Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “GaC”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Analytical Methods and Testbeds for Characterizing Adsorbents and Catalysts for Atmosphere Revitalization of Crewed Spacecraft

Spacecraft environmental control and life support systems (ECLSS) include a number of air revitalization (AR) technologies to provide breathable air and a comfortable living environment to the crew. Crew health and comfort is ensured by controlling human produced CO2 (1 kg person-1 day-1) and water vapor (~2 kg person-1 day-1), and by removing trace contaminants (TCs) from cabin air. These life support functions on-board the International Space Station (ISS) are carried out by the Carbon Dioxide Removal Assembly (CDRA), the Water Processor Assembly (WPA), and the trace contaminant control system (TCCS). During the development of the TCCS, new analytical and theoretical methods were developed in the 1970s for characterizing adsorption and desorption characteristics of activated carbons for the purpose of designing suitable AR technologies required for controlling airborne trace contaminants within spacecraft cabins during long exploration missions. The TCCS removes harmful volatile organic compounds and other trace contaminants from the circulating air. It consists of a granular activated carbon (GAC) bed for the removal of high molecular weight contaminants and ammonia followed by a heated catalytic bed for low molecular weight hydrocarbons. The high temperature catalytic oxidizer (HTCO) of the TCCS, which operates at 400°C and requires 120W average power, removes low molecular weight compounds such as carbon monoxide (CO), formaldehyde (CH2O), and methane (CH4), that pass through the GAC bed. The Air Revitalization Laboratory at the Kennedy Space Center (KSC) was established to develop new analytical methods for evaluating emerging ECLSS technologies for use in future AR architectures. General properties of adsorbents and catalysts are required for trace contaminant control system design calculations and vendor-supplied data are seldom available at relevant process conditions of interest to spacecraft cabin applications. To address this shortcoming, appropriate testbeds were developed to measure the desired properties of AR technologies being considered for use in ECLS architectures. Generally, the testbeds developed at KSC challenge the test media (activated carbon, impregnated activated carbon, catalysts, zeolites, solid amines, or pleated filters) with simulated spacecraft gas streams containing representative mixtures of trace contaminants (volatile organic compounds, ammonia, CO, CO2, or siloxanes) at the flow rates, temperatures, and relative humidity that will be encountered within manned spacecraft. Work performed at KSC funded by NASA’s Advanced Exploration (AES) Program has included: Identifying candidate sorbents to replace commercially obsolete impregnated carbons for NH3 control within the TCCS, characterizing their adsorptive capacities using simulated spacecraft gas streams, and ranking their appropriateness in various AR applications; evaluating novel low temperature catalysts for controlling CO and formaldehyde by traditional and photocatalytic methods for trace contaminant control; development of analytical methods to assess regenerable solid amine performance for CO2 control via pressure swing adsorption. The Air Revitalization lab was also funded to study trace contaminant control by other NASA programs. These include: screening of candidate sorbents for the design of new Charcoal HEPA Integrated Particle Scrubber (CHIPS) filters for removing siloxanes from cabin air; characterizing the performance of an impregnated activated carbon at low humidity for use in ORION ECLS; screening of sorbents for protecting the Sabatier 2.0 catalyst from DMSO2, siloxanes, NH3, and solid amine byproducts.

Monje, Oscar↗
NASA NTRSDate not supplied

PFAS Treatment Pilot Study using Granular Activated Carbon at Kennedy Space Center, Florida

