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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Novel Functional Thermal Energy Storage Materials for Buildings Applications

The leakage of solid-liquid phase change materials (PCMs) tremendously limits their long-term application in thermal energy storage (TES). In this work, we present durable and form-stable shape-stabilized PCMs (ss-PCMs) for TES in building envelopes. These ss-PCMs are fabricated by encapsulating polyethylene glycol (PEG) consisting of different molecular weights within mesoporous magnesium oxide and silica dioxide. For the first time, the phase transition temperature (Tt) of ss-PCMs has been fine-tuned synthetically to be comfortable to building occupants by utilizing PEG blends with molecular weights of 600 and 800 g/mol. Several parameters, including surface hydrophilicity/hydrophobicity, surface area, and PCM loading percentage, have been studied to maximize the latent heat enthalpy for high energy efficiency and maintain form stability. The best ss-PCM candidate with suitable Tt and appreciable latent heat enthalpy exhibits a repeatable phase change behavior for up to 1,000 thermal cycles without leakage, which provides a promising solution for durable TES in buildings. The Tt tunability extends its application over a wider temperature range beyond buildings.

building envelope↗

Corrosion-Resistant Plug Materials for Geothermal Well Fluid Control

Conventional cements and plugs are challenged by corrosion in CO 2 -rich and extreme geothermal environments, due to the hostile chemistry and high temperatures. Thermite-based sealing and well intervention technologies are being applied in the oil and gas industry, combining the energy delivery capability of thermite materials with the sealing characteristics of low melt temperature alloys. The thermite reaction products (ceramics) and the sealing alloys used in these plugs both have very attractive corrosion properties, and their operating envelopes extend into geothermal conditions. Thermite plugs and platforms, without supplemental sealing materials, have been considered for nuclear waste isolation, carbon sequestration, and geothermal applications due to the geochemical stability of the ceramic product and its very high service temperature. This study addresses corrosion resistance of the thermite reaction products. A range of engineered thermite systems which yield thermite reaction products including pure aluminum oxide, feldspar, or aluminosilicate solid solutions (in addition to the iron produced in thermite reactions) was developed. These materials were evaluated for their strong acid resistance (pH 1), carbonate resistance (sodium carbonate) and thermal shock resistance (600 °C heating → cold water quenching repeated three times). Performance of different materials was evaluated based on the changes in mechanical properties, water-fillable porosity, phase changes under stress conditions. The aluminosilicate product exhibited very good corrosion resistance, both from material loss and strength perspectives, while the other products performed with varying degrees of stability. This paper presents the results of the thermite corrosion studies and describes the novel tools being deployed, and under development, to satisfy challenging barrier and intervention applications.

02 PETROLEUM↗

Experimental Operation of a Prototype 750C Advanced Chloride Molten Salt Bellows Valve

To achieve DOE 2030 SunShot targets that reduce the cost of liquid-based solar by an additional 40% to 70% beyond 2018 costs, a more reliable, highly manufacturable flow valve, capable of achieving operational temperatures of >700°C is required [1]. This paper investigates the development of an innovative high-temperature chloride molten salt valve, with operation up to 750°C. This valve is intended to be employed within Gen 3 CSP liquid-based thermal energy storage (TES) systems as well as Gen 4 modular salt reactor (MSR) technologies. This work details the general design and flow testing of a bellows-seal flow control valve (FCV). This design includes an integrated closed-loop thermal control system to ensure robust design for freeze-thaw cycles. The self-contained thermal management STM system, is unique in the salt valve industry since it is an integrated solution to provide a consistent, repeatable alternative to typical heat tracing. Additionally, the design includes the employment of a novel heat pipe valve stem to facilitate enhanced passive thermal management into the valve assembly. This valve stem heat pipe is designed to facilitate natural circulation within the bonnet to ensure robust operation, during both nominal and transient thermal operation. The valve body and trim will be designed using SS316H, consistent with Flowserve Corporation’s existing product base and is code qualified but will utilize clad material for materials corrosion, manufacturing cost reduction and compatibility to ensure design flexibility. A test campaign was performed in this investigation utilizing a novel 750°C ternary chloride (20%NaCl/40%MgCl2/40%KCl by mol. wt. %) molten salt flow loop. A discussion about the design and installation of the valves within this test bed is provided for this investigation. Valve test results from this study assessed Cv curves as well as multiple actuator cycles, under varying thermodynamic and operational mode conditions, which would be characteristic within a commercial molten salt facility. The results indicate nominal operation for the baseline design, though improved performance and reliability is expected with the full designed FCV.

