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All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

The Apollo 16 Mare Component: Petrography, Geochemistry, and Provenance

The A16 (Apollo16) site in the lunar nearside highlands is 220 km from the nearest mare. Thus it is no surprise that mare basalt samples are uncommon at the site. Here, we present the petrography and geochemistry of 5 new mare basalt samples found at the A16 site. We also discuss possible provenances of all A16 mare basalt samples using high-resolution global data for the distribution of Fe and Ti on the lunar surface derived from Clementine UV-VIS data [1-2].

Zeigler, R. A.↗
NASA NTRS1997

Geochemistry of approximately 1.9 Ga sedimentary rocks from northeastern Labrador, Canada

Fifty-eight rock chips from fifteen samples of sedimentary rocks from the Ramah Group (approximately 1.9 Ga) in northeastern Labrador, Canada, were analyzed for major and minor elements, including C and S, to elucidate weathering processes on the Earth's surface about 1.9 Ga ago. The samples come from the Rowsell Harbour, Reddick Bight, and Nullataktok Formations. Two rock series, graywackes-gray shales of the Rowsell Harbour, Reddick Bight and Nullataktok Formations, and black shales of the Nullataktok Formation, are distinguishable on the basis of lithology, mineralogy, and major and trace element chemistry. The black shales show lower concentrations than the graywackes-gray shales in TiO2 (0.3-0.7 wt% vs. 0.7-1.8 wt%), Al2O3 (9.5-20.1 wt% vs. 13.0-25.0 wt%), and sigma Fe (<1 wt% vs. 3.8-13.9 wt% as FeO). Contents of Zr, Th, U, Nb, Ce, Y, Rb, Y, Co, and Ni are also lower in the black shales. The source rocks for the Ramah Group sediments were probably Archean gneisses with compositions similar to those in Labrador and western Greenland. The major element chemistry of source rocks for the Ramah Group sedimentary rocks was estimated from the Al2O3/TiO2 ratios of the sedimentary rocks and the relationship between the major element contents (e.g., SiO2 wt%) and Al2O3/TiO2 ratios of the Archean gneisses. This approach is justified, because the Al/Ti ratios of shales generally retain their source rock values; however, the Zr/Al, Zr/Ti, and Cr/Ni ratios fractionate during the transport of sediments. The measured SiO2 contents of shales in the Ramah Group are generally higher than the estimated SiO2 contents of source rocks by approximately 5 wt%. This correction may also have to be applied when estimating average crustal compositions from shales. Two provenances were recognized for the Ramah Group sediments. Provenance I was comprised mostly of rocks of bimodal compositions, one with SiO2 contents approximately 45 wt% and the other approximately 65 wt%, and was the source for most sedimentary rocks of the Ramah Group, except for black shales of the Nullataktok Formation. The black shales were apparently derived from Provenance II that was comprised mostly of felsic rocks with SiO2 contents approximately 65 wt%. Comparing the compositions of the Ramah Group sedimentary rocks and their source rocks, we have recognized that several major elements, especially Ca and Mg, were lost almost entirely from the source rocks during weathering and sedimentation. Sodium and potassium were also leached almost entirely during the weathering of the source rocks. However, significant amounts of Na were added to the black shales and K to all the rock types during diagenesis and/or regional metamorphism. The intensity of weathering of source rocks for the Ramah Group sediments was much higher than that of typical Phanerozoic sediments, possibly because of a higher PCO2 in the Proterozoic atmosphere. Compared to the source rock values, the Fe3+/Ti ratios of many of the graywackes and gray shales of the Ramah Group are higher, the Fe2+/Ti ratios are lower, and the sigma Fe/Ti ratios are the same. Such characteristics of the Fe geochemistry indicate that these sedimentary rocks are comprised of soils formed by weathering of source rocks under an oxygen-rich atmosphere. The atmosphere about 1.9 Ga was, therefore, oxygen rich. Typical black shales of Phanerozoic age exhibit positive correlations between the organic C contents and the concentrations of S, U, and Mo, because these elements are enriched in oxygenated seawater and are removed from seawater by organic matter in sediments. However, such correlations are not found in the Ramah Group sediments. Black shales of the Ramah Group contain 1.7-2.8 wt% organic C, but are extremely depleted in sigma Fe (<1 wt% as FeO), S (<0.3 wt%), U (approximately l ppm), Mo (<5 ppm), Ni (<2 ppm), and Co (approximately 0 ppm). This lack of correlation, however, does not imply that the approximately 1.9 Ga atmosphere-ocean system was anoxic. Depletion of these elements from the Ramah Group sediments may have occurred during diagenesis.