Per- and polyfluoroalkyl substances (PFAS) have been found in investigative derived waste (IDW) generated from groundwater sampling and remediation activities conducted at Kennedy Space Center (KSC), Florida. PFAS are exceptionally strong compounds because of carbon-fluorine bonds resulting in resistance to degradation, low chemical reactivity, compound stability, and persistence in the environment. The regulatory status of PFAS is very dynamic. PFAS is not considered a hazardous waste and has no federal or state (Florida) cleanup requirements at this time. Due to the current and unknown future of the regulatory and treatment landscape, non-hazardous IDW, based upon site volatile organic compounds (VOCs) regulated under Title 40 of Federal Regulations part 261, containing PFAS is not being processed for off-site waste disposal under KSC’s Resource Conservation and Recovery Act permit as a proactive precaution. Long-term storage of aqueous IDW in the meantime was determined to be inadequate due to the potential for spills and/or leaks. A very limited number treatment methods are available at this time. To date, granular activated carbon (GAC) and ion exchange technologies have been found to be some of the most consistent treatment options for removing PFAS from aqueous media. Therefore, a pilot study using GAC was developed at KSC to determine the feasibility of treating non-hazardous IDW containing PFAS to reduce the total volume of PFAS waste and minimize the risk of leaks or spills while storing the waste until complete PFAS-destructive treatment options are more readily available. NASA wanted the pilot test to be able to demonstrate the ability to completely remove 18 PFAS compounds and the site VOCs to below the state of Florida groundwater cleanup target levels (GCTLs).

Michael J Deliz↗
NASA NTRS2024

Interim Measures Work Plan: South Repeater Building: Solid Waste Management Unit 121: Hydraulic Containment and Groundwater Treatment System for Per- and Polyfluoroalkyl Substances: Kennedy Space Center, Florida

This document presents the design details of a granular activated carbon (GAC) hydraulic containment and groundwater treatment system Interim Measures Work Plan for the South Repeater Building site (South Repeater, Solid Waste Management Unit 121), located at John F. Kennedy Space Center (KSC), Florida. The interim measures (IM) treatment area includes the source area and downgradient property boundary, which have been impacted by per- and polyfluoroalkyl substances (PFAS). The objectives of the IM are to treat the source area and mitigate PFAS migration to areas outside of KSC boundaries. This document was prepared by AECOM Technical Services, Inc., for the National Aeronautics and Space Administration under Contract 80KSC019D0010, Task Order 80KSC021F0096. The IM consists of the installation and operation of 19 extraction wells and an associated groundwater treatment system. A total of 13 wells will be installed to a depth of 34 feet below land surface (bls) to target the upper medium-grained sand with shell layer. A total of six wells will be installed to a depth of 56 feet bls to target the lower layer of poorly graded sand with shell fragments. The system will be designed to operate each extraction well simultaneously using submersible pumps at flow rates of 5 or 10 gallons per minute (gpm), excluding one extraction well with a flow rate of 30 gpm. The extracted groundwater will be conveyed to a groundwater treatment system, where it will be treated via GAC prior to disposal via infiltration. To evaluate treatment system performance, baseline groundwater sampling will be conducted prior to treatment system startup. Performance monitoring will be completed quarterly for the first year. A total of eight performance monitoring wells will be installed to a depth of 12 feet bls, and eight performance monitoring wells will be installed to a depth of 30 feet bls. In addition to the installation of 16 performance monitoring wells, 12 existing monitoring wells will be incorporated into the performance monitoring program.

groundwater treatment↗
DOE OSTI2026

Model-based economic analysis under uncertainty for PFAS treatment by granular activated carbon and ion exchange technologies

Recent drinking water regulations have imposed the need for per- and polyfluoroalkyl substances (PFAS) remediation. In response, treatment facilities may be required to retrofit existing treatment schemes to treat PFAS below maximum contaminant levels (MCLs). Adsorption technologies such as granular activated carbon (GAC) and ion exchange (IX) have been demonstrated to be effective; however, there are limited techno-economic metrics available which provide guidance on technology selection and design for diverse PFAS-containing source water conditions. Process systems engineering (PSE) tools which can traditionally perform these analyses are hindered by the data availability, model validity, and understanding of treatment phenomena for emerging contaminants. This work employs published data regressions, statistical models, process models, techno-economic analyses, and other process systems tools in a model-based uncertainty framework to consider the limitations of emerging contaminant research. Through this analysis framework, economic results are provided as probabilistic distributions based on the uncertainty of the models and diverse conditions that treatment facilities experience.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Adaptive laboratory evolution and genetic engineering improved terephthalate utilization in Pseudomonas putida KT2440

