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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

On the Retrieval and Analysis of Multilevel Clouds

An accurate satellite retrieval of cloud properties depends upon the detection and analysis of multilayered, overlapping cloud systems that surface observations show to be common. Multiple cloud layers are often found, for instance, in frontal situations, where cirrus overlays boundary layer convective cloud or low-to mid-level stratus cloud. Surface observers (Hahan et al., 1982) indicate that over ocean in the Northern Hemisphere between 30 deg. N and 60 deg. N, 51 percent of observations are of multilevel clouds. A satellite analysis by Coakley (1983) over the Pacific Ocean finds that more than 50 percent of 500 (250 sq km) frames exhibit evidence of multilayered cloud systems. The questions addressed in this study are the following: What error is introduced when inferring the cloud pressure from a Field-Of-View (FOV) that contains some arbitrary amount of transparent cloud overlaying a lower-level black cloud, such as stratus, by making the assumption that there is only a single cloud layer in the FOV, and what may be done to improve the cloud retrieval? The CO2 slicing methods (e.g. McCleese and Wilson, 1976; Smith and Platt, 1978; Chahine, 1974) have been shown to provide accurate means of inferring cirrus cloud altitude from passive infrared radiance measurements. The CO2 techniques have been applied to radiometric data from several instruments, notably the High Resolution Infrared Radiometric Sounder (HIRS/2, hereafter referred to as HIRS), the VISSR Atmospheric Sounder (VAS) (e.g., Menzel et al., 1983; Wylie and Menzel, 1989), and most recently to the High Resolution Interferometer Sounder (HIS) (Smith and Frey, 1990). The methods take advantage of the fact that infrared CO2 sounding channels spaced closely in wavenumber each have varying opacity to CO2, thereby causing each channel to be sensitive to a different level in the atmosphere. The techniques have been shown to be effective for single-layered, nonblack, mid- to high-level clouds such as cirrus, but are generally applied operationally to any given cloud occurrence. The CO2 slicing algorithms are most accurate for clouds than occur in a single, well-defined layer, or for multi-layered cloud cases in which the uppermost cloud layer is nearly black. Significant cloud height retrieval errors may ensue if the HIRS Field-Of-View (FOV) is cotaminated with low cloud. McCleese and Wilson (1976) have shown that the retrieved cloud height for the case of multiple cloud layers is a weighted average of the cloud heights actually present. The weight is approximately proportional to the product of the cloud heigt and the effective cloud amount. The effect of their result is that the uppermost cloud layer dominates the cloud pressure retrieval. Beyond stating that the higher cloud dominates the cloud pressure retrieval, there is no quantitative information to provide a way of estimating the errors in cloud pressure retrieval one should expect for certain common multilevel cloud situations or any suggestions on how to reduce the errors. In this paper we estimate the magnitude of the errors and use a simple algorithm to reduce the errors in optically thin cloud height retrival.

Baum, Bryan A.↗
NASA NTRS1999

Development and Validation of a Polar Cloud Algorithm for CERES

The objectives of this project, as described in the original proposal, were to develop an algorithm for diagnosing cloud properties over snow- and ice-covered surfaces, particularly at night, using satellite radiances from the Advanced Very High Resolution Radiometer (AVHRR) and High-resolution Infrared Radiation Sounder (HIRS) sensors. Products from this algorithm include a cloud mask and additional cloud properties such as cloud phase, amount, and height. The SIVIS software package, developed as a part of the CERES project, was originally the primary tool used to develop the algorithm, but as it is no longer supported we have had to pursue a new tool to enable the combination and analysis of collocated radiances from AVHRR and HIRS. This turned out to be a much larger endeavor than we expected, but we now have the data sets collocated (with many thanks to B. Baum for the fundamental code) and we have developed a nighttime cloud detection algorithm. Using this algorithm we have also computed realistic-looking cloud fractions from AVHRR brightness temperatures. A method to identify cloud phase has also been implemented. Atmospheric information from the TIROS Operational Vertical Sounder (TOVS) Polar Pathfinder Data Set, which includes temperature and moisture profiles as well as surface information, provides information required for determining cloud-top height.

