordered and chemically disordered phases of CrPt 3 , allowing us to investigate the effect of magnetic ordering on unconventional-torque generation. We use angle-dependent spin-torque-ferromagnetic-resonance and second-harmonic Hall measurements to probe the spin torques generated from epitaxial CrPt 3 in CrPt 3 /Cu/Ni 81 ⁢Fe 19 heterostructures. With current applied along specific directions with respect to the crystal order, we reveal unconventional spin torques in both ordered and disordered films. When current flows parallel to the [$1\bar{1}1$] and [ $\bar{1}11$] directions, we observe an unconventional fieldlike torque that is opposite in sign for the two directions. Finally, our calculations reveal that this unconventional torque originates from an indirect nonlocal spin-orbit torque due to spin scattering at the CrPt 3 /Cu interface, in addition to symmetry breaking at this interface.

ferromagnetic resonance↗
DOE OSTI2021

A Noncentrosymmetric Polymorph of LuRuGe

In this work, we report a new polymorph of LuRuGe, obtained in indium flux. This phase exhibits the noncentrosymmetric ZrNiAl-type structure with the space group $Ρ\bar 62m$ as determined by single-crystal X-ray diffraction. This polymorph can convert into another centrosymmetric polymorph (TiNiSi-type structure, space group Pnma ) at high temperatures. In this work, we performed electrical transport, magnetization, and specific heat measurements on this new phase. It shows metallic behavior with a Hall sign change from negative at 2 K to positive at 125 K. LuRuGe exhibits Pauli paramagnetism as the ground state with no local magnetic moments from either the Ru or Lu site. The Debye temperature Θ = 348 K and electronic coefficient γ e = 3.6 mJ K –2 mol –1 are extracted from the low-temperature specific heat data in LuRuGe. We also carried out first-principles density functional theory calculations to map out the electronic band structure and density of states. There are several electronic bands crossing the Fermi level, supporting a multiband scenario consistent with the Hall sign change. The density of states around the Fermi level is mainly from Ru 4d and Ge 4p electrons, indicating a strong hybridization between those atomic orbitals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Device and material investigations of GaN enhancement-mode transistors for Venus and harsh environments

This Letter reports the device and material investigations of enhancement-mode p-GaN-gate AlGaN/GaN high electron mobility transistors (HEMTs) for Venus exploration and other harsh environment applications. The GaN transistor in this work was subjected to prolonged exposure (11 days) in a simulated Venus environment (460 °C, 94 bar, complete chemical environment including CO2/N2/SO2). The mechanisms affecting the transistor performance and structural integrity in harsh environment were analyzed using a variety of experimental, simulation, and modeling techniques, including in situ electrical measurement (e.g., burn-in) and advanced microscopy (e.g., structural deformation). Through transistor, Transmission Line Method (TLM), and Hall-effect measurements vs temperature, it is revealed that the mobility decrease is the primary cause of reduction of on-state performance of this GaN transistor at high temperature. Material analysis of the device under test (DUT) confirmed the absence of foreign elements from the Venus atmosphere. No inter-diffusion of the elements (including the gate metal) was observed. The insights of this work are broadly applicable to the future design, fabrication, and deployment of robust III-N devices for harsh environment operation.

Physics↗
DOE OSTI2022

Central star formation in double-peak, gas-rich radio galaxies

The respective contributions of gas accretion, galaxy interactions, and mergers to the mass assembly of galaxies, as well as the evolution of their molecular gas and star-formation activity are still not fully understood. In a recent work, a large sample of double-peak (DP) emission-line galaxies have been identified from the SDSS. While the two peaks could represent two kinematic components, they may be linked to the large bulges that their host galaxies tend to have. Star-forming DP galaxies display a central star-formation enhancement and have been discussed as compatible with a sequence of recent minor mergers. In order to probe merger-induced star-formation mechanisms, we conducted observations of the molecular-gas content of 35 star-forming DP galaxies in the upper part of the main sequence (MS) of star formation (SF) with the IRAM 30 m telescope. Including similar galaxies 0.3 dex above the MS and with existing molecular-gas observations from the literature, we finally obtained a sample of 52 such galaxies. We succeeded in fitting the same kinematic parameters to the optical ionised- and molecular-gas emission lines for ten (19%) galaxies. We find a central star-formation enhancement resulting most likely from a galaxy merger or galaxy interaction, which is indicated by an excess of gas extinction found in the centre. This SF is traced by radio continuum emissions at 150 MHz, 1.4 GHz, and 3 GHz, all three of which are linearly correlated in log with the CO luminosity with the same slope. The 52 DP galaxies are found to have a significantly larger amount of molecular gas and longer depletion times, and hence a lower star-formation efficiency, than the expected values at their distance of the MS. The large bulges in these galaxies might be stabilising the gas, hence reducing the SF efficiency. This is consistent with a scenario of minor mergers increasing the mass of bulges and driving gas to the centre. We also excluded the inwards-directed gas migration and central star-formation enhancement as the origin of a bar morphology. Hence, these 52 DP galaxies could be the result of recent minor mergers that funnelled molecular gas towards their centre, triggering SF, but with moderate efficiency.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Velocity circulation intermittency in finite-temperature turbulent superfluid helium