Armijo, Kenneth (ORCID:0000000346832147)↗

Electrically-nonlinear composite material

Low-temperature sinter of semiconductor and polymer resin is useful in manufacture of circuit boards, cables, and electroexplosive devices. Material can absorb large amounts of heat and can withstand repeated exposures to electrostatic discharges with little deteriorating effects. These characteristics offer significant advantages over high-temperature-sintered, metal-oxide semiconducting materials.

Menichelli, V. J.↗

Advanced radiator concepts feasibility demonstration

An innovative pumped loop concept for 600 K space power system radiators is under development utilizing direct contact heat transfer, which facilitates repeated startup/shutdown of the power system without complex and time-consuming coolant thawing during power startup. The melting/freezing process of Li in a NaK flow was studied experimentally to demonstrate the Li/NaK radiator feasibility during startup (thawing) and shutdown (cold-trapping). Results of the vapor grown carbon fiber/composite thermal conductivity measurements are also presented.

Rhee, Hyop S.↗

Effects of Martian Surface Materials on the Thermal Decomposition of Hydrogen Peroxide

While hydrogen peroxide (H2O2) has been detected in the martian atmosphere, it has not been detected in surface materials. Since the Viking lander mission, we have sent instruments to Mars with the capability to detect H2O2. The Sample Analysis at Mars (SAM) instrument onboard the Curiosity Rover and Thermal and Evolved Gas Analyzer (TEGA) instrument on the Phoenix lander both detected water and oxygen releases from analyzed sediments but whether or not peroxide could be the source of these gases has not been investigated. We are investigating the possible presence of H2O2 in martian materials by analyzing Mars-relevant minerals that have been mixed with hydrogen peroxide using lab instruments configured as analogs to Mars mission instruments. The object of this research is to use lab instruments to find the effects of Mars analog minerals on hydrogen peroxide gas release temperatures, specifically gas releases of water and oxygen and also determine the effect of the peroxide on the minerals. Data that we get from the lab can then be compared to the data collected from Mars. The minerals hematite, siderite, San Carlos olivine, magnetite and nontronite were chosen as our Mars analog minerals. ~20 mg of analog Mars minerals with 5μl of 50% H2O2, and were either run immediately or placed in a sealed tube for 2, 4, or 9 days to look for changes over time with two reps being done at each time step to determine repeatability. Each sample was heated from -60 degC to 500 degC at 20 degC/min and the evolved gases were monitored with a mass spectrometer. Each sample was also analyzed with an X-ray diffraction instrument to look for changes in mineralogy. Preliminary results show three potential outcomes: 1) peroxide has no effect on the sample (e.g., hematite), 2) the mineral is unaffected but catalyzes peroxide decomposition (magnetite, siderite), or 3) peroxide alters the mineral (pyrrhotite, San Carlos olivine).

Archer, P. D., Jr.↗

Heat transfer enhancement in channels with turbulence promoters

Repeated rib-roughness elements have been used in advanced turbine cooling designs to enhance the internal heat transfer. Often the ribs are perpendicular to the main flow direction so that they have an angle-of-attack of 90 degrees. The objective of this investigation was to determine the effect of rib angle-of-attack on the pressure drop and the average heat-transfer coefficients in the fully developed turbulent air flow in a square duct with two opposite rib-roughened walls for Reynolds numbers varied from 7,000 to 90,000. The rib height-to-equivalent diameter ratio was kept at a constant value of 0.063, the rib pitch-to-height ratio was varied from 10 to 20, and the rib angle-of-attack (alpha) was varied from 90 to 60 deg to 45 to 30 deg, respectively. The thermal-performance comparison indicated that the increased heat conductance for the rib with an oblique angle to the flow (alpha = 45 deg - 30 deg) was about 10-20 percent higher than the rib with a 90 deg angle to the flow, and the pumping power requirement for the angled rib was about 20-50 percent lower than the transverse rib. Semi-empirical correlations for friction factor and heat-transfer coefficients were developed to account for rib spacing and rib angle. The correlations can be used in the design of turbine-blade cooling passages.