Source record↗
NASA NTRS1997

Ice velocity at the ice front of the Filchner-Ronne Ice Shelf, Antarctica, as observed with ERS interferometry

ERS images of the two ends of the ice front of the Filchner-Ronne ice shelf (Antarctica) were utilized interferometrically to study the deformation rate of the ice shelf in response to viscous creep. On the western bank of Berkner Island (BI), near Hemmen Ice Rise (HIR), a time series of ERS data acquired in February 1992, in both ascending and descending mode, and with a three-day time interval, were utilized to map the ice velocity in two dimensions. Finite-element ice-shelf flow simulations are compared with the ERS interferograms to interpret the ice motion in terms of the physical constraints on ice-shelf flow. The efforts to fit artificial interferograms generated with model velocity output suggest that the flow regime is strongly influenced by three processes. First, a void-creation process responsible for rifts at coastal margins tends to uncouple the ice shelf from the ice rise and neighboring coast of BI. Secondly, sea ice within the void space appears to act as a binding agent between discrete ice-shelf fragments, allowing rigid-body rotations of these fragments. Third, strain rates appear to be enhanced in a narrow zone adjacent to HIR, implying significant strain softening along the boundary. It is believed that synthetic aperture radar (SAR) interferogram/model intercomparison represents a powerful impetus towards the development of better, more physically realistic ice-shelf flow models.

Rignot, Eric↗
NASA NTRS1999

Comparisons of Upper Tropospheric Humidity Retrievals from TOVS and METEOSAT

Two different methods for retrieving Upper Tropospheric Humidities (UTH) from the TOVS (TIROS Operational Vertical Sounder) instruments aboard NOAA polar orbiting satellites are presented and compared. The first one, from the Environmental Technology Laboratory, computed by J. Bates and D. Jackson (hereafter BJ method), estimates UTH from a simplified radiative transfer analysis of the upper tropospheric infrared water vapor channel at wavelength measured by HIRS (6.3 micrometer). The second one results from a neural network analysis of the TOVS (HIRS and MSU) data developed at, the Laboratoire de Meteorologie Dynamique (hereafter the 3I (Improved Initialization Inversion) method). Although the two methods give very similar retrievals in temperate regions (30-60 N and S), an absolute bias up to 16% appears in the convective zone of the tropics. The two datasets have also been compared with UTH retrievals from infrared radiance measurements in the 6.3 micrometer channel from the geostationary satellite METEOSAT (hereafter MET method). The METEOSAT retrievals are systematically drier than the TOVS-based results by an absolute bias between 5 and 25%. Despite the biases, the spatial and temporal correlations are very good. The purpose of this study is to explain the deviations observed between the three datasets. The sensitivity of UTH to air temperature and humidity profiles is analysed as are the clouds effects. Overall, the comparison of the three retrievals gives an assessment of the current uncertainties in water vapor amounts in the upper troposphere as determined from NOAA and METEOSAT satellites.

Escoffier, C.↗
DOE OSTI2024

Electrochemical Capacitance Traces with Interlayer Spacing in Two‐dimensional Conductive Metal–Organic Frameworks

Abstract Electrically conductive metal–organic frameworks (MOFs) are promising candidates for electrochemical capacitors (EC) for fast energy storage due to their high specific surface areas and potential for redox activity. To maximize energy density, traditional inorganic pseudocapacitors have utilized faradaic processes in addition to double‐layer capacitance. Although conductive MOFs are usually comprised of redox active ligands which allow faradaic reactions upon electrochemical polarization, systematic studies providing deeper understanding of the charge storage processes and structure‐function relationships have been scarce. Here, we investigate the charge storage mechanisms of a series of triazatruxene‐based 2D layered conductive MOFs with variable alkyl functional groups, Ni 3 (HIR 3 ‐TAT) 2 (TAT=triazatruxene; R=H, Et, n ‐Bu, n ‐Pent). Functionalization of the triazatruxene core allows for systematic variation of structural parameters while maintaining in‐plane conjugation between ligands and metals. Specifically, R groups modulate interlayer spacing, which in turn shifts the charge storage mechanism from double‐layer capacitance towards pseudocapacitance, leading to an increase in molar specific capacitance from Ni 3 (HIH 3 ‐TAT) 2 to Ni 3 (HIBu 3 ‐TAT) 2 . Partial exfoliation of Ni 3 (HIBu 3 ‐TAT) 2 renders redox active ligand moieties more accessible, and thus increases the dominance of faradaic processes. Our strategy of controlling charge storage mechanism through tuning the accessibility of redox‐active sites may motivate further design and engineering of electrode materials for EC.

