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Volatiles working group

The physical behavior of water and carbon dioxide on Mars was studied. Topics discussed include: physics of polar frosts, CO2 budget, atmospheric minor constituents, chemical and physical properties of surface materials, layered deposits, and the role of volatiles in the Martian landscape formation.

Cutts, J. A.↗

Asymptotic behavior of solutions of the renormalization group K-epsilon turbulence model

Presently, the only efficient way to calculate turbulent flows in complex geometries of engineering interest is to use Reynolds-average Navier-Stokes (RANS) equations. As compared to the original Navier-Stokes problem, these RANS equations posses much more complicated nonlinear structure and may exhibit far more complex nonlinear behavior. In certain cases, the asymptotic behavior of such models can be studied analytically which, aside from being an interesting fundamental problem, is important for better understanding of the internal structure of the models as well as to improve their performances. The renormalization group (RNG) K-epsilon turbulence model, derived directly from the incompresible Navier-Stokes equations, is analyzed. It has already been used to calculate a variety of turbulent and transitional flows in complex geometries. For large values of the RNG viscosity parameter, the model may exhibit singular behavior. In the form of the RNG K-epsilon model that avoids the use of explicit wall functions, a = 1, so the RNG viscosity parameter must be smaller than 23.62 to avoid singularities.

Yakhot, A.↗

Human Behavior and Performance Support for ISS Operations and Astronaut Selections: NASA Operational Psychology for Six-Crew Operations

The Behavioral Health and Performance group at NASA Johnson Space Center provides psychological support services and behavioral health monitoring for ISS astronauts and their families. The ISS began as an austere outpost with minimal comforts of home and minimal communication capabilities with family, friends, and colleagues outside of the Mission Control Center. Since 1998, the work of international partners involved in the Space Flight Human Behavior and Performance Working Group has prepared high-level requirements for behavioral monitoring and support. The "buffet" of services from which crewmembers can choose has increased substantially. Through the process of development, implementation, reviewing effectiveness and modifying as needed, the NASA and Wyle team have proven successful in managing the psychological health and well being of the crews and families with which they work. Increasing the crew size from three to six brought additional challenges. For the first time, all partners had to collaborate at the planning and implementation level, and the U.S. served as mentor to extrapolate their experiences to the others. Parity in available resources, upmass, and stowage had to be worked out. Steady progress was made in improving off-hours living and making provisions for new technologies within a system that has difficulty moving quickly on certifications. In some respect, the BHP support team fell victim to its previous successes. With increasing numbers of crewmembers in training, requests to engage our services spiraled upward. With finite people and funds, a cap had to placed on many services to ensure that parity could be maintained. The evolution of NASA BHP services as the ISS progressed from three- to six-crew composition will be reviewed, and future challenges that may be encountered as the ISS matures in its assembly-complete state will be discussed.

VanderArk, Steve↗

Interdiffusion behavior of tungsten or rhenium and group 5 and 6 elements and alloys of the periodic table, part 1

Arc cast W, CVD W, CVD Re, and powder metallurgy Re materials were hot isostatically pressure welded to ten different refractory metals and alloys (Cb, Cb-1Zr, Ta, Ta-10W, T-111, ASTAR-811C, W-25Re, Mo-50Re, W-30Re-20Mo, ect.) and thermally aged at 10 to the minus 8th power torr at 1200, 1500, 1630, 1800, and 2000 C for 100 to 2000 hours. Electron beam microprobe analysis was used to characterize the interdiffusion zone width of each couple system as a function of age time and temperature. Extrapolations of interdiffusion zone thickness to 10,000 hours were made. Classic interdiffusion analysis was performed for several of the systems by Boltzmann-Matano analysis. A method of inhibiting Kirkendall voids from forming during thermal ageing of dissimilar metal junctions was devised and experimentally demonstrated. An electron beam weld study of Cb-1Zr to Re and W-25Re demonstrated the limited acceptability of these welds.