Han, J. C.↗

Exploratory Environmental Tests of Several Heat Shields

Exploratory tests have been conducted with several conceptual radiative heat shields of composite construction. Measured transient temperature distributions were obtained for a graphite heat shield without insulation and with three types of insulating materials, and for a metal multipost heat shield, at surface temperatures of approximately 2,000 F and 1,450 F, respectively, by use of a radiant-heat facility. The graphite configurations suffered loss of surface material under repeated irradiation. Temperature distribution calculated for the metal heat shield by a numerical procedure was in good agreement with measured data. Environmental survival tests of the graphite heat shield without insulation, an insulated multipost heat shield, and a stainless-steel-tile heat shield were made at temperatures of 2,000 F and dynamic pressures of approximately 6,000 lb/sq ft, provided by an ethylene-heated jet operating at a Mach number of 2.0 and sea-level conditions. The graphite heat shield survived the simulated aerodynamic heating and pressure loading. A problem area exists in the design and materials for heat-resistant fasteners between the graphite shield and the base structure. The insulated multipost heat shield was found to be superior to the stainless-steel-tile heat shield in retarding heat flow. Over-lapped face-plate joints and surface smoothness of the insulated multi- post heat shield were not adversely affected by the test environment. The graphite heat shield without insulation survived tests made in the acoustic environment of a large air jet. This acoustic environment is random in frequency and has an overall noise level of 160 decibels.

Goodman, George P.↗

Disorder-induced time effect in the antiferromagnetic domain state of Fe 1+ y Te

Herein we report on temperature-dependent soft X-ray absorption spectroscopy (XAS) measurements utilizing linearly polarized synchrotron radiation to probe magnetic phase transitions in iron-rich Fe 1+y Te (y ≈ 0.12). X-ray magnetic linear dichroism (XMLD) signals, which sense magnetic ordering processes at surfaces, start to increase monotonically below the Néel temperature T N = 57 K. This increase is due to a progressive bicollinear antiferromagnetic (AFM) alignment of Fe spins of the monoclinic Fe 1+y Te parent phase. This AFM alignment was achieved by a [1 0 0]-oriented biasing field favoring a single-domain state during cooling across T N . Our specific heat and magnetization measurements confirm the bulk character of this AFM phase transition. On longer time scales, however, we observe that the field-biased AFM state is highly unstable even at the lowest temperature of T = 3 K. After switching off the biasing field, the XMLD signal decays exponentially with a time constant τ = 1506 s. The initial XMLD signal is restored only upon repeating a cycle consisting of heating and field-cooling through T N . We explain the time effect by a gradual formation of a multi-domain state with 90° rotated AFM domains, promoted by structural disorder, facilitating the motion of twin-domains. Significant disorder in our Fe 1+y Te sample is evident from our X-ray diffraction and specific heat data. The stability of magnetic phases in Fe-chalcogenides is an important material property, since the Fe(Te 1-x Se x ) phase diagram shows magnetism intimately connected with superconductivity.

36 MATERIALS SCIENCE↗

Fluid flow and heat convection studies for actively cooled airframes

The work done during the progress report period from May-October 1992 is summarized. The effect of wall thermal boundary conditions on flows over a step or rib when repeated rib roughness is used for heating augmentation is examined. In numerical investigations of various such laminar and turbulent flows, the local heat transfer coefficients on a forward-facing step or on a rib were found to be very sensitive to the wall thermal boundary condition. For the computation of constant property laminar flow, the wall thermal boundary conditions were either a uniform heat flux or a uniform temperature. Results (Nusselt number and isotherms) of the studies are included. The second part of the work consisted of using PHOENICS to solve the conjugate heat transfer problem of flow over a rib in channel. Finally, the algebraic stress model in the TEAM (Turbulent Elliptic Algorithm-Manchester) code was tested for jet impingement flow, but there needs to be an addition of the energy equation to the code.

Mills, A. F.↗

Results of an Icing test on a NACA 0012 airfoil in the NASA Lewis Icing Research Tunnel

Tests were conducted in the Icing Research Tunnel (IRT) at the NASA Lewis Research Center to document the current capability of the IRT, focused mainly on the repeatability of the ice shape over a range of icing conditions. Measurements of drag increase due to the ice accretion were also made to document the repeatability of drag. Surface temperatures of the model were obtained to show the effects of latent-heat release by the freezing droplets and heat transfer through the ice layer. The repeatability of the ice shape was very good at low temperatures, but only fair at near freezing temperatures. In general, drag data shows good repeatability.

Shin, Jaiwon↗

Results of an icing test on a NACA 0012 airfoil in the NASA Lewis Icing Research Tunnel

Tests were conducted in the Icing Research Tunnel (IRT) at the NASA Lewis Research Center to document the current capability of the IRT, focused mainly on the repeatability of the ice shape over a range of icing conditions. Measurements of drag increase due to the ice accretion were also made to document the repeatability of drag. Surface temperatures of the model were obtained to show the effects of latent-heat release by the freezing droplets and heat transfer through the ice layer. The repeatability of the ice shape was very good at low temperatures, but only fair at near freezing temperatures. In general, drag data shows good repeatability.