Su, Alice Y.↗
DOE OSTI2024

Electrochemical Capacitance Traces with Interlayer Spacing in Two‐dimensional Conductive Metal–Organic Frameworks

Abstract Electrically conductive metal–organic frameworks (MOFs) are promising candidates for electrochemical capacitors (EC) for fast energy storage due to their high specific surface areas and potential for redox activity. To maximize energy density, traditional inorganic pseudocapacitors have utilized faradaic processes in addition to double‐layer capacitance. Although conductive MOFs are usually comprised of redox active ligands which allow faradaic reactions upon electrochemical polarization, systematic studies providing deeper understanding of the charge storage processes and structure‐function relationships have been scarce. Here, we investigate the charge storage mechanisms of a series of triazatruxene‐based 2D layered conductive MOFs with variable alkyl functional groups, Ni 3 (HIR 3 ‐TAT) 2 (TAT=triazatruxene; R=H, Et, n ‐Bu, n ‐Pent). Functionalization of the triazatruxene core allows for systematic variation of structural parameters while maintaining in‐plane conjugation between ligands and metals. Specifically, R groups modulate interlayer spacing, which in turn shifts the charge storage mechanism from double‐layer capacitance towards pseudocapacitance, leading to an increase in molar specific capacitance from Ni 3 (HIH 3 ‐TAT) 2 to Ni 3 (HIBu 3 ‐TAT) 2 . Partial exfoliation of Ni 3 (HIBu 3 ‐TAT) 2 renders redox active ligand moieties more accessible, and thus increases the dominance of faradaic processes. Our strategy of controlling charge storage mechanism through tuning the accessibility of redox‐active sites may motivate further design and engineering of electrode materials for EC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Data driven investigation to understand the influence of total solids on biological biogas upgrading

In situ biogas upgrading achieves CO 2 conversion to CH 4 via hydrogenotrophic methanogenesis; however, gas-liquid mass transfer constraints limit the upgrading performance. Recognizing that optimization studies often underrepresent the effects of total solids (TS) and organic loading rate (OLR), this study undertook a holistic, statistics driven assessment of operating conditions for in situ H 2 assisted biogas upgrading, centering the analysis on TS and OLR. A dataset of 31 studies was compiled and comprised 99 observations. A rigorous analytical framework was employed, combining data standardization, fixed- and random-effects (REML) weighted regressions with cluster-robust errors, stratified analyses, and machine learning. Mixed-effects meta regression indicated that TS was the main factor explaining differences of methane fraction (CH 4 %) when considering the between studies heterogeneity. Focusing on a near-stoichiometric subset (H 2 /CO 2 ≈ 4:1), TS remained significant. Stratified results showed a stronger negative relationship between TS and CH 4 % in UASB reactors than in CSTRs, with a negative effect under mesophilic conditions and no significant effect under thermophilic conditions. A Random Forest model corroborated the statistical findings, consistently ranking H 2 /CO 2 ratio, OLR, TS, and hydrogen injection rate (HIR) as the most influential predictors. These findings delineate trends across increasing TS levels, particularly between 1% and 10%, and provide preliminary insights for TS above 15% in in situ biogas upgrading. They further provide insights for the influence of TS by reactor type and temperature, thereby advancing the evidence base for implementing biological CO 2 conversion to CH 4 in practice.

In situ biogas upgrading↗
DOE OSTI2023

A Theoretical Study of NH 2 Radical Reactions with Propane and Its Kinetic Implications in NH 3 -Propane Blends’ Oxidation