Non-NASA Center↗
NASA NTRS1992

The combined application of organic sulphur and isotope geochemistry to assess multiple sources of palaeobiochemicals with identical carbon skeletons

Five immature sediments from a Messinian evaporitic basin, representing one evaporitic cycle, were studied using molecular organic sulphur and isotope geochemistry. It is shown that a specific carbon skeleton which is present in different "modes of occurrence" ("free" hydrocarbon, alkylthiophene, alkylthiolane, alkyldithiane, alkylthiane, and sulphur-bound in macromolecules) may have different biosynthetic precursors which are possibly derived from different biota. It is demonstrated that the mode of occurrence and the carbon isotopic composition of a sedimentary lipid can be used to "reconstruct" its biochemical precursor. This novel approach of recognition of the suite of palaeobiochemicals present during the time of deposition allows for identification of the biological sources with an unprecedented specificity.

Non-NASA Center↗
NASA NTRS2005

Petrology, Geochemistry and Genesis of Ureilites

Ureilites are enigmatic achondrites that have some characteristics resulting from high temperature igneous processing, yet retain other characteristics inherited from the solar nebula. They are basalt-depleted ultramafic rocks containing 7-66 mg/g elemental C. They are rich in noble gases and display a correlation between mg# and Delta (17)O. This mishmash of properties has engendered various models for ureilite genesis, from those in which nebular processes dominate to those in which parent body igneous processes dominate. Characterization of new ureilites, especially of new subtypes, is an important part of attempts to unravel the history of the ureilite parent body or bodies. Here we report on the petrology and geochemistry of a suite of ureilites, mostly from Antarctica, and use these data to discuss ureilite petrogenesis. Additional information is included in the original extended abstract.

Mittlefehldt, D. W.↗
NASA NTRS2005

Applicability of Electrical and Electroanalytical Techniques to Detect Water and Characterize the Geochemistry of Undisturbed Planetary Soils

The search for life is a primary goal of NASA s planetary exploration program. The search is, of necessity, tiered in both the detection approach (looking for evidence of microbial fossils or the presence of water in the geological history of a planetary body and/or looking for evidence of water, energy sources, precursors to life, signatures of life and/or life itself in the present day planetary environment) and in the survey method (scale, range, specificity) employed. Terrestrial investigations suggests that life as we know it requires water. Thus, the search for extant microbial life and habitats requires identifying water-bearing soils. Determining Reduction-Oxidation (REDOX) couples present in water, once it is found, provides information on soil geochemistry and identifies potential chemical energy sources for life. Mars offers a near-term target for conducting this search. The identification of gully formation [1], layered deposits [2] and elemental ratios of bromine and chlorine [3] present indirect evidence that water was abundant locally in the Martian past. Additionally, Viking images of polar ice and frost formation on the surface of Mars demonstrate that water can exist in at least some near-surface regions of present-day Mars. Atmospheric pressure data further suggest that liquid water may be stable for short periods of time in the mid-latitudes of the Martian surface. [4] Measurements of the global distribution of hydrogen in the Martian regolith offer tantalizing indirect evidence that water may at least exist in near-surface soils. [5] Evidently, any water to be found is likely to exist as soil mixtures at levels ranging between approx.0.5% and approx.5 %.

Seshadri, S.↗
NASA NTRS2004

Microbial Paleontology, Mineralogy and Geochemistry of Modern and Ancient Thermal Spring Deposits and Their Recognition on the Early Earth and Mars"

The vision of this project was to improve our understanding of the processes by which microbiological information is captured and preserved in rapidly mineralizing sedimentary environments. Specifically, the research focused on the ways in which microbial mats and biofilms influence the sedimentology, geochemistry and paleontology of modem hydrothermal spring deposits in Yellowstone national Park and their ancient analogs. Toward that goal, we sought to understand how the preservation of fossil biosignatures is affected by 1) taphonomy- the natural degradation processes that affect an organism from the time of its death, until its discovery as a fossil and 2) diagenesis- longer-term, post-depositional processes, including cementation and matrix recrystallization, which collectively affect the mineral matrix that contains fossil biosignature information. Early objectives of this project included the development of observational frameworks (facies models) and methods (highly-integrated, interdisciplinary approaches) that could be used to explore for hydrothermal deposits in ancient terranes on Earth, and eventually on Mars.