Shin, Jaiwon↗

Constraining dark matter substructure with Gaia wide binaries

ABSTRACT We use a catalogue of stellar binaries with wide separations (up to 1 pc) identified by the Gaia satellite to constrain the presence of extended substructure within the Milky Way galaxy. Heating of the binaries through repeated encounters with substructure results in a characteristic distribution of binary separations, allowing constraints to be placed independent of the formation mechanism of wide binaries. Across a wide range of subhalo density profiles, we show that subhaloes with masses $\gtrsim 65\, \mathrm{ M}_\odot$ and characteristic length scales similar to the separation of these wide binaries cannot make up 100 per cent of the Galaxy’s dark matter. Constraints weaken for subhaloes with larger length scales and are dependent on their density profiles. For such large subhaloes, higher central densities lead to stronger constraints. Subhaloes with density profiles similar to those expected from cold dark matter must be at least ∼5000 times denser than predicted by simulation to be constrained by the wide binary catalogue.

Astronomy & Astrophysics↗

Robust Combined Heat and Hybrid Power (CHHP) for High Electrical Efficiency Cogeneration

Georgia Tech (Prime Recipient), the University of Texas at El Paso (UTEP) and the National Energy Technology Laboratory (NETL) investigated a hybrid fuel cell/ gas turbine system concept as a combined heat and hybrid power (CHHP) system for both robust and high power-to-process heat ratio cogeneration. The novelty of the proposed system entailed the distinct, elevated electrical efficiencies it maintains while simultaneously supporting a broad span of heating needs (e.g., supply temperatures) demanded across variable heat loads. The scope included: 1) leveraging a pioneering national lab facility configured for dynamic system operability development of hybrid fuel cell/gas turbine cycles; 2) enabling technology development to adjust and modulate the quality and quantity of thermal supply to bottoming heat loads via novel extreme temperature gas bypass valves. Hybrid fuel cell/gas turbine systems have primarily been reduced-to-practice in a constrained (e.g., initial proof-of-concept) manner and have still demonstrated considerable electrical efficiencies. However, these pre-pilot systems have focused upon electrical efficiencies and electrical power generation as the exclusive energy demand. Such hybrid systems had not been extensively researched or developed for flexible and variable operation consisting of both power and heat demands; however, these variable combined power and heat demands are characteristic of many types of manufacturers such as animal/poultry processing, bakeries and milk/flour/pastry manufacturing, textile mills, and electrochemical processing. Commercially, developing the system into a working combined heat and power system benefits these types of manufacturers by allowing them to meet their power and heat demands at a lower cost, higher efficiency, and/or through onsite generation. Therefore, the technical scope of this project was largely to study and facilitate these hybrid systems as combined heat and hybrid power (CHHP) systems that include dynamic operability for variable heat and power loads and/or grid dynamics for various types of manufacturers. Simulation results were used to predict the performance of the CHHP system and conceptually develop it to achieve desired dynamic operability. Experimentally, the primary goal was to design, manufacture, and experiment upon a high-temperature bypass valve. Experimental data included air mass flow rates through the valve orifice when the valve was changed to variable extent between fully closed and fully open. The experimental data was then used to create a semi-empirical computational model of the bypass valve. Concluded simulation goals for the research included developing computational heat exchanger models for the hybrid system inclusive of the bottoming heat exchanger and the recuperative heat exchanger, and then combining the computational recuperator model with the computational valve model. Afterwards, the computational models were then integrated to predict the dynamic operation of hybrid fuel cell/gas turbine cycles throughout a design space and reporting such. The scope stated in the preceding paragraph was packaged into five specific goals: 1) enabling the simulation of dynamic combined heat and power through the creation of computational, modular heat exchanger models; 2) simulation and exploration of the CHHP system’s performance by integrating the heat exchanger models with the national lab’s pre-existing hybrid system (computational) simulation, but without the recuperator bypass valve concept in order to initially determine how the (baseline) system behaves and can be controlled in order to meet variable heat and power demands; 3) development and initial deployment of the high-temperature recuperator bypass valve technology in order to confirm and characterize the approach; 4) usage of the experimental data for the valve to create a semi-empirical computational model for the bypass valve which could then be combined with the heat exchanger computational models; 5) repeat of the second task of simulating and exploring the system’s performance, but this time including the bypass valve to resolve its efficacy. Tasks were successfully completed, and the general notion of flexibly operating, high electrical efficiency CHHP was further corroborated. Supportive details are provided in the report.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Phase Change Material Heat Exchanger Life Test