Poly(ethylene terephthalate) (PET) is one of the most ubiquitous plastics and can be depolymerized through biological and chemo-catalytic routes to its constituent monomers, terephthalic acid (TPA) and ethylene glycol (EG). TPA and EG can be re-synthesized into PET for closed-loop recycling or microbially converted into higher-value products for open-loop recycling. Here, in this study, we expand on our previous efforts engineering and applying Pseudomonas putida KT2440 for PET conversion by employing adaptive laboratory evolution (ALE) to improve TPA catabolism. Three P. putida strains with varying degrees of metabolic engineering for EG catabolism underwent an automation-enabled ALE campaign on TPA, a TPA and EG mixture, and glucose as a control. ALE increased the growth rate on TPA and TPA-EG mixtures by 4.1- and 3.5-fold, respectively, in approximately 350 generations. Evolved isolates were collected at the midpoints and endpoints of 39 independent ALE experiments, and growth rates were increased by 0.15 and 0.20 h -1 on TPA and a TPA-EG, respectively, in the best performing isolates. Whole-genome re-sequencing identified multiple converged mutations, including loss-of-function mutations to global regulators gacS, gacA, and turA along with large duplication and intergenic deletion events that impacted the heterologously-expressed tphAB II catabolic genes. Reverse engineering of these targets confirmed causality, and a strain with all three regulators deleted and second copies of tphAB II and tpaK displayed improved TPA utilization compared to the base strain. Taken together, an iterative strain engineering process involving heterologous pathway engineering, ALE, whole genome sequencing, and genome editing identified five genetic interventions that improve P. putida growth on TPA, aimed at developing enhanced whole-cell biocatalysts for PET upcycling.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Generation of ionic liquid tolerant Pseudomonas putida KT2440 strains via adaptive laboratory evolution

Although the use of ionic liquids (ILs) for the pretreatment of lignocellulosic biomass has been limited due to high costs, recent efforts to develop low-cost protic ILs show promise for achieving cost-effectiveness for biorefineries. However, an additional challenge remains in that ILs present in biomass hydrolysates are toxic to most microbial hosts, resulting in poor growth phenotypes. To address this issue, we applied an adaptive laboratory evolution (ALE) approach for tolerizing Pseudomonas putida KT2440, an industrially relevant bacterial host, to two low-cost ILs (triethanolammonium acetate [TEOH][OAc] and triethylammonium hydrogen sulfate [TEA][HS]). After continuous cultivations with gradually increased IL levels, we obtained evolved strains showing significant improvements in their growth performance under high concentrations of the ILs (maximum 4% [TEOH][OAc] and 8% [TEA][HS], in w/v) at which the wild-type strain cannot grow. Sequencing of evolved strains revealed multiple regions where mutations were associated with improved performance in minimal media conditions (relA, gacS, oprB/PP_1446, fleQ, tktA, and uvrY/PP_4100) and in IL-specific conditions (PP_5350, PP_4929/emrE, oprD, and PP_5324). We further validated the causality of the PP_5350 and emrE genes for improved IL tolerance via reverse engineering and transcriptomic analysis. Here, a common mutation in the PP_5350 gene, encoding a RpiR family transcriptional regulator, was shown to significantly upregulate the glyoxylate cycle for efficient acetate catabolism. In addition, it was suggested that the emrE gene encodes an efflux pump which can export [TEA][HS]. Finally, the cultivation of two of the best performing evolved strains with IL-treated biomass hydrolysates demonstrated their considerable potential to be used as platform strains. Taken as a whole, this work provides strains for utilization of IL-treated biomass and a mechanistic understanding that could be further leveraged to develop efficient microbial bioprocesses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Towards a mechanistic understanding of the sol–gel syntheses of ternary carbides