Farmer, Jack D.↗
NASA NTRS2010

In Situ Instrumentation for Sub-Surface Planetary Geochemistry

Novel instrumentation is under development at NASA's Goddard Space Flight Center, building upon earth-based techniques for hostile environments, to infer geochemical processes important to formation and evolution of solid bodies in our Solar System. A prototype instrument, the Pulsed Neutron Generator Gamma Ray and Neutron Detectors (PNG-GRAND), has a 14 MeV pulsed neutron generator coupled with gamma ray and neutron detectors to measure quantitative elemental concentrations and bulk densities of a number of major, minor and trace elements at or below the surfaces with approximately a meter-sized spatial resolution down to depths of about 50 cm without the need to drill. PNG-GRAND's in situ a meter-scale measurements and adaptability to a variety of extreme space environments will complement orbital kilometer-scale and in-situ millimeter scale elemental and mineralogical measurements to provide a more complete picture of the geochemistry of planets, moons, asteroids and comets.

Bodnarik, J.↗
NASA NTRS2012

The Grand Geochemistry of 4 Vesta: First Results

On 12-Dec-2011, the Dawn spacecraft commenced low altitude mapping of the giant asteroid, 4 Vesta (264-km mean radius). Dawn's roughly circular, polar, low altitude mapping orbit (LAMO) has a mean radius of 470 km, placing the spacecraft within about 210 km of Vesta's surface. At these altitudes, Dawn s Gamma Ray and Neutron Detector (GRaND) is sensitive to Vesta's elemental com-position (Fig. 1). GRaND will acquire data in LAMO for up to 16 weeks, which is sufficient to map the elemental composition of the entire surface of Vesta. The timing of LAMO enables us to report the first results of our geochemistry investigation at this conference. In this abstract, we present an overview of our initial observations, based on data acquired at high altitude and during the first weeks of LAMO. GRaND overview. A detailed description of the GRaND instrument, science objectives and prospective results is given in [1]. At low altitudes, GRaND is sensitive to gamma rays and neutrons produced by cosmogenic nuclear reactions and radioactive decay occurring within the top few decimeters of the surface and on a spatial scale of a few hundred kilometers. From these nuclear emissions, the abundance of several major- and minor-elements, such as Fe, Mg, Si, K, and Th can be determined. Assuming the howardite, eucrite, and diogenite (HED) meteorites are representative of Vesta s crustal composition [2], then GRaND will be able to map the mixing ratios of whole-rock HED end-members, enabling the determination of the relative proportions of basaltic eucrite, cumulate eucrite, and diogenite as well as the proportions of mafic and plagioclase minerals [1,3]. GRaND will also search for compositions not well-represented in the meteorite collection, such as evolved, K-rich lithologies [4], and outcrops of olivine from Vesta s mantle or igneous intrusions in major impact basins [5]. The search for a possible mesosiderite source region is described in [6]. GRaND will globally map the abundance of H, providing constraints on the delivery of H by solar wind and the infall of carbonaceous chondrite materials.

Prettyman, T. H.↗
NASA NTRS2012

Time-Resolved Data Acquisition for In Situ Subsurface Planetary Geochemistry

The current gamma-ray/neutron instrumentation development effort at NASA Goddard Space Flight Center aims to extend the use of active pulsed neutron interrogation techniques to probe the subsurface geochemistry of planetary bodies in situ. All previous NASA planetary science missions, that used neutron and/or gamma-ray spectroscopy instruments, have relied on a constant neutron source produced from galactic cosmic rays. One of the distinguishing features of this effort is the inclusion of a high intensity 14.1 MeV pulsed neutron generator synchronized with a custom data acquisition system to time each event relative to the pulse. With usually only one opportunity to collect data, it is difficult to set a priori time-gating windows to obtain the best possible results. Acquiring time-tagged, event-by-event data from nuclear induced reactions provides raw data sets containing channel/energy, and event time for each gamma ray or neutron detected. The resulting data set can be plotted as a function of time or energy using optimized analysis windows after the data are acquired. Time windows can now be chosen to produce energy spectra that yield the most statistically significant and accurate elemental composition results that can be derived from the complete data set. The advantages of post-processing gamma-ray time-tagged event-by-event data in experimental tests using our prototype instrument will be demonstrated.

Bodnarik, Julia Gates↗
NASA NTRS2014

Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars

Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine-rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.