Arcella, F. G.↗

Interdiffusion behavior of tungsten or rhenium and group 5 and 6 elements and alloys of the periodic table. Part 2A: Appendices A-G

Arc cast W, CVD, W, CVD Re, and powder metallurgy Re materials were hot isostatically pressure welded to ten different refractory metals and alloys and thermally aged at 10 to the minus 8th power torr at 1200 C, 1500 C, 1630 C, 1800 C, and 2000 C for 100 hours to 2000 hours. Electron beam microprobe analysis was used to characterize the interdiffusion zone width of each couple system as a function of age time and temperature. Each system was least squares fitted to the equation: In (delta X sq/t) = B/T + A, where delta X is net interdiffusion zone width, t is age time, and T is age temperature. Detailed descriptions of experimental and analytical procedures utilized in conducting the experimental program are provided. For Vol. 1, see N74-34046.

Arcella, F. G.↗

Behavioral and biological interactions with small groups in confined microsocieties

Requirements for high levels of human performance in the unfamiliar and stressful environments associated with space missions necessitate the development of research-based technological procedures for maximizing the probability of effective functioning at all levels of personnel participation. Where the successful accomplishment of such missions requires the coordinated contributions of several individuals collectively identified with the achievement of a common objective, the conditions for characterizing a team, crew, or functional group are operationally defined. For the most part, studies of group performances under operational conditions which emphasize relatively long exposure to extended mission environments have been limited by the constraints imposed on experimental manipulations to identify critical effectiveness factors. On the other hand, laboratory studies involving relatively brief exposures to contrived task situations have been considered of questionable generality to operational settings requiring realistic group objectives.

Brady, J. V.↗

Effect of Environmental Enrichment on Singly- and Group-Housed Squirrel Monkeys

Nonhuman primates display an interest in novel places, habituate to new situations, and spend most of their daily activity in the wild in large groups engaging in feeding behaviors. Captivity changes these behaviors, and disrupts normal social hierarchies. In captivity, animals may exhibit stereotypical behaviors which are thought to indicate decreased psychological well-being (PWB). If an animal's behaviors can be made to approach those seen in the wild, and stereotypical behaviors are minimal it is assumed that PWB is adequate. Environmental enrichment (EE) devices have been used to address the Animal Welfare Act's requirement that the PWB of captive nonhuman primates be considered. The purpose of the present study was to examine whether various EE devices improve the PWB of captive squirrel monkeys. The present study used behavioral observation to quantify the effectiveness of several EE devices in reducing stereotypical behaviors in squirrel monkeys housed singly or in groups. Results showed that the EE devices used did not affect the expression of normal or stereotypical behaviors, but that the type of housing did.

Spring, Sarah E.↗

Fireball end heights - A diagnostic for the structure of meteoric material

An earlier analysis of Prairie Network fireball trajectory data failed to discriminate between the varieties of meteoric materials that are thought to be present. The Lost City meteorite event offers another calibration of the fireball data and prompts a reanalysis intended to distinguish between ordinary chondritic meteorites and the more fragile early-type carbonaceous chondrites. The carbonaceous material is expected to ablate more readily and have shorter trajectories or higher end heights. Observational error and natural dispersion in the structures produce severe smoothing effects, and the end-height diagnostic is, in itself, not entirely convincing. However, after making a tentative division of the data, one can discern differences in orbits and beginning heights among the three end-height groups. These are consistent with expectations of the behavior of chondritic stones (group I), weak carbonaceous chondrites (group II), and still more fragile cometary material (group III). It is concluded that if the carbonaceous material occurs in reasonable abundance among the fireballs, it has been properly identified by this analysis.