The reaction of NH 2 radicals with C 3 H 8 is crucial for understanding the combustion behavior of NH 3 /C 3 H 8 blends. In this study, we investigated the temperature dependence of the rate coefficients for the hydrogen abstraction reactions of C 3 H 8 by NH 2 radicals using high-level theoretical approaches. The potential energy surface was constructed at the CCSD(T)/cc-pV(T, Q)//M06-2X/aug-cc-pVTZ level of theory, and the rate coefficients were computed using conventional transition state theory, incorporating the corrections for quantum tunneling and hindered internal rotors (HIR). The computed rate coefficients showed a strong curvature in the Arrhenius behavior, capturing the experimental literature data well at low temperatures. However, at T > 1500 K, the theory severely overpredicted the experimental data. The available theoretical studies did not align with the experiment at high temperatures, and the possible reasons for this discrepancy are discussed. At 300 K, the reaction of NH 2 with C 3 H 8 predominantly occurs at the secondary C-H site, which accounts for approximately 95% of the total reaction flux. However, the hydrogen abstraction reaction at the primary C-H site becomes the dominant reaction above 1700 K. A composite kinetic model was built, which incorporated the computed rate coefficients for NH 2 + C 3 H 8 reactions. The importance of NH 2 + C 3 H 8 reactions in predicting the combustion behavior of NH 3 /C 3 H 8 blends was demonstrated by kinetic modeling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Size-resolved process understanding of stratospheric sulfate aerosol following the Pinatubo eruption

Stratospheric sulfate aerosol produced by volcanic eruptions plays important roles in atmospheric chemistry and the global radiative balance of the atmosphere. The simulation of stratospheric sulfate concentrations and optical properties is highly dependent on the chemistry scheme and microphysical treatment. In this work, we implemented a sophisticated gas-phase chemistry scheme (full chemistry, FC) and a 5-mode version of the Modal Aerosol Module with Prognostic Stratospheric Aerosol (MAM5-PSA) for the interactive treatment of stratospheric sulfate aerosol in the Department of Energy's Energy Exascale Earth System Model version 2 (E3SMv2) model to better simulate the chemistry-aerosol feedback following the Pinatubo eruption, and to compare it against a simulation using simplified chemistry (SC) and the default 4-mode version of the Modal Aerosol Module (MAM4). MAM5-PSA experiments were found to better capture the stratospheric sulfate burden from the eruption of the volcano to the end of 1992 as compared to the High-resolution Infrared Sounder (HIRS) observations, and the formation of sulfate in MAM5-PSA with FC (with an additional OH replenishment reaction) was significantly faster than in MAM4 with FC. Analyses of microphysical processes indicate that more sulfate aerosol mass was generated in total in FC experiments than in SC experiments. MAM5-PSA performs better than MAM4 in simulation of aerosol optical depth (AOD); AOD anomalies from the MAM5-PSA experiment have better agreement with observations. The simulated largest changes in global mean net radiative flux at the top of the atmosphere following the eruption were about −3 W m −2 in MAM5-PSA experiments and roughly −1.5 W m −2 in MAM4 experiments.

AEROSOL↗
NASA NTRS1973

High resolution infrared radiation sounder for the Nimbus F spacecraft

The activities on the HIRS program are described for the period of July through September, 1973. Completion of design activity and early fabrication effort on the protoflight unit were the major efforts. Operation of the engineering model in spacecraft integration tests was completed during July and August, after which the unit was returned for added test and evaluation.

Koenig, E. W.↗
NASA NTRS1976

Sounder design considerations in the selection of temperature sensing channels

Simulation studies on the performance of IR sounders under varying conditions of cloud cover and cloud heights are carried out for Nimbus 6. An analytic function is derived for calculating the relative response to cloud height errors for arbitrary cloud-sensing channels. Based on the values of the response function, the best choice of channels for determining cloud amounts are obtained. An algorithm is described for determining cloud heights, and the sensitivity of cloud-height sensing channels is tested. It is found that for the HIRS instrument, the most transparent channel in the 4.3-micron band is optimal for adjusting cloud heights, while the channel in the 15-micron band peaking closest to the surface is best for determining cloud amounts

Halem, M.↗
NASA NTRS1975

The Nimbus 6 data catalog. Volume 1: 12 June 1975 through 31 August 1975. Data orbits 1 through 1082

Subsections 1.2 through 1.10 of this catalog summarize the operational highlights of the individual experiments, present preliminary experiment results, and call attention to known data anamolies. Section 2 lists the on-off times for each experiment and provides a method for determining the geographical coverage of each experiment. Section 3 shows selected HIRS, SCAMS and ESMR images, and Section 4 presents THIR montages. Section 5 presents corrections to The Nimbus 6 User's Guide.