Research Support, U.S. Gov't, Non-P.H.S.↗
NASA NTRS2012

The Mojave Subsurface Bio-Geochemistry Explorer (MOSBE)

The MOSBE Team has developed a terrestrial field campaign to explore two subsurface biological habitats under the Mojave Desert. This field campaign will not only help us understand terrestrial desert biology, but also will develop methodologies and strategies for potential future Mars missions that would seek to explore the Martian subsurface. We have proposed to the ASTEP program to integrate a suite of field demonstrated instruments with a 20 m subsurface drill as a coherent unit, the Mojave Subsurface Bio-geochemistry Explorer. The ATK Space Modular Planetary Drill System (MPDS) requires no drilling fluid, which allows aseptic sampling, can penetrate lithic ground up to 20 meters of depth, and utilizes less than 100 Watts throughout the entire depth. The drill has been developed and demonstrated in field testing to a depth of 10 meters in Arizona, December 2002. In addition to caching a continuous core throughout the drilling depth, it also generates and caches cuttings and fines that are strata-graphically correlated with the core. As a core segment is brought to the surface, it will be analyzed for texture and structure by a color microscopic imager and for relevant chemistry and mineralogy with a UV fluorescence/Raman spectrometer. Organic and soluble ionic species will be identified through two instruments -- a microcapillary electrophoresis, and an ion trap mass spectrometer that have been developed under PIDDP, ASTID and MIDP funding.

robotic subsurface drilling↗
NASA NTRS2016

Petrography and Geochemistry of Lunar Meteorite Miller Range 13317

Miller Range (MIL) 13317 is a 32-g lunar meteorite collected during the 2013-2014 ANSMET (Antarctic Search for Meteorites) field season. It was initially described as having 25% black fusion crust covering a light- to dark-grey matrix, with numerous clasts ranging in size up to 1 cm; it was tenta-tively classified as a lunar anorthositic breccia. Here we present the petrography and geochemistry of MIL 13317, and examine possible pairing relationships with previously described lunar meteorites.

Zeigler, R. A.↗
NASA NTRS2019

Experimental Insights into the Geochemistry of Mercury

With the recent estimate of Mercury's surface composition from the X-Ray Spectrometer and Gamma-Ray Spectrometer that were onboard NASA's MErcury Surface, Space ENvironment, Geochemistry and Ranging (MESSENGER) spacecraft, we now have our first opportunity to directly investigate the compositions of lavas from the planet Mercury and indirectly investigate the chemical make-up of its interior. Results from MESSENGER showed exotic surface compositions with more than 3 wt% sulfur in some lavas and relatively low amounts of iron (less than 3 wt%) across the surface. These striking features are consistent with magmatism occurring under highly reducing conditions which has an impact on the thermal and chemical evolution of a planetary body. Here we'll explore the geochemical evolution of Mercury through a series of experimental studies and discuss the implications of low oxygen fugacity on elemental behavior and magmatic processes.

Vander Kaaden, Kathleen E.↗
NASA NTRS2019

The Geochemistry of Aubrites: Investigating Reduced Parent Bodies

The aubrites (~30 known meteorites) are a unique group of differentiated meteorites that formed on asteroids with oxygen fugacities (ƒO2) from ~2 to ~6 log units below the iron-wüstite buffer [1–2]. At these highly reduced conditions, elements deviate from the geochemical behavior exhibited at terrestrial ƒO2, forming FeO-poor silicates, Si-bearing metals, and exotic sulfides [3]. Here we examine the 3D mineralogy and the geochemistry of fourteen aubrites, including mineral major element compositions, bulk-rock compositions, and oxygen isotopic compositions to understand their formation and evolution at extreme ƒO2 conditions. While previous studies have described the petrology and 2D modal abundances of aubrites, this work investigates the 3D modal mineralogies of silicate, metal, and sulfide phases in aubrite samples, which are then com-pared to the available 2D data. We utilize X-ray computed tomography (XCT) to non-destructively analyze the distribution and abundances of mineral phases in aubrites and locate composite clasts of sulfide grains for future analysis.

Wilbur, Z. E.↗
NASA NTRSDate not supplied

Overview of the Bedrock Geochemistry and Mineralogy Observed By Supercam During Perseverance’S Delta Front Campaign

In February 2021, the Perseverance rover landed in Jezero crater, Mars. The crater floor was found to be composed of lava flows and cumulate rocks. These magmatic rocks appear to have undergone some limited aqueous alteration; however, it is not clear whether this alteration is related to the lacustrine phase of the crater. After completing its exploration of the crater floor, Perseverance reached the foot of the Jezero western fan in late April 2022 (sol ~422). Long-distance images acquired earlier in the mission had already confirmed the deltaic nature of the fan, which had long been suspected from orbital observations. Between April and December 2022, Perseverance investigated the basal layers of the delta at two locations named Hawksbill Gap and Cape Nukshak, which are ~400 m apart. Here, we present an overview of the geochemistry and mineralogy of the delta rocks as observed by SuperCam and show that these rocks record a diversity of past aqueous alteration environments.

E. Dehouck↗