Ceplecha, Z.↗

Using Fuzzy Clustering for Real-time Space Flight Safety

To ensure space flight safety, it is necessary to monitor myriad sensor readings on the ground and in flight. Since a space shuttle has many sensors, monitoring data and drawing conclusions from information contained within the data in real time is challenging. The nature of the information can be critical to the success of the mission and safety of the crew and therefore, must be processed with minimal data-processing time. Data analysis algorithms could be used to synthesize sensor readings and compare data associated with normal operation with the data obtained that contain fault patterns to draw conclusions. Detecting abnormal operation during early stages in the transition from safe to unsafe operation requires a large amount of historical data that can be categorized into different classes (non-risk, risk). Even though the 40 years of shuttle flight program has accumulated volumes of historical data, these data don t comprehensively represent all possible fault patterns since fault patterns are usually unknown before the fault occurs. This paper presents a method that uses a similarity measure between fuzzy clusters to detect possible faults in real time. A clustering technique based on a fuzzy equivalence relation is used to characterize temporal data. Data collected during an initial time period are separated into clusters. These clusters are characterized by their centroids. Clusters formed during subsequent time periods are either merged with an existing cluster or added to the cluster list. The resulting list of cluster centroids, called a cluster group, characterizes the behavior of a particular set of temporal data. The degree to which new clusters formed in a subsequent time period are similar to the cluster group is characterized by a similarity measure, q. This method is applied to downlink data from Columbia flights. The results show that this technique can detect an unexpected fault that has not been present in the training data set.

Lee, Charles↗

Deformation modeling and constitutive modeling for anisotropic superalloys

A study of deformation mechanisms in the single crystal superalloy PWA 1480 was conducted. Monotonic and cyclic tests were conducted from 20 to 1093 C. Both (001) and near-(123) crystals were tested, at strain rates of 0.5 and 50 percent/minute. The deformation behavior could be grouped into two temperature regimes: low temperatures, below 760 C; and high temperatures, above 820 to 950 C depending on the strain rate. At low temperatures, the mechanical behavior was very anisotropic. An orientation dependent CRSS, a tension-compression asymmetry, and anisotropic strain hardening were all observed. The material was deformed by planar octahedral slip. The anisotropic properties were correlated with the ease of cube cross-slip, as well as the number of active slip systems. At high temperatures, the material was isotropic, and deformed by homogeneous gamma by-pass. It was found that the temperature dependence of the formation of superlattice-intrinsic stacking faults was responsible for the local minimum in the CRSS of this alloy at 400 C. It was proposed that the cube cross-slip process must be reversible. This was used to explain the reversible tension-compression asymmetry, and was used to study models of cross-slip. As a result, the cross-slip model proposed by Paidar, Pope and Vitek was found to be consistent with the proposed slip reversibility. The results were related to anisotropic viscoplastic constitutive models. The model proposed by Walter and Jordan was found to be capable of modeling all aspects of the material anisotropy. Temperature and strain rate boundaries for the model were proposed, and guidelines for numerical experiments were proposed.

Milligan, Walter W.↗

Anomalous phase separation behavior of gel-derived soda-silica glasses

The effects of retained bound hydroxyl groups on amorphous immiscibility behavior and on the kinetics of phase separation were studied in glasses containing from 10 to 19 percent sodium oxide preparaed by the gel process. Differences in behavior as functions of preliminary thermal treatment of the gel precursor and of melting conditions were studied, employing IR spectroscopy, SAXS and WAXD to monitor the variation in glass microstructure. Both the initial gel treatment and the OH concentration in the prepared glasses were found to affect the immiscibility temperatures, and the magnitude of the maximum temperature increase was also a function of the sodium oxide concentration. It is suggested that the variation in thermodynamic behavior may be caused by the structural arrangement attained by the OH groups during the gel condensation process, which in turn affects the extent of hydrogen bonding to nonbridging oxygen ions.

Neilson, G. F.↗

A renormalization group model for the stick-slip behavior of faults

A fault which is treated as an array of asperities with a prescribed statistical distribution of strengths is described. For a linear array the stress is transferred to a single adjacent asperity and for a two dimensional array to three ajacent asperities. It is shown that the solutions bifurcate at a critical applied stress. At stresses less than the critical stress virtually no asperities fail on a large scale and the fault is locked. At the critical stress the solution bifurcates and asperity failure cascades away from the nucleus of failure. It is found that the stick slip behavior of most faults can be attributed to the distribution of asperities on the fault. The observation of stick slip behavior on faults rather than stable sliding, why the observed level of seismicity on a locked fault is very small, and why the stress on a fault is less than that predicted by a standard value of the coefficient of friction are outlined.