Sol–gel chemistry, while being extremely established, is to this day not fully understood, and much of the underlying chemistry and mechanisms are yet to be unraveled. Here, in this work, we elaborate on the sol–gel chemistry of Cr 2 GaC, the first layered ternary carbide belonging to the MAX phase family to ever be synthesized using this wet chemical approach. Leveraging a variety of both in- and ex situ characterization techniques, including X-ray and neutron powder diffraction, X-ray absorption fine structure analyses, total scattering analyses, and differential scanning calorimetry coupled with mass spectrometry, in-depth analyses of the local structures and reaction pathways are elucidated. While the metals first form tetrahedrally and octahedrally coordinated oxidic structures, that subsequently grow and crystallize into oxides, the carbon source citric acid sits on a separate reaction pathway, that does not merge with the metals until the very end. In fact, after decomposing it remains nanostructured and disordered graphite until the temperature allows for the reduction of the metal oxides into the layered carbide. Based on this, we hypothesize that the method is mostly applicable to systems where the needed metals are reducible by graphite around the formation temperature of the target phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Development and Characterization of Cementitious Waste Forms for Immobilization of Granular Activated Carbon, Silver Mordenite, and HEPA Filter Media Solid Secondary Waste

At the Department of Energy’s Hanford site, over 53 million gallons of chemically complex and radioactive wastes have been stored in 177 underground tanks. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is under construction and is designed to treat and immobilize these wastes. During operations of WTP, solid secondary wastes (SSWs) will be generated as a result of waste treatment, vitrification, off-gas management, and supporting process activities. SSW treatment processes and resulting disposal pathways for the final disposition form of the SSW are needed to support direct feed low activity waste (DFLAW) operations and facilitate continued operation of WTP. The SSWs produced through WTP operations are expected to include used process equipment, contaminated tools and instruments, decontamination wastes, high-efficiency particulate air (HEPA) filters, carbon absorption beds (granular activated carbon, GAC), silver mordenite (AgM) and spent ion-exchange resins. These waste streams are planned to be immobilized in a cementitious waste form and disposed of either as stabilized/blended (non-debris) or encapsulated (debris) in a cementitious waste form. Accordingly, cementitious waste forms from these streams were included in the 2017 Integrated Disposal Facility (IDF) Performance Assessment (PA). The input data used to represent these SSW forms in the 2017 IDF PA involved many assumptions and associated uncertainties. This data limitation was due to the lack of material- and site-specific data available for representative SSW materials in cementitious matrices. To verify the assumed values used in the IDF PA and fill this limitation in available data, Washington River Protection Solutions, LLC (WRPS), has initiated a program targeted toward gathering site specific data relevant to Hanford SSW disposal. The work within this report is a continuation of this ongoing program.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Development of Engineered Metal-Organic Framework (MOF) materials for perfluorooctane sulfonate (PFOS) Remediation

In this project, an engineered form of a Metal-Organic Framework (MOF) based material is developed for the removal of perfluorooctane sulfonate (PFOS) for real-world applications. The powdered MOF material has been demonstrated at the Pacific Northwest National Laboratory (PNNL) to selectively capture PFOS from distilled (DI) water with a large performance advantage over granulated activated carbon (GAC). In this project, the powdered material was transformed into an engineered form (using a polymer) to demonstrate PFOS adsorption capacity in tap water. PNNL developed and processed the MOF material in the engineering form (granules). After thorough characterization and stability testing, these engineered MOF granules were provided to an industrial collaborator, AVANTech, LLC, for testing and demonstration of continuous, long-term PFOS removal from tap water. The preliminary results showed PFOS sorption capacities at parts per billion (ppb) concentrations in tap water under a flow system. Also provided insight into sorbent-based material utilization in a continuous flow system. Further studies are required to optimize and understand sorption in such industrial-scale applications.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Study to assess the importance of errors introduced by applying NOAA 6 and NOAA 7 AVHRR data as an estimator of vegetative vigor: Feasibility study of data normalization