We study intermittency of circulation moments in turbulent superfluid helium by using experimental grid turbulence and numerical simulations of the Hall-Vinen-Bekarevich-Khalatnikov model. More precisely, we compute the velocity circulation Γ r in loops of size r laying in the inertial range. For both experimental and numerical data, the circulation variance shows a clear Kolmogorov scaling < $Γ$$^2_r$ > ~ r 8/3 in the inertial range, independently of the temperature. Scaling exponents of high-order moments are comparable, within error bars, to previously reported anomalous circulation exponents in classical turbulence and low-temperature quantum turbulence numerical simulations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

The CLAS12 Central Time-of-Flight system

The Central Time-of-Flight system for the large-acceptance CLAS12 spectrometer in Hall B at the Thomas Jefferson National Accelerator Facility is described. The system consists of a hermetic barrel of 48 scintillation counters at a radius of 25 cm from the beamline. The wedge-shaped counters are 3.4 cm wide, 3.0 cm thick, and 90 cm long, and span a range of polar angles relative to the center of the nominal target location from roughly 35° to 125°. The counters reside in the 5-T field of the CLAS12 superconducting solenoid. The bars are read out via bent light guides 1 m long on the upstream end of the counters and 1.6 m long on the downstream end. The phototubes are shielded by a multi-layer dynamical magnetic shield system to reduce the local fringe fields in the range from 400 G to 1000 G down to the level of 0.2 G at the location of the photocathodes. The average effective time resolution of the counters is 80 ps.

47 OTHER INSTRUMENTATION↗
DOE OSTI2026

Ammonia Synthesis by a Supported Iron-Lithium Hydride Precatalyst: Silicon Nitride Support Enabled Synthesis and Nitrogen Reservoir Dynamics

Amorphous silicon nitride (Si 3 N 4 ) is an unconventional support for the chemisorption of organometallic complexes and offers potential improvements in active site stability and reactivity through enhanced metal-nitrogen covalency and orbital overlap in bonding interactions with the nitride framework. Here, we show that silicon nitride-supported iron mesityl complexes display divergent reactivity compared to their silica-supported homologues, resisting metallic particle formation under reducing pretreatment conditions (exposure to excess organolithium reagents) and maintaining active iron/lithium speciation under ammonia synthesis conditions that is absent on the oxide support. When the organometallic iron complex on silicon nitride is exposed to excess n-butyllithium, iron remains isolated, catalyzing the conversion of butyllithium to lithium hydride, resulting in a divalent iron site in a polyhydride environment. In contrast, the silica-supported complex is converted to reduced iron clusters without forming persistent isolated hydrides. These structural differences lead to markedly different catalytic behaviors under ammonia synthesis conditions. The Li/Fe/Si 3 N 4 catalyst is highly active (7.5 mol NH 3 /mol Fe/h at 300 °C, 10 bar, or 46 mol NH 3 /mol Fe/h at 400 °C, 10 bar), while both the silica-supported analog and the nonlithiated Si 3 N 4 -supported species are inactive. Notably, this activity is enhanced relative to previously reported iron-lithium hydride composite catalysts (0.43–4.1 mol NH 3 /mol Fe/h at 300 °C, 10 bar) and relative to the industrial benchmark promoted iron catalyst KM1 (3.0 mol NH 3 /mol Fe/h at 400 °C, 10 bar). The catalyst activation and LiH/LiNH x nitrogen reservoir dynamics for Li/Fe/Si 3 N 4 are studied by X-ray Absorption, Mössbauer, and in situ DRIFT spectroscopies and isotopic exchange kinetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

A control-oriented combustion model framework for compression ignition engines operating on low-reactivity fuel