Smalley, R. F., Jr.↗

A renormalization group approach to the stick-slip behavior of faults

A fault which is treated as an array of asperities with a perscribed statistical distribution of strengths is described. For a linear array the stress is transferred to a single adjacent asperity and for a two dimensional array to three adjacent asperities. It is shown that the solutions bifurcate at a critical applied stress. At stresses less than the critical stress virtually no asperities fail on a large scale and the fault is locked. At the critical stress the solution bifurcates and asperity failure cascades away from the nucleus of failure. It is found that the stick slip behavior of most faults can be attributed to the distribution of asperities on the fault. The observation of stick slip behavior on faults rather than stable sliding, why the observed level of seismicity on a locked fault is very small, and why the stress on a fault is less than that predicted by a standard value of the coefficient of friction are outlined.

Smalley, R. F., Jr.↗

Psychological Support Operations and the ISS One-Year Mission

Since NASA began human presence on the International Space Station (ISS) in November 1998, crews have spent two to seven months onboard. In March 2015 NASA and Russia embarked on a new era of ISS utilization, with two of their crewmembers conducting a one-year mission onboard ISS. The mission has been useful for both research and mission operations to better understand the human, technological, mission management and staffing challenges that may be faced on missions beyond Low Earth Orbit. The work completed during the first 42 ISS missions provided the basis for the pre-flight, in-flight and post-flight work completed by NASA's Space Medicine Operations Division, while our Russian colleagues provided valuable insights from their long-duration mission experiences with missions lasting 10-14 months, which predated the ISS era. Space Medicine's Behavioral Health and Performance Group (BHP) provided pre-flight training, evaluation, and preparation as well as in-flight psychological support for the NASA crewmember. While the BHP team collaboratively planned for this mission with the help of all ISS international partners within the Human Behavior and Performance Working Group to leverage their collective expertise, the US and Russian BHP personnel were responsible for their respective crewmembers. The presentation will summarize the lessons and experience gained within the areas identified by this Working Group as being of primary importance for a one-year mission.

Beven, G.↗

Highly functional microspheres facilitating Diels–Alder network formation

Introducing particles to dynamic covalent networks is a common approach to improve their performance. However, network formation can be impacted by their size and functionality. The influence can be predicted by common theories for small molecular precursors, but it is unclear whether they are applicable to precursors bearing numerous reactive groups and micrometer-scale dimensions. In this work, an experimental study was undertaken using dynamic covalent networks formed by the Diels–Alder reaction between furan and maleimide groups. The gelation behavior of the Diels–Alder networks was studied using rheometry to track their network formation at 40 °C with varying maleimide-functionalized microsphere loading. The highly functional microspheres can interact with the furan precursor, aiding in the formation of the Diels–Alder networks. A 5 wt% microsphere sample can reduce the gelation time by 23% and facilitate network formation in an unbalanced stoichiometry near the critical composition to form a percolating network.

36 MATERIALS SCIENCE↗

Development and Evaluation of Elastomeric Materials for Geothermal Applications

A material was formulated having about 250-350 psi tensile strength and 30-80 percent elongation at 260 C for at least 24 hours in simulated brine. The relationship between these laboratory test results and sealing performance in actual or simulated test conditions is not entirely clear; however, it is believed that no conventional formation or casing packer design is likely to perform well using these materials. The synthetic effort focused on high temperature block copolymers and development of curable polystyrene. Procedures were worked out for synthesizing these new materials. Initial results with heat-cured unfilled polystyrene 'gum' at 260 C indicate a tensile strength of about 50 psi. Cast films of the first sample of polyphenyl quinoxaline-polystyrene block copolymer, which has 'graft-block' structure consisting of a polystyrene chain with pendant polyphenyl quinoxaline groups, show elastomeric behavior in the required temperature range. Its tensile strength and elongation at 260 C were 220-350 psi and 18-36 percent, respectively. All of these materials also showed satisfactory hydrolytic stability.

Mueller, W. A.↗