Low Lunar Orbit (LLO) poses unique thermal challenges for the orbiting space craft, particularly regarding the performance of the radiators. The emitted infrared (IR) heat flux from the lunar surface varies drastically from the light side to the dark side of the moon. Due to the extremely high incident IR flux, especially at low beta angles, a radiator is oftentimes unable to reject the vehicle heat load throughout the entire lunar orbit. One solution to this problem is to implement Phase Change Material (PCM) Heat Exchangers. PCM Heat Exchangers act as a "thermal capacitor," storing thermal energy when the radiator is unable to reject the required heat load. The stored energy is then removed from the PCM heat exchanger when the environment is more benign. Because they do not use an expendable resource, such as the feed water used by sublimators and evaporators, PCM Heat Exchangers are ideal for long duration Low Lunar Orbit missions. The Advanced Thermal Control project at JSC is completing a PCM heat exchanger life test to determine whether further technology development is warranted. The life test is being conducted on four nPentadecane, carbon filament heat exchangers. Fluid loop performance, repeatability, and measurement of performance degradation over 2500 melt-freeze cycles will be performed and reported in the current document.

Lillibridge, Sean↗

High-Pressure Oxygen Generation for Outpost EVA

Low Lunar Orbit (LLO) poses unique thermal challenges for the orbiting space craft, particularly regarding the performance of the radiators. The emitted infrared (IR) heat flux from the lunar surface varies drastically from the light side to the dark side of the moon. Due to the extremely high incident IR flux, especially at low beta angles, a radiator is oftentimes unable to reject the vehicle heat load throughout the entire lunar orbit. One solution to this problem is to implement Phase Change Material (PCM) Heat Exchangers. PCM Heat Exchangers act as a "thermal capacitor, storing thermal energy when the radiator is unable to reject the required heat load. The stored energy is then removed from the PCM heat exchanger when the environment is more benign. Because they do not use an expendable resource, such as the feed water used by sublimators and evaporators, PCM Heat Exchangers are ideal for long duration Low Lunar Orbit missions. The Advanced Thermal Control project at JSC is completing a PCM heat exchanger life test to determine whether further technology development is warranted. The life test is being conducted on four nPentadecane, carbon filament heat exchangers. Fluid loop performance, repeatability, and measurement of performance degradation over 2500 meltfreeze cycles will be performed and reported in the current document.

Jeng, Frank↗

Phase Change Material Heat Exchanger Life Test

Low Lunar Orbit (LLO) poses unique thermal challenges for the orbiting space craft, particularly regarding the performance of the radiators. The IR environment of the space craft varies drastically from the light side to the dark side of the moon. The result is a situation where a radiator sized for the maximal heat load in the most adverse situation is subject to freezing on the dark side of the orbit. One solution to this problem is to implement Phase Change Material (PCM) Heat Exchangers. PCM Heat Exchangers act as a "thermal capacitor," storing thermal energy when there is too much being produced by the space craft to reject to space, and then feeding that energy back into the thermal loop when conditions are more favorable. Because they do not use an expendable resource, such as the feed water used by sublimators and evaporators, PCM Heat Exchangers are ideal for long duration LLO missions. In order to validate the performance of PCM Heat Exchangers, a life test is being conducted on four n-Pentadecane, carbon filament heat exchangers. Fluid loop performance, repeatability, and measurement of performance degradation over 2500 melt-freeze cycles will be performed.

Lillibridge, Sean↗

Milestone 5 test report. Task 5, subtask 5.2: Tile to foam strength tests

This report summarizes work that has been performed to date on the strength of a cryotank insulation system using Rohacell foam and TUFI-coated AETB-12 ceramic tiles directly bonded to a simulated graphite-epoxy tank wall. Testing utilized a custom specimen design which consists of a long tensile specimen with eccentric loading to induce curvature similar to the curvature expected due to 'pillowing' of the tank when pressurized. A finite element model was constructed to predict the specific element strains in the test article, and to assist with design of the test specimen to meet the specific goals of curvature and laminate strain. The results indicate that the heat treated 3.25-pcf density Rohacell foam does not provide sufficient strength for the induced stresses due to curvature and stress concentration at the RTV bondline to the TUFI tile. The test was repeated using higher density non-heat treated Rohacell foam (6.9 pcf) without foam failure. The finite element model was shown to predict specimen behavior, and validation of the model was successful. It is pertinent to mention that the analyses described herein accurately predicted the failure of the heat treated foams and based on this analysis method it is expected that the untreated 3.25 pcf Rohacell foam will be successful.

Greenberg, H. S.↗