This work focuses on zero-dimensional modeling of the heat release rate in a compression ignition engine operating on gasoline-like fuels. Due to the properties of gasoline, such as high volatility and longer ignition delay than diesel, the injection strategies can vary significantly from the operation with conventional diesel fuel. Different injection strategies are commonly used to achieve varying degrees of in-cylinder stratification in order to shape the combustion event and maximize efficiency. The proposed zero-dimensional combustion model was developed to account for the different stages in combustion caused by the fuel stratification. As the ignition delay model is an integral part of the entire combustion process and significantly affects the prediction accuracy, special attention has been paid to local phenomena influencing ignition delay. A one-dimensional spray model by Musculus and Kattke was employed in conjunction with a Lagrangian tracking approach in order to estimate the local air–fuel ratio within the spray tip, as a proxy for reactivity. The local air–fuel ratio, in-cylinder temperature and pressure were used in an integral fashion to estimate the ignition delay. Heat release rates were modeled using first-order non-linear differential equations. The proposed combustion model was validated against experimental data of a heavy-duty compression ignition engine with up to three injection events at mostly 1038 r/min and 14 bar brake mean effective pressure. Further validation of the model was carried out at other engine loads and speeds. Model prediction errors in CA50 of less than 1 °CA across all conditions were found. Modeling results of other combustion metrics such as combustion duration and indicated mean effective pressure are also highly satisfactory. In addition, the model has been shown to be capable of estimating the ringing intensity for most conditions.

Pamminger, Michael↗
DOE OSTI2022

Plastic Waste Product Captures Carbon Dioxide in Nanometer Pores

We discuss, plastic waste (PW) and increasing atmospheric carbon dioxide (CO 2 ) levels are among the top environmental concerns presently facing humankind. With an ambitious 2050 zero-CO 2 emissions goal, there is a demand for economical CO 2 capture routes. Here we show that the thermal treatment of PW in the presence of potassium acetate yields an effective carbon sorbent with pores width of 0.7–1.4 nm for CO 2 capture. The PW to carbon sorbent process works with single or mixed streams of polyolefin plastics. The CO 2 capacity of the sorbent at 25 °C is 17.0 ± 1.1 wt % (3.80 ± 0.25 mmol g –1 ) at 1 bar and 5.0 ± 0.6 wt % (1.13 ± 0.13 mmol g –1 ) at 0.15 bar, and it regenerates upon reaching 75 ± 5 °C. The CO 2 capture cost from flue gas via this technology is estimated to be <$21 ton –1 CO 2 , much lower than competing CO 2 capture technologies. Hence, this PW-derived carbon material should find utility in the capture of CO 2 from point sources of high CO 2 emissions while providing a use for otherwise deleterious PW.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2024

Evaluation of the Performance and Exhaust Emissions of a 4 Cylinder CI Engine Operating With Dimethyl Ether (DME) and Propane Blends

In response to stringent emissions regulations and the need for higher efficiency engines, the utilization of DME and propane fuel blends in compression ignition (CI) engines has gained interest in the automotive industry. In this study, a range of DME-propane blends are explored in a CI combustion strategy at high injection pressures. A GT-Power model of a 2.2 L Hyundai CI engine was developed to facilitate evaluation of the impacts of variations of DME and propane blends at a light and medium engine speed-torque-load operating condition; specifically at 1500 rpm, 50 Nm and 2.84 bar brake mean effective pressure (BMEP); and 2000 rpm, 150 Nm, 8.53 bar BMEP speed-torque-load combination. Here, the GT-Power model was validated using Computational Fluid Dynamics (CFD) simulations. The results indicate that high diesel-like efficiencies can be achieved with a 100% DME mass substitution and up to 50% propane-DME blends could be implemented without a significant penalty on engine performance indicators. Significant brake specific nitrogen oxides (BSNOx) reductions were also observed along with reductions in carbon dioxide (CO2) and soot when leveraging these fuel blends.

computational fluid dynamics↗
DOE OSTI2021

Evaluation of Modular and Scalable Downstream Passage Systems for Silver American Eels

Implementation of effective downstream passage for silver-phase American Eel (Anguilla rostrata) at hydropower dams using methods that are economically feasible has been a challenge for many project owners. Due to the potential for high mortality rates during turbine passage, resource agencies have focused on mandatory prescriptions that prevent entrainment by physically excluding eels (i.e., narrow trash rack bar spacing) or eliminating turbines as a passage route (i.e., unit shutdowns at night when eel movement is greatest). Both of these options can significantly impact the economic viability of a project. Consequently, there is a need for alternative technologies that can provide safe and effective downstream passage for silver eels without having a major impact on the ability of a project to generate power during the eel downstream migration period. This need is of particular concern now because about 300 hydropower projects within the range of American Eel freshwater habitats are scheduled to be relicensed by the Federal Energy Regulatory Commission (FERC) in the next 15 years

13 HYDRO ENERGY↗
DOE OSTI2022

Parton distribution function uncertainties in theoretical predictions for far-forward tau neutrinos at the Large Hadron Collider