The use of NOAA AVHRR data to map and monitor vegetation types and conditions in near real-time can be enhanced by using a portion of each GAC image that is larger than the central 25% now considered. Enlargement of the cloud free image data set can permit development of a series of algorithms for correcting imagery for ground reflectance and for atmospheric scattering anisotropy within certain accuracy limits. Empirical correction algorithms used to normalize digital radiance or VIN data must contain factors for growth stage and for instrument spectral response. While it is not possible to correct for random fluctuations in target radiance, it is possible to estimate the necessary radiance difference between targets in order to provide target discrimination and quantification within predetermined limits of accuracy. A major difficulty lies in the lack of documentation of preprocessing algorithms used on AVHRR digital data.

Duggin, M. J.↗
NASA NTRS1984

Twin tilt nacelle V/STOL aircraft

This paper describes the second government-conducted, piloted flight simulation of the Grumman Design 698 V/STOL (vertical and short takeoff and landing) aircraft. Emphasis is on the aircraft's handling qualities as rated by various NASA, Navy, and GAC pilots with flight experience ranging from CTOL (conventional take-off and landing) to V/STOL aircraft. The Design 698 had been modified to resolve the flight problems that were of most concern to the pilots in the first investigation (Phase I). Those problems included an adverse nonminimum phase (NMP) acceleration response in both the longitudinal and lateral axes, a large thrust-response lag, and adverse ground effects. The adverse NMP acceleration is an attribute of the vertical vanes (a Grumman patent) positioned in the fan exhaust flow. The primary modifications included using the vertical-vane deflection as a thrust spoiling method, the addition of the cross-shafted propulsion system, and the implementation of two velocity and attitude control modes (standard and precision) for speeds below 50 knots.

Eskey, M. A.↗
NASA NTRS1986

Investigation of scene identification algorithms for radiation budget measurements

The computation of Earth radiation budget from satellite measurements requires the identification of the scene in order to select spectral factors and bidirectional models. A scene identification procedure is developed for AVHRR SW and LW data by using two radiative transfer models. These AVHRR GAC pixels are then attached to corresponding ERBE pixels and the results are sorted into scene identification probability matrices. These scene intercomparisons show that there generally is a higher tendency for underestimation of cloudiness over ocean at high cloud amounts, e.g., mostly cloudy instead of overcast, partly cloudy instead of mostly cloudy, for the ERBE relative to the AVHRR results. Reasons for this are explained. Preliminary estimates of the errors of exitances due to scene misidentification demonstrates the high dependency on the probability matrices. While the longwave error can generally be neglected the shortwave deviations have reached maximum values of more than 12% of the respective exitances.

Diekmann, F. J.↗
NASA NTRS1989

Investigation of scene identification algorithms for radiation budget measurements

The computation of earth radiation budget from satellite measurements requires the identification of the scene in order to select spectral factors and bidirectional models. A scene identification procedure is developed for AVHRR SW and LW data by using two radiative transfer models. These AVHRR GAC pixels are then attached to corresponding ERBE pixels and the results are sorted into scene identification probability matrices. These scene intercomparisons show that there generally is a higher tendency for underestimation of cloudiness over ocean at high cloud amounts, e.g., mostly cloudy instead of overcast, partly cloudy instead of mostly cloudy, for the ERBE relative to the AVHRR results. Reasons for this are explained. Preliminary estimates of the errors of exitances due to scene misidentification demonstrates the high dependency on the probability matrices. While the longwave error can generally be neglected the shortwave deviations have reached maximum values of more than 12 percent of the respective exitances.

Diekmann, F. J.↗
NASA NTRS1989

AVHRR for monitoring global tropical deforestation

Advanced Very High Resolution Radiometer (AVHRR) data have been used to assess the dynamics of forest trnsformations in three parts of the tropical belt. A large portion of the Amazon Basin has been systematically covered by Local Area Coverage (LAC) data in the 1985-1987 period. The analysis of the vegetation index and thermal data led to the identification and measurement of large areas of active deforestation. The Kalimantan/Borneo forest fires were monitored and their impact was evaluated using the Global Area Coverage (GAC) 4 km resolution data. Finally, High Resolution Picture Transmission (HRPT) data have provided preliminary information on current activities taking place at the boundary between the savanna and the forest in the Southern part of West Africa. The AVHRR approach is found to be a highly valuable means for carrying out deforestation assessments in regional and global perspectives.