Source record↗
NASA NTRS1980

Feasibility of modifying the high resolution infrared radiation sounder (HIRS/2) for measuring spectral components of Earth radiation budget

The concept of adding four spectral channels to the 20 channel HIRS/2 instrument for the purpose of determining the origin and profile of radiant existence from the Earth's atmosphere is considered. Methods of addition of three channels at 0.5, 1.0 and 1.6 micron m to the present 0.7 micron m visible channel and an 18-25 micron m channel to the present 19 channels spaced from 3.7 micron m to 15 micron m are addressed. Optical components and physical positions were found that permit inclusion of these added channels with negligible effect on the performance of the present 20 channels. Data format changes permit inclusion of the ERB data in the 288 bits allocated to HIRS for each scan element. A lamp and collimating optic assembly may replace one of the on board radiometric black bodies to provide a reference source for the albedo channels. Some increase in instrument dimensions, weight and power will be required to accommodate the modifications.

Koenig, E. W.↗
NASA NTRS1981

Cloud retrieval using infrared sounder data - Error analysis

An error analysis is presented for cloud-top pressure and cloud-amount retrieval using infrared sounder data. Rms and bias errors are determined for instrument noise (typical of the HIRS-2 instrument on Tiros-N) and for uncertainties in the temperature profiles and water vapor profiles used to estimate clear-sky radiances. Errors are determined for a range of test cloud amounts (0.1-1.0) and cloud-top pressures (920-100 mb). Rms errors vary by an order of magnitude depending on the cloud height and cloud amount within the satellite's field of view. Large bias errors are found for low-altitude clouds. These bias errors are shown to result from physical constraints placed on retrieved cloud properties, i.e., cloud amounts between 0.0 and 1.0 and cloud-top pressures between the ground and tropopause levels. Middle-level and high-level clouds (above 3-4 km) are retrieved with low bias and rms errors.

Wielicki, B. A.↗
NASA NTRS1980

Temperature retrievals from TIROS-N

A nonstatistical, nonlinear iterative scheme, has been developed, based on the methods of Chahine (1970), to retrieve surface temperature, vertical temperature profile and cloud distribution from TIROS-N HIRS 2/MSU observations. Fundamental to the technique is the ability to accurately calculate clear column radiances given atmospheric and surface characteristics. The cloud filtering algorithm, making simultaneous use of IR 15 micron channels and microwave channels, allows accurate infrared retrievals in the presence of up to 80 percent cloud cover. Details for the iterative scheme are presented together with preliminary results from analysis of TIROS-N data.

Susskind, J.↗
NASA NTRS1981

Comparison of observed and computed brightness temperatures for the HIRS2 and MSU sounders on TIROS-N

Given the radiosonde temperature and humidity profile, brightness temperatures for the temperature sounding IR channels on HIRS 2 were calculated. The temperature profile was interpolated to 53 levels between 1000 and 30 mb assuming temperature to be linear in the logarithm of the pressure between the mandatory levels. The 11 levels above 30 mb were extrapolated according to climatology. The surface was taken to be the climatological sea surface temperature. The specific humidity was interpolated between mandatory levels assuming a p(n) dependence. A specific humidity corresponding to a climatological water vapor mixing ratio of 2 ppmv was assumed at and above 100 mb. Zonally averaged climatological ozone profiles were used to compute the ozone component of the transmittance.

Susskind, J.↗
NASA NTRS1981

Convergent-tapered annular seals - Analysis for rotordynamic coefficients

A combined analytical-computational solution based on Hirs' lubrication equations (1970) is developed for tapered high-pressure annular seals typical of neck-ring and interstage seals employed in multistage centrifugal pumps. The results obtained coincide with earlier straight seal results at taper angles approaching zero and, under comparable assumptions, agree with Fleming's (1977) predictions for the direct stiffness coefficients. An optimal taper angle is shown to exist with respect to direct stiffness and the ratio of direct stiffness to leakage. Stiffness increases of about 85% are predicted.

Childs, D. W.↗
NASA NTRS1982

Determination of the horizontal and vertical distribution of clouds from infrared satellite sounding data

A numerical algorithm, based on a physical inversion of the radiative transfer equation, is developed to retrieve the global distribution of the horizontal cloud cover, the cloud-top pressure levels and their temperature. The algorithm makes use of infrared and microwave temperature sounding data to derive the clear-column vertical temperature profiles and then uses the same infrared sounding data to obtain the corresponding cloud parameters. Experimental verification of this method is carried out using data from the High resolution Infrared Sounder (HIRS) and the Microwave Sounding Unit (MSU) operating on the NOAA weather satellite system.

Chahine, M. T.↗