New experiments dealing with neutrinos in the far-forward region at the Large Hadron Collider (LHC) are under design or already in preparation. Two of them, FASERν and SND@LHC, are expected to be active during Run 3 and have the potential to detect the interactions of ν and $\bar {v}$ that come from high-energy collisions in one of the LHC interaction points, extracted along the direction tangent to the beam line. Tau neutrinos and antineutrinos come predominantly from $D^{±}_{s}$ production in pp collisions, followed by the leptonic decay of these mesons. Neutrino pseudorapidities in the range of η > 6.9 and η > 8.9 are relevant to these future experiments. At such pseudorapidities at high energies, QCD theoretical predictions for the flux of ν τ plus $\bar {v}_τ$ rely on parton distribution functions (PDFs) in a combination of very small and large parton–x values. We evaluate PDF un certainties affecting the flux of ν τ + $\bar {v}_τ$ produced by $D^{±}_{s}$ decay in the far forward region at the LHC. Next-to-leading order (NLO) QCD uncertainties are included in the calculation of $D^{±}_{s}$ production and NLO PDF sets are used for consistency. The theoretical uncertainty associated with the 40 PDF sets of the PROSA19 group amounts to ±(20 – 30)% for the (ν τ + $\bar {v}_τ$) number of charged-current (CC) events. Scale uncertainties are much larger, resulting in a range of CC event predictions from ~70% lower to ~90% higher than the central prediction. A comparison of the predictions with those obtained using as input the central PDFs from the 3-flavour NLO PDF sets of the CT14, ABMP16 and NNPDF3.1 collaborations show that far-forward neutrino energy distributions vary by as much as a factor of ~2 – 4 relative to the PROSA19 predictions at TeV neutrino energies. The Forward Physics Facility in the high luminosity LHC era will provide data capable of constraining NLO QCD evaluations with these PDF sets.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Production of Creep-Resistant FeCrAl-ODS

Four ODS FeCrAl alloys with base alloy composition Fe-16Cr-4Al-2Mo-0.2Y (wt.%) were mechanically alloyed with minor additions of CeO 2 and Y 2 O 3 additions and were successfully extruded into rectangular-shaped bars. Two oxide compositions were explored, which were designated NC with oxide addition of 0.5CeO 2 plus 0.2Yin solution of the base alloy powder and PC with additions of 0.5CeO 2 and 0.7Y 2 O 3 to elevate the O level. The microstructure of both alloys revealed by SEM and EBSD to consist of very small grains with sizes of ~450-520 nm and weak texture components. Sub-size tensile specimens fabricated from both alloys were tensile tested from room temperature to 800ºC. The results for both alloys from room temperature to 400ºC showed very high strengths, but low ductilities, especially uniform strain. From 500ºC to 800ºC, the strengths decreased rapidly, and the ductilities increased significantly. The reason for the rapid decreases in tensile strengths above 500ºC for both alloys is not clear, but will require advanced characterization techniques including atom probe tomography, to determine the size and number density of the nano-size oxide particles, and TEM/EFTEM, for investigating the dispersion of nano-size oxide particles on grain boundaries to assess the Zener grain boundary pinning effect, which will hinder grain coarsening at high temperatures that may enhance the Hall Petch strengthening mechanism.

36 MATERIALS SCIENCE↗
DOE OSTI2023

L-H transition studies in tritium and deuterium–tritium campaigns at JET with Be wall and W divertor

The recent deuterium–tritium campaign in JET-ILW (DTE2) has provided a unique opportunity to study the isotope dependence of the L-H power threshold in an ITER-like wall environment (Be wall and W divertor). Here we present results from dedicated L-H transition experiments at JET-ILW, documenting the power threshold in tritium and deuterium–tritium plasmas, comparing them with the matching deuterium and hydrogen datasets. From earlier experiments in JET-ILW it is known that as plasma isotopic composition changes from deuterium, through varying deuterium/hydrogen concentrations, to pure hydrogen, the value of the line averaged density at which the threshold is minimum, ${\bar n_{{\text{e}},{\text{min}}}}$, increases, leading us to expect that ${\bar n_{{\text{e}},{\text{min}}}}$(T) < ${\bar n_{{\text{e}},{\text{min}}}}$(DT) < ${\bar n_{{\text{e}},{\text{min}}}}$(D) < ${\bar n_{{\text{e}},{\text{min}}}}$(H). The new power threshold data confirms these expectations in most cases, with the corresponding ordering of the minimum power thresholds. We present a comparison of this data to power threshold scalings, used for extrapolation to future devices such as ITER and DEMO.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