Malingreau, J. P.↗
NASA NTRS1990

The analysis of polar clouds from AVHRR satellite data using pattern recognition techniques

The cloud cover in a set of summertime and wintertime AVHRR data from the Arctic and Antarctic regions was analyzed using a pattern recognition algorithm. The data were collected by the NOAA-7 satellite on 6 to 13 Jan. and 1 to 7 Jul. 1984 between 60 deg and 90 deg north and south latitude in 5 spectral channels, at the Global Area Coverage (GAC) resolution of approximately 4 km. This data embodied a Polar Cloud Pilot Data Set which was analyzed by a number of research groups as part of a polar cloud algorithm intercomparison study. This study was intended to determine whether the additional information contained in the AVHRR channels (beyond the standard visible and infrared bands on geostationary satellites) could be effectively utilized in cloud algorithms to resolve some of the cloud detection problems caused by low visible and thermal contrasts in the polar regions. The analysis described makes use of a pattern recognition algorithm which estimates the surface and cloud classification, cloud fraction, and surface and cloudy visible (channel 1) albedo and infrared (channel 4) brightness temperatures on a 2.5 x 2.5 deg latitude-longitude grid. In each grid box several spectral and textural features were computed from the calibrated pixel values in the multispectral imagery, then used to classify the region into one of eighteen surface and/or cloud types using the maximum likelihood decision rule. A slightly different version of the algorithm was used for each season and hemisphere because of differences in categories and because of the lack of visible imagery during winter. The classification of the scene is used to specify the optimal AVHRR channel for separating clear and cloudy pixels using a hybrid histogram-spatial coherence method. This method estimates values for cloud fraction, clear and cloudy albedos and brightness temperatures in each grid box. The choice of a class-dependent AVHRR channel allows for better separation of clear and cloudy pixels than does a global choice of a visible and/or infrared threshold. The classification also prevents erroneous estimates of large fractional cloudiness in areas of cloudfree snow and sea ice. The hybrid histogram-spatial coherence technique and the advantages of first classifying a scene in the polar regions are detailed. The complete Polar Cloud Pilot Data Set was analyzed and the results are presented and discussed.

Smith, William L.↗
NASA NTRS1992

Purification system

A system for prolonging the life of a granulated activated charcoal (GAC) water treatment device is disclosed in which an ultraviolet light transparent material is used to constrain water to flow over carbon surfaces. It is configured to receive maximum flux from a UV radiation source for the purpose of preventing microbial proliferation on the carbon surfaces; oxidizing organic contaminants adsorbed from the water onto the carbon surfaces and from biodegradation of adsorbed microbial forms; disinfecting water; and oxidizing organic contaminants in the water.

Flanagan, David T.↗
NASA NTRS1992

A comprehensive comparison between satellite-measured skin and multichannel sea surface temperature

Three algorithms for computing sea-surface temperature (SST) from AVHRR channel-4 and -5 brightness temperatures were compared using 1-week blocks of global-area-coverage (GAC) data archived at NCAR. These are the multichannel SST (MCSST), the cross-product SST (CPSST), and the AVHRR-only satellite-measured ocean-surface skin temperature (SMSST). Maps of each SST product were produced and were compared for various time periods. The difference between the algorithms range from +1.6 to -1.2 K, resulting from the different forms of both the algorithms and the ground truth from which the algorithms were derived. It is concluded that, for the study of relative SST patterns, any of the algorithms can be used. However, for applications requiring accurate absolute temperature measurements, the differences are significant and the derivation of the algorithm must be considered when an algorithm is selected.

Wick, Gary